In order to study effects of application of contmllE=d release fertilizer on ni- trous oxide (N2O) emission in slope cultivated land with purple soil, four treatments including the control group (CK), urea (UR),...In order to study effects of application of contmllE=d release fertilizer on ni- trous oxide (N2O) emission in slope cultivated land with purple soil, four treatments including the control group (CK), urea (UR), controlled release nitrogen fertilizer (CR), and controlled release nitrogen fertilizer+urea (25%CR, 75%UR) were set up, and their impacts on maize yield, surface runoff and nitrogen loss in the growth pe- riod of maize and N2O emission were studied. The results show that maize yield, surface runoff, nitrogen loss from subsurface flow, and N2O emission in the control group was far lower than that in the fertilization treatments, revealing that fertilization was the main reason for nitrogen loss and N2O emission. Among the four treat- ments, nitrogen loss from subsurface flow in the treatment CR was the highest, up to 31.7 kg/hm^2, but N2O emission was 0.35 kg/hm^2, which was 37% less than that in the treatment UR. Nitrogen loss from subsurface flow in the treatment 25% CR was the lowest, only 20.9 kg/hm^2, and N2O emission was 15% less than that in the treatment UR. Nitrogen was slowly released from controlled release nitrogen fertilizer in the growth period, and controlled release nitrogen fertilizer could reduce N2O emis- .sion from slope cultivated land due to low content of soil inorganic nitrogen, but it could increase the nitrogen loss from subsurface flow. Therefore, the combination of controlled release fertilizer and urea can not only reduce N2O emission but also de- crease nitrogen loss from subsurface flow.展开更多
Nitrogen and phosphorous concentrations of effluent water must be taken into account for the design and operation of wastewater treatment plants. In addition, the requirement for effluent quality is becoming strict. T...Nitrogen and phosphorous concentrations of effluent water must be taken into account for the design and operation of wastewater treatment plants. In addition, the requirement for effluent quality is becoming strict. Therefore, intelligent control approaches are recently required in removing biological nutrient. In this study, fuzzy control has been successfully applied to improve the nitrogen removal. Experimental results showed that a close relationship between nitrate concentration and oxidation-reduction potential (ORP) at the end of anoxic zone was found for anoxic/oxic (A/O) nitrogen removal process treating synthetic wastewater. ORP can be used as online fuzzy control parameter of nitrate recirculation and external carbon addition. The established fuzzy logic controller that includes two inputs and one output can maintain ORP value at - 86 mV and - 90 mV by adjusting the nitrate recirculation flow and external carbon dosage respectively to realize the optimal control of nitrogen removal, improving the effluent quality and reducing the operating cost.展开更多
Orobanche spp. (broomrapes) are holoparasitic plants distributed predominantly in the Northern Hemisphere parasitizing the roots of a range of plant species mainly in wild ecosystems. Orobanche species cause severe ...Orobanche spp. (broomrapes) are holoparasitic plants distributed predominantly in the Northern Hemisphere parasitizing the roots of a range of plant species mainly in wild ecosystems. Orobanche species cause severe yield reduction of many important crops. There are only very few herbicides which are able to selectively control broomrapes and different approaches have been put forward to develop natural product based pesticides to control Orobanche. Several phytopathogenic fungi were evaluated for their use as potential mycoherbicide and for ability to produce toxic metabolites which could be applied as herbicides. Using the alternative approach "suicidal germination", interesting results were obtained by testing two microbial metabolites (fusicoccins and ophiobolin A) especially with Orobanche species whose germination is not induced by the synthetic strigolactone GR24. From pea root exudates, peagol and peagoldione, close related to strigolactones, and three polyphenols, named peapolyphenols A-C, together with already well known polyphenol and a chalcone, were isolated. They showed a selective stimulation of Orobanche seed germination with the last two and peapolyphenol A showing a specific stimulatory activity on O. foetida. This review describes the most recent results achieved on Orobanche bio-control, mainly focusing on those regarding O. ramosa, O. crenata and O. foetida.展开更多
Low-dimensional Bi2Fe4O9 nanosheets and microrods have been selectively prepared by a solvothermal method, from which the growth of the Bi2Fe4O9 crystals can be controlled by the variation of reaction conditions. Stru...Low-dimensional Bi2Fe4O9 nanosheets and microrods have been selectively prepared by a solvothermal method, from which the growth of the Bi2Fe4O9 crystals can be controlled by the variation of reaction conditions. Structure determination showed that the nanosheets are mainly exposed by {001} facets while the microrods are exposed by {110} facets. Ab- sorption spectra revealed that there are two bandgaps observed for both nanosheets (at 1.9 and 1.55 eV) and microrods (1.7 and 1.45 eV), and they both would be available for the sunlight photocatalysis e ciently due to the intensive absorption ability in a wide region. Photocatalytic investigation demonstrated that the overall photocatalytic performance of the microrods is prior to that of the nanosheets due to the variation of bandgaps and exposed facets. The present report provides a useful alternative strategy for the controlling growth of nanostructures and/or microcrystals besides the present demonstration of the Bi2Fe4O9 crystals with diflerent bandgaps and facets that would be able to tune the corresponding photocatalytic ability selectively.展开更多
This work investigates synchronization of two fractional unified hyperchaotic systems via impulsive control.The stable theory about impulsive fractional equation is studied based on the stable theory about fractional ...This work investigates synchronization of two fractional unified hyperchaotic systems via impulsive control.The stable theory about impulsive fractional equation is studied based on the stable theory about fractional linear system.Then according to the theorem proposed the sufficient condition on feedback strength and impulsive interval are established to guarantee the synchronization.Numerical simulations show the effectiveness of the theorem.展开更多
In this paper three controllers for A/O process are developed, including a DO cascade controller, an external carbon flow rate controller and an internal recycling flow rate controller. The objective of the different ...In this paper three controllers for A/O process are developed, including a DO cascade controller, an external carbon flow rate controller and an internal recycling flow rate controller. The objective of the different controllers is to control the nitrate and ammonia concentration. Simulation study demonstrated that these controllers could efficiently control nitrogen removal and meet stricter effluent quality standards at a minimum cost.展开更多
Reducing ammonia(NH3) and nitrous oxide(N2O) emissions have great effects on mitigating nitrogen(N) nutrient loss and greenhouse gas emissions. Controlled release urea(CRU) can control the N release rate, which reduce...Reducing ammonia(NH3) and nitrous oxide(N2O) emissions have great effects on mitigating nitrogen(N) nutrient loss and greenhouse gas emissions. Controlled release urea(CRU) can control the N release rate, which reduces reactive N loss and increases nitrogen use efficiency relative to conventional urea(CU). However, the crucial factors influencing the responses of NH3and N2O emissions to CRU relative to CU are still unclear. In this study, we evaluated the responses of NH3and N2O emissions to CRU based on collected field data with a meta-analysis. CRU reduced the NH3and N2O emissions by 32.7 and 25.0% compared with CU, respectively. According to subgroup analysis, CRU presented better mitigation of NH3and N2O emissions in soils with pH 6.5–7.5(–47.9 and –23.7%) relative to either pH<6.5(–28.5and –21.4%) or pH>7.5(–29.3 and –17.3%), and in the rice season(–34.8 and –29.1%) relative to the wheat season(–19.8 and –22.8%). The responses of NH3and N2O emissions to CRU increased from rainfed(–30.5 and –17.0%) to irrigated(–32.5 and –22.9%), and then to paddy(–34.8 and –29.1%) systems. In addition, the response of N2O emission mitigation increased with increases in soil total nitrogen(TN);however, soil TN did not significantly affect the response of NH3volatilization. The reduction in NH3emission was greater in sandy-textured soil(–57.7%) relative to loam-textured(–32.9%) and clay-textured(–32.3%) soils, whereas soil texture did not affect N2O emission. Overall, CRU was a good option for reducing the NH3and N2O emissions relative to CU in agricultural production. This analysis improves our understanding of the crucial environmental and management factors influencing the mitigation of NH3and N2O emissions under CRU application, and these site-specific factors should be considered when applying CRU to reduce reactive N loss and increase NUE.展开更多
Magnetite (Fe3O4) nanoparticles with different sizes and shapes are synthesized by the thermal decomposition method. Two approaches, non-injection one-pot and hot-injection methods, are designed to investigate the g...Magnetite (Fe3O4) nanoparticles with different sizes and shapes are synthesized by the thermal decomposition method. Two approaches, non-injection one-pot and hot-injection methods, are designed to investigate the growth mechanism in detail. It is found that the size and shape of nanoparticles are determined by adjusting the precursor concentration and duration time, which can be well explained by the mechanism based on the LaMer model in our synthetic system. The monodisperse Fe3O4 nanoparticles have a mean diameter from 5nm to 16nm, and shape evolution from spherical to triangular and cubic. The magnetic properties are size-dependent, and Fe3O4 nanoparticles in small size about 5 nm exhibit superparamagnetie properties at room temperature and maximum saturation magnetization approaches to 78 emu/g, whereas Fe3O4 nanoparticles develop ferromagnetic properties when the diameter increases to about 16nm.展开更多
We report a facile method for the synthesis of manganese oxide(Mn3O4) nanorods via the direct reaction of MnCl2 and H2 O2 by doping Yb3+ ions at room temperature and air atmosphere. The Mn3O4:Yb3+ samples were ch...We report a facile method for the synthesis of manganese oxide(Mn3O4) nanorods via the direct reaction of MnCl2 and H2 O2 by doping Yb3+ ions at room temperature and air atmosphere. The Mn3O4:Yb3+ samples were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), cyclic voltammetry(CVs), electrochemical impedance spectroscopy(EIS), and charging-discharging test(CD). The results show that trace Yb3+ doping(6 at%) could effectively induce crystalline transformation of Mn3O4 from cubic system(space group Fd-3 m) to tetragonal system(space group I41/amd) and incite the morphology changing from irregular particles to uniform nanorods. When Yb3+ doping amount is 3%, the capacitance of Mn3O4 reaches the maximum, 246 F/g, which is related to the morphology change and the corresponding decrease of impedance.展开更多
Spatial control of lithium deposition is the most important issue in lithium-metal batteries because of the considerable control of lithium dendrite suppression via the uniform distribution of Li^(+)flux.Although seed...Spatial control of lithium deposition is the most important issue in lithium-metal batteries because of the considerable control of lithium dendrite suppression via the uniform distribution of Li^(+)flux.Although seed materials are crucial for the behavior of lithium deposition,in-depth studies on their physical and chemical control have not been conducted.Here,we describe a new design of seed structure comprising a wrinkled Cu/graphene substrate surrounded by copper(Ⅰ)oxide(Cu_(2)O)on a graphene grain boundary over a large area,which is fabricated by the oxidation of the Cu surface via graphene boundary defects by using chemical vapor deposition(CVD).Scanning and transmission electron microscopy results reveal that Cu_(2)O on the graphene boundary can render a preferential reaction with lithium during the first deposition and assist in the uniform deposition of lithium by preventing the agglomeration of lithium clusters during the second deposition.This two-step process is attributed to the degree of selectivity due to the difference in lithium affinity,which allows long-term electrochemical stability and a high rate capability via boundary effects.This study highlights the significance of the boundary effect,which can open new avenues for the formation of a large family of seed structures in lithium-metal batteries.展开更多
Using in situ electric-field-modulated anisotropic magnetoresistance measurement, a large reversible and non- volatile in-plane rotation of magnetic easy axis of -35° between the positive and negative electrical ...Using in situ electric-field-modulated anisotropic magnetoresistance measurement, a large reversible and non- volatile in-plane rotation of magnetic easy axis of -35° between the positive and negative electrical poling states is demonstrated in C040Fe40B20//(001)-cut Pb(Mgl/3Nb2/3)O3-25PbTiO3 (PMN-PT). The specific magneto- electric coupling mechanism therein is experimentally verified to be related to the synchronous in-plane strain rotation induced by 109° ferroelastic domain switching in the (001)-cut PMN-PT substrate.展开更多
Control logix5000系列PLC功能强大,将密炼机控制系统PLC程序模块化为:加料门、卸料门、上顶栓、附属设备、主机控制、报警等子程序功能模块,便于密炼机的调试和日常维护,同时采用AB公司的2711P-T10C4D1触摸屏作为PLC的参数设置及状态...Control logix5000系列PLC功能强大,将密炼机控制系统PLC程序模块化为:加料门、卸料门、上顶栓、附属设备、主机控制、报警等子程序功能模块,便于密炼机的调试和日常维护,同时采用AB公司的2711P-T10C4D1触摸屏作为PLC的参数设置及状态监视等辅助控制,以及1794-AENT作为PLC远程I/O,大大提高了密炼机控制系统的自动化水平。展开更多
The Maximum Power Point Tracker (MPPT) is the optimum operating point of a photovoltaic module. It plays a very important role to obtain the maximum power of a solar panel as it allows an optimal use of a photovoltaic...The Maximum Power Point Tracker (MPPT) is the optimum operating point of a photovoltaic module. It plays a very important role to obtain the maximum power of a solar panel as it allows an optimal use of a photovoltaic system, regardless of irradiation and temperature variations. In this research, we present a novel technique to improve the control’s performances optimization of the system consisting of a photovoltaic panel, a buck converter and a load. Simulations of different parts of the system are developed under Matlab/Simulink, thus allowing a comparison between the performances of the three studied controllers: “Fuzzy TS”, “P&O” and “PSO”. The three algorithms of MPPT associated with these techniques are tested in different meteorological conditions. The obtained results, in different operating conditions, reveal a clear improvement of controlling performances of MPPT of a photovoltaic system when the PSO tracking technique is used.展开更多
The MPPT (maximum power point tracking) is one of the most important features of a regulator system that processes the energy produced by a photovoltaic generator. It is necessary, in fact, to design a controller th...The MPPT (maximum power point tracking) is one of the most important features of a regulator system that processes the energy produced by a photovoltaic generator. It is necessary, in fact, to design a controller that is able to set the output value of the voltage and ensure the working within the maximum power point. In this paper, we propose the application of the robust sliding mode control technique to a DC-DC buck converter which is combined with a classical P & O (perturbation and observation) algorithm to enhance the solar system efficiency. Dynamic equations describing the boost converter are derived and a sliding mode controller for a buck converter is designed. It is shown that, this control approach gives good results in terms of robustness toward load and input voltage variations. The effectiveness of the proposed work is verified by the simulation results under PowerSim environment.展开更多
基金Supported by Financial Innovation Ability Promotion Project of Sichuan Province,China(2013XXXK-013,2016GYSH-023)National Key Technology R&D Program(2012BAD05B03-8)~~
文摘In order to study effects of application of contmllE=d release fertilizer on ni- trous oxide (N2O) emission in slope cultivated land with purple soil, four treatments including the control group (CK), urea (UR), controlled release nitrogen fertilizer (CR), and controlled release nitrogen fertilizer+urea (25%CR, 75%UR) were set up, and their impacts on maize yield, surface runoff and nitrogen loss in the growth pe- riod of maize and N2O emission were studied. The results show that maize yield, surface runoff, nitrogen loss from subsurface flow, and N2O emission in the control group was far lower than that in the fertilization treatments, revealing that fertilization was the main reason for nitrogen loss and N2O emission. Among the four treat- ments, nitrogen loss from subsurface flow in the treatment CR was the highest, up to 31.7 kg/hm^2, but N2O emission was 0.35 kg/hm^2, which was 37% less than that in the treatment UR. Nitrogen loss from subsurface flow in the treatment 25% CR was the lowest, only 20.9 kg/hm^2, and N2O emission was 15% less than that in the treatment UR. Nitrogen was slowly released from controlled release nitrogen fertilizer in the growth period, and controlled release nitrogen fertilizer could reduce N2O emis- .sion from slope cultivated land due to low content of soil inorganic nitrogen, but it could increase the nitrogen loss from subsurface flow. Therefore, the combination of controlled release fertilizer and urea can not only reduce N2O emission but also de- crease nitrogen loss from subsurface flow.
基金Supported by the Key International Cooperation Project of NSFC, Key Project of NSFC (No. 50138010)863 Hi-Technology Research and Development Program of China (2003AA601010).
文摘Nitrogen and phosphorous concentrations of effluent water must be taken into account for the design and operation of wastewater treatment plants. In addition, the requirement for effluent quality is becoming strict. Therefore, intelligent control approaches are recently required in removing biological nutrient. In this study, fuzzy control has been successfully applied to improve the nitrogen removal. Experimental results showed that a close relationship between nitrate concentration and oxidation-reduction potential (ORP) at the end of anoxic zone was found for anoxic/oxic (A/O) nitrogen removal process treating synthetic wastewater. ORP can be used as online fuzzy control parameter of nitrate recirculation and external carbon addition. The established fuzzy logic controller that includes two inputs and one output can maintain ORP value at - 86 mV and - 90 mV by adjusting the nitrate recirculation flow and external carbon dosage respectively to realize the optimal control of nitrogen removal, improving the effluent quality and reducing the operating cost.
文摘Orobanche spp. (broomrapes) are holoparasitic plants distributed predominantly in the Northern Hemisphere parasitizing the roots of a range of plant species mainly in wild ecosystems. Orobanche species cause severe yield reduction of many important crops. There are only very few herbicides which are able to selectively control broomrapes and different approaches have been put forward to develop natural product based pesticides to control Orobanche. Several phytopathogenic fungi were evaluated for their use as potential mycoherbicide and for ability to produce toxic metabolites which could be applied as herbicides. Using the alternative approach "suicidal germination", interesting results were obtained by testing two microbial metabolites (fusicoccins and ophiobolin A) especially with Orobanche species whose germination is not induced by the synthetic strigolactone GR24. From pea root exudates, peagol and peagoldione, close related to strigolactones, and three polyphenols, named peapolyphenols A-C, together with already well known polyphenol and a chalcone, were isolated. They showed a selective stimulation of Orobanche seed germination with the last two and peapolyphenol A showing a specific stimulatory activity on O. foetida. This review describes the most recent results achieved on Orobanche bio-control, mainly focusing on those regarding O. ramosa, O. crenata and O. foetida.
基金This work was supported by the National Natu-ral Science Foundation of China (No.21571166 and No.51271173) and the National Basic Research Pro- gram of China (No.2012CB922001).
文摘Low-dimensional Bi2Fe4O9 nanosheets and microrods have been selectively prepared by a solvothermal method, from which the growth of the Bi2Fe4O9 crystals can be controlled by the variation of reaction conditions. Structure determination showed that the nanosheets are mainly exposed by {001} facets while the microrods are exposed by {110} facets. Ab- sorption spectra revealed that there are two bandgaps observed for both nanosheets (at 1.9 and 1.55 eV) and microrods (1.7 and 1.45 eV), and they both would be available for the sunlight photocatalysis e ciently due to the intensive absorption ability in a wide region. Photocatalytic investigation demonstrated that the overall photocatalytic performance of the microrods is prior to that of the nanosheets due to the variation of bandgaps and exposed facets. The present report provides a useful alternative strategy for the controlling growth of nanostructures and/or microcrystals besides the present demonstration of the Bi2Fe4O9 crystals with diflerent bandgaps and facets that would be able to tune the corresponding photocatalytic ability selectively.
基金Key Creative Project of Shanghai Education Community,China(No.13ZZ050)Key Basic Research Project of Shanghai,China(No.12JC1400400)
文摘This work investigates synchronization of two fractional unified hyperchaotic systems via impulsive control.The stable theory about impulsive fractional equation is studied based on the stable theory about fractional linear system.Then according to the theorem proposed the sufficient condition on feedback strength and impulsive interval are established to guarantee the synchronization.Numerical simulations show the effectiveness of the theorem.
基金This work was supported by"863"Program of China (2004AA601020),The Project of Beijing Science and technology Committee(H020620010120) and the project of Beijing city key laboratory
文摘In this paper three controllers for A/O process are developed, including a DO cascade controller, an external carbon flow rate controller and an internal recycling flow rate controller. The objective of the different controllers is to control the nitrate and ammonia concentration. Simulation study demonstrated that these controllers could efficiently control nitrogen removal and meet stricter effluent quality standards at a minimum cost.
基金financially supported by the Smart Fertilization Project (05)the National Key Research & Development Program of China (2022YFD1700605)。
文摘Reducing ammonia(NH3) and nitrous oxide(N2O) emissions have great effects on mitigating nitrogen(N) nutrient loss and greenhouse gas emissions. Controlled release urea(CRU) can control the N release rate, which reduces reactive N loss and increases nitrogen use efficiency relative to conventional urea(CU). However, the crucial factors influencing the responses of NH3and N2O emissions to CRU relative to CU are still unclear. In this study, we evaluated the responses of NH3and N2O emissions to CRU based on collected field data with a meta-analysis. CRU reduced the NH3and N2O emissions by 32.7 and 25.0% compared with CU, respectively. According to subgroup analysis, CRU presented better mitigation of NH3and N2O emissions in soils with pH 6.5–7.5(–47.9 and –23.7%) relative to either pH<6.5(–28.5and –21.4%) or pH>7.5(–29.3 and –17.3%), and in the rice season(–34.8 and –29.1%) relative to the wheat season(–19.8 and –22.8%). The responses of NH3and N2O emissions to CRU increased from rainfed(–30.5 and –17.0%) to irrigated(–32.5 and –22.9%), and then to paddy(–34.8 and –29.1%) systems. In addition, the response of N2O emission mitigation increased with increases in soil total nitrogen(TN);however, soil TN did not significantly affect the response of NH3volatilization. The reduction in NH3emission was greater in sandy-textured soil(–57.7%) relative to loam-textured(–32.9%) and clay-textured(–32.3%) soils, whereas soil texture did not affect N2O emission. Overall, CRU was a good option for reducing the NH3and N2O emissions relative to CU in agricultural production. This analysis improves our understanding of the crucial environmental and management factors influencing the mitigation of NH3and N2O emissions under CRU application, and these site-specific factors should be considered when applying CRU to reduce reactive N loss and increase NUE.
基金Supported by the National Natural Science Foundation of China under Grant Nos 51571135,11274214 and 61434002the Special Funds of Shanxi Scholars Program under Grant No IRT1156+1 种基金Collaborative Innovation Center for Shanxi Advanced Permanent Materials and Technologythe Special Funds of the Ministry of Education of China under Grant No 20121404130001
文摘Magnetite (Fe3O4) nanoparticles with different sizes and shapes are synthesized by the thermal decomposition method. Two approaches, non-injection one-pot and hot-injection methods, are designed to investigate the growth mechanism in detail. It is found that the size and shape of nanoparticles are determined by adjusting the precursor concentration and duration time, which can be well explained by the mechanism based on the LaMer model in our synthetic system. The monodisperse Fe3O4 nanoparticles have a mean diameter from 5nm to 16nm, and shape evolution from spherical to triangular and cubic. The magnetic properties are size-dependent, and Fe3O4 nanoparticles in small size about 5 nm exhibit superparamagnetie properties at room temperature and maximum saturation magnetization approaches to 78 emu/g, whereas Fe3O4 nanoparticles develop ferromagnetic properties when the diameter increases to about 16nm.
基金Supported by the National Natural Science Funds Youth Project of China(No.51704064)the Fundamental Research Funds for the Central Universities(No.N162302001)+3 种基金Hebei Province Higher Education Science and Technology Research Project(No.ZD2017309)the Scientific and Technological Research and Development Plan of Qinhuangdao City(201701B063)the further support fund of Key Laboratory of Nanomaterials and Photoelectrocatalysis in Qinhuangdao City(201705B021)the Northeastern University at Qinhuangdao Campus Research Fund(XNK201602)
文摘We report a facile method for the synthesis of manganese oxide(Mn3O4) nanorods via the direct reaction of MnCl2 and H2 O2 by doping Yb3+ ions at room temperature and air atmosphere. The Mn3O4:Yb3+ samples were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), cyclic voltammetry(CVs), electrochemical impedance spectroscopy(EIS), and charging-discharging test(CD). The results show that trace Yb3+ doping(6 at%) could effectively induce crystalline transformation of Mn3O4 from cubic system(space group Fd-3 m) to tetragonal system(space group I41/amd) and incite the morphology changing from irregular particles to uniform nanorods. When Yb3+ doping amount is 3%, the capacitance of Mn3O4 reaches the maximum, 246 F/g, which is related to the morphology change and the corresponding decrease of impedance.
基金funded by the Saudi Aramco-KAIST CO_(2)Management Centersupported by a grant from the National Research Foundation of Korea+1 种基金funded by the Ministry of Science,ICT,and Future Planning(Grant no.2021K1A4A8A01079356)supported by the National Research Foundation of Korea(NRF)fund(NRF-2020M3H4A3081874).
文摘Spatial control of lithium deposition is the most important issue in lithium-metal batteries because of the considerable control of lithium dendrite suppression via the uniform distribution of Li^(+)flux.Although seed materials are crucial for the behavior of lithium deposition,in-depth studies on their physical and chemical control have not been conducted.Here,we describe a new design of seed structure comprising a wrinkled Cu/graphene substrate surrounded by copper(Ⅰ)oxide(Cu_(2)O)on a graphene grain boundary over a large area,which is fabricated by the oxidation of the Cu surface via graphene boundary defects by using chemical vapor deposition(CVD).Scanning and transmission electron microscopy results reveal that Cu_(2)O on the graphene boundary can render a preferential reaction with lithium during the first deposition and assist in the uniform deposition of lithium by preventing the agglomeration of lithium clusters during the second deposition.This two-step process is attributed to the degree of selectivity due to the difference in lithium affinity,which allows long-term electrochemical stability and a high rate capability via boundary effects.This study highlights the significance of the boundary effect,which can open new avenues for the formation of a large family of seed structures in lithium-metal batteries.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11374010 and 11434009the Fundamental Research Funds for the Central Universities
文摘Using in situ electric-field-modulated anisotropic magnetoresistance measurement, a large reversible and non- volatile in-plane rotation of magnetic easy axis of -35° between the positive and negative electrical poling states is demonstrated in C040Fe40B20//(001)-cut Pb(Mgl/3Nb2/3)O3-25PbTiO3 (PMN-PT). The specific magneto- electric coupling mechanism therein is experimentally verified to be related to the synchronous in-plane strain rotation induced by 109° ferroelastic domain switching in the (001)-cut PMN-PT substrate.
文摘The Maximum Power Point Tracker (MPPT) is the optimum operating point of a photovoltaic module. It plays a very important role to obtain the maximum power of a solar panel as it allows an optimal use of a photovoltaic system, regardless of irradiation and temperature variations. In this research, we present a novel technique to improve the control’s performances optimization of the system consisting of a photovoltaic panel, a buck converter and a load. Simulations of different parts of the system are developed under Matlab/Simulink, thus allowing a comparison between the performances of the three studied controllers: “Fuzzy TS”, “P&O” and “PSO”. The three algorithms of MPPT associated with these techniques are tested in different meteorological conditions. The obtained results, in different operating conditions, reveal a clear improvement of controlling performances of MPPT of a photovoltaic system when the PSO tracking technique is used.
文摘The MPPT (maximum power point tracking) is one of the most important features of a regulator system that processes the energy produced by a photovoltaic generator. It is necessary, in fact, to design a controller that is able to set the output value of the voltage and ensure the working within the maximum power point. In this paper, we propose the application of the robust sliding mode control technique to a DC-DC buck converter which is combined with a classical P & O (perturbation and observation) algorithm to enhance the solar system efficiency. Dynamic equations describing the boost converter are derived and a sliding mode controller for a buck converter is designed. It is shown that, this control approach gives good results in terms of robustness toward load and input voltage variations. The effectiveness of the proposed work is verified by the simulation results under PowerSim environment.