The phase transformation activation energy of the Cu61.13Zn33.94A14.93 alloys, which were treated at 4 GPa and 700 ℃ for 15 minutes, was calculated by means of differential scanning calorimetry curves obtained at var...The phase transformation activation energy of the Cu61.13Zn33.94A14.93 alloys, which were treated at 4 GPa and 700 ℃ for 15 minutes, was calculated by means of differential scanning calorimetry curves obtained at various heating and cooling rates. Then, the effects of high-pressure heat treatments on the solid-state phase transformation and the microstructures of Cu61.13Zn33.94A14.93 alloys were investigated. The results show that high-pressure heat treatments can refine the grains and can change the preferred orientation from （111） to （200） of α phase. Compared with the as-cast alloy, the sample with high-pressure heat treatment has finer grains, lower β＇→β and/β→β＇ transformation temperature and activation energy. Furthermore, we found that high cooling rate favours the formation of fine needle-like α phase in the range of 5-20℃/min.展开更多
Based on the tests of a build-up welding at plate edge (BWPE) and amulti-layer build-up welding on plate (MBWP), the article studies on the solid-state phasetransformations which affect welding distortion process and ...Based on the tests of a build-up welding at plate edge (BWPE) and amulti-layer build-up welding on plate (MBWP), the article studies on the solid-state phasetransformations which affect welding distortion process and on the influence rule of transformationstarting temperature (TST) of welded metal to the welding residual distortion. The weldingdistortion can be decreased or controlled by the transformation volume expansion caused bysolid-state phase transformation of welded metal during the cooling. The test results of BWPE showthat when TST is at about 190 deg C, the bending distortion of welded specimen is the smallest, andits displacements at free end are decreased to 58 percent and 67 percent compared with those ofconventional welding electrodes A102 and E5015, which TST are less than room temperature and equalto 758 deg C respectively. The test results of MBWP show that when TST were at 100 approx 250 deg C.the welded specimen would appear reversible bending distortion compared with those of A102 andE5015. The maximum deflection value of reversible bending distortion in 8 mm thick plate is -2.94 mmat about 170 deg C of TST. The test results provide a valuable method to decrease or to controlwelding residual distortion.展开更多
The solid-state phase transformation microstructure of Cu-Zn alloy under different high pressure were investigated by means of SEM and XRD. The results show that the α phase with smaller grain size, different shape a...The solid-state phase transformation microstructure of Cu-Zn alloy under different high pressure were investigated by means of SEM and XRD. The results show that the α phase with smaller grain size, different shape and random distribution appears in the Cu-Zn alloy, when the solid-state phase transformation generation in the Cu-Zn alloy under 25～750 ℃ and 3～6 GPa high pressure, and the volume fraction of transformation phase decreases with increasing pressure, under high pressure (6 GPa), the changes of microstructure of Cu-Zn alloy is not obvious. In addition, the effect of high pressure on the solid-state phase transformation microstructure of Cu-Zn alloy was discussed.展开更多
The nanosized zirconia was synthesized via solid state reaction in the presence of surfactant. The results indicate that crystal phase of zirconia can be controlled by tuning the synthesis parameters such as OH^-/Zr m...The nanosized zirconia was synthesized via solid state reaction in the presence of surfactant. The results indicate that crystal phase of zirconia can be controlled by tuning the synthesis parameters such as OH^-/Zr molar ratio, crystallizing temperature and time. It can be transformed among amorphous, tetragonal and monoclinic phases. The transformation is driven by particle size. The research shows the nanocrystalline zirconia possesses the higher thermal stability compared with amorphous framework. The ＂glow exotherm＂ can be observed for the amorphous samples. Otherwise, it is in the absence for nanocrystalline samples. Herein, the reason for retention of tetragonal zirconia is demonstrated.展开更多
The isochronal y—m transformation of Fe-ISi alloy was measured by high-resolution dilatometry. According to the variation of the ferrite formation rate, an abnormal y—>a phase transformation was recognized, while...The isochronal y—m transformation of Fe-ISi alloy was measured by high-resolution dilatometry. According to the variation of the ferrite formation rate, an abnormal y—>a phase transformation was recognized, while normal reaction, i.e. one peak continuous reaction, was also detected. The occurrence the one or the other type of y—?a transformation strongly depends on the grain size: the transformation type changes from abnormal to normal with decreasing grain size. In the abnormal transformation process the first stage of the transformation corresponds to the first peaks in the transformation rate, which are not thermally activated.展开更多
This paper proposes a modified centralized shifted Rayleigh filter（MCSRF） algorithm for tracking boost phase of ballistic missile（BM） trajectory with a highly nonlinear dynamical model based on bearings-only.This ...This paper proposes a modified centralized shifted Rayleigh filter（MCSRF） algorithm for tracking boost phase of ballistic missile（BM） trajectory with a highly nonlinear dynamical model based on bearings-only.This paper contributes three folds.Firstly,the mathematical model of an MCSRF for multiple passive sensors is derived.Then,minimum entropy based onedimensional optimization search to adaptively adjust the probability of the different filters for real time state estimation is deployed.Finally,the unscented transform（UT） is introduced to resolve the asymmetric state estimation problem.Simulation results show that the proposed algorithm can consecutively track the BM precisely during the boost phase.In comparison with the unscented Kalman filter（UKF） algorithm,the proposed algorithm effectively reduces the tracking position and velocity root mean square（RMS） errors,which will make more sense for early precision interception.展开更多
The phase-field method has emerged as the method of choice for the description of microstructure evolution and phase transitions in metallic materials.Following general thermodynamic laws a set of evolution equations ...The phase-field method has emerged as the method of choice for the description of microstructure evolution and phase transitions in metallic materials.Following general thermodynamic laws a set of evolution equations for the structural variables of the system,the so called phase-fields,are derived.The paper reviews shortly the theoretical background of the multi-phase-field.Different examples demonstrating the applicability of the method to technical steels will be presented ranging from deformation of the dendritic strand shell during peritectic transformation,grain growth in Austenite to stress driven growth of Pearlite.展开更多
文摘The phase transformation activation energy of the Cu61.13Zn33.94A14.93 alloys, which were treated at 4 GPa and 700 ℃ for 15 minutes, was calculated by means of differential scanning calorimetry curves obtained at various heating and cooling rates. Then, the effects of high-pressure heat treatments on the solid-state phase transformation and the microstructures of Cu61.13Zn33.94A14.93 alloys were investigated. The results show that high-pressure heat treatments can refine the grains and can change the preferred orientation from （111） to （200） of α phase. Compared with the as-cast alloy, the sample with high-pressure heat treatment has finer grains, lower β＇→β and/β→β＇ transformation temperature and activation energy. Furthermore, we found that high cooling rate favours the formation of fine needle-like α phase in the range of 5-20℃/min.
基金This project is supported by National Natural Science Foundation of China (No.50175079) China Postdoctoral Science Foundation (No.2003033348).
文摘Based on the tests of a build-up welding at plate edge (BWPE) and amulti-layer build-up welding on plate (MBWP), the article studies on the solid-state phasetransformations which affect welding distortion process and on the influence rule of transformationstarting temperature (TST) of welded metal to the welding residual distortion. The weldingdistortion can be decreased or controlled by the transformation volume expansion caused bysolid-state phase transformation of welded metal during the cooling. The test results of BWPE showthat when TST is at about 190 deg C, the bending distortion of welded specimen is the smallest, andits displacements at free end are decreased to 58 percent and 67 percent compared with those ofconventional welding electrodes A102 and E5015, which TST are less than room temperature and equalto 758 deg C respectively. The test results of MBWP show that when TST were at 100 approx 250 deg C.the welded specimen would appear reversible bending distortion compared with those of A102 andE5015. The maximum deflection value of reversible bending distortion in 8 mm thick plate is -2.94 mmat about 170 deg C of TST. The test results provide a valuable method to decrease or to controlwelding residual distortion.
文摘The solid-state phase transformation microstructure of Cu-Zn alloy under different high pressure were investigated by means of SEM and XRD. The results show that the α phase with smaller grain size, different shape and random distribution appears in the Cu-Zn alloy, when the solid-state phase transformation generation in the Cu-Zn alloy under 25～750 ℃ and 3～6 GPa high pressure, and the volume fraction of transformation phase decreases with increasing pressure, under high pressure (6 GPa), the changes of microstructure of Cu-Zn alloy is not obvious. In addition, the effect of high pressure on the solid-state phase transformation microstructure of Cu-Zn alloy was discussed.
文摘The nanosized zirconia was synthesized via solid state reaction in the presence of surfactant. The results indicate that crystal phase of zirconia can be controlled by tuning the synthesis parameters such as OH^-/Zr molar ratio, crystallizing temperature and time. It can be transformed among amorphous, tetragonal and monoclinic phases. The transformation is driven by particle size. The research shows the nanocrystalline zirconia possesses the higher thermal stability compared with amorphous framework. The ＂glow exotherm＂ can be observed for the amorphous samples. Otherwise, it is in the absence for nanocrystalline samples. Herein, the reason for retention of tetragonal zirconia is demonstrated.
文摘The isochronal y—m transformation of Fe-ISi alloy was measured by high-resolution dilatometry. According to the variation of the ferrite formation rate, an abnormal y—>a phase transformation was recognized, while normal reaction, i.e. one peak continuous reaction, was also detected. The occurrence the one or the other type of y—?a transformation strongly depends on the grain size: the transformation type changes from abnormal to normal with decreasing grain size. In the abnormal transformation process the first stage of the transformation corresponds to the first peaks in the transformation rate, which are not thermally activated.
基金supported by the Aerospace Science and Technology Innovation Foundation (CASC0202-3)
文摘This paper proposes a modified centralized shifted Rayleigh filter（MCSRF） algorithm for tracking boost phase of ballistic missile（BM） trajectory with a highly nonlinear dynamical model based on bearings-only.This paper contributes three folds.Firstly,the mathematical model of an MCSRF for multiple passive sensors is derived.Then,minimum entropy based onedimensional optimization search to adaptively adjust the probability of the different filters for real time state estimation is deployed.Finally,the unscented transform（UT） is introduced to resolve the asymmetric state estimation problem.Simulation results show that the proposed algorithm can consecutively track the BM precisely during the boost phase.In comparison with the unscented Kalman filter（UKF） algorithm,the proposed algorithm effectively reduces the tracking position and velocity root mean square（RMS） errors,which will make more sense for early precision interception.
文摘The phase-field method has emerged as the method of choice for the description of microstructure evolution and phase transitions in metallic materials.Following general thermodynamic laws a set of evolution equations for the structural variables of the system,the so called phase-fields,are derived.The paper reviews shortly the theoretical background of the multi-phase-field.Different examples demonstrating the applicability of the method to technical steels will be presented ranging from deformation of the dendritic strand shell during peritectic transformation,grain growth in Austenite to stress driven growth of Pearlite.
