Design,preparation,application of advanced array structured materials and their action mechanism analyses for high performance lithium-sulfur batteries

Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,etc.In various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li PSs.Thus many novel array structured materials are applied to battery for tackling thorny problems mentioned above.In this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are summarized.Meanwhile,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery performances.Lastly,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are generalized.We hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.

Current situation and development trend of design methods for subgrade structure of high speed railways

Purpose–This method will become a new development trend in subgrade structure design for high speed railways.Design/methodology/approach–This paper summarizes the structural types and design methods of subgrade bed for high speed railways in China,Japan,France,Germany,the United States and other countries based on the study and analysis of existing literature and combined with the research results and practices of high speed railway subgrade engineering at home and abroad.Findings–It is found that in foreign countries,the layered reinforced structure is generally adopted for the subgrade bed of high speed railways,and the unified double-layer or multi-layer structure is adopted for the surface layer of subgrade bed,while the simple structure is adopted in China;in foreign countries,different inspection parameters are adopted to evaluate the compaction state of fillers according to their respective understanding and practice,while in China,compaction coefficient,subsoil coefficient and dynamic deformation modulus are adopted for such evaluation;in foreign countries,the subgrade top deformation control method,the subgrade bottom deformation control method,the subsurface fill strength control method are mainly adopted in subgrade bed structure design of high speed railways,while in China,dynamic deformation control of subgrade surface and dynamic strain control of subgrade bed bottom layer is adopted in the design.However,the cumulative deformation of subgrade caused by train cyclic vibration load is not considered in the existing design methods.Originality/value–This paper introduces a new subgrade structure design method based on whole-process dynamics analysis that meets subgrade functional requirements and is established on the basis of the existing research at home and abroad on prediction methods for cumulative deformation of subgrade soil.

Generalized response displacement methods for seismic analysis of underground structures with complex cross section

The response displacement method(RDM)is recommended for the seismic analysis of underground structures in the transverse direction for many codes,including bases for design of structures-seismic actions for designing geotechnical works(ISO 23469)and code for seismic design of urban rail transit structures(GB 50909-2014).However,there are some obvious limitations in the application of RDM.Springs and the shear stress of the soil could be approximately evaluated for the structures having a simple cross section,such as rectangular and circular structures.It is necessary to propose simplified seismic analysis methods for structures with complex cross sections.This paper refers to the idea of RDM and proposes three generalized response displacement methods(GRDM).In GRDM1,a part of the soil surrounding a structure is selected to generate a generalized underground structure with a rectangular cross section,and the same analysis model as RDM is applied to analyze the responses of the structure.In GRDM2,a hollow soil model without a generalized structure is used to compute the equivalent load caused by the relative displacement of the soil,and the soil-structure interaction model is applied to calculate the responses of the structure.In GRDM3,a continuous soil model is applied to compute the equivalent load caused by the relative displacement and shear stress of the soil,and the soil-structure interaction model is applied to analyze the responses of the structure,which is the same as the model used in GRDM2.The time-history analysis method(THAM)is used to evaluate the accuracy of the proposed simplified methods.Results show that the error of GRDM1 is about 20%,while the error is only 5%for GRDM2 and GRDM3.Among the three proposed methods,GRDM3 has obvious advantages regarding calculation efficiency and accuracy.Therefore,it is recommended to use GRDM3 for the seismic response analysis of underground structures that have conventional simple or complex cross sections.

A Footpad Structure with Reusable Energy Absorption Capability for Deep Space Exploration Lander:Design and Analysis

The footpad structure of a deep space exploration lander is a critical system that makes the initial contact with the ground,and thereby plays a crucial role in determining the stability and energy absorption characteristics during the impact process.The conventional footpad is typically designed with an aluminum honeycomb structure that dissipates energy through plastic deformation.Nevertheless,its effectiveness in providing cushioning and energy absorption becomes significantly compromised when the structure is crushed,rendering it unusable for reusable landers in the future.This study presents a methodology for designing and evaluating structural energy absorption systems incorporating recoverable strain constraints of shape memory alloys(SMA).The topological configuration of the energy absorbing structure is derived using an equivalent static load method(ESL),and three lightweight footpad designs featuring honeycomb-like Ni-Ti shape memory alloys structures and having variable stiffness skins are proposed.To verify the accuracy of the numerical modelling,a honeycomb-like structure subjected to compression load is modeled and then compared with experimental results.Moreover,the influence of the configurations and thickness distribution of the proposed structures on their energy absorption performance is comprehensively evaluated using finite element simulations.The results demonstrate that the proposed design approach effectively regulates the strain threshold to maintain the SMA within the constraint of maximum recoverable strain,resulting in a structural energy absorption capacity of 362 J/kg with a crushing force efficiency greater than 63%.

Hydraulic Design Method of Wave Dissipating Structure with Partially Perforated Front Wall

Based on the matching conditions of different fluid regions, the eigenfunction expansion method is used to develop a theoretical formula for wave reflection in front of the perforated structure with a partially slit front wall. The accuracy of the solution is verified by comparing the numerical results with experimental data. In addition, a new hydraulic design method is developed by derivation of the theoretical formula with respect to the porosity of the slit wall, and the results of this design method is drafted for harbour engineers to use.

An improved pseudo-static method for seismic resistant design of underground structures

This paper describes a commonly used pseudo-static method in seismic resistant design of the cross section of underground structures. Based on dynamic theory and the vibration characteristics of underground structures, the sources of errors when using this method are analyzed. The traditional seismic motion loading approach is replaced by a method in which a one-dimensional soil layer response stress is differentiated and then converted into seismic live loads. To validate the improved method, a comparison of analytical results is conducted for internal forces under earthquake shaking of a typical shallow embedded box-shaped subway station structure using four methods： the response displacement method, finite element response acceleration method, the finite element dynamic analysis method and the improved pseudo-static calculation method. It is shown that the improved finite element pseudo-static method proposed in this paper provides an effective tool for the seismic design of underground structures. The evaluation yields results close to those obtained by the finite element dynamic analysis method, and shows that the improved finite element pseudo-static method provides a higher degree of precision.

Analysis and Research of Ice Loads Acting on Offshore Structures

Usually, the action of sea ice on offshore engineering structures is one of the controlling loads in cold waters engineering structure design. The reasonable selection of environmental condition and the physical mechanical properties of ice in the region are directly related to the structure design, operation and safety. In this paper, the sea ice force acting on the structure, the physical mechanical properties of ice and the selection of parameters in calculation are discussed. Some suggestions are proposed as to the calculation of various kinds of ice loads acting on the structure.

A novel robust design method for improving stability of optimized structures

It is known that structural optimization may lead to designs of structures having low stability and sometimes even kinematically unstable designs. This paper presents a robust design method for improving the stability of opti mized structures. A new approach is proposed, in which cer tain perturbation loads are introduced and the corresponding compliance is added to the objective function as a penaliza tion. The stability of the optimized structures can thus be improved substantially by considering structural responses to the original and the introduced loads. Numerical exam ples show the simplicity and effectiveness of the proposed method.

Optimum Environmental Load Design Criterion for Marine Structures Based on Investment and Benefit Analysis

Marine structures operating in natural ocean environment are subjected to various stochastic loads. For design of the marine structures, the most important task is to determine environmental load design criterion. This paper presents a method to determine the optimum environmental load design criterion for marine structures. This method is based on the investment and benefit analysis and it can reach the design purpose of decreasing total costs during the service life of the structures and increasing economic benefits.

Design methods of rhombic tensegrity structures

As a special type of novel flexible structures, tensegrity holds promise for many potential applications in such fields as materials science, biomechanics, civil and aerospace engineering. Rhombic systems are an important class of tensegrity structures, in which each bar constitutes the longest diagonal of a rhombus of four strings. In this paper, we address the design methods of rhombic structures based on the idea that many tensegrity structures can be constructed by assembling one-bar elementary cells. By analyzing the properties of rhombic cells, we first develop two novel schemes, namely, direct enumeration scheme and cell-substitution scheme. In addition, a facile and efficient method is presented to integrate several rhombic systems into a larger tensegrity structure. To illustrate the applications of these methods, some novel rhombic tensegrity structures are constructed.

Topology optimization of 3D structures with design-dependent loads

Topology optimization of continuum structures with design-dependent loads has long been a challenge. In this paper, the topology optimization of 3D structures subjected to design-dependent loads is investigated. A boundary search scheme is proposed for 3D problems, by means of which the load surface can be identified effectively and efficiently, and the difficulties arising in other approaches can be overcome. The load surfaces are made up of the boundaries of finite elements and the loads can be directly applied to corresponding element nodes, which leads to great convenience in the application of this method. Finally, the effectiveness and efficiency of the proposed method is validated by several numerical examples.

STOCHASTIC BOUNDARY ELEMENT METHOD FOR RELIABILITY ANALYSIS OF PLATE AND BEAMS COMPOSITE STRUCTURES

In this paper, the reliability of orthotropic plate and beams composite structures, which is under the actions of the stochastic loading and stochastic boundary conditions, have been analyzed by stochastic boundary element method. First, the boundary integral equation of orthotropic plate and beams composite structures is given in this paper, and then based on the stochastic boundary element method, the method for reliability analysis of stochastic structures is establishes and formulas for computation of reliability index of orthotropic plate and beams composite structures are obtained. The computed examples show the efficient of the method used in this paper.

Discrete Element Simulations of Ice Load and Mooring Force on Moored Structure in Level Ice

Moored structures are suitable for operations in ice-covered regions owing to their security and efficiency.This paper aims to present a new method for simulating the ice load and mooring force on the moored structure during ice-structure interaction with a spherical Discrete Element Method(DEM).In this method,the level ice and mooring lines consist of bonded sphere elements arranged in different patterns.The level ice model has been widely validated in simulation of the ice load of fixed structures.In the mooring line simulation,a string of spherical elements was jointed with the parallel bond model to simulate the chains or cable structure.The accuracy of the mooring line model was proved by comparing the numerical results with the nonlinear FEM results and model towing experiment results.The motion of the structure was calculated in the quaternion method,considering the ice load,mooring force,and hydrodynamic force.The hydrodynamic force comprised wave-making damping,current drag,and buoyancy force.Based on the proposed model,the interaction of a semi-submersible structure with level ice was simulated,and the effect of ice thickness on the ice load was analyzed.The numerical results show that the DEM method is suitable to simulate the ice load and mooring force on moored floating structures.

REQUIREMENTS AND DESIGN METHOD FOR MATCHING AIRCRAFT GUNS WITH THEIR SUPPORTING STRUCTURE

In aircraft structural dynamic design the matching of guns with their supportingstructure is one of the most important tasks on which hinges the success or failure of thestructural design.The design curves for matching guns with their supporting structure can be obtained fromresponse calculations of the plate-spring system supporting the gun on the ground,the modelstructure tested on the ground and the actual structure.A set of matching curves is given forengineering application.Then,the matching design can be accomplished by means of impactload spectrograms so as to perform an optimal structural design and to make further improvementson dynamic design program.

Lightweight Design and Verification of Gantry Machining Center Crossbeam Based on Structural Bionics

The lightweight and high efficiency of natural structures are the inexhaustible sources for engineering improvements. The goal of the study is to find innovative solutions for mechanical lightweight design through the application of structural bionic approaches. Giant waterlily leaf ribs and cactus stem are investigated for their optimal framework and superior performance. Their structural characteristics are extracted and used in the bio-inspired design of Lin MC6000 gantry machining center crossbeam. By mimicking analogous network structure, the bionic model is established, which has better load-carrying capacity than conventional distribution. Finite Element Method （FEM） is used for numerical simulation. Results show better specific stiffness of the bionic model, which is increased by 17.36%. Finally the scaled models are fabricated by precision casting for static and dynamic tests. The physical experiments are compared to numerical simulation. The results show that the maximum static deformation of the bionic model is reduced by about 16.22%, with 3.31% weight reduction. In addition, the first four natural frequencies are improved obviously. The structural bionic design is a valuable reference for updating conventional mechanical structures with better performance and less material consumption.

PREDICTION OF FATIGUE LIVES OF RC BEAMS STRENGTHENED WITH CFL UNDER RANDOM LOADING

The investigation on fatigue lives of reinforced concrete （RC） structures strength- ened with fiber laminate under random loading is important for the repairing or the strengthening of bridges and the safety of the traffic. In this paper, two methods are developed for predicting the fatigue lives of RC structures strengthened with carbon fiber [aminate （CFL） under random loading based on a residual life and a residual strength model. To discuss the efficiency of the model, 12 RC beams strengthened with CFL are tested under random loading by the MTS810 testing system. The predicted residual strength approximately agrees with test results.

A Rework Reduction Mechanism in Complex Projects Using Design Structure Matrix Clustering Methods

To reduce the uncertainty and reworks in complex projects,a novel mechanism is systematically developed in this paper based on two classical design structure matrix(DSM)clustering methods:Loop searching method(LSM)and function searching method(FSM).Specifically,the optimal working areas for the two clustering methods are first obtained quantitatively in terms of non-zero fraction(NZF)and singular value modularity index(SMI),in which the whole working area is divided into six sub-zones.Then,a judgement procedure is proposed for conveniently choosing the optimal DSM clustering method,which makes it easy to determine which DSM clustering method performs better for a given case.Subsequently,a conceptual model is constructed to assist project managers in effectively analyzing the network of projects and greatly reducing reworks in complex projects by defining preventive actions.Finally,the aircraft design process is presented to show how the proposed judgement mechanism can be utilized to reduce the reworks in actual projects.

Estimating Design Loads with Environmental Contour Approach Using Copulas for an Offshore Jacket Platform

Jacket-type offshore platforms are widely used for oil, gas field, and energy development in shallow water. The design of a jacket structure is highly dependent on target environmental variables. This study focuses on a strategy to estimate design loads for offshore jacket structures based on an environmental contour approach. In addition to the popular conditional distribution model, various classes of bivariate copulas are adopted to construct joint distributions of environmental variables. Analytical formulations of environmental contours based on various models are presented and discussed in this study. The design loads are examined by dynamic response analysis of jacket platform. Results suggest that the conditional model is not recommended for use in estimating design loads in sampling locations due to poor fitting results. Independent copula produces conservative design loads and the extreme response obtained using the conditional model are smaller than those determined by copulas. The suitability of a model for contour construction varies with the origin of wave data. This study provides a reference for the design load estimation of jacket structures and offers an alternative procedure to determine the design criteria for offshore structures.

Structural analysis and design of frost resistance function for subgrade of high-speed railway ballasted track in cold regions

According to the technical characteristics of short fixed wheelbase of a high-speed carriage, a subgrade-track integrated space mechanical response analysis model is proposed for trains under the action ofbiaxial load after the comparison of the stress distribution characteristics of the ballast track subgrade bed structures for high-speed railway under the action of uniaxial load and biaxial load. The loading threshold value （high-cycle long-term dynamic strength） under the circum- stance where the cumulative deformation of subgrade structure gradually develops and finally reaches the convergent state, and its relationship with the foundation coefficient K30 were deduced, based on the characteristics of cumulative defor- mation evolution obtained from the unit structure filling model test under the action of cyclic loading. In view of structure stability and frost resistance requirements of the railway subgrade in cold regions, technical conditions to maintain good service performance of subgrade structure of high-speed railway ballasted track are discussed and analyzed. Study results show that the additive effect manifests itself obviously for railway train bogies under the action of biaxial load than uni- axial load, which has a significant dynamic effect on the subgrade bed bottom and a slight effect on the surface layer. Thus, the adoption of a biaxial load model in the design of a high-speed railway subgrade accurately reflects the vehicle load. Pursuant to the structure design principle, the design method of the subgrade structure of high-speed railway ballasted track is proposed to meet the technical requirements such as structural strength, bearing stiffness and high-cyclic and long-term stability. Technical indicators are obtained for the variation of thickness of the surface layer of reinforced sub- grade bed in the double-layer subgrade mode along with the change of K30 at the subgrade bed bottom. The double-layer structure mode of ＂closure on the upper layer and drainage on the lower layer＂ was proposed in order to meet the water- proofing and drainage requirements of the upper layer of the subgrade bed in cold regions. A dense-framework graded gravel filler with weak water permeability at a coefficient of 10 4 cm/s is used on the upper layer and the void-framework graded gravel filler at the water permeability coefficient of 10 2 cm/s is adopted on the lower layer.