Development of Slippery Liquid-Infused Porous Surface on AZ31 Mg Alloys for Corrosion Protection

The relatively poor corrosion resistance remarkably limits the wide applications of Mg alloys in practice,although they possess many attractive properties,like low density,high specific strength,and good biocompatibility.The formation of a protective coating can effectively suppress the corrosion.In this work,a slippery liquid-infused porous surface(SLIPS),with good surface hydrophobicity,stability,and self-healing property,was formed on AZ31 Mg alloys.The development of SLIPS requires suitable porous micro/nanostructures.Layered double hydroxide(LDH),with effective corrosion resistance for Mg alloys,was a good candidate to accommodate the liquid lubricant.Especially,different temperatures were applied to in situ form MgAl-LDH on AZ31 Mg alloys.The results showed that the temperature of 120℃was the best condition for the SLIPS to provide good corrosion protection for Mg alloys,with the lowest corrosion current density of 3.19×10^(-9)A cm^(−2).In addition,the SLIPS performed well in the long-term immersion test and abrasion test.The AZ31 Mg alloys with superior corrosion resistance and good mechanical and chemical stability can be extensively applied in areas of automotive,electronics,and aerospace.

Fabrications and Applications of Slippery Liquid-infused Porous Surfaces Inspired from Nature: A Review

The slippery liquid-infused porous surfaces inspired by the microstructure of carnivorous nepenthes have aroused widespread attention,which show stable liquid repellency,glorious self-repairing powers and effective anti-fouling properties.The surfaces are manufactured via the infusion of lubricant oil into porous structures,a process which allows other fluids to slide off the interfaces readily.However,the practical applications of slippery liquid-infused surfaces are limited to the complicated preparation processes and poor oil lock ability.We aim to,in this review,present the fundamental theories of the slippery liquid-infused porous surface.Some typical natural examples are clarified while representative fabricating methods such as liquid flame spray,layer-by-layer assembly,lithography and so on are listed.The slippery surface can facilitate the manufacture of transparent and multi-functional slippery materials by means of straightforward procedures.The slippery liquid-infused porous surfaces were applied in hot water repellency,anti-fouling,ice-phobic,water condensation,control of underwater bubble transport and drag reduction.This article discusses all these issues along with emerging applications as well as future challenges.

Research Progress on Corrosion Resistance of Magnesium Alloys with Bio-inspired Water-repellent Properties:A Review

Thanks to its excellent mechanical properties,magnesium alloys have many potential applications in the aerospace and other fields.However,failure to adequately solve corrosion problems of magnesium alloy becomes one of the factors restricting its wide use in many industrial fields.Inspired by nature,researchers designed and fabricated bio-inspired water-repellent(superhydrophobic and slippery liquid-infused porous surface)surfaces with special wetting properties by exploring the surface microstructures of plants and animals such as lotus leaf and nepenthes pitcher,exhibiting excellent corrosion-resistant performance.This article summarizes the research progress on corrosion resistance of magnesium alloys with bio-inspired water-repellent properties in recent years.It mainly introduces the corrosion reasons,types of corrosion of magnesium alloys,and the preparation of magnesium alloys with bio-inspired water-repellent properties to improve corrosion resistance.In particular,it is widely used and effective to construct water-repellent and anti-corrosion coating on the surface of magnesium alloy by surface treatment.It is hoped that the research in this review can broaden the application range of magnesium alloys and provide a powerful reference for the future research on corrosion resistance of magnesium alloys.

Lubricant self-replenishing slippery surface with prolonged service life for fog harvesting

Slippery lubricant-infused surfaces exhibit excellent fog-harvesting capacities compared with superhydrophobic and superhydrophilic surfaces.However,lubricant depletion is typically unavoidable under dynamic conditions,and reinfused oil is generally needed to recover the fog-harvesting capacity.Herein,an effective strategy for delaying the depletion of lubricant to prolong the service life of fog harvesting is proposed.An ultrathin transparent lubricant self-replenishing slippery surface was fabricated via facile one-step solvent evaporation polymerization.The gel film of the lubricant self-replenishing slippery surface,which was embedded with oil microdroplets,was attached to glass slides via the phase separation and evaporation of tetrahydrofuran.The gel film GFs-150(with oil content 150 wt%of aminopropyl-terminated polydimethyl siloxane(PDMS–NH2))exhibited superior slippery and fog-harvesting performance to other gel films.Furthermore,the slippery surfaces with the trait of oil secretion triggered by mechanical stress exhibited better fog-harvesting capabilities and longer service life than surfaces without the function of lubricant self-replenishment.The lubricant self-replenishing,ultrathin,and transparent slippery surfaces reported herein have considerable potential for applications involving narrow spaces,visualization,long service life,etc.