This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_...This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite batteries.After 450 cycles at room temperature(25℃),the discharge capacity retentions of batteries with blank and PHIS-containing electrolyte are 56.03%and 94.92%respectively.After 230 cycles at high temperatures(45℃),their values are 75.30%and 88.38%respectively.The enhanced electrochemical performance of the batteries with PHIS-containing electrolyte is supported by the spectroscopic characterization and theoretical calculations.It is demonstrated that this PHIS electrolyte additive can facilitate the construction of the electrode interface films,remove the H2O/HF in the electrolyte,and improve the electrochemical performance of the batteries.This work not only develops a sulfonate-based electrolyte but also can stimulate new ideas of functional additives to improve the battery performance.展开更多
With the emergence of some solid electrolytes(SSEs)with high ionic conductivity being comparable to liquid electrolytes,solid-state lithium-sulfur batteries(SSLSBs)have been widely regarded as one of the most promisin...With the emergence of some solid electrolytes(SSEs)with high ionic conductivity being comparable to liquid electrolytes,solid-state lithium-sulfur batteries(SSLSBs)have been widely regarded as one of the most promising candidates for the next generation of power generation energy storage batteries,and have been extensively researched.Though many fundamental and technological issues still need to be resolved to develop commercially viable technologies,SSLSBs using SSEs are expected to address the present limitations and achieve high energy and power density while improving safety,which is very attractive to large-scale energy storage systems.SSLSBs have been developed for many years.However,there are few systematic discussions related to the working mechanism of action of various electrolytes in SSLSBs and the defects and the corresponding solutions of various electrolytes.To fill this gap,it is very meaningful to review the recent progress of SSEs in SSLSBs.In this review,we comprehensively investigate and summarize the application of SSEs in LSBs to determine the differences which still exist between current progresses and real-world requirements,and comprehensively describe the mechanism of action of SSLSBs,including lithium-ion transport,interfacial contact,and catalytic conversion mechanisms.More importantly,the selection of solid electrolyte materials and the novel design of structures are reviewed and the properties of various SSEs are elucidated.Finally,the prospects and possible future research directions of SSLSBs including designing high electronic/ionic conductivity for cathodes,optimizing electrolytes and developing novel electrolytes with excellent properties,improving electrode/-electrolyte interface stability and enhancing interfacial dynamics between electrolyte and anode,using more advanced test equipment and characterization techniques to analyze conduction mechanism of Li^(+)in SSEs are presented.It is hoped that this review can arouse people’s attention and enlighten the development of functional materials and novel structures of SSEs in the next step.展开更多
Lithium-sulfur(Li-S)battery is one of the promising high-energy battery systems for future use.However,the shuttle effect due to the dissolved lithium polysulfides in ether electrolyte hampers its practical applicatio...Lithium-sulfur(Li-S)battery is one of the promising high-energy battery systems for future use.However,the shuttle effect due to the dissolved lithium polysulfides in ether electrolyte hampers its practical application.Applying electrolyte additives in Li-S battery has been widely acknowledged as an effective way to reduce the shuttle effect and improve cycling efficiency.In this work,benzoselenol(PhSeH)is used as an organic electrolyte additive in Li-S battery.It reacts with elemental sulfur to form phenyl selenosulfide,altering the redox pathway of the cathode with the regeneration of S8 at the end of charge and enabling new redox reactions with high reversibility.The Li-S coin cell with an optimized amount of PhSeH in the electrolyte delivers a high discharge capacity of 1,436 mAh·g^(−1)and a capacity retention of 92.86%in 200 cycles,and exhibits lower discharge overpotential in comparison to the cell with blank electrolyte.The Li-S pouch cell with a low electrolyte/sulfur(E/S)ratio of 4.0μL·mg^(−1)shows a discharge capacity of 1,398 mAh and excellent capacity retention for 20 cycles.展开更多
Sodium-ion battery is a potential application system for large-scale energy storage due to the advantage of higher nature abundance and lower production cost of sodium-based materials.However,there exist inevitably th...Sodium-ion battery is a potential application system for large-scale energy storage due to the advantage of higher nature abundance and lower production cost of sodium-based materials.However,there exist inevitably the safety problems such as flammability due to the use of the same type of organic liquid electrolyte with lithium-ion battery.Gel polymer electrolytes are being considered as an effective solution to replace conventional organic liquid electrolytes for building safer sodium-ion batteries.In this review paper,the authors present a comprehensive overview of the research progress in electrochemical and physical properties of the gel polymer electrolyte-based sodium batteries.The gel polymer electrolytes based on different polymer hosts namely poly(ethylene oxide),poly(acrylonitrile),poly(methyl methacrylate),poly(vinylidene fluoride),poly(vinylidene fluoride-hexafluoro propylene),and other new polymer networks are summarized.The ionic conductivity,ion transference number,electrochemical window,thermal stability,mechanical property,and interfacial issue with electrodes of gel polymer electrolytes,and the corresponding influence factors are described in detail.Furthermore,the ion transport pathway and ion conduction mechanism are analyzed and discussed.In addition,the advanced gel polymer electrolyte systems including flame-retardant polymer electrolytes,composite gel polymer electrolytes,copolymerization,single-ion conducting polymer electrolytes,etc.with more superior and functional performance are classified and summarized.Finally,the application prospects,development opportunities,remaining challenges,and possible solutions are discussed.展开更多
The construction of stable cathode electrolyte interphase(CEI)is the key to improve the NCM811 particle structure and interfacial stability via electrolyte engineering.In He’s work,lithium hexamethyldisilazide(LiHMDS...The construction of stable cathode electrolyte interphase(CEI)is the key to improve the NCM811 particle structure and interfacial stability via electrolyte engineering.In He’s work,lithium hexamethyldisilazide(LiHMDS)as the electrolyte additive is proposed to facilitate the generation of stable CEI on NCM811 cathode surface and eliminate H_(2)O and HF in the electrolyte at the same time,which boosts the cycling performance of Li||NCM811 battery up to 1000 or 500 cycles with 4.5 V cut-off voltage at 25 or 60℃.展开更多
因钠储量丰富和相对价格便宜,钠离子电池(SIBs)已明确为大规模储能的首选电化学器件,其中电解液是SIBs的重要组成部分.众所周知,传统碳酸酯类电解液的挥发性和易燃性,对电池的安全性能产生重大的影响.因此,开发高安全性的电解液已成为...因钠储量丰富和相对价格便宜,钠离子电池(SIBs)已明确为大规模储能的首选电化学器件,其中电解液是SIBs的重要组成部分.众所周知,传统碳酸酯类电解液的挥发性和易燃性,对电池的安全性能产生重大的影响.因此,开发高安全性的电解液已成为钠离子电池领域重点研究方向之一.本工作提出使用1-(2,2,2-三氟乙基)-1,1,2,2-四氟乙基醚(TTE)桥接全氟阻燃添加剂全氟丁基硫酰氟(PFSF)和碳酸酯基电解液提升电解液的阻燃性能,同时有效提升了正极材料Na3V2(PO4)3(NVP@rGO)的电化学性能.高度氟化的电解液可在充放电过程中在正负极表面构建致密均匀的保护层,使用电解液1.0 M NaTFSI+碳酸丙烯酯(PC)/氟代碳酸乙烯酯(FEC)/TTE(3/3/4,V)+0.5%(体积分数)PFSF的Na/NVP@rGO半电池在200次循环后的容量保持率可维持在88.0%,明显优于传统碳酸酯基电解液,这为安全型钠离子电池的设计提供新思路.展开更多
基金financially supported by the Scientific and Technological Plan Projects of Guangzhou City(202103040001)。
文摘This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite batteries.After 450 cycles at room temperature(25℃),the discharge capacity retentions of batteries with blank and PHIS-containing electrolyte are 56.03%and 94.92%respectively.After 230 cycles at high temperatures(45℃),their values are 75.30%and 88.38%respectively.The enhanced electrochemical performance of the batteries with PHIS-containing electrolyte is supported by the spectroscopic characterization and theoretical calculations.It is demonstrated that this PHIS electrolyte additive can facilitate the construction of the electrode interface films,remove the H2O/HF in the electrolyte,and improve the electrochemical performance of the batteries.This work not only develops a sulfonate-based electrolyte but also can stimulate new ideas of functional additives to improve the battery performance.
基金supported by the National Natural Science Foundation of China(52203066,51973157,51673148,51678411)the Science and Technology Plans of Tianjin,China(19PTSYJC00010)+3 种基金the China Postdoctoral Science Foundation Grant(2019M651047)the Tianjin Research Innovation Project for Postgraduate Students,China(2020YJSB062)the Tianjin Municipal college student’innovation and entrepreneurship training program,China(202110058052)the National innovation and entrepreneurship training program for college students,China(202110058017)。
文摘With the emergence of some solid electrolytes(SSEs)with high ionic conductivity being comparable to liquid electrolytes,solid-state lithium-sulfur batteries(SSLSBs)have been widely regarded as one of the most promising candidates for the next generation of power generation energy storage batteries,and have been extensively researched.Though many fundamental and technological issues still need to be resolved to develop commercially viable technologies,SSLSBs using SSEs are expected to address the present limitations and achieve high energy and power density while improving safety,which is very attractive to large-scale energy storage systems.SSLSBs have been developed for many years.However,there are few systematic discussions related to the working mechanism of action of various electrolytes in SSLSBs and the defects and the corresponding solutions of various electrolytes.To fill this gap,it is very meaningful to review the recent progress of SSEs in SSLSBs.In this review,we comprehensively investigate and summarize the application of SSEs in LSBs to determine the differences which still exist between current progresses and real-world requirements,and comprehensively describe the mechanism of action of SSLSBs,including lithium-ion transport,interfacial contact,and catalytic conversion mechanisms.More importantly,the selection of solid electrolyte materials and the novel design of structures are reviewed and the properties of various SSEs are elucidated.Finally,the prospects and possible future research directions of SSLSBs including designing high electronic/ionic conductivity for cathodes,optimizing electrolytes and developing novel electrolytes with excellent properties,improving electrode/-electrolyte interface stability and enhancing interfacial dynamics between electrolyte and anode,using more advanced test equipment and characterization techniques to analyze conduction mechanism of Li^(+)in SSEs are presented.It is hoped that this review can arouse people’s attention and enlighten the development of functional materials and novel structures of SSEs in the next step.
基金supported by the National Natural Science Foundation of China(Nos.22179120 and U2004214)and Zhengzhou University.
文摘Lithium-sulfur(Li-S)battery is one of the promising high-energy battery systems for future use.However,the shuttle effect due to the dissolved lithium polysulfides in ether electrolyte hampers its practical application.Applying electrolyte additives in Li-S battery has been widely acknowledged as an effective way to reduce the shuttle effect and improve cycling efficiency.In this work,benzoselenol(PhSeH)is used as an organic electrolyte additive in Li-S battery.It reacts with elemental sulfur to form phenyl selenosulfide,altering the redox pathway of the cathode with the regeneration of S8 at the end of charge and enabling new redox reactions with high reversibility.The Li-S coin cell with an optimized amount of PhSeH in the electrolyte delivers a high discharge capacity of 1,436 mAh·g^(−1)and a capacity retention of 92.86%in 200 cycles,and exhibits lower discharge overpotential in comparison to the cell with blank electrolyte.The Li-S pouch cell with a low electrolyte/sulfur(E/S)ratio of 4.0μL·mg^(−1)shows a discharge capacity of 1,398 mAh and excellent capacity retention for 20 cycles.
基金supported by the National Natural Science Foundation of China(Nos.21771164,U1804129)the Natural Science Foundation of Henan Province(No.222300420525)the Zhongyuan Youth Talent Support Program of Henan Province
文摘Sodium-ion battery is a potential application system for large-scale energy storage due to the advantage of higher nature abundance and lower production cost of sodium-based materials.However,there exist inevitably the safety problems such as flammability due to the use of the same type of organic liquid electrolyte with lithium-ion battery.Gel polymer electrolytes are being considered as an effective solution to replace conventional organic liquid electrolytes for building safer sodium-ion batteries.In this review paper,the authors present a comprehensive overview of the research progress in electrochemical and physical properties of the gel polymer electrolyte-based sodium batteries.The gel polymer electrolytes based on different polymer hosts namely poly(ethylene oxide),poly(acrylonitrile),poly(methyl methacrylate),poly(vinylidene fluoride),poly(vinylidene fluoride-hexafluoro propylene),and other new polymer networks are summarized.The ionic conductivity,ion transference number,electrochemical window,thermal stability,mechanical property,and interfacial issue with electrodes of gel polymer electrolytes,and the corresponding influence factors are described in detail.Furthermore,the ion transport pathway and ion conduction mechanism are analyzed and discussed.In addition,the advanced gel polymer electrolyte systems including flame-retardant polymer electrolytes,composite gel polymer electrolytes,copolymerization,single-ion conducting polymer electrolytes,etc.with more superior and functional performance are classified and summarized.Finally,the application prospects,development opportunities,remaining challenges,and possible solutions are discussed.
基金the support from the National Natural Science Foundation of China(Grant No.51971090 and U21A20311)。
文摘The construction of stable cathode electrolyte interphase(CEI)is the key to improve the NCM811 particle structure and interfacial stability via electrolyte engineering.In He’s work,lithium hexamethyldisilazide(LiHMDS)as the electrolyte additive is proposed to facilitate the generation of stable CEI on NCM811 cathode surface and eliminate H_(2)O and HF in the electrolyte at the same time,which boosts the cycling performance of Li||NCM811 battery up to 1000 or 500 cycles with 4.5 V cut-off voltage at 25 or 60℃.
文摘因钠储量丰富和相对价格便宜,钠离子电池(SIBs)已明确为大规模储能的首选电化学器件,其中电解液是SIBs的重要组成部分.众所周知,传统碳酸酯类电解液的挥发性和易燃性,对电池的安全性能产生重大的影响.因此,开发高安全性的电解液已成为钠离子电池领域重点研究方向之一.本工作提出使用1-(2,2,2-三氟乙基)-1,1,2,2-四氟乙基醚(TTE)桥接全氟阻燃添加剂全氟丁基硫酰氟(PFSF)和碳酸酯基电解液提升电解液的阻燃性能,同时有效提升了正极材料Na3V2(PO4)3(NVP@rGO)的电化学性能.高度氟化的电解液可在充放电过程中在正负极表面构建致密均匀的保护层,使用电解液1.0 M NaTFSI+碳酸丙烯酯(PC)/氟代碳酸乙烯酯(FEC)/TTE(3/3/4,V)+0.5%(体积分数)PFSF的Na/NVP@rGO半电池在200次循环后的容量保持率可维持在88.0%,明显优于传统碳酸酯基电解液,这为安全型钠离子电池的设计提供新思路.