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Solid Reference Electrode of Metallurgical Oxygen Sensor 被引量:2
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作者 LOU Tian-jun KONG Xiang-hua +1 位作者 HUANG Ke-qin LIU Qing-guo 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2006年第5期18-20,46,共4页
The thermal equilibrium state of the reference electrode was investigated. The results show that the temperature difference between the inside and the outside of zirconia tube was very small and the Seebeck effect can... The thermal equilibrium state of the reference electrode was investigated. The results show that the temperature difference between the inside and the outside of zirconia tube was very small and the Seebeck effect can be ignored after the sensor was dipped into liquid steel for more than 2 s. A special sensor was designed to test the relation between the EMF (electromotive force) of sensor and the thermal equilibrium state of the reference elec- trode. Based on these results, it is suggested that the peak in EMF curve was caused by the change of oxygen potential in reference electrode before the thermal equilibrium was reached. If NiO was added by 2 M- 5 M to the Cr/Cr2O3 reference electrode, the peak in EMF curve could be eliminated. 展开更多
关键词 ZRO2 solid electrolyte oxygen sensor reference electrode
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Preparation and Properties of Embeddable Ag/Ag Cl Gelling Reference Electrode for Rebars Corrosion Monitoring in Concrete 被引量:1
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作者 汤雁冰 王胜年 +1 位作者 陈龙 范志宏 《China Ocean Engineering》 SCIE EI CSCD 2015年第6期925-932,共8页
Reference electrodes are a key part for corrosion monitoring and measurement of rebars in concrete. A reference electrode that can be buried in concrete is fabricated by using Ag/Ag Cl electrode and methyl cellulose g... Reference electrodes are a key part for corrosion monitoring and measurement of rebars in concrete. A reference electrode that can be buried in concrete is fabricated by using Ag/Ag Cl electrode and methyl cellulose gelling electrolyte. The stability, repeatability and anti-polarization of the reference electrode are investigated; the influences of the inner electrolyte loss, exterior OH- contamination, and temperature on the potential of the reference electrode are also investigated in this paper. The results show that the reference electrode has good stability, repeatability, and antipolarization. The influences of inner electrolyte loss, exterior OH- contamination, and temperature on the potential of the reference electrode are minimal. Therefore, it can be used for corrosion monitoring and measurement of rebars in concrete. 展开更多
关键词 reference electrode methyl cellulose gelling electrolyte Ag/AgCl electrode corrosion monitoring rebarsconcrete
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Parameter-independent error correction for potential measurements by reference electrode in lithium-ion batteries 被引量:1
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作者 Yalun Li Xinlei Gao +4 位作者 Xuning Feng Xuebing Han Jiuyu Du Languang Lu Minggao Ouyang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第4期34-45,共12页
The safety monitoring of lithium-ion batteries(LIBs) is of great significance for realizing all-climate and full-lifespan battery management. In-situ measurement of anode potential with implanted reference electrodes(... The safety monitoring of lithium-ion batteries(LIBs) is of great significance for realizing all-climate and full-lifespan battery management. In-situ measurement of anode potential with implanted reference electrodes(REs) has proven to be effective to monitor and avoid the occurrence of severe side reactions like Li plating to ensure the safe and fast charging. However, the intrinsic measurement errors caused by local blocking effects, which also can be referred to as potential artefacts, are seldom taken into consideration in existing studies, yet they highly dominate the correctness of conclusions inferred from REs. In this study, aiming at exploring the physical origin of the measurement errors and ensure reliable potential monitoring, electrochemical and post-mortem tests are conducted using commercial pouch cells with implanted REs. Corresponding electrochemical model which describes the blocking effects, is established to validate the abnormal absence of lithium plating that predicted by measured anode potentials under various charging rates. Theoretical derivation is further presented to explain the error sources, which can be attributed to increased local liquid potential of the RE position. Most importantly, with the guidance of error analysis, a novel parameter-independent error correction method for RE measurements is proposed for the first time, which is proven to be adequate to estimate the real anode potentials and deduce the critical C-rate of Li plating with extra safety margin. After error correction, the resulting critical C-rates are all within the range of 0.55 ± 0.03 C, which is close to the C-rate of 0.6–0.7 C obtained from experiments. In addition, this error correction method can be performed conveniently with only some simple RE measurements of polarization voltages, totally independent of battery electrochemical and geometric parameters. This study provides highly practical error correction method for RE measurements in real LIBs, substantially facilitating the fast diagnosis and safety evaluation of Li plating during charging of LIBs. 展开更多
关键词 reference electrode Lithium-ion battery Potential artefacts Measurement error correction
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A Reliable Reference Electrode in Molten Carbonate and Its Applications
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作者 方百增 刘新宇 +1 位作者 王新东 段淑贞 《Rare Metals》 SCIE EI CAS CSCD 2000年第2期91-95,共5页
A Ag|AgCl reference electrode which can be used in molten carbonate media has been described in this paper.It consists of a silver wire immersed in a solution of AgCl(1mol%) in (Li 0.62 ,K 0.38 ) 2CO 3,with ... A Ag|AgCl reference electrode which can be used in molten carbonate media has been described in this paper.It consists of a silver wire immersed in a solution of AgCl(1mol%) in (Li 0.62 ,K 0.38 ) 2CO 3,with a zirconia junction.The main properties of reference electrode,such as reproducibility ,stability and reversibility, were checked.The results have demonstrated that the reference electrode is reliable.With such reference electrode catalysis of various electrode materials to oxygen reduction in molten alkali carbonate media was investigated.It is found that as catalysts for oxygen reduction oxidized nickel niobium alloy is superior to nickel oxide. 展开更多
关键词 reference electrode Molten carbonate Oxygen reduction Catalytic activity
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Study on the High Conductive Polymer as the Miniaturized Reference Electrode
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作者 Jung-Chuan Chou Chien-Cheng Chen 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2006年第A03期254-255,共2页
The polypyrrole is the high conductive polymer which was coated onto indium tin oxide (ITO) glass substrate by electroplated technique to fabricate a miniaturized reference electrode.Besides,the morphology of the ITO... The polypyrrole is the high conductive polymer which was coated onto indium tin oxide (ITO) glass substrate by electroplated technique to fabricate a miniaturized reference electrode.Besides,the morphology of the ITO glass reference electrode electroplated with pyrrole has been studied through the instrumental analysis utilizing cyclic voltammetry (CV). Furthermore,the sensing characteristics of the reference electrode have been measured by using commercial instrumental amplifier as the readout circuit.Using the high conductive polymer as miniaturized reference electrode has many advantages such as easy fabrication of coating polymer,without any expensive fabricating equipment,easy carry by the miniaturized technique.Hence,it is suitable for the reference electrode production. 展开更多
关键词 miniaturized reference electrode POLYPYRROLE conductive polymer cyclic voltammetry
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Preparation of Ti/MnO_2 Reference Electrode and Its Application in Concrete Structures
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作者 卢爽 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2009年第S1期161-165,共5页
A novel Ti/MnO2 reference electrode (TMRE) used for concrete environment was fabricated by the electro-deposition method and encapsulated carefully.The properties of the electrode were characterized by open-circuit po... A novel Ti/MnO2 reference electrode (TMRE) used for concrete environment was fabricated by the electro-deposition method and encapsulated carefully.The properties of the electrode were characterized by open-circuit potential,potentiodynamic polarization behavior in synthetic concrete pore solutions and electrochemical performance in cement mortar.The experimental results indicate that the TMRE shows good stability with and without the addition of Cl-ions and desirable polarization behavior in synthetic pore solution.Results of tests in cement mortar indicate that the potential of TMRE will be stable after about 7 days.The stability and desirable polarization behavior make it a promising reference electrode for concrete environment. 展开更多
关键词 reference electrode ELECTRO-DEPOSITION concrete environment potentiodynamic polarization
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High-temperature Reference Electrodes Used in Molten Fluorides
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作者 王新东 段淑贞 +1 位作者 ChristensenE. BjerrumN.J. 《Rare Metals》 SCIE EI CAS CSCD 1993年第3期170-174,共5页
The thermodynamic and dynamic behaviour of Ni^(2+)|Ni couple in FLINAK melt is investigated by us- ing EMF measurement and micropolarization method.The couple shows the Nernstian reversibility and a large exchange cur... The thermodynamic and dynamic behaviour of Ni^(2+)|Ni couple in FLINAK melt is investigated by us- ing EMF measurement and micropolarization method.The couple shows the Nernstian reversibility and a large exchange current density(6 mA·cm^(-2)).A single crystal LaF_3 which is a fluoride ion conductor used as a membrane of the Ni^(2+)|Ni couple reference electrode is reliable in FLINAK melts at 973 K.The poten- tial of LaF_3 membrane reference electrode is constant within±2 mV.The boron nitride used as a salt bridge was not good in FLINAK melts.The platinum electrode is studied by using micropolarization.The equilibrium potential of Pt electrode is dependent on the absorption and the electrochemical reaction.The potential is stable for a constant composition at constant temperature. 展开更多
关键词 Molten fluorides reference electrode Micro-polarization
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STUDY OF FEASIBILITY OF USING Ag-AgCl ELECTRODE AS REFERENCE ELECTRODE OF THE ISFET
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作者 何杏君 王守琦 《Journal of Electronics(China)》 1990年第3期285-288,共4页
The preparation,principle and measurement results of the complex ISFET withAg-AgCl reference electrode are presented in this paper.Through experiment and theory weendeavor to show the feasibility of using the Ag-AgCl ... The preparation,principle and measurement results of the complex ISFET withAg-AgCl reference electrode are presented in this paper.Through experiment and theory weendeavor to show the feasibility of using the Ag-AgCl electrode which is without solution contactas reference electrode and the way of overcoming its instability;it gives a rational explanationfor phenomenon of the ion sensitive field effect transistor which does not conform to Nernstianresponse,when we measured cations of Na<sup>+</sup>, Ca<sup>++</sup>,etc.with the Ag-AgCl reference electrode. 展开更多
关键词 complex-ion SENSITIVE field effect TRANSISTOR activity reference electrode response time
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Electrochemical study of different membrane materials for the fabrication of stable,reproducible and reusable reference electrode
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作者 Nawar K.Al-Shara Farooq Sher +2 位作者 Sania Z.Iqbal Zaman Sajid George Z.Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第10期33-41,共9页
Fabrication of stable,reproducible and reusable reference electrodes for low energy and high-temperature steam splitting is of great interest for hydrogen fuel production without anthropogenic carbon dioxide(CO2)emiss... Fabrication of stable,reproducible and reusable reference electrodes for low energy and high-temperature steam splitting is of great interest for hydrogen fuel production without anthropogenic carbon dioxide(CO2)emission.This study has been conducted for the detection of suitable material for the fabrication of novel reference electrode.In the present scenario,this research is designed to fabricate a novel nickel reference electrode by using operating conditions of eutectic molten hydroxide(NaOH-KOH,49-51 mol%)at temperature 300℃in an ion-conducting membrane of alumina and mullite tube.Afterwards,the designed nickel reference electrode has been examined for its reusability and stability by using electrochemical technique and cyclic voltammetry.Five scans of cyclic voltammetry are performed for both membrane fabricated reference electrode.A slight positive shift in oxidation peaks is observed for mullite membrane electrode(64 mV from scan 1 to 5).The stability measurements are noted by changing the scan rate between 50 and 150 mV s−1.Furthermore,the results show that the Ni/Ni(OH)2 reference electrode covered with a mullite membrane is stable and reusable at 300℃temperature without any deterioration.The stability and reusability of prepared nickel reference electrode covered by mullite tube in the eutectic molten hydroxide were up to 9 days to carry out an electrochemical investigation,while for alumina tube reference electrode the stability and reliability were up to 3 days.The internal electrolytic material and ionic conductance can play an important role for future studies with this reference electrode along with optimisation of temperature and scan rate parameters. 展开更多
关键词 Renewable energy Hydrogen production electrode process Cyclic voltammetry reference electrode and Molten salts
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Enhanced Electrochemical and Physical Properties of Ag/AgCl Planar Reference Electrodesin Potentiometric Sensors by Graphite Oxide Layer
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作者 Tung Son Vinh Nguyen Tien Minh Huynh +1 位作者 Tin Chanh Duc Doan Chien Mau Dang 《材料科学与工程(中英文A版)》 2019年第2期83-90,共8页
The most common reference electrode (RE) which is used in electrochemical measurements is the Ag/AgCl electrode. In this study, we present a novel solid-state Ag/AgCl planar electrode that was coated with a thin layer... The most common reference electrode (RE) which is used in electrochemical measurements is the Ag/AgCl electrode. In this study, we present a novel solid-state Ag/AgCl planar electrode that was coated with a thin layer of Graphite Oxide (GO) as a protective layer. The Ag/AgCl planar electrode was fabricated by using the photolithography and lift-off method combined with the Ag[NH3]2Cl complex. The GO was produced by Hummer’s method and was deposited on top of the Ag/AgCl layer by drop-casting method. The layers of the fabricated reference electrode were characterized by micro Raman spectroscopy, Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDX). The responding time of the planar electrode was short and the signal was more stable in comparison to the plainAg/AgCl electrode. The Open Circuit Potential (OCP) measurement with the fabricated electrode as the RE and the platinum electrode as the working electrode in electrolyte solutions which had various pH values was performed with a linear response in pH ranges from pH 5 to pH 8 and the linear correlation coefficient (R^2 = 0.9899). Moreover, the coating of the GO layers also enhanced the durability of the modified electrode. The results showed that the modified Ag/AgCl electrode with a thin layer GO as the protective layer could be used as plana REs for the potentiometric sensors. 展开更多
关键词 GRAPHITE OXIDE POTENTIOMETRIC sensor Ag/AgCl reference electrode
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聚多巴胺修饰的Ag/AgCl参比电极的制备及其性能试验
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作者 张西良 苏小青 +1 位作者 陈成 徐云峰 《江苏大学学报(自然科学版)》 CAS 北大核心 2024年第4期490-496,共7页
为了适应栽培基质等非均相体系pH值的在线检测,并提供稳定的参考电位,采用磁控溅射沉积银膜、NaClO溶液氯化获得的AgCl层和多巴胺沉积修饰膜,研制了聚多巴胺修饰的Ag/AgCl固体薄膜参比电极,并在沉积时间分别为4、8、12、16 h时,对聚多... 为了适应栽培基质等非均相体系pH值的在线检测,并提供稳定的参考电位,采用磁控溅射沉积银膜、NaClO溶液氯化获得的AgCl层和多巴胺沉积修饰膜,研制了聚多巴胺修饰的Ag/AgCl固体薄膜参比电极,并在沉积时间分别为4、8、12、16 h时,对聚多巴胺修饰的参比电极在磷酸缓冲盐溶液(phosphate buffered saline,PBS)中的稳定性、可逆性和循环伏安特性曲线进行了对比测试.结果表明:参比电极在PBS溶液中电位标准差均约为1.00 mV,在不同pH缓冲溶液中均能够恢复到相对稳定的电位,且偏差小于5.00 mV,具有良好的可逆性;在50次循环伏安试验中电位漂移很小;根据参比电极的氯离子灵敏度为2.00~2.50 mV/pCl,聚多巴胺修饰的参比电极对氯离子浓度不敏感,证实聚多巴胺修饰的参比电极可以用作参比电极;沉积时间为12 h时的参比电极在各项试验中综合性能表现最优,应用试验表明该参比电极更适用于开展栽培基质pH检测. 展开更多
关键词 参比电极 聚合物膜 电化学行为 表面改性 沉积时间
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基于参比电极的析锂电池安全充电控制
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作者 钱广俊 汪宇 +1 位作者 卢兰光 韩雪冰 《电力工程技术》 北大核心 2024年第3期71-77,共7页
电池系统是支撑下一代新型电网的关键,然而不合理的充放电策略会使电池发生析锂副反应,导致电池充放电性能大幅减弱。因此,文中针对三元锂离子电池,基于参比电极揭示了析锂后电池的充电性能变化情况,并对其安全充电电流进行控制。首先,... 电池系统是支撑下一代新型电网的关键,然而不合理的充放电策略会使电池发生析锂副反应,导致电池充放电性能大幅减弱。因此,文中针对三元锂离子电池,基于参比电极揭示了析锂后电池的充电性能变化情况,并对其安全充电电流进行控制。首先,设计不同温度下的充放电循环实验,得到低温循环与高温循环后的电池;其次,通过植入参比电极标定安全充电曲线对比电池的负极电位,发现高温循环后的电池发生了析锂,且平均充电电流相比新电池降低了61.7%;最后,对析锂后的电池建立安全充电荷电状态-温度-电流等高线图,对比新电池等高线图后发现,200 A以上的充电电流区域减少了69.84%。文中提供了一个析锂后电池充电性能衰减的量化指标,需要在实际的锂离子电池全寿命周期管理中予以考虑。 展开更多
关键词 析锂电池 参比电极 负极电位 充电标定 充电性能 等高线图
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基于伪参比电极的锂离子电池正负极相对开路电势曲线测量方法研究
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作者 李泊言 金锋 +3 位作者 冬雷 张睿思 赵贺明 张宇 《电机与控制应用》 2024年第9期24-32,共9页
用于获取锂离子电池正负极开路电势曲线的纽扣电池试验需要对电池进行破坏性拆解,而且试验过程中电池极易受到污染。为解决此问题,提出了一种利用伪参比电极获取锂离子电池正负极相对开路电势曲线的方法。该方法将锂电池外壳作为参比电... 用于获取锂离子电池正负极开路电势曲线的纽扣电池试验需要对电池进行破坏性拆解,而且试验过程中电池极易受到污染。为解决此问题,提出了一种利用伪参比电极获取锂离子电池正负极相对开路电势曲线的方法。该方法将锂电池外壳作为参比电极,通过小倍率充放电试验直接测得电极与外壳之间的相对开路电势。通过商用钛酸锂电池对所提方法进行试验验证,结果表明利用所提方法计算得到的电池电压和实际测量的电池电压的均方根误差仅为4.2 mV,且在同批次电池上辨识得到的热力学参数随电池容量衰减而减小。试验结果验证了伪参比电极法可在不破坏电池的情况下获取到可信度较高的相对开路电势曲线。 展开更多
关键词 锂离子电池 参比电极 开路电势曲线 参数辨识
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锂电池用参比电极的设计与应用 被引量:1
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作者 肖也 徐磊 +1 位作者 闫崇 黄佳琦 《储能科学与技术》 CSCD 北大核心 2024年第1期82-91,共10页
参比电极对于解析高安全、高性能锂电池内部物理化学过程具有重要意义。然而在科学研究及产品开发中,可靠参比电极的实际构建和集成仍具有挑战性。本文首先阐明锂电池用参比电极的原理和特性,进而梳理基本设计参数,包括活性材料选择、... 参比电极对于解析高安全、高性能锂电池内部物理化学过程具有重要意义。然而在科学研究及产品开发中,可靠参比电极的实际构建和集成仍具有挑战性。本文首先阐明锂电池用参比电极的原理和特性,进而梳理基本设计参数,包括活性材料选择、几何尺寸、制备工艺和检测设置。然后介绍了引入参比电极的三电极体系在锂电池工作/失效机制分析方面的应用实例。最后展望了开发和部署锂电池用参比电极的挑战和发展方向。 展开更多
关键词 参比电极 锂离子电池 锂金属电池 电极电势 电化学阻抗谱
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集成PVB修饰Ag/AgCl参比电极的pH传感硅探针阵列
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作者 王卓 刘景全 《传感器与微系统》 CSCD 北大核心 2024年第9期68-70,共3页
介绍了一种带有集成Ag/AgCl参比电极的硅记录探针,通过表面聚乙烯醇缩丁醛(PVB)的修饰实现稳定的pH传感,用于应用神经科学。集成参比电极通过恒流电化学镀法实现银层的制备以及氯化,滴涂的PVB主要用作参比电极的保护膜,参比电极面积为0.... 介绍了一种带有集成Ag/AgCl参比电极的硅记录探针,通过表面聚乙烯醇缩丁醛(PVB)的修饰实现稳定的pH传感,用于应用神经科学。集成参比电极通过恒流电化学镀法实现银层的制备以及氯化,滴涂的PVB主要用作参比电极的保护膜,参比电极面积为0.44 mm^(2)。最终硅记录探针的pH灵敏度为53.13 mV/pH,电位漂移为8 000 s下20 mV,并且探针工艺与硅基探针高度融合。总之,集成参比电极并且提高其稳定性对于生物传感器以及脑疾病诊断生物标志物的电化学检测具有重要意义。 展开更多
关键词 Ag/AgCl参比电极 PH传感器 生物稳定性
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基于改进点源扩散模型的电极极差电位研究
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作者 尹红 《船电技术》 2024年第1期38-41,共4页
本文建立点源扩散模型,研究了电极电位的变化规律,将圆柱体Ag/AgCl电极等效为点源模型,通过Fick定律建立Cl-浓度扩散方程,利用0阶贝塞尔函数得到了浓度与时间、距离的函数关系,通过浓度依赖动力学方程建立浓度、温度与电极电位的表达式... 本文建立点源扩散模型,研究了电极电位的变化规律,将圆柱体Ag/AgCl电极等效为点源模型,通过Fick定律建立Cl-浓度扩散方程,利用0阶贝塞尔函数得到了浓度与时间、距离的函数关系,通过浓度依赖动力学方程建立浓度、温度与电极电位的表达式,利用数值计算分析了不同浓度、温度、时间对电极电位的影响,并与传统的互补误差函数模型作对比,在点源扩散模型的基础上,将氯离子扩散系数视为变量的同时,引入其对时间、温度的影响。利用数值计算分析了不同浓度、温度、时间对电极电位的影响,结果表明:改进的点源模型所推导的极差电位精度更高。 展开更多
关键词 Ag/AgCl参比电极 点源扩散 氯离子扩散系数 电极电位
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基于参比电极的三电极电池快充研究
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作者 邹岱江 唐小波 +2 位作者 秦宇迪 曹晟阁 李香杰 《时代汽车》 2024年第17期85-87,共3页
本文聚焦于电动汽车快充技术中的关键问题,特别是动力电池的耐久性和安全性。为解决这些问题,本文提出一种基于参比电极的三电极电池快充研究方法。该方法通过参比电极实时监测负极电位,并控制负极电位,以防止充电过程中的析锂现象,从... 本文聚焦于电动汽车快充技术中的关键问题,特别是动力电池的耐久性和安全性。为解决这些问题,本文提出一种基于参比电极的三电极电池快充研究方法。该方法通过参比电极实时监测负极电位,并控制负极电位,以防止充电过程中的析锂现象,从而得出更安全的快充策略。文中还介绍了一种快速充电算法,该算法通过两个闭环控制环节实现无损快速充电,同时还提出了一种基于“虚拟电池”的仿真开发方案,以验证快速充电算法的有效性。 展开更多
关键词 参比电极 析锂现象 快速充电算法 仿真开发
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Electrochemical Performance of High Purity Zinc and Zn-Al-Cd Alloy as Reference Electrodes
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作者 YUAN Chuanjun LIANG Chenghao AN Xiaowen 《Wuhan University Journal of Natural Sciences》 CAS 2010年第1期64-70,共7页
The effects of Cl-concentration,temperature,pH,flow velocity,soluble oxygen content of seawater and anodic current on the potential of high purity zinc and Zn-Al-Cd reference electrodes were investigated. The results ... The effects of Cl-concentration,temperature,pH,flow velocity,soluble oxygen content of seawater and anodic current on the potential of high purity zinc and Zn-Al-Cd reference electrodes were investigated. The results show that the investigated metal materials are liable to establish stable potential and act as reference electrodes in seawater,diluted seawater and urban tap water. Cl-concentration,temperature,seawater flow velocity and anodic current have an obvious effect on zinc potentials. However,seawater pH has no obvious effect on zinc potentials. 展开更多
关键词 high purity zinc Zn-Al-Cd reference electrodes electrochemical performance
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恒电位法制备Ag/AgCl纱线参比电极性能研究
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作者 刘璐 李津 刘皓 《天津纺织科技》 2023年第4期41-45,共5页
以镀银纱线为基底材料,采用恒电位法在0.9%的NaCl溶液中制备了4种不同沉积电压(0.50、0.60、0.70、0.80 V)Ag/AgCl纱线参比电极。研究了Ag/AgCl纱线参比电极电化学阻抗、电位稳定性、温度影响、酸碱度影响、可逆性和再现性。结果表明,... 以镀银纱线为基底材料,采用恒电位法在0.9%的NaCl溶液中制备了4种不同沉积电压(0.50、0.60、0.70、0.80 V)Ag/AgCl纱线参比电极。研究了Ag/AgCl纱线参比电极电化学阻抗、电位稳定性、温度影响、酸碱度影响、可逆性和再现性。结果表明,随着沉积电压的升高,镀银纱线表面生成的氯化银颗粒粒径增大且分布面积增大,其中0.60 V沉积电压制备的Ag/AgCl纱线参比电极,氯化银颗粒均匀分布,纱线表面为极化-非极化复合结构,电化学阻抗最低、电位稳定性最好、温度及酸碱环境的变化对电极电位影响小、可逆性好且具有良好的电位重现性。 展开更多
关键词 镀银纱线 恒电位法 纱线参比电极 电位稳定
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基于原位参比的氧化亚硅--石墨复合负极循环衰减机制
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作者 宋缙华 张兴浩 +4 位作者 丰震河 程广玉 顾洪汇 顾海涛 王可 《储能科学与技术》 CAS CSCD 北大核心 2023年第4期1059-1065,共7页
为了研究氧化亚硅和石墨在复合应用时的循环衰减机制,本工作通过在循环过程中增加小电流可逆容量标定,消除了电压极化对衰减行为的影响。通过在软包装电池内部预先埋入参比电极,对比不同循环次数时正极和负极的电化学特征变化,利用负极... 为了研究氧化亚硅和石墨在复合应用时的循环衰减机制,本工作通过在循环过程中增加小电流可逆容量标定,消除了电压极化对衰减行为的影响。通过在软包装电池内部预先埋入参比电极,对比不同循环次数时正极和负极的电化学特征变化,利用负极微分曲线解析氧化亚硅和石墨的去锂化容量演变过程和衰减程度。同时,结合交流阻抗谱(EIS)、扫描电子显微技术(SEM)、元素能谱(EDS)和等离子体发射光谱(ICP)等测试。结果表明,造成电池循环衰减的主要原因是活性锂损失和氧化亚硅衰减,两者造成的容量损失分别为0.45 Ah和0.36 Ah。负极衰减速率明显快于正极,循环600次后,负极中石墨和氧化亚硅的衰减程度分别为2.2%和30.3%。电池在循环过程中产生了新的界面阻抗,所有动力学阻抗参数呈逐渐增大的趋势。拆解电池发现,循环后负极发生了严重的体积膨胀和副反应,导致锂损失在负极并失活,引起界面阻抗的增长和电池容量的衰减。本研究可以无损定量识别氧化亚硅和石墨在循环过程中的衰减程度,为含硅复合负极的工程化应用提供了研究基础。 展开更多
关键词 氧化亚硅 参比电极 循环衰减 锂离子电池
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