Slurry-like hybrid electrolyte with high lithium-ion transference number for dendrite-free lithium metal anode

Lithium metal anode is regarded as the ultimate choice for next-generation energy storage systems,due to the lowest negative electrochemical potential and super high theoretical specific capacity.However,the growth of lithium dendrite during the cycling process is still one of the most critical bottlenecks for its application.In this work,a slurry-like hybrid electrolyte is proposed towards the application for lithium metal anode,which is composed of a liquid electrolyte part and a nanometric silane-Al2O3 particle part.The hybrid electrolyte shows high ionic conductivity(3.89×10-3 S cm-1 at 25℃)and lithium-ion transference number(0.88).Especially,the resistance of hybrid electrolyte decreases compared to that of liquid electrolyte,while the viscosity of hybrid electrolyte increases.It is demonstrated that the hybrid electrolyte can effectively suppress the growth of lithium dendrite.Stable cycling of Li/Li cells at a current density up to 1 mA cm-2 is possible.The hybrid electrolyte helps to uniform the lithium ion flux inside the battery and partly comes from the formation of a rigid and highly conductive hybrid interfacial layer on the surface of lithium metal.This work not only provides a fresh way to stabilize lithium metal anode but also sheds light on further research for electrolyte optimization and design of lithium metal battery system.

Thermal runaway evolution of a 280 Ah lithium-ion battery with LiFePO_(4) as the cathode for different heat transfer modes constructed by mechanical abuse

Lithium iron phosphate batteries have been increasingly utilized in recent years because their higher safety performance can improve the increasing trend of recurring thermal runaway accidents.However,the safety performance and mechanism of high-capacity lithium iron phosphate batteries under internal short-circuit challenges remain to be explored.This work analyzes the thermal runaway evolution of high-capacity LiFePO_(4) batteries under different internal heat transfer modes,which are controlled by different penetration modes.Two penetration cases involving complete penetration and incomplete penetration were detected during the test,and two modes were performed incorporating nails that either remained or were removed after penetration to comprehensively reveal the thermal runaway mechanism.A theoretical model of microcircuits and internal heat conduction is also established.The results indicated three thermal runaway evolution processes for high-capacity batteries,which corresponded to the experimental results of thermal equilibrium,single thermal runaway,and two thermal runaway events.The difference in heat distribution in the three phenomena is determined based on the microstructure and material structure near the pinhole.By controlling the heat dissipation conditions,the time interval between two thermal runaway events can be delayed from 558 to 1417 s,accompanied by a decrease in the concentration of in-situ gas production during the second thermal runaway event.

The Transference Number

The performance of rechargeable batteries and other electrochemical systems depends on the rate at which the working ion(often a cation)is transported from one electrode to the other.The cation transference number is an important transport parameter that affects this rate.The purpose of this perspective is to distinguish between approximate and rigorous methods used in the literature to measure the transference number.We emphasize the fact that this parameter is dependent on the reference frame used in the analysis;care must be taken when comparing values obtained from different sources to account for differences in reference frames.We present data obtained from a well-characterized electrolyte.We compare rigorously determined transference numbers in two reference frames with values obtained by an approximate method.We conclude with a qualitative discussion of the relationship between the transference number and salt concentration gradients that are obtained when current is drawn through a battery。

Nusselt number correlation for turbulent heat transfer of helium-xenon gas mixtures

A gas-cooled nuclear reactor combined with a Brayton cycle shows promise as a technology for highpower space nuclear power systems.Generally,a helium-xenon gas mixture with a molecular weight of14.5-40.0 g/mol is adopted as the working fluid to reduce the mass and volume of the turbomachinery.The Prandtl number for helium-xenon mixtures with this recommended mixing ratio may be as low as 0.2.As the convective heat transfer is closely related to the Prandtl number,different heat transfer correlations are often needed for fluids with various Prandtl numbers.Previous studies have established heat transfer correlations for fluids with medium-high Prandtl numbers(such as air and water)and extremely lowPrandtl fluids(such as liquid metals);however,these correlations cannot be directly recommended for such helium-xenon mixtures without verification.This study initially assessed the applicability of existing Nusselt number correlations,finding that the selected correlations are unsuitable for helium-xenon mixtures.To establish a more general heat transfer correlation,a theoretical derivation was conducted using the turbulent boundary layer theory.Numerical simulations of turbulent heat transfer for helium-xenon mixtures were carried out using Ansys Fluent.Based on simulated results,the parameters in the derived heat transfer correlation are determined.It is found that calculations using the new correlation were in good agreement with the experimental data,verifying its applicability to the turbulent heat transfer for helium-xenon mixtures.The effect of variable gas properties on turbulent heat transfer was also analyzed,and a modified heat transfer correlation with the temperature ratio was established.Based on the working conditions adopted in this study,the numerical error of the property-variable heat transfer correlation was almost within 10%.

Collisional Quantum Interference on Rotational Energy Transfer： Relation Between Integral Interference Angle and Rotational Quantum Number in Na2（A^1∑u^＋,ν=8～b^3∏0u,ν=14）-Na System

Collisional quantum interference （CQI） on rotational energy transfer was observed in Na2（A^1∑u^＋,ν=8～b^3∏0u,ν=14） system in collision with Na [Chem. Phys. Lett. 318 （2000） 107], and the degree of the interference was measured. The integral interference angle was obtaJned through theoretical calculation. We will research the factors that have effect on collisional quantum interference on rotational energy transfer in Na2（A^1∑u^＋,ν=8～b^3∏0u,ν=14）-Na system. Basing on the time-dependent first order Born approximation, and taking into account the anlsotroplc Lennard Jones interaction potentials and ＂straight-line＂ trajectory approximation, we obtain the factors that have effect on CQI in Na2-Na system, and obtain the relation between the integral interference angle and rotational quantum number.

Hydrogen-bonded organic framework modified separator for simultaneously enhancing the safety and electrochemical performance of Ni-rich lithium-ion battery

Nickel-rich layered oxide cathode(LiNi_(x)Co_(y)Mn_(1−x−y)O_(2),x>0.5,NCM)shows substantial potential for applications in longer-range electrical vehicles.However,the rapid capacity decay and serious safety concerns impede its practical viability.This work provides a hydrogen-bonded organic framework(HOF)modification strategy to simultaneously improve the electrochemical performance,thermal stability and incombustibility of separator.Melamine cyanurate(MCA),as a low-cost and reliable flame-retardant HOF,was implemented in the separator modification layer,which can prevent the battery short circuit even at a high temperature.In addition,the supermolecule properties of MCA provide unique physical and chemical microenvironment for regulating ion-transport behavior in electrolyte.The MCA coating layer enabled the nickel-rich layered oxide cathode with a high-capacity retention of 90.3%after 300 cycles at 1.0 C.Collectively,the usage of MCA in lithium-ion batteries(LIBs)affords a simple,low-cost and efficient strategy to improve the security and service life of nickel-rich layered cathodes.

Relationship between lower number of oocytes retrieved and clinical outcomes of in vitro fertilization-embryo transfer

Objective:To explore the clinical outcomes of the infertile women with retrieved oocytes less than or equal to 5 undergoing in vitro fertilization-embryo transfer（IVF-ET） or intracytoplasmic sperm injection（1CSI）. Methods:The clinical data of 216 embryo transfer cycles with retrieved oocytes less than or equal to 5 during the procedure of IVF/ICSI in Reproductive Medicine Center of the 105th Hospital of PLA from Jul.2008 to Dec.2011 were analyze retrospectively.All the patients were divided into group A（< 35 years）,group B（35-39 years） and group C（≥40 years） according to the ages,and 409 IVF/ICSI cycles with patients’ age less than 35 years old and 6-15 retrieved oocytes in the same period were served as controlled group.Then the patients≥35 years were subdivided into gonadotropin-releasing hormone agonist（GnRH-a） long protocol group,GnRH-a short group and GnRH antagonist group according to the protocols of controlled ovarian hyperstimulation（COH）.The clinical date and the outcomes were analyzed and compared among all groups. Results:There were significantly differences in clinical pregnancy rate（38.3%vs.19.4%） and early abortion rate（16.1%vs.50.0%） between group A and group C（P<0.05）,and there were no significant differences in clinical pregnancy rate（38.3%vs.41.6%）and early abortion rate（16.1%vs.10.0%） between group A and control group（P>0.05）.There were no significant differences in clinical pregnancy rates（29.01%vs.26.1%vs.25.9%） and early abortion rates（33.3%vs.33.3%vs.40.0%） among GnRH-a long protocol group,GnRH-a short group and GnRH antagonist group（P>0.05）. Conclusions:Relatively satisfactory clinical outcomes of IVF/ICSI would still be got for the patients <35 years with retrieved oocytes less than or equal to 5,but whatever COH protocols such as GnRH-a long protocol,GnRH-a short and GnRH antagonist could not improve the outcomes of IVF/ICSI for the patients aged≥35 with retrieved oocytes less than or equal to 5.

Numerical Investigation on Flow and Heat Transfer Performance of Supercritical Carbon Dioxide Based on Variable Turbulent Prandtlnumber Model

Flow and heat transfer characteristic of supercritical carbon dioxide(SCO_(2))are numerically investigated in the horizontal and vertical tubes.TWL turbulent Prandtl number model could well describe the behavior of SCO_(2) affected by the buoyancy.Under the cooling condition,the heat transfer performance of SCO_(2) along the upward direction is best and that along the downward direction is worst when bulk fluid temperatures are below the pseudocritical temperature.Reducing the ratio of heat flux to mass flux could decrease the difference of convective heat transfer coefficient in three flow directions.Under the heating condition,heat transfer deterioration only occurs in vertical upward and horizontal flow directions.Heat transfer deterioration of SCO_(2) could be delayed by increasing the mass flux and the deterioration degree is weakened in the second half of tube along the vertical upward flow direction.Compared with the straight tube,the corrugated tube shows better comprehensive thermal performance.

Bidirectional transfer of quantum information for unknown photons via cross-Kerr nonlinearity and photon-number-resolving measurement

We propose an arbitrary controlled-unitary （CU） gate and a bidirectional transfer scheme of quantum information （BTQI） for unknown photons. The proposed CU gate utilizes quantum non-demolition photon-number-resolving measure- ment based on the weak cross-Kerr nonlinearities （XKNLs） and two quantum bus beams; the proposed CU gate consists of consecutive operations of a controlled-path gate and a gathering-path gate. It is almost deterministic and is feasible with current technology when a strong amplitude of the coherent state and weak XKNLs are employed. Compared with the existing optical multi-qubit or controlled gates, which utilize XKNLs and homodyne detectors, the proposed CU gate can increase experimental realization feasibility and enhance robustness against decoherence. According to the CU gate, we present a BTQI scheme in which the two unknown states of photons between two parties （Alice and Bob） are mutually swapped by transferring only a single photon. Consequently, by using the proposed CU gate, it is possible to experimentally implement the BTQI scheme with a certain probability of success.

Comparative Numerical Analysis of Heat and Mass Transfer Characteristics in Sisko Al_(2)O_(3)-Eg and TiO_(2)-Eg Fluids on a Stretched Surface

In the current research,a thorough examination unfolds concerning the attributes of magnetohydrodynamic(MHD)boundary layer flow and heat transfer inherent to nanoliquids derived from Sisko Al_(2)O_(3)-Eg and TiO_(2)-Eg compositions.Such nanoliquids are subjected to an extending surface.Consideration is duly given to slip boundary conditions,as well as the effects stemming from variable viscosity and variable thermal conductivity.The analytical approach applied involves the application of suitable similarity transformations.These conversions serve to transform the initial set of complex nonlinear partial differential equations into a more manageable assembly of ordinary differential equations.Through the utilization of the FEM,these reformulated equations are solved,considering the specified boundary conditions.The outcomes attained are graphically depicted by means of plots and tables.These visual aids facilitate a comprehensive exploration of how diverse parameters exert influence over the distributions of velocity,temperature,and concentration.Furthermore,detailed scrutiny is directed towards the fluctuations characterizing pivotal parameters,viz.,Nusselt number,skin-friction coefficient,and Sherwood number.It is identified that the Nusselt number showcases a diminishing trend coinciding with increasing values of the volume fraction parameter(φ).This trend remains consistent regardless of whether the nanoliquid under consideration is Al_(2)O_(3)-Eg or TiO_(2)-Eg based.In contrast,both the skin-friction coefficient and Sherwood number assume lower values as the volume fraction parameter(φ)escalates.This pattern remains congruent across both classifications of nanoliquids.The findings of the study impart valuable insights into the complex interplay governing the characteristics of HMT pertaining to Sisko Al_(2)O_(3)-Eg and TiO_(2)-Eg nanoliquids along an extending surface.

THEORETICAL INVESTIGATION ON HEAT TRANSFER CHARACTERISTICS WITH ROTATING THERMAL SOURCE

By reduction to one dimensional, periodic as well as rotating pulse heat sources, investigation on heat transfer characteristics with rotating body is carried out. Similar to the fluid flow, a new set of dimensionless numbers, namely quasi-Peclet numbers Pe 1, Pe 2 and Biot number Bi composed of angular velocity ω , thermophysical parameter, and geometry size are proposed, and applied to the dimensionless equations. Simulation result shows that it plays a decisive role in the process of the heat transfer. However, more important is that the numerical simulation depicts the difference between microcosmic and macroscopic structures of the temperature distribution, and reveals the influence of the relative relation of the dimensionless criterion numbers upon heat transfer characteristics.

Experimental mass transfer coefficients in a pilot plant multistage column extractor

The volumetric overall mass transfer coefficients in a multistage column have been measured using axial dispersion model for toluene–acetone–water system. The effect of operating parameters on the volumetric overall mass transfer coefficients has been investigated for both mass transfer directions. The results show that the mass transfer performance is strongly dependent on rotor speed and mass transfer direction, although only slightly dependent on phase flow rates. In addition, empirical correlations to predict the overall mass transfer coefficients have been developed. The proposed correlations based on dimensionless numbers can be considered as a useful tool for the possible scale up of the multistage column extractor.

Determination of Mass Transfer Parameters During Deep Fat Frying of Rice Crackers

The accuracy of the knowledge of mass transfer parameters （effective moisture diffusivity, mass transfer Biot number and mass transfer coefficient） in the case of frying food, is essential and important for designing, modeling and process optimization. This study is undertaken to develop an approach for determining mass transfer parameters during frying of spherical rice cracker in sunflower oil at 150, 170 and 190 ℃. These parameters were evaluated from the plots of dimensionless concentration ratios against time of frying. Effective moisture diffusivity, mass transfer Biot number and mass transfer coefficient ranged between 1.24×10^-8 to 2.36×10^-8 m^2/s, 1.96 to 2.34 and 5.51×10^-6 to 9.70×10^-6 m/s, respectively. Effective moisture diffusivity and mass transfer coefficient were found to increase with an increasing frying temperature, whereas mass transfer Biot number decreased. An Arrhenius-type relationship was found between effective diffusivity coefficient and frying temperature.

Experimental and CFD Heat Transfer Studies of Al2Oa-Water Nanofluid in a Coiled Agitated Vessel Equipped with Propeller

This paper presents the heat transfer characteristics of A1203-water nanofluid in a coiled agitated vessel with propeller agitator. The experimental study was conducted using 0.10%, 0.20% and 0.30% volume concentra tion of A1203-water nanofluids. The results showed considerable enhancement of convective heat transfer using the nanofluids. The empirical correlations developed for Nusselt number in terms of Reynolds number, Prandtl number, viscosity ratio and volume concentration fit with the experimental data within ±10%. The heat transfer characteris tics were also simulated using computational fluid dynamics using FLUENT software with the standard ke model and multiple reference frame were adopted. The computational fluid dynamics （CFD） predicted Nusselt number agrees well with the experimental value and the discrepancy is found to be less than ＋8%.

Strategies for Rational Design of High-Power Lithium-ion Batteries

Lithium-ion batteries(LIBs)have shown considerable promise as an energy storage system due to their high conversion efficiency,size options(from coin cell to grid storage),and free of gaseous exhaust.For LIBs,power density and energy density are two of the most important parameters for their practical use,and the power density is the key factor for applications such as fast-charging electric vehicles,high-power portable tools,and power grid stabilization.A high rate of performance is also required for devices that store electrical energy from seasonal or irregular energy sources,such as wind energy and wave energy.Significant efforts have been made over the last several years to improve the power density of LIBs through anodes,cathodes,and electrolytes,and much progress has been made.To provide a comprehensive picture of these recent achievements,this review discusses the progress made in high-power LIBs from 2013 to the present,including general and fundamental principles of high-power LIBs,challenges facing LIB development today,and an outlook for future LIB development.

Blockage effects on viscous fluid flow and heat transfer past a magnetic obstacle in a duct

The effect of lateral walls on fluid flow and heat transfer is investigated when a fluid passes a magnetic obstacle. The blockage ratio β that represents the ratio between the width of external magnet M y and the spanwise width L y is employed to depict the effect. The finite volume method （FVM） based on the PISO algorithm is applied for the blockage ratios of 0.2, 0.3, and 0.4. The results show that the value of Strouhal number St increases as the blockage ratio β increases, and for small β , the variation of St is very small when the interaction parameter and Reynolds number are increasing. Moreover, the cross-stream mixing induced by the magnetic obstacle can enhance the wall-heat transfer and the maximum value of the overall heat transfer increment is about 50.5%.

Heat Transfer and Flow Characteristics Predictions with a Refined k-ε-f_u Turbulent Model in Impinging Jet

Local heat transfer and flow characteristics in a round turbulent impinging jet for Re≈23 000 is predicted numerically with the RANS approach and a k-ε-fu turbulence model. The heat transfer predictions and turbulence parameters are verified against the axis-symmetric free jet impingement measurements and compared with previous other turbulence models, and results show the k-ε-fu model has a good performance in predictions of the local wall heat transfer coefficient, and in agreement with measurements in mean velocity profiles at different radial positions as well. The numerical model is further used to examine the effect of the fully confined impingement jet on the local Nusselt number. Local Nusselt profiles in x and y-centerlines for the target plate over three separation distances are predicted. Compared with the experimental data, the numerical results are accurate in the central domain around the stagnation region and present a consistent structure distribution.

Transfer kinetics of phenol between aqueous phase and N,N-di(1-methyl-heptyl) acetamide in kerosene

The transfer kinetics of phenol between aqueous phase and N,N di(methyl heptyl) acetaminde (N503) in kerosene has been studied using Lewis cell technique. The effects of the factors including the concentrations of phenol in aqueous phase and organic phase, the concentration of N503 in organic phase, the acidity of aqueous phase, the stirring speed and the temperature on the rates of forward and backward extraction of phenol have been examined. The regularity of extraction rate has been obtained. According to experimental results, the rates of both forward and backward extraction of phenol might be controlled by diffusion process. The diffusion step of phenol from aqueous phase to interface for forward extraction and from interface to aqueous phase for backward extraction might be the rate controlling steps.

Redox-assisted Li^+-storage in lithium-ion batteries

Interfacial charge transfer is the key kinetic process dictating the operation of lithium-ion battery. Redox-mediated charge propagations of the electronic （e- and h＋ ） and ionic species （Li＋） at the electrode-electrolyte interface have recently gained increasing attention for better exploitation of battery materials. This article briefly summarises the energetic and kinetic aspects of lithium-ion batteries, and reviews the recent progress on various redox-assisted Li＋ storage approaches. From molecular wiring to polymer wiring and from redox targeting to redox flow lithium battery, the role of redox mediators and the way of the redox species functioning in lithium-ion batteries are discussed.

Estimating the State of Health for Lithium-ion Batteries:A Particle Swarm Optimization-Assisted Deep Domain Adaptation Approach

The state of health(SOH)is a critical factor in evaluating the performance of the lithium-ion batteries(LIBs).Due to various end-user behaviors,the LIBs exhibit different degradation modes,which makes it challenging to estimate the SOHs in a personalized way.In this article,we present a novel particle swarm optimization-assisted deep domain adaptation(PSO-DDA)method to estimate the SOH of LIBs in a personalized manner,where a new domain adaptation strategy is put forward to reduce cross-domain distribution discrepancy.The standard PSO algorithm is exploited to automatically adjust the chosen hyperparameters of developed DDA-based method.The proposed PSODDA method is validated by extensive experiments on two LIB datasets with different battery chemistry materials,ambient temperatures and charge-discharge configurations.Experimental results indicate that the proposed PSO-DDA method surpasses the convolutional neural network-based method and the standard DDA-based method.The Py Torch implementation of the proposed PSO-DDA method is available at https://github.com/mxt0607/PSO-DDA.