Atomistic insights into early stage corrosion of bcc Fe surfaces in oxygen dissolved liquid lead-bismuth eutectic(LBE-O)

Classical molecular dynamics simulations with global neural network machine learning potential are used to study early stage oxidation and dissolution behaviors of bcc Fe surfaces contacting with stagnant oxygen dissolved liquid leadbismuth eutectic(LBE-O).Both static and dynamic simulation results indicate that the early stage oxidation and dissolution behaviors of bcc Fe show strong orientation dependence under the liquid LBE environments,which may explain the experimental observations of uneven interface between iron-based materials and liquid LBE.Our investigations show that it is the delicate balance between the oxide growth and metal dissolution that leads to the observed corrosion anisotropy for bcc Fe contacting with liquid LBE-O.

Effect of silicon on ductility of T91 steel in liquid lead-bismuth eutectic environment

The tensile tests of T91 and T91Si steels at 200-450℃in air and at 350℃in oxygen-depleted liquid lead-bismuth eutectic(LBE)environment with strain rate of 1×10^(-5)-5×10^(-3)were performed.Results show that the activation energy of T91 steel is 103.45-246.76 kJ/mol and that of T91Si steel is 146.98-172.11 kJ/mol when Portevin-Le Chatelie(PLC)phenomenon occurs.The elongation reduction of T91 steel at 350℃is not specific to LBE environment,whereas the presence of LBE promotes crack initiation and propagation and affects the elongation of the material in the necking stage.With Si addition,the elongation,especially the uniform elongation at 350℃in LBE environment,improves,and the tendency toward crack propagation in T91 steel after slow tensile necking is reduced.The PLC phenomenon can be seen in both T91 and T91Si steels at high temperatures owing to the dynamic strain aging(DSA).The temperature ranges are different when DSA occurs,with 300-350℃and 250-350℃for T91 and T91Si steels,respectively.

Effect of Heat Flux Distribution on Entropy Generation and Irreversibility of Lead-Bismuth Eutectic(LBE)Forced Convective Heat Transfer

Investigations on entropy generation and thermal irreversibility analysis are conducted for liquid lead-bismuth eutectic(LBE)in an annular pipe.To find better performance in convective heat transfer,the computational fluid dynamics(CFD)code based on the finite volume method(FVM)is adopted to solve this problem.The elevated temperature LBE flows in the annular pipe,and four types of heat flux,including constant,linear increase and decrease,and parabolic distributions are imposed at the inside wall of the annular pipe.The investigations are conducted for the specific average heat input of 200 kW/m^(2),and the different Peclet number Pe is set from 1200 to 3200.The SST k-ωturbulent model and Cheng-Tak Prt model are adopted.The mesh independence validation and models verification are also conducted and the maximum Nu error is 5.43%compared with previous experimental correlations.The results from the local and system scales,respectively,including volumetric dimensionless entropy generation,Ns,Be,and Ep,are discussed.The results indicate that the viscous friction and heat transfer caused by entropy generation can be found in the viscous sub-layer and buffer layer respectively.Heat transfer is the primary factor that leads to irreversible losses.Besides,the results show that the best thermodynamic performance occurs under parabolic distributed heat flux in the research scope.

液态铅铋合金与钢铁交互作用的微尺度仿真研究进展

液态铅铋合金(LLBE)是加速器驱动次临界系统和反应堆冷却剂的候选材料,其与钢铁材料接触会造成材料腐蚀。理清LLBE与钢铁材料交互作用的机理对揭示LLBE中钢铁材料腐蚀机制具有重要作用。目前,微尺度仿真技术已大量用于研究LLBE与钢铁交互作用的微观机理及规律。系统介绍了微尺度仿真技术在LLBE环境中钢铁材料的腐蚀与防护以及腐蚀产物污染研究中的应用,探讨了LLBE与钢铁材料交互作用微观仿真研究的发展方向。