This paper presents a study on CO<sub>2</sub> atmospheric transformation which was reacted directly with lithium hydroxide solution and metallic lithium. This solution was obtained through the reaction bet...This paper presents a study on CO<sub>2</sub> atmospheric transformation which was reacted directly with lithium hydroxide solution and metallic lithium. This solution was obtained through the reaction between metallic lithium and deionized water where hydrogen is produced and by exposing the metal at ambient conditions. In the transformation process, atmospheric CO<sub>2</sub> gas reacts directly with LiOH solution, in both cases, the CO<sub>2</sub> transformation kinetics was different. For this purpose, reactions between CO<sub>2</sub> and LiOH solution were carried out under controlled temperature and the second process only with metallic lithium, which was exposed at room temperature, however, in these two processes lithium carbonate oxide was formed and identified. According to the results, the efficiency in CO<sub>2</sub> transformation is a function of temperature value which was variable until completely obtaining the by-product, its XRD characterization indicated the formation only of Li<sub>2</sub>CO<sub>3</sub> in both procedures. Under laboratory conditions lithium compounds selectively reacted with CO<sub>2</sub>. In the same way, there is an alternative procedure to obtain LiOH and Li<sub>2</sub>CO<sub>3</sub> for different applications in various areas.展开更多
Chemical interferences （ionization and oxide/hydroxide formation） on the atomic absorbance signal of lithium in FAAS analysis of brine samples are elaborated in this article. It is suggested that inadequate or overa...Chemical interferences （ionization and oxide/hydroxide formation） on the atomic absorbance signal of lithium in FAAS analysis of brine samples are elaborated in this article. It is suggested that inadequate or overaddition of deionization buffers can lead to loss of sensitivities under particular operating conditions. In the analysis of brine samples, signal enhancing and oxide/hydroxide formation inducing signal reduction resulting from overaddition of deionization buffers can be seen with varying amounts of chemical buffers. Based on experimental results, the authors have arrived at the optimized operating conditions for the detection of lithium, under which both ionization and stable compound formation can be suppressed. This is a simplified and quick method with adequate accuracy and precision for the determination of lithium in routine brine samples from chemical plants or R＆D laboratories, which contain comparable amounts of lithium with some other components.展开更多
AI（OH）3 was prepared to extract lithium ions from calcium chloride-type oil field brine. The influences of four factors, namely temperature, Al3＋/Li＋ molar ratio, OH-/Al3＋ molar ratio, and contact time between AI...AI（OH）3 was prepared to extract lithium ions from calcium chloride-type oil field brine. The influences of four factors, namely temperature, Al3＋/Li＋ molar ratio, OH-/Al3＋ molar ratio, and contact time between AI（OH）3 and the brine, on the yield of lithium ions were investigated. It is found that their optimal values are 35℃, 4.5, 2.6, and 6 h, respectively. In the course of the experiment, the apparent pH value was observed. The results reveal that the apparent pH value has no remarkable influence on the yield of lithium ions. Meanwhile, the effects of the concentrations of calcium ions and magnesium ions in the brine on lithium recovery were studied. The results indicate that cal- cium ions have minor negative influence on the yield of lithium ions under optimal conditions, and magnesium ions slightly influence the yield of lithium ions.展开更多
The tmiform layered Li（Ni2/8Co3/8Mn3/8）O2, Li（Ni3/8Co2/8Mn3/8）O2, and Li（Ni3/8Co3/8Mn2/8）O2 cathode materials for lithium ion batteries were prepared using the hydroxide co-precipitation method. The effects of c...The tmiform layered Li（Ni2/8Co3/8Mn3/8）O2, Li（Ni3/8Co2/8Mn3/8）O2, and Li（Ni3/8Co3/8Mn2/8）O2 cathode materials for lithium ion batteries were prepared using the hydroxide co-precipitation method. The effects of calcination temperature and transition metal contents on the structure and electrochemical properties of the Li-Ni-Co-Mn-O were systemically studied. The results of XRD and electrochemical performance measurement show that the ideal preparation conditions were to prepare the Li（Ni3/8Co3/8Mn2/8）O2 cathode material calcined at 900℃ for 10 h. The well-ordered Li（Ni3/8Co3/8Mn2/8）O2 synthesized under the optimal conditions has the I003/I104 ratio of 1.25 and the R value of 0.48 and delivers the initial discharge capacity of 172.9 mA·h·g^-1, the discharge capacity of 166.2 mA·h·g^-1 after 20 cycles at 0.2C rate, and the impedance of 558 Ω after the first cycle. The decrease of Ni content results in the decrease of discharge capacity and the bad cycling performance of the Li-Ni-Co-Mn-O cathode materials, but the decreases of Mn content and Co content to a certain extent can improve the electrochemical properties of the Li-Ni-Co-Mn-O cathode materials.展开更多
Chemical interferences (ionization and oxide/hydroxide formation) on the atomic absorbance signal of lithium in FAAS analysis of brine samples are elaborated in this article. It is suggested that inadequate or overadd...Chemical interferences (ionization and oxide/hydroxide formation) on the atomic absorbance signal of lithium in FAAS analysis of brine samples are elaborated in this article. It is suggested that inadequate or overaddition of deionization buffers can lead to loss of sensitivities under particular operating conditions. In the analysis of brine samples,signal enhancing and oxide/hydroxide formation inducing signal reduction resulting from overaddition of deionization buffers can be seen with varying amounts of chemical buffers. Based on experimental results,the authors have arrived at the optimized operating conditions for the detection of lithium,under which both ionization and stable compound formation can be suppressed. This is a simplified and quick method with adequate accuracy and precision for the determination of lithium in routine brine samples from chemical plants or R&D laboratories,which contain comparable amounts of lithium with some other components.展开更多
With the growing concerns on global energy crisis and the greenhouse effect,the exploration on renewable energy and related emerging energy conversion and storage technologies are highly interested [1].Lithium sulfur ...With the growing concerns on global energy crisis and the greenhouse effect,the exploration on renewable energy and related emerging energy conversion and storage technologies are highly interested [1].Lithium sulfur (Li–S) battery system receives great attention for its high theoretical specific energy(2600 Wh/kg),which is deemed to be a promising candidate as next generation high energy density batteries [2].展开更多
文摘This paper presents a study on CO<sub>2</sub> atmospheric transformation which was reacted directly with lithium hydroxide solution and metallic lithium. This solution was obtained through the reaction between metallic lithium and deionized water where hydrogen is produced and by exposing the metal at ambient conditions. In the transformation process, atmospheric CO<sub>2</sub> gas reacts directly with LiOH solution, in both cases, the CO<sub>2</sub> transformation kinetics was different. For this purpose, reactions between CO<sub>2</sub> and LiOH solution were carried out under controlled temperature and the second process only with metallic lithium, which was exposed at room temperature, however, in these two processes lithium carbonate oxide was formed and identified. According to the results, the efficiency in CO<sub>2</sub> transformation is a function of temperature value which was variable until completely obtaining the by-product, its XRD characterization indicated the formation only of Li<sub>2</sub>CO<sub>3</sub> in both procedures. Under laboratory conditions lithium compounds selectively reacted with CO<sub>2</sub>. In the same way, there is an alternative procedure to obtain LiOH and Li<sub>2</sub>CO<sub>3</sub> for different applications in various areas.
文摘Chemical interferences （ionization and oxide/hydroxide formation） on the atomic absorbance signal of lithium in FAAS analysis of brine samples are elaborated in this article. It is suggested that inadequate or overaddition of deionization buffers can lead to loss of sensitivities under particular operating conditions. In the analysis of brine samples, signal enhancing and oxide/hydroxide formation inducing signal reduction resulting from overaddition of deionization buffers can be seen with varying amounts of chemical buffers. Based on experimental results, the authors have arrived at the optimized operating conditions for the detection of lithium, under which both ionization and stable compound formation can be suppressed. This is a simplified and quick method with adequate accuracy and precision for the determination of lithium in routine brine samples from chemical plants or R＆D laboratories, which contain comparable amounts of lithium with some other components.
基金supported by the Ministry of Science and Technology of People's Republic of China (No.2006BAB09B07)National Nature Science Foundation of China (No.41073023)Research Project of Science and Technology Department of Qinghai Province, China (No.2010-G-210)
文摘AI（OH）3 was prepared to extract lithium ions from calcium chloride-type oil field brine. The influences of four factors, namely temperature, Al3＋/Li＋ molar ratio, OH-/Al3＋ molar ratio, and contact time between AI（OH）3 and the brine, on the yield of lithium ions were investigated. It is found that their optimal values are 35℃, 4.5, 2.6, and 6 h, respectively. In the course of the experiment, the apparent pH value was observed. The results reveal that the apparent pH value has no remarkable influence on the yield of lithium ions. Meanwhile, the effects of the concentrations of calcium ions and magnesium ions in the brine on lithium recovery were studied. The results indicate that cal- cium ions have minor negative influence on the yield of lithium ions under optimal conditions, and magnesium ions slightly influence the yield of lithium ions.
基金supported by the Natural Science Foundation of Hunan Province, China (No. 07JJ6082)
文摘The tmiform layered Li（Ni2/8Co3/8Mn3/8）O2, Li（Ni3/8Co2/8Mn3/8）O2, and Li（Ni3/8Co3/8Mn2/8）O2 cathode materials for lithium ion batteries were prepared using the hydroxide co-precipitation method. The effects of calcination temperature and transition metal contents on the structure and electrochemical properties of the Li-Ni-Co-Mn-O were systemically studied. The results of XRD and electrochemical performance measurement show that the ideal preparation conditions were to prepare the Li（Ni3/8Co3/8Mn2/8）O2 cathode material calcined at 900℃ for 10 h. The well-ordered Li（Ni3/8Co3/8Mn2/8）O2 synthesized under the optimal conditions has the I003/I104 ratio of 1.25 and the R value of 0.48 and delivers the initial discharge capacity of 172.9 mA·h·g^-1, the discharge capacity of 166.2 mA·h·g^-1 after 20 cycles at 0.2C rate, and the impedance of 558 Ω after the first cycle. The decrease of Ni content results in the decrease of discharge capacity and the bad cycling performance of the Li-Ni-Co-Mn-O cathode materials, but the decreases of Mn content and Co content to a certain extent can improve the electrochemical properties of the Li-Ni-Co-Mn-O cathode materials.
文摘Chemical interferences (ionization and oxide/hydroxide formation) on the atomic absorbance signal of lithium in FAAS analysis of brine samples are elaborated in this article. It is suggested that inadequate or overaddition of deionization buffers can lead to loss of sensitivities under particular operating conditions. In the analysis of brine samples,signal enhancing and oxide/hydroxide formation inducing signal reduction resulting from overaddition of deionization buffers can be seen with varying amounts of chemical buffers. Based on experimental results,the authors have arrived at the optimized operating conditions for the detection of lithium,under which both ionization and stable compound formation can be suppressed. This is a simplified and quick method with adequate accuracy and precision for the determination of lithium in routine brine samples from chemical plants or R&D laboratories,which contain comparable amounts of lithium with some other components.
基金supported by the National Key Research and Development Program (No.2016YFA0202500)CAS Key Laboratory of Carbon Materials (No.KLCMKFJJ1701)
文摘With the growing concerns on global energy crisis and the greenhouse effect,the exploration on renewable energy and related emerging energy conversion and storage technologies are highly interested [1].Lithium sulfur (Li–S) battery system receives great attention for its high theoretical specific energy(2600 Wh/kg),which is deemed to be a promising candidate as next generation high energy density batteries [2].
基金the financial supports from the National Natural Science Foundation of China(Nos.51704011,51904003)the Joint Funds of the National Natural Science Foundation of China(No.U1703130)。
