In this paper, a kinetics model for the liquid-phase oxidation of 2-methyl-6-acetyl-naphthalene to 2,6-naphthalene dicarboxylic acid catalyzed by cobalt-manganese-bromide is proposed. The effects of the reaction tempe...In this paper, a kinetics model for the liquid-phase oxidation of 2-methyl-6-acetyl-naphthalene to 2,6-naphthalene dicarboxylic acid catalyzed by cobalt-manganese-bromide is proposed. The effects of the reaction temperature, catalyst concentration and ratio of catalyst on the lime evolution of the experimental concentration for the constituents including raw material, intermediates and product are investigated. The model parameters are determined in a nonlinear optimization, minimizing the difference between the simulated and experimental time evolution of the product composition obtained in a semi-batch oxidation reactor where the gas and liquid phase were well nuxed. The kinetics data demonstrate that the model is suitable to the liquid-phase oxidation of 2-methyl-6-acetyl-naphthalene to 2,6-naphthalene dicarboxylic acid.展开更多
For the goal of sulfur recovery, most methods are aimed at the tail gas with high-concentration H2S, but few effective methods are used for low-concentration H2S. In this work, Low-concentration H2S could be purified ...For the goal of sulfur recovery, most methods are aimed at the tail gas with high-concentration H2S, but few effective methods are used for low-concentration H2S. In this work, Low-concentration H2S could be purified well by liquid phase catalytic oxidation (LCO), and the sulfur resource could also be recovered. The absorption solution was prepared by FeCl3 and sulfosalicylic acid. Under the experimental conditions, the conversion of H2S to S could be maintained above 94% at 60 ℃. In order to enhance the economical efficiency of LCO method, the absorption solution was modified by doping Ce, and a series of experiments were designed to investigate its performance. The results showed that the conversion of H2S had no obvious improvement, but above 98% conversion could be gained at 60 ℃, and the H2S conversion rate was enhanced. The optimum addition quality of Ce(NO3)3 was 0.08 g to 50 ml Fe3+ solution.展开更多
Hydrogen sulfide in rural biogas was removed with liquid-phase catalytic oxidation.By using rare earth as catalyst,and sulfosalicylic acid as stabilizer,H2S purification efficiency could increase as high as 96%,and su...Hydrogen sulfide in rural biogas was removed with liquid-phase catalytic oxidation.By using rare earth as catalyst,and sulfosalicylic acid as stabilizer,H2S purification efficiency could increase as high as 96%,and sulfur capacity of the composite solution was about 3 g/L.The results show that purification efficiency was affected by catalyst addition,pH,experimental temperature,and sulfur capacity.The parameters effects on catalytic oxidation were studied,and the optimized conditions were that Fe3+ concentration 0.08 mg/L,reaction temperature 70°C,pH 9.0,with a absorption solution volume of 50 mL,a gas flow rate 200 mL/min,and H2S mass concentration of 1.58-2.02 mg/m3.展开更多
文摘In this paper, a kinetics model for the liquid-phase oxidation of 2-methyl-6-acetyl-naphthalene to 2,6-naphthalene dicarboxylic acid catalyzed by cobalt-manganese-bromide is proposed. The effects of the reaction temperature, catalyst concentration and ratio of catalyst on the lime evolution of the experimental concentration for the constituents including raw material, intermediates and product are investigated. The model parameters are determined in a nonlinear optimization, minimizing the difference between the simulated and experimental time evolution of the product composition obtained in a semi-batch oxidation reactor where the gas and liquid phase were well nuxed. The kinetics data demonstrate that the model is suitable to the liquid-phase oxidation of 2-methyl-6-acetyl-naphthalene to 2,6-naphthalene dicarboxylic acid.
基金the Natural Science Foundation of Yunnan Province (2001E0011Q)the Science Foundation of The Education Department of Yunnan Province (0142111 and 07Z11402)
文摘For the goal of sulfur recovery, most methods are aimed at the tail gas with high-concentration H2S, but few effective methods are used for low-concentration H2S. In this work, Low-concentration H2S could be purified well by liquid phase catalytic oxidation (LCO), and the sulfur resource could also be recovered. The absorption solution was prepared by FeCl3 and sulfosalicylic acid. Under the experimental conditions, the conversion of H2S to S could be maintained above 94% at 60 ℃. In order to enhance the economical efficiency of LCO method, the absorption solution was modified by doping Ce, and a series of experiments were designed to investigate its performance. The results showed that the conversion of H2S had no obvious improvement, but above 98% conversion could be gained at 60 ℃, and the H2S conversion rate was enhanced. The optimum addition quality of Ce(NO3)3 was 0.08 g to 50 ml Fe3+ solution.
基金Project(2008ZX07105-002) supported by the Erhai Lake Project of National Science and Technology Major Project in the 11th Five years Plan of China
文摘Hydrogen sulfide in rural biogas was removed with liquid-phase catalytic oxidation.By using rare earth as catalyst,and sulfosalicylic acid as stabilizer,H2S purification efficiency could increase as high as 96%,and sulfur capacity of the composite solution was about 3 g/L.The results show that purification efficiency was affected by catalyst addition,pH,experimental temperature,and sulfur capacity.The parameters effects on catalytic oxidation were studied,and the optimized conditions were that Fe3+ concentration 0.08 mg/L,reaction temperature 70°C,pH 9.0,with a absorption solution volume of 50 mL,a gas flow rate 200 mL/min,and H2S mass concentration of 1.58-2.02 mg/m3.
