This study explores the molding processes by using the Multi-component-injection molding (MCM) method, in which monolithic products are molded by attaching mixed liquid-silicone-rubbers (LSRs) to polybutylene terephth...This study explores the molding processes by using the Multi-component-injection molding (MCM) method, in which monolithic products are molded by attaching mixed liquid-silicone-rubbers (LSRs) to polybutylene terephthalate (PBT) that has the characteristic of self-binding while burning due to Pt catalysts. It is seen that this method increases the binding force between LSR and PBT. The surfaces coated with Polytetrafluoroethylene (PTFE), Cr, Ni, etc. have excellent peeling with plastic and such surfaces are compared with those treated with hot forging die and micro blasting without coating. When peeling tests are performed at the specified polymerization temperature and molding time after LSR molding on these surfaces of hot working die molds without coating, these surfaces show excellent peeling of molds and LSR products. In particular, they show better peeling after micro blasting than surfaces with Cr and Ni coating as well as surfaces without coating, and the peeling strength also decreases. The results of contact angle and XPS analysis indicate that the LSR binding force is enhanced as an effect of catalysts, though it is not found by SEM. According to the XPS analysis, the structures of the surfaces are close to methyl and vinyl materials that are produced while LSR molding.展开更多
宁夏福祥变220 k V电流互感器因绝缘外套严重电蚀损缺陷而退运。福祥变地区气候干燥,降雨少,雾日少,互感器外套的电蚀损现象无法用常规污闪理论模型解释。从污秽分析、材料分析、电磁场计算3个方面,对互感器复合外套电蚀损缺陷进行了分...宁夏福祥变220 k V电流互感器因绝缘外套严重电蚀损缺陷而退运。福祥变地区气候干燥,降雨少,雾日少,互感器外套的电蚀损现象无法用常规污闪理论模型解释。从污秽分析、材料分析、电磁场计算3个方面,对互感器复合外套电蚀损缺陷进行了分析,并且在实验室中模拟出了材料表面放电及蚀损现象,验证了原因分析的结论:福祥变地区积污严重,污秽中含可导电颗粒;互感器绝缘外套硅橡胶材料憎水性良好,主要元素含量未发生明显变化;互感器护套低压端伞裙设计存在缺陷,低压端法兰与护套伞裙直接相连导致连接处液体硅橡胶材料运行场强过高诱发放电。特殊污秽条件以及伞裙设计缺陷是互感器外套缺陷的主要原因。展开更多
文摘This study explores the molding processes by using the Multi-component-injection molding (MCM) method, in which monolithic products are molded by attaching mixed liquid-silicone-rubbers (LSRs) to polybutylene terephthalate (PBT) that has the characteristic of self-binding while burning due to Pt catalysts. It is seen that this method increases the binding force between LSR and PBT. The surfaces coated with Polytetrafluoroethylene (PTFE), Cr, Ni, etc. have excellent peeling with plastic and such surfaces are compared with those treated with hot forging die and micro blasting without coating. When peeling tests are performed at the specified polymerization temperature and molding time after LSR molding on these surfaces of hot working die molds without coating, these surfaces show excellent peeling of molds and LSR products. In particular, they show better peeling after micro blasting than surfaces with Cr and Ni coating as well as surfaces without coating, and the peeling strength also decreases. The results of contact angle and XPS analysis indicate that the LSR binding force is enhanced as an effect of catalysts, though it is not found by SEM. According to the XPS analysis, the structures of the surfaces are close to methyl and vinyl materials that are produced while LSR molding.
文摘宁夏福祥变220 k V电流互感器因绝缘外套严重电蚀损缺陷而退运。福祥变地区气候干燥,降雨少,雾日少,互感器外套的电蚀损现象无法用常规污闪理论模型解释。从污秽分析、材料分析、电磁场计算3个方面,对互感器复合外套电蚀损缺陷进行了分析,并且在实验室中模拟出了材料表面放电及蚀损现象,验证了原因分析的结论:福祥变地区积污严重,污秽中含可导电颗粒;互感器绝缘外套硅橡胶材料憎水性良好,主要元素含量未发生明显变化;互感器护套低压端伞裙设计存在缺陷,低压端法兰与护套伞裙直接相连导致连接处液体硅橡胶材料运行场强过高诱发放电。特殊污秽条件以及伞裙设计缺陷是互感器外套缺陷的主要原因。
