The liquid state undercoolability and crystal growth kinetics of ternary Ni-5%Cu-5%Sn and Ni-10%Cu-10%Sn alloys are investigated by the glass fluxing method. In these two alloys, experimental maximum undercoolings of ...The liquid state undercoolability and crystal growth kinetics of ternary Ni-5%Cu-5%Sn and Ni-10%Cu-10%Sn alloys are investigated by the glass fluxing method. In these two alloys, experimental maximum undercoolings of 304 K （0.18TL ） and 286K （0.17TL ） are achieved and the dendritic growth velocities attain 39.8 and 25.1 m/s, respectively. The transition of morphology from coarse dendrite into equiaxed structure occurs and the grain size of the a （Ni） phase decreases remarkably when the undercooling increases. Both the lattice constant and microhardness increase obviously with the enhancement of undercooling. The enrichment of Cu and Sn solute contents reduces the dendritic growth velocity, while enhances the lattice constant and microhardness of a （Ni） phase.展开更多
The heat capacities (C_p) ofglassy and crystalline Fe_(40)Ni_(40)B_(20) alloy have been measured by means ofdifferential scanning calorimeter(DSC). A larger C_p value at the glass transition temperature (T_g) can be o...The heat capacities (C_p) ofglassy and crystalline Fe_(40)Ni_(40)B_(20) alloy have been measured by means ofdifferential scanning calorimeter(DSC). A larger C_p value at the glass transition temperature (T_g) can be obtained. The reproducible C_p values ofrelaxed glass at certain heating rate are lower than that ofas quenched glass below 500 K, and are much higher at T_g than that of the crystal. The heating rate affects C_p values of the glass. At last, C_p val ues ofthe undercooled liquid are estimated.展开更多
The density of liquid Incone1718 alloy was experimentally measured by electrostatic levitation technique, where the maximum undercooling of 100 K was realized for the commercial sample. The measured density of liquid ...The density of liquid Incone1718 alloy was experimentally measured by electrostatic levitation technique, where the maximum undercooling of 100 K was realized for the commercial sample. The measured density of liquid lnconel 718 alloy is 7.39 g cm^-3 at the liquidus temperature of 1663 K which was confirmed by DSC experiment, with the linear temperature coefficient of -6.89 × 10^-4 gcm^-3 K^-1. Correspondingly, four ternary Ni-Cr-Fe compositions were designed to simulate the density of liquid lnconel 718 alloy with 16000 atoms, from which the liquid structure is revealed by pair distribution function, The predicted result shows a remarkable enhancement with the decrease of temperature at the first neighbor distance.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 51327901 and 51301138the Specialized Research Fund for the Doctoral Program of Higher Education under Grant No 20126102120064+1 种基金the Aviation Science Foundation of China under Grant No 2014ZF53069the Fundamental Research Funds for the Central Universities under Grant No3102014KYJD044
文摘The liquid state undercoolability and crystal growth kinetics of ternary Ni-5%Cu-5%Sn and Ni-10%Cu-10%Sn alloys are investigated by the glass fluxing method. In these two alloys, experimental maximum undercoolings of 304 K （0.18TL ） and 286K （0.17TL ） are achieved and the dendritic growth velocities attain 39.8 and 25.1 m/s, respectively. The transition of morphology from coarse dendrite into equiaxed structure occurs and the grain size of the a （Ni） phase decreases remarkably when the undercooling increases. Both the lattice constant and microhardness increase obviously with the enhancement of undercooling. The enrichment of Cu and Sn solute contents reduces the dendritic growth velocity, while enhances the lattice constant and microhardness of a （Ni） phase.
文摘The heat capacities (C_p) ofglassy and crystalline Fe_(40)Ni_(40)B_(20) alloy have been measured by means ofdifferential scanning calorimeter(DSC). A larger C_p value at the glass transition temperature (T_g) can be obtained. The reproducible C_p values ofrelaxed glass at certain heating rate are lower than that ofas quenched glass below 500 K, and are much higher at T_g than that of the crystal. The heating rate affects C_p values of the glass. At last, C_p val ues ofthe undercooled liquid are estimated.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 51327901, 51474175, 51522102 and 51734008)
文摘The density of liquid Incone1718 alloy was experimentally measured by electrostatic levitation technique, where the maximum undercooling of 100 K was realized for the commercial sample. The measured density of liquid lnconel 718 alloy is 7.39 g cm^-3 at the liquidus temperature of 1663 K which was confirmed by DSC experiment, with the linear temperature coefficient of -6.89 × 10^-4 gcm^-3 K^-1. Correspondingly, four ternary Ni-Cr-Fe compositions were designed to simulate the density of liquid lnconel 718 alloy with 16000 atoms, from which the liquid structure is revealed by pair distribution function, The predicted result shows a remarkable enhancement with the decrease of temperature at the first neighbor distance.
