The liquid-solid phase change process of a simple one-dimensional slab is studied in this paper.By taking entransy dissipation minimization as optimization objective,the optimal external reservoir temperature profiles...The liquid-solid phase change process of a simple one-dimensional slab is studied in this paper.By taking entransy dissipation minimization as optimization objective,the optimal external reservoir temperature profiles are derived by using optimal control theory under the condition of a fixed freezing or melting time.The entransy dissipation corresponding to the optimal heat exchange strategies of minimum entransy dissipation is 8/9 of that corresponding to constant reservoir temperature operations,which is independent of all system parameters.The obtained results for entransy dissipation minimization are also compared with those obtained for the optimal heat exchange strategies of minimum entropy generation and constant reservoir temperature operations by numerical examples.The obtained results can provide some theoretical guidelines for the choice of optimal cooling or heating strategy in practical liquid-solid phase change processes.展开更多
After compositing with SiO_2 layers, it is shown that superlattice-like Sb/SiO_2 thin films have higher crystallization temperature（~240°C）, larger crystallization activation energy（6.22 e V）, and better data...After compositing with SiO_2 layers, it is shown that superlattice-like Sb/SiO_2 thin films have higher crystallization temperature（~240°C）, larger crystallization activation energy（6.22 e V）, and better data retention ability（189°C for 10 y）. The crystallization of Sb in superlattice-like Sb/SiO_2 thin films is restrained by the multilayer interfaces. The reversible resistance transition can be achieved by an electric pulse as short as 8 ns for the Sb（3 nm）/SiO_2（7 nm）-based phase change memory cell. A lower operation power consumption of 0.09 m W and a good endurance of 3.0 × 10~6 cycles are achieved. In addition, the superlattice-like Sb（3 nm）/SiO_2（7 nm） thin film shows a low thermal conductivity of 0.13 W/（m·K）.展开更多
The selection of phase change material(PCM)plays an important role in developing high-efficient thermal energy storage(TES)processes.Ionic liquids(ILs)or organic salts are thermally stable,non-volatile,and non-flammab...The selection of phase change material(PCM)plays an important role in developing high-efficient thermal energy storage(TES)processes.Ionic liquids(ILs)or organic salts are thermally stable,non-volatile,and non-flammable.Importantly,researchers have proved that some ILs possess higher latent heat of fusion than conventional PCMs.Despite these attractive characteristics,yet surprisingly,little research has been performed to the systematic selection or structural design of ILs for TES.Besides,most of the existing work is only focused on the latent heat when selecting PCMs.However,one should note that other properties such as heat capacity and thermal conductivity could affect the TES performance as well.In this work,we propose a computer-aided molecular design(CAMD)based method to systematically design IL PCMs for a practical TES process.The effects of different IL properties are simultaneously captured in the IL property models and TES process models.Optimal ILs holding a best compromise of all the properties are identified through the solution of a formulated CAMD problem where the TES performance of the process is maximized.[MPyEtOH][TfO]is found to be the best material and excitingly,the identified top nine ILs all show a higher TES performance than the traditional PCM paraffin wax at 10 h thermal charging time.展开更多
The crystallization characteristics of a ubiquitous T-shaped phase change memory(PCM) cell, under SET current pulse and very small disturb current pulse, have been investigated by finite element modelling. As analyzed...The crystallization characteristics of a ubiquitous T-shaped phase change memory(PCM) cell, under SET current pulse and very small disturb current pulse, have been investigated by finite element modelling. As analyzed in this paper, the crystallization region under SET current pulse presents first on the corner of the bottom electron contact(BEC) and then promptly forms a filament shunting down the amorphous phase to achieve the low-resistance state, whereas the tiny disturb current pulse accelerates crystallization at the axis of symmetry in the phase change material. According to the different crystallization paths, a new structure of phase change material layer is proposed to improve the data retention for PCM without impeding SET operation.This structure only requires one or two additional process steps to dope nitrogen element in the center region of phase change material layer to increase the crystallization temperature in this confined region. The electrical-thermal characteristics of PCM cells with incremental doped radius have been analyzed and the best performance is presented when the doped radius is equal to the radius of the BEC.展开更多
Mathematical models are been proposed to simulate the thermal and metallurgical behaviors of the strip occtLrring on the run-out table （ROT） in a hot strip mill. A variational method is utilized for the discretizati...Mathematical models are been proposed to simulate the thermal and metallurgical behaviors of the strip occtLrring on the run-out table （ROT） in a hot strip mill. A variational method is utilized for the discretization of the governing transient conduction-convection equation, with heat transfer coefficients adaptively determined by the actual mill data. To consider the thermal effect of phase transformation during cooling, a constitutive equation for describing austenite decomposition kinetics of steel in air and water cooling zones is coupled with the heat transfer model. As the basic required inputs in the numerical simulations, thermal material properties are experimentally measured for three carbon steels and the least squares method is used to statistically derive regression models for the properties, including specific heat and thermal conductivity. The numerical simulation and experimental results show that the setup accuracy of the temperature prediction system of ROT is effectively improved.展开更多
The objective of this study was to establish the thermal characteristics of the lauric acid (95% purity) as a latent heat storage material filled in the annulus of vertical concentric double pipe during its melting pr...The objective of this study was to establish the thermal characteristics of the lauric acid (95% purity) as a latent heat storage material filled in the annulus of vertical concentric double pipe during its melting process,The temperature data were used to determine the thermal characteristics,including the temporal temperature variations and the effects of the mass flow rate and the inlet temperature of the heat transfer fluid on the heat transfer coefficient and the heat charging fraction during the melting process,The results indicated that the time to reach to heat charging fraction of 1.0 could be altered by changing the mass flow rate and the inlet temperature of the heat transfer fluid.展开更多
A numerical model is proposed to analyze mass, momentum, and energy transfer between plasma andparticles in d.c. arc-heated and confined jet reactors at atmospheric pressure. It emphasizes the phasechange and thermal ...A numerical model is proposed to analyze mass, momentum, and energy transfer between plasma andparticles in d.c. arc-heated and confined jet reactors at atmospheric pressure. It emphasizes the phasechange and thermal chemistry of particles and includes some other effects such as flow turbulence, gascompressibility and temperature-dependence of the transport properties under the plasma condition.Example calculations for plasma-dissociated zircon process indicate the influences of reactor operationparameters on the plasma jet and particle behavior.展开更多
Compared to the conventional phase change materials,the new phase change material Ta-Sb2Te3 has the advantages of excellent data retention and good material stability.In this letter,the etching characteristics of Ta-S...Compared to the conventional phase change materials,the new phase change material Ta-Sb2Te3 has the advantages of excellent data retention and good material stability.In this letter,the etching characteristics of Ta-Sb2Te3 were studied by using CF4/Ar.The results showed that when CF4/Ar=25/25,the etching power was 600 W and the etching pressure was 2.5 Pa,the etching speed was up to 61 nm/min.The etching pattern of Ta-Sb2Te3 film had a smooth side wall and good perpendicularity(close to 90°),smooth surface of the etching(RMS was 0.51nm),and the etching uniformity was fine.Furthermore,the mechanism of this etching process was analyzed by X-ray photoelectron spectroscopy(XPS).The main damage mechanism of ICP etching in CF4/Ar was studied by X-ray diffraction(XRD).展开更多
As an important parameter in the single airborne passive locating system, the rate of phase difference change contains range information of the radio emitter. Taking single carrier sine pulse signals as an example, th...As an important parameter in the single airborne passive locating system, the rate of phase difference change contains range information of the radio emitter. Taking single carrier sine pulse signals as an example, this article illustrates the principle of passive location through measurement of rates of phase difference change and analyzes the structure of measurement errors. On the basis of the Cramér-Rao lower bound (CRLB), an algorithm associated with time-chips is proposed to determine the rates of pha...展开更多
基金supported by the Program for New Century Excellent Talents in Universities of China (Grant No 20041006)the Foundation for the Authors of National Excellent Doctoral Dissertation of China (Grant No 200136)
文摘The liquid-solid phase change process of a simple one-dimensional slab is studied in this paper.By taking entransy dissipation minimization as optimization objective,the optimal external reservoir temperature profiles are derived by using optimal control theory under the condition of a fixed freezing or melting time.The entransy dissipation corresponding to the optimal heat exchange strategies of minimum entransy dissipation is 8/9 of that corresponding to constant reservoir temperature operations,which is independent of all system parameters.The obtained results for entransy dissipation minimization are also compared with those obtained for the optimal heat exchange strategies of minimum entropy generation and constant reservoir temperature operations by numerical examples.The obtained results can provide some theoretical guidelines for the choice of optimal cooling or heating strategy in practical liquid-solid phase change processes.
基金Supported by the National Natural Science Foundation of China under Grant No 11774438the Natural Science Foundation of Jiangsu Province under Grant No BK20151172+2 种基金the Changzhou Science and Technology Bureau under Grant No CJ20160028the Qing Lan Project,the Opening Project of State Key Laboratory of Silicon Materials under Grant No SKL2017-04the Opening Project of Key Laboratory of Microelectronic Devices and Integrated Technology of Institute of Microelectronics of Chinese Academy of Sciences
文摘After compositing with SiO_2 layers, it is shown that superlattice-like Sb/SiO_2 thin films have higher crystallization temperature（~240°C）, larger crystallization activation energy（6.22 e V）, and better data retention ability（189°C for 10 y）. The crystallization of Sb in superlattice-like Sb/SiO_2 thin films is restrained by the multilayer interfaces. The reversible resistance transition can be achieved by an electric pulse as short as 8 ns for the Sb（3 nm）/SiO_2（7 nm）-based phase change memory cell. A lower operation power consumption of 0.09 m W and a good endurance of 3.0 × 10~6 cycles are achieved. In addition, the superlattice-like Sb（3 nm）/SiO_2（7 nm） thin film shows a low thermal conductivity of 0.13 W/（m·K）.
基金the financial support from Max Planck Society,Germany,for the Computer-Aided Material and Process Design(CAMPD)project
文摘The selection of phase change material(PCM)plays an important role in developing high-efficient thermal energy storage(TES)processes.Ionic liquids(ILs)or organic salts are thermally stable,non-volatile,and non-flammable.Importantly,researchers have proved that some ILs possess higher latent heat of fusion than conventional PCMs.Despite these attractive characteristics,yet surprisingly,little research has been performed to the systematic selection or structural design of ILs for TES.Besides,most of the existing work is only focused on the latent heat when selecting PCMs.However,one should note that other properties such as heat capacity and thermal conductivity could affect the TES performance as well.In this work,we propose a computer-aided molecular design(CAMD)based method to systematically design IL PCMs for a practical TES process.The effects of different IL properties are simultaneously captured in the IL property models and TES process models.Optimal ILs holding a best compromise of all the properties are identified through the solution of a formulated CAMD problem where the TES performance of the process is maximized.[MPyEtOH][TfO]is found to be the best material and excitingly,the identified top nine ILs all show a higher TES performance than the traditional PCM paraffin wax at 10 h thermal charging time.
基金support of the"Strategic Priority Research Program"of the Chinese Academy of Sciences(No.XDA09020402)the National Integrate Circuit Research Program of China(No.2009ZX02023-003)+2 种基金the National Natural Science Foundation of China(Nos.61261160500,61376006,61401444,61504157)the Science and Technology Council of Shanghai(Nos.14DZ2294900,15DZ2270900,14ZR1447500)the National Natural Science Foundation of China(61874178)
文摘The crystallization characteristics of a ubiquitous T-shaped phase change memory(PCM) cell, under SET current pulse and very small disturb current pulse, have been investigated by finite element modelling. As analyzed in this paper, the crystallization region under SET current pulse presents first on the corner of the bottom electron contact(BEC) and then promptly forms a filament shunting down the amorphous phase to achieve the low-resistance state, whereas the tiny disturb current pulse accelerates crystallization at the axis of symmetry in the phase change material. According to the different crystallization paths, a new structure of phase change material layer is proposed to improve the data retention for PCM without impeding SET operation.This structure only requires one or two additional process steps to dope nitrogen element in the center region of phase change material layer to increase the crystallization temperature in this confined region. The electrical-thermal characteristics of PCM cells with incremental doped radius have been analyzed and the best performance is presented when the doped radius is equal to the radius of the BEC.
基金the National Basic Research Program (973) of China (No. 2006CB705400)the National Natural Science Foundation of China (No. 50575200)
文摘Mathematical models are been proposed to simulate the thermal and metallurgical behaviors of the strip occtLrring on the run-out table （ROT） in a hot strip mill. A variational method is utilized for the discretization of the governing transient conduction-convection equation, with heat transfer coefficients adaptively determined by the actual mill data. To consider the thermal effect of phase transformation during cooling, a constitutive equation for describing austenite decomposition kinetics of steel in air and water cooling zones is coupled with the heat transfer model. As the basic required inputs in the numerical simulations, thermal material properties are experimentally measured for three carbon steels and the least squares method is used to statistically derive regression models for the properties, including specific heat and thermal conductivity. The numerical simulation and experimental results show that the setup accuracy of the temperature prediction system of ROT is effectively improved.
文摘The objective of this study was to establish the thermal characteristics of the lauric acid (95% purity) as a latent heat storage material filled in the annulus of vertical concentric double pipe during its melting process,The temperature data were used to determine the thermal characteristics,including the temporal temperature variations and the effects of the mass flow rate and the inlet temperature of the heat transfer fluid on the heat transfer coefficient and the heat charging fraction during the melting process,The results indicated that the time to reach to heat charging fraction of 1.0 could be altered by changing the mass flow rate and the inlet temperature of the heat transfer fluid.
文摘A numerical model is proposed to analyze mass, momentum, and energy transfer between plasma andparticles in d.c. arc-heated and confined jet reactors at atmospheric pressure. It emphasizes the phasechange and thermal chemistry of particles and includes some other effects such as flow turbulence, gascompressibility and temperature-dependence of the transport properties under the plasma condition.Example calculations for plasma-dissociated zircon process indicate the influences of reactor operationparameters on the plasma jet and particle behavior.
基金This work was financially supported by the Natural Science Foundation of China(61874129)the National Key Research and Development Program of China(2017YFB0405601).
文摘Compared to the conventional phase change materials,the new phase change material Ta-Sb2Te3 has the advantages of excellent data retention and good material stability.In this letter,the etching characteristics of Ta-Sb2Te3 were studied by using CF4/Ar.The results showed that when CF4/Ar=25/25,the etching power was 600 W and the etching pressure was 2.5 Pa,the etching speed was up to 61 nm/min.The etching pattern of Ta-Sb2Te3 film had a smooth side wall and good perpendicularity(close to 90°),smooth surface of the etching(RMS was 0.51nm),and the etching uniformity was fine.Furthermore,the mechanism of this etching process was analyzed by X-ray photoelectron spectroscopy(XPS).The main damage mechanism of ICP etching in CF4/Ar was studied by X-ray diffraction(XRD).
基金Aeronautical Science Foundation of China (2007ZC53030)
文摘As an important parameter in the single airborne passive locating system, the rate of phase difference change contains range information of the radio emitter. Taking single carrier sine pulse signals as an example, this article illustrates the principle of passive location through measurement of rates of phase difference change and analyzes the structure of measurement errors. On the basis of the Cramér-Rao lower bound (CRLB), an algorithm associated with time-chips is proposed to determine the rates of pha...
