Micro-macro evolution of mechanical behaviors of thermally damaged rock:A state-of-the-art review

The influence of thermal damage on macroscopic and microscopic characteristics of different rocks has received much attention in the field of rock engineering.When the rocks are subjected to thermal treatment,the change of macroscopic characteristics and evolution of micro-structure would be induced,ultimately resulting in different degrees of thermal damage in rocks.To better understand the thermal damage mechanism of different rocks and its effect on the rock performance,this study reviews a large number of test results of rock specimens experiencing heating and cooling treatment in the laboratory.Firstly,the variations of macroscopic behaviors,including physical parameters,mechanical parameters,thermal conductivity and permeability,are examined.The variations of mechanical parameters with thermal treatment variables(i.e.temperature or the number of thermal cycles)are divided into four types.Secondly,several measuring methods for microstructure,such as polarizing microscopy,fluorescent method,scanning electron microscopy(SEM),X-ray computerized tomography(CT),acoustic emission(AE)and ultrasonic technique,are introduced.Furthermore,the effect of thermal damage on the mechanical parameters of rocks in response to different thermal treatments,involving temperature magnitude,cooling method and thermal cycle,are discussed.Finally,the limitations and prospects for the research of rock thermal damage are proposed.

Experimental study on reactions between alkaline basaltic melt and orthopyroxenes: constraints on the evolution of lithospheric mantle in the North China Craton

The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this paper.The reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric mantle.The starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei Province.The results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T conditions.The formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff ect.Temperature is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the melt.Temperature also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted melt.The formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this mineral.Therefore,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 contents.In addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions between the latter and orthopyroxene.

Formation,evolution,reconstruction of black shales and their influence on shale oil and gas resource

Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment.

Research Progress in the Failure Behavior onthe Interface of Thermal Barrier Coatings

This paper mainly introduces the research progress on interface failure behavior in high-temperature alloy surface thermal barrier coating systems.The degradation failure and structural evolution behavior during high-temperature service were analyzed for the matrix/bonding layer interface,bonding layer/TGO interface,and TGO/ceramic layer interface in thermal barrier coatings.The research focus and direction that affect the interface performance of thermal barrier coatings were proposed.

NUMERICAL MODELLING OF LITHOSPHERE EVOLUTION IN THE NORTH CHINA CRATON: THERMAL THINNING VERSUS TECTONIC EXTENSION THINNING

The boundary between lithosphere and asthenosphere essentially represents a thermal boundary (the solidus). Temperature variation across this boundary can lead to the change of lithosphere thickness. In the case of elevated temperatures in a lithospheric layer above 1 200℃, partial melting will begin and the result of that is a thinned lithosphere. The other mechanism that can also thin lithosphere is extension. Stretching during an extension event can result in a thinner and longer lithosphere. The two mechanisms above are the reason why we can alserve large variations in lithosphere thickness spatially across various continents and temporally throughout the geological history.

STRUCTURAL AND THERMAL EVOLUTION OF THE SOUTH ASIAN CONTINENTAL MARGIN ALONG THE KARAKORAM AND HINDU KUSH RANGES,NORTH PAKISTAN

Prior to the collision and accretion of the Kohistan arc terrane during the late Cretaceous and the Indian plate after the early Eocene, the southern margin of Asia along the Hindu Kush, Karakoram and Lhasa block terranes was an active Andean\|type continental margin. In south Tibet this margin was dominated by the calc\|alkaline Ladakh—Gangdese granite batholith, associated andesitic volcanic rocks and continental red\|beds. In contrast, the southern Karakoram exposes deep crustal metamorphic rocks and crustal melt leucogranites. New U\|Pb age dating from the Hunza valley and Baltoro glacier region has revealed four spatially and temporally distinct metamorphic episodes. M1 sillimanite grade metamorphism in Hunza was a late Cretaceous event, probably caused by the accretion of the Kohistan arc to Asia. M2 was the major kyanite and sillimanite grade event during late Eocene—Oligocene crustal thickening and shortening, following India\|Asia collision. Numerous melting events resulted in the formation of crustal melt granites throughout the last 50Ma with multiple generations of dykes and very large scale crustal melting along the Baltoro monzogranite\|leucogranite ba tholith during the late Oligocene—early Miocene. M3 metamorphism was a high\| T , low\| p contact thermal metamorphism around the Baltoro granite. In Hunza, younger staurolite grade metamorphism has been dated by U\|Pb monazites at 16Ma, with the Sumayar leucogranite intruded at 9 5Ma cross\|cutting the metamorphic isograds. In the Baltoro region the youngest metamorphism, M4, is the sillimanite grade Dassu gneiss core complex dated by U\|Pb on monazites as late Miocene—Pliocene (5 4±0 25)Ma with Precambrian protolith zircon cores (1855±11)Ma. Numerous gem\|bearing pegmatite dykes cross\|cut these rocks and are thought to have been intruded within the last 2～3Ma. Structural mapping, combined with U\|Pb geochronology shows that major metamorphic events can be both long\|lasting (up to 20Ma) and very restrictive, both in time and space.

The Experimental Study of Iron Sulfide Mineral Evolution Under Thermal Sulfurization Condition

Iron sulfide minerals are widely distributed, of which characteristics had the identification significance of formation environment. Previously, there were more research on iron sulfide minerals under hydrothermal condition, and few studies under volcanism formation condition. To simulate volcanic mineralization, the study of different temperature from 250 to 410℃ , different iron sulfur ratio from Fe:S=2∶1 to 1∶8, and two different sources of iron, reduced iron powder (Fe) and ferrous sulfide (FeS), on iron sulfide mineral evolution was investigated under thermal sulfurization condition. By using scanning electron microscopy (SEM), X-ray diffraction (XRD) and other methods, the morphology, composition and structural characteristics of the products were observed and analyzed.

Microstructure Evolution of Organic Matter and Clay Minerals in Shales with Increasing Thermal Maturity

As the two important components of shale, organic matter(OM) and clay minerals are usually thought to strongly influence the hydrocarbon generation, enrichment and exploitation. The evolution process of OM and clay minerals as well as their interrelationship over a wide range of thermal maturities are not completely clear. Taking Yanchang(T3y), Longmaxi(S1l) and Niutitang(?1n) shales as examples, we have studied the microstructure characteristics of OM and clay minerals in shales with different thermal maturities. The effects of clay minerals and OM on pores were reinforced through sedimentation experiments. Using a combination of field emission scanning electron microscopy(FESEM) and low-pressure N2 adsorption, we investigated the microstructure differences among the three shales. The results showed that both OM and clay minerals have strong effects on pores, and small mesopore(2–20 nm) is the dominant pore component for all three samples. However, the differences between the three samples are embodied in the distribution of pore size and the location. For the T3y shale, clay minerals are loosely arranged and develop large amounts of pores, and fine OM grains often fill in intergranular minerals or fractures. Widespread OM pores distribute irregularly in S1l shale, and most of the pores are elliptical and nondirectional. The ?1n shale is characterized by the preferred orientational OM-clay aggregates, and lots of pores in the composites are in the mesopore range, suggesting that over maturity lead to the collapse and compaction of pores under huge pressure of strata. The results of the current research imply that with increasing thermal maturity, OM pores are absent at low maturity(T3y), are maximized at high maturity(S1l) and are destroyed or compacted at over-mature stage(?1n). Meanwhile, clay minerals have gone through mineral transformation and orientational evolution. The interaction of the two processes makes a significant difference to the microstructure evolution of OM and clay minerals in shale, and the findings provide scientific foundation in better understanding diagenetic evolution and hydrocarbon generation of shale.

Microstructure, hardness evolution and thermal stability of binary Al-7Mg alloy processed by ECAP with intermediate annealing

A binary Al-7Mg alloy was processed by equal channel angular pressing （ECAP） at room temperature via route Bc, combined with intermediate annealing. After 6 passes, a high hardness of HV218 is achieved. Transmission electron microscopy （TEM） observations demonstrate that ECAP leads to a significant grain refinement and ultrafine grains down to 100-200 nm are developed after 5 or 6 passes. X-ray diffraction （XRD） analysis indicates that the major part of Mg atoms are in solid solution in the deformed material, and the possible strengthening effect of Mg solute atom clusters or precipitates is neglected. The high hardness of the 6 pass-treated materials comes mainly from grain boundary strengthening, which contributes about 41% to the total strength, while dislocations and Mg solid solution contribute about 24% and 35% to the remaining strength, respectively. Also, the thermal stability of this severely deformed material was investigated by hardness measurements. The material is relatively stable when annealed at a temperature lower than 250 ℃, while annealing at 300 ℃ leads to a rapid softening of the material.

Thermal Evolution of Plutons and Uplift Process of the Yanshan Orogenic Belt

Abstract: Thermochronological dating was used to study the thermal evolution of the Mesozoic plutons and uplift history of the Yanshan orogenic belt. The results show that the cooling history of the plutons is complicated, corresponding to the inhomogeneous uplift process of the Yanshan orogenic belt. The Panshan granite cooled fast during 226.48–204.95 Ma at a rate of 10.22°C/Ma after its emplacement at a depth of about 10 km, and its fast uplift occurred in about 96–35 Ma at an average rate of 0.115 mm/a. The Wulingshan pluton cooled fast during 132–127.23 Ma at a rate of 94.34°C/Ma, and its rapid uplift occurred in 86–45 Ma at an average rate of 0.186 mm/a. The Yunmengshan granite cooled fast during 143–120.99 Ma at a rate of 19.51°C/Ma, and its rapid uplift occurred in 106–103.95 Ma and 20–0.0 Ma at a rate of 1.06 mm/a and 0.15 mm/a respectively. The Sihetang granite-gneiss uplifted rapidly since 13 Ma at an average rate of 0.256 mm/a. The Badaling granite uplifted rapidly since 6 Ma at an average rate of 0.556 mm/a. The Cenozoic uplift of the Yanshan Mountains can be well correlated to the rifting process of the surrounding basins.

Thermal properties of harzburgite and dunite at 0.8–3 GPa and 300–823 K and implications for the thermal evolution of Tibet

Thermal diffusivity(D)and thermal conductivity(κ)of harzburgite and dunite from Luobusha ophiolite were simultaneously measured up to 3 GPa and 823 K using the transient plane-source method in a multi anvil apparatus.The results show that the values of D andκof both samples systematically decrease with increasing temperature and increase with increasing pressure.By combination of the thermal physical data of rocks and minerals and geophysical constraints,we performed numerical simulation on the thermal evolution of Tibet vary over depth,distance and geologic ages.The present results provide new constraints on occurrence of partial melting and its geophysical significance beneath Tibetan crust.

Thermal Evolution of Organic Matter and Secondary Hydrocarbon Generation from Upper Paleozoic Coal Deposits in Northern China

The metamorphism and hydrocarbon generation from the Upper Paleozoic coal-bearing strata in Northern China have been widely studied by Chinese geologists since the 1990s. Based on a large amount of data of Ro values,combined with geological background,we have systematically analyzed the thermal evolutionary characteristics of or-ganic matter and the stages of hydrocarbon generation from the Permo-Carboniferous coal deposits and discussed the condition of secondary hydrocarbon generation. The distribution range of secondary hydrocarbon generation in North-ern China is thus determined. It is shown that the coal ranks of the Upper Paleozoic coal deposits are higher in the southern and western belts than those in the northern and eastern belts. Really significant secondary hydrocarbon gen-eration is mainly related to the thermal evolution of organic matter during the Himalayan Period. Profitable areas for secondary hydrocarbon generation should be buried at 3000-4000 m up to the present. Maturity of the Permo-Carbon-iferous source rocks is not very high. It is suggested that the Bohai Bay depression is favourable for secondary hydro-carbon generation and has good oil and gas prospects.

EVOLUTION OF TROPOSPHERIC TEMPERATURE FIELDS AND CORRESPONDING THERMAL MECHANISMS BEFORE/AFTER ONSET PERIODS OF ASIAN SUMMER MONSOON

The evolution of the tropospheric temperature fields over Indian and South China Sea monsoon areas and their thermal mechanisms are compared and analyzed during the period from March to June, 1996. The results show that the onsets of the Indian and South China Sea summer monsoons are closely associated with the seasonal warming in the troposphere over the zonal belt of 10(N ~ 30(N in these areas, which leads to the inversion of meridional temperature gradient. During the pre-onset period, the warming over the South China Sea monsoon region is mainly due to the warm horizontal advection and diabatic (latent) heating processes. Meanwhile, the warming is suppressed by the vertical adiabatic process (cooling). In spring over the Indian monsoon region, the significant adiabatic heating due to the subsidence motion, which compensates the cooling due to the strong cold advection and diabatic cooling processes, results in a larger warming rate than over the South China Sea monsoon region. However, the meridional temperature gradient over the Indian monsoon region is so large during the late winter and early spring that it takes longer time to warm the troposphere to have the reversion of meridional temperature gradient than it does over the South China Sea monsoon region. It results in the phenomenon that the South China Sea summer monsoon generally breaks out earlier than the Indian summer monsoon.

Thermal evolution characteristics of Triassic coal in Chuxiong Basin and its geological significance

Chuxiong Basin in Yunnan is a typical Mesozoic foreland basin which is enriched in widely distributed Triassic coal resources with thick deposits and of important strategic significance. By applying vitrinite reflectance measurement, inclusion thermometry, fission track dating and EASY% Ro numerical simulation, the Triassic coal thermal evolution history of the Chuxiong Basin was analyzed, and the results were concluded. The vitrinite reflectance of Chuxiong Basin is higher in the west and south in general.Vertically, in the east, west, and north of the basin, the vitrinite reflectance increases with increasing depth, and in the northern part, exceptionally high values occur, and there is no significant regularity in the east. The formation of inclusions inside quartz veins in Chuxiong Basin Triassic coal are unrelated with magmatic hydrothermal fluid, and there are multi-phase inclusions formed in three or four sections of tectonic movements. The main heating period(apparent age) of the Triassic coal is concentrated in the late Cenozoic, during which the coal was subjected to repeated thermal disturbance, resulting in a multimodal distribution of the fission track data, which reveals mild burial features of the early stages of the Late Cenozoic. The Triassic coal of Chuxiong Basin has experienced two major temperature increasing processes, which occurred in the early-mid Yanshan and the early Himalayan, respectively. The first hydrocarbon generation period of coal organic matter occurred in the formation stage of the foreland basin, during which the south and west of the basin generated large amounts of hydrocarbon, but little was preserved. The second generation stage in the Early Himalayan had conditions suitable for high gas accumulation, especially in the western and southern regions. The upper Triassic coal is of moderate burial depth and is less affected by the strike-slip effect. There are key areas of Chuxiong Basin oil and gas exploration, such as the Yanfeng Basin in the north-central, Yongren and Yunlong areas.

Multi-Method Chronometric Constraints on the Thermal Evolution of the Central Tianshan,NW China

The Tianshan orogenic belt is a major part of the southern Central Asian Orogenic Belt（CAOB）,extending from west to east for over 2500 km through Uzbekistan,Tajikistan,Kyrgyzstan and Kazakhstan to Xinjiang in NW China,and contains the record of multi-phase tectonothermal evolution.Till now.

Structural Evolution of Graphene Oxide and Its Thermal Stability During High Temperature Sintering

The thermal reduction of graphene oxide(GO)was performed by a tube furnace at different temperatures,and its structure evolution was investigated in detail.The results showed that the oxygen-containing functional groups on the carbon plane surface of GO gradually decomposed as the temperature increase,and the reduced graphene oxide(rGO)powder was obtained at 800℃.Then,rGO powder was sintered under 30 MPa at 1800℃using spark plasma sintering(SPS)and hot-pressing(HP)to evaluate its structural stability at high temperatures.The defect densities of rGO were reduced after high-temperature sintering.The edge flatness and sp^(2) hybrid carbon plane structure were reconstructed effectively.These results demonstrate that the lamellar structure of rGO maintains the structural integrity during high-temperature sintering without obvious deterioration,which provides experimental and theoretical supports for GO reinforced ceramics.

Tectono-thermal evolution of the Liwan Sag, deepwater area in the Zhujiang River Mouth Basin, northern South China Sea

The Liwan Sag, with an area of 4 000 km-2, is one of the deepwater sags in the Zhujiang River（Pearl River） Mouth Basin, northern South China Sea. Inspired by the exploration success in oil and gas resources in the deepwater sags worldwide, we conducted the thermal modeling to investigate the tectono-thermal history of the Liwan Sag,which has been widely thought to be important to understand tectonic activities as well as hydrocarbon potential of a basin. Using the multi-stage finite stretching model, the tectonic subsidence history and the thermal history have been obtained for 12 artificial wells, which were constructed on basis of one seismic profile newly acquired in the study area. Two stages of rifting during the time periods of 49–33.9 Ma and 33.9–23 Ma can be recognized from the tectonic subsidence pattern, and there are two phases of heating processes corresponding to the rifting.The reconstructed average basal paleo-heat flow values at the end of the rifting events are -70.5 and -94.2 mW/m^2 respectively. Following the heating periods, the study area has undergone a persistent thermal attenuation phase since 23 Ma and the basal heat flow cooled down to -71.8–82.5 mW/m^2 at present.

Hydrothermal Systems Characterized by Crustal Thermally-dominated Structures of Southeastern China

Southeastern China(SE China)is located in the Pacific tectonic domain and has experienced a series of tectono-magmatic events induced by the subduction of the Paleo-Pacific Plate since the late Mesozoic.The subduction formed a series of NE-NNE oriented faults under a NW-SE regional stress field,along which a number of thermal springs occur.Previous studies have focused on the genesis mechanism of specific geothermal fields in SE China,but the general characteristics of hydrothermal systems in SE China remains unclear.In this study,we investigate the correlation between geothermal activity,hydrochemical type and regional faults by studying the distribution of hydrothermal activity and geochemical properties of typical hydrothermal systems in SE China.The hydrothermal systems in SE China have a crustal thermally-dominated structural origin unique to the specific geological and tectonic conditions of the Eurasian Plate margin.The upwelling of the asthenosphere and the widespread granitoids with high radiogenic heat production in SE China provide major heat sources for regional geothermal anomalies.The NE-oriented crustal thermally-dominated faults are critical for the formation of geothermal anomalies and NW-oriented extensional faults have created favorable conditions for meteoric water infiltration,transportation and the formation of thermal springs.

CENOZOIC VOLCANISM AND LITHOSPHERETECTONIC EVOLUTION IN NORTH TIBET

Volcanism is the direct indication of the upper mantle thermodynamic activities, and it is an efficient path to study the lithosphere tectonic evolution. Cenozoic volcanism in North Tibet is of obviously time circles. In the space, from south to north, the chemical composition of volcanics changed from Na\|rich alkalic basaltic series formed 44Ma. ago into high\|K calcalkali series formed in about 40～31Ma.in Qiangtang area, into minor amount of leucite basalt and phonolite series of 26Ma., further into shoshonite series aged at 19～7Ma. in Cocoxili basin, until Quaternary shoshonite series in Karakunlun and Qilian Mt.\|Yumen region(Xiaoguo Chi etc.1999).Isotopes of Sr,Nd,Pb and trace elements in volcanic rocks provide wide range of information for the evolution of lithosphere in North Tibet after 45Ma. Present research shows that Na\|rich alkalic basalt series formed 44Ma. ago has the features of a primitive mantle in Sr,Nd,Pb isotopes. Along with the evolutionary tendency to high\|K calcalkali series and phonolite series, isotopes of Sr,Nd,Pb evolve towards EM2\|rich mantle end. The North Tibet is a compound continental mass combined from several terrains of different geological periods and the lithosphere mantle sees a complicated evolutionary history. Hence, the mixing of different rocks in ancient subduction zones and long history of metasomatism in the upper mantle offered excellent and favorable conditions for the formation of EM2 mantle end and for potassic enrichment. Isotopic evolutionary features indicate that the early magma came from the asthenosphere while later magmas were derived from partial remelting of lithosphere mantle.

CENOZOIC COLLISIONAL DEFORMATION AND LITHOSPHERE TECTONIC EVOLUTION OF THE EASTERN HIMALAYAN SYNTAXIS

The Eastern Himalayan Syntaxis (EHS) is one of the strongest deformation area along the Himalayan belt resulted from the collision between Indian plate and the Eurasian plate since 50～60Ma, and has sensitivity tracked and preserved the whole collisional processes. It should depend on the detail geological investigations to establish the deformational accommodate mode, and the uplift history, to elucidate the deep structure and the crust\|mantle interaction of the EHS. The Namjabarwa metamorphic complex indented into the Gangdise arc along the sinistral Pai shear fault and the dextral Aniqiao shear fault on the both sides of the Great Canyon of Yalung Zangbo river since the collision of the NE corner of the Indian plate and the Eurasian Plate at 60～70Ma [1] . The distance between Yarlung Zangbo suture and Bangong—Nujiang suture is shortened more 120km in the EHS area than that of the Lhasa block.