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Study on a Novel Disphase Supplying Supported Liquid Membrane for Transport Behavior of Divalent Nickel Ions
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作者 裴亮 王理明 +1 位作者 郭维 赵楠 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第4期633-640,共8页
A novel d!sphase supplying supported liquid membrane (DSSLM), containing supplying feed phase andsupplying stripping phase tor transport behavior ot NI(Ⅱ), have been studied. The supplying supported feed phase in... A novel d!sphase supplying supported liquid membrane (DSSLM), containing supplying feed phase andsupplying stripping phase tor transport behavior ot NI(Ⅱ), have been studied. The supplying supported feed phase included feed solution and di(2-ethyhexyl) phosphoric acid (HDEHP) as the carrier in kerosene, and supplying stripping phase included HDEHP as the cartier in kerosene and HC1 as the stripping agent. The effects of volume ratio of membrane solution to feed solution (O/F), pH, initial concentration of Ni(Ⅱ) and ionic strength in the feedsolution, volume ratio of membrane solution to stripping solution (O/S), concentration of H2SO4 solution, HDEHP concentration in the supplying stripping phase on transport of Ni(/I), the advantages of DSSLM compared to the traditional supported liquid membrane (SLM), the system stability, the reuse of membrane solution and the reten- tion of membrane phase were studied. Experimental results indicated that the optimum transpgrt of Ni(Ⅱ) was oh-tained when H2SO4 concentration was 2.00 mol'L-', HDEHP concentration was 0.120 mol·L-1, and O/S was 4· 1 in the supplying stripping phase, O/F was 1 : 10 and pH was 5.20 in the supplying feed phase. The ionic strength in supplying feed phase had no obvious effect on transport of Ni(Ⅱ). When initial Ni(Ⅱ) concentration was 2.00x 10-4 mol/L, the transport percentage of Ni(Ⅱ) was up to 93.1% in 250 min. The kinetic equation was deduced in terms of the law of mass diffusion and the interface chemistry. 展开更多
关键词 disphase supplying supported liquid membrane organic phosphonic acid supplying feed phase sup-plying stripping phase nickel ion
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A Review on the Precise Control of the Liquid Nitrogen Supplying System in Transonic Cryogenic Wind Tunnel
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作者 ZHANG Wei GAO Rong +3 位作者 CHENG Jun CHEN Wanhua SONG Yuanjia LIAO Daxiong 《Journal of Thermal Science》 SCIE EI CAS CSCD 2023年第2期692-707,共16页
The liquid nitrogen(LN2)supplying system,one of the four key systems of the cryogenic wind tunnel(CWT),is an essential guarantee for the precise control,fast and safe regulation of the wind tunnel’s total temperature... The liquid nitrogen(LN2)supplying system,one of the four key systems of the cryogenic wind tunnel(CWT),is an essential guarantee for the precise control,fast and safe regulation of the wind tunnel’s total temperature.Firstly,the technical schemes,advantages and disadvantages of different LN2 supplying systems are discussed and analyzed based on the operation conditions and test requirements of different CWTs.Then,together with the development of the pilot cryogenic transonic wind tunnel(PCTW),the key technologies of the system,including the supplying mode,rapid and accurate regulation of injection pressure,development of large scale cryogenic centrifugal pump,and matching technology between pumps and pipe network,have been summarized and the solutions to the existing issues are given.Finally,a supplying process suitable for large-scale CWT is proposed,which has the ability of independent commissioning,rapid regulation,accurate control of injection pressure and transient response to the wind tunnel’s wide range of working conditions.The breakthrough in LN2 supplying system enables China to construct a CWT for the future competitive high Reynolds number aircraft. 展开更多
关键词 cryogenic wind tunnel liquid nitrogen supplying system working principle injection pressure dynamic simulation
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