The transmutation of long-lived fission products through spallation induced by light nuclides was investi-gated for the purpose of determining the feasibility of this approach for long-lived fission products,in both e...The transmutation of long-lived fission products through spallation induced by light nuclides was investi-gated for the purpose of determining the feasibility of this approach for long-lived fission products,in both economic and environmental terms.The cross-section data were obtained from the TALYS Evaluated Nuclear Data Library(TENDL).A thick target model was used to study the consumption of the target isotopes in the transmutation process.The transmutation yield was calculated using the highest beam intensity available with the China initiative accelerator-driven system.It was found that the light nuclide-induced spallation reaction can significantly reduce the radio toxicity of the investigated long-lived fission products.Using the transmutation target made of elemental LLFP and the proton beam with an intensity of 5 mA,the consumption of 90 Sr,93 Zr,107 Pd,or 137 Cs can reach approximately 500 g per year.展开更多
Background The accelerator-driven subcritical transmutation system(ADS)is an advanced technology for the harmless disposal of nuclear waste.A theoretical analysis of the ingredients and content of nuclear waste,partic...Background The accelerator-driven subcritical transmutation system(ADS)is an advanced technology for the harmless disposal of nuclear waste.A theoretical analysis of the ingredients and content of nuclear waste,particularly long-lived waste in a pressurized water reactor(PWR),will provide important information for future spent fuel disposal.Purpose The present study is an attempt to investigate the yields of isotopes in the neutron-induced fission process and estimate the content of long-lived ingredients of nuclear waste in a PWR.Method We combined an approximation of the mass distribution of five Gaussians with the most probable charge model(Zp model)to obtain the isotope yields in the^(235)U(n,f)and^(239)Pu(n,f)processes.The potential energy surface based on the concept of a di-nuclear system model was applied to an approximation using five Gaussian functions.A mathematical formula for the neutron spectrum in a PWR was established,and sets of differential equations were solved to calculate the content of long-lived nuclides in a PWR.Results The calculated isotopic fission yields were in good agreement with the experimental data.Except for 238U,the contents of^(239)Pu,^(240)Pu,^(241)Pu,^(242)Pu,^(237)Np,^(235)U,and^(236)U are predominant in the PWR after reaching a discharge burnup.In addition,some isotope pairs of heavy nuclei reach a similar value after stabilization,which can be explained by the decay chain and effective fission crosssections.For fission fragments,we simulated the content evolution of some long-lived nuclides^(90)Sr,^(107)Pd,^(135)Cs,and their isobars^(90)Rb,^(107)Rh,and^(135)Xe during a fuel cycle in a PWR.The variations in the inventories of uranium and plutonium were in good agreement with the data in Daya Bay.Conclusion A new method is proposed for the prediction of the isotopic fission yield.The inventory of long-lived nuclides was analyzed and predicted after reaching a discharge burnup.展开更多
We observe the spectra of molybdenum for the first time since the first wall of our experimental advanced superconducting tokamak (EAST) was changed mainly to molybdenum tiles. A large amount of molybdenum accumulat...We observe the spectra of molybdenum for the first time since the first wall of our experimental advanced superconducting tokamak (EAST) was changed mainly to molybdenum tiles. A large amount of molybdenum accumulated in the central plasma where the long-lived m = 1 mode instability bursts is shown. Molybdenum is proved to be the main impurity species observed during the formation and lifetime of impurity-induced long-lived m= 1 mode. This may indicate that a close relationship exists between the high-Z impurity accumulation and the occurrence of long-lived m = 1 mode in EAST plasmas.展开更多
Bulk thanks to their characteristics of being environmentally benign,easily fabricated and relatively stable,dyesensitized solar cells(DSSCs)have attracted attention over decades as a potential alternative to solar en...Bulk thanks to their characteristics of being environmentally benign,easily fabricated and relatively stable,dyesensitized solar cells(DSSCs)have attracted attention over decades as a potential alternative to solar energy conversion[1].However,as L.M.Peter pointed out in 2011,'although much more is now known about the physical and chemical processes taking place during operation of the DSSCs,the exponential increase in research effort during this period has not been matched by large increases in efficiency'[2].To date,展开更多
The B3LYP/6-31G^* level of theory was used for the optimization of nonclassical platinum drugs with planar aromatic heterocycle ligands in addition to their monoaqua species, diaqua species and monofunctional adducts...The B3LYP/6-31G^* level of theory was used for the optimization of nonclassical platinum drugs with planar aromatic heterocycle ligands in addition to their monoaqua species, diaqua species and monofunctional adducts. Single point calculations were performed on optimized geometries using the MP2/6-31G^** method, and the Lanl2dz pseudo potential for the Pt atom remained constant in all calculations. It can be easily seen that the trans effect can influence both geometrical structures and bond dissociating energies (BDEs). On the basis of our calculation, we get that the long-lived monofunctional adducts with chloride ligand may be in existence, because they possessed higher stability energies, easily dissociated chloride compared with the monoaqua species dissociating chloride and that replacement of the first chloride by bases became exothermic in solution. Our calculated results also demonstrate that the strongest H-bonds appear in the complexes of q-wG and t-wG using different methods. In comparison with adenine complexes, the corresponding guanine complexes possess larger interaction energies as well as higher stability energies either corrected by basis set superposition error (bsse) of Boys-Bernardi counterpoise method or uncorrected both in gas phase and in solution with one exception that the stability energy of q-CIA complex in solution is larger than that of q,CIG complex. Finally, the nature of bond was analyzed in terms of partial charges distribution based on NBO population.展开更多
For the Na + I2 collision system, theoretical study is performed on the QCISD(T) level by using ab initio method. The ab initio potential energy surfaces are got and on them the long-lived complexes are found and opti...For the Na + I2 collision system, theoretical study is performed on the QCISD(T) level by using ab initio method. The ab initio potential energy surfaces are got and on them the long-lived complexes are found and optimized. These results verify the crossed molecule beam experimental phenomenon and the detailed geometry structures are given for the first time. The role of the complexes in the reaction path is also described in detail.展开更多
Systematization for the maintenance of buildings enables their supporting system to be more practical than before. This study aims to make the maintenance and the long-term repairs for the buildings to be easier. In J...Systematization for the maintenance of buildings enables their supporting system to be more practical than before. This study aims to make the maintenance and the long-term repairs for the buildings to be easier. In Japan, 30-40-year-old buildings seem to have been planned and built with little thought about their future maintenances, which have made them very difficult to be repaired on a large scale. This is why effective management systems about dealing with the data should be strongly suggested. Since the Building Standard Law was amended on April 1, 2008, in Japan, the regular investigation and report for particular buildings are legally obligated every three years, thus a variety of useful data can be obtained through Kitakyushu City cases as well as former data personally obtained. With those data used usefully, systematization for the maintenance of the buildings will produce satisfactory results by building up a connection between those data and the long-term repair planning.展开更多
An intense 14 MeV neutron source facility named OKTAVIAN was installed in the A15 building,Osaka University in 1981.Along the operation period,new radioisotopes with various half-life have been produced as neutron act...An intense 14 MeV neutron source facility named OKTAVIAN was installed in the A15 building,Osaka University in 1981.Along the operation period,new radioisotopes with various half-life have been produced as neutron activation products in its concrete wall shield.In this work,we investigated the concrete wall in the heavy irradiation room of OKTAVIAN using gamma spectrometry method to discover the presence of radioisotope having large half-life value(long-lived radioisotope)as neutron activation products.Computational simulations were performed prior to measurement to predict the presence of long-lived radioisotopes by employing MCNP5 and FISPACT codes.A pre-calibrated Germanium detector with high energy resolution was employed to measure the concrete.Several long-lived activation products have been observed such as 152 Eu,54 Mn,65 Zn,22 Na and 60 Co.The activity of each radioisotope was derived after estimating the detector efficiency using MCNP5.As a result of the measurement and analysis,the followings are concluded:(1)Though presence of activation products represents radiological risk to everyone who performs an experimental activity in the irradiation room of the OKTAVIAN facility,the present result shows that past experiments were carried out safely without any significant additional exposure dose coming from the wall for the last 38 years.(2)The approximated total fluence of D-T neutrons to the wall was successfully estimated from the produced radioisotope,152 Eu,because it has the longest half-life of 13.5 years among the observed radioisotopes.(3)From the results of(1)and(2),it could be possible to estimate the total activity of the concrete wall in the OKTAVIAN facility,which is very essential and important information,because this would be very valuable for decommissioning or disposal of the facility in the future.展开更多
There is presented the review of publications connecting with creation of matrices for the immobilization of long-lived radionuclides and radioactive waste for storage and disposal, as well as for the transmutation. T...There is presented the review of publications connecting with creation of matrices for the immobilization of long-lived radionuclides and radioactive waste for storage and disposal, as well as for the transmutation. This paper substantiates the practicability and feasibility of obtaining the carbon matrces by carbonization of imidoderivatives.展开更多
<strong>Introduction</strong>.<span><span><span style="font-family:;" "=""><span style="font-family:Verdana;"> The molecular biological mechanism ...<strong>Introduction</strong>.<span><span><span style="font-family:;" "=""><span style="font-family:Verdana;"> The molecular biological mechanism of the increased incidence of the various types of cancer in obesity or type 2 diabetes in rodents or humans has largely been resolved in recent years. By contrast, the molecular biological mechanism of the decreased, not increased, incidence of the various types of cancer in the homozygous long-lived Ames dwarf mice still remains unresolved. </span><b><span style="font-family:Verdana;">Objective.</span></b><span style="font-family:Verdana;"> The first objective of the present study was to investigate whether the decrease in the incidence of cancer in the homozygous long-lived Ames dwarf mice is due to the increase, not decrease, in the expression of p27Kip1, a cell cycle repressor protein. The second objective was to investigate whether the decrease in the incidence of cancer in the homozygous long-lived Ames dwarf mice is due to the decrease, not increase, in the levels of glucose or insulin. </span><b><span style="font-family:Verdana;">Methods.</span></b><span style="font-family:Verdana;"> To achieve these objectives, we first performed western immunoblot analysis of the hepatic expression of p27Kip1 protein. We then performed, using a human breast cancer cell line </span><i><span style="font-family:Verdana;">in</span></i> <i><span style="font-family:Verdana;">vitro</span></i><span style="font-family:Verdana;">, the luciferase reporter plasmid assay to determine whether the translation initiation activity of the p27Kip1 mRNA is increased when the concentrations of either glucose or insulin are decreased. </span><b><span style="font-family:Verdana;">Results and Conclusion. </span></b><span style="font-family:Verdana;">The results of the first objective indicated that the hepatic expression of p27Kip1 protein was up-regulated in the homozygous long-lived Ames dwarf mice as expected. We also found that the lower concentrations of glucose or insulin increased the translation initiation activity of the p27Kip1 mRNA.</span></span></span></span>展开更多
The iconic image of a giant radiating dyke swarm subsequently fragmented into three pieces via supercontinental breakup was produced by Paul May in1971(see next page).That figure presented a large part of
A summary is given on the activation cross section measurements performed byChina Institute of Atomic Energy(CIAE),Lanzhou University(LU),Peking University(PU)and Sichuan University(SU)from 1989 to 1994 for ge...A summary is given on the activation cross section measurements performed byChina Institute of Atomic Energy(CIAE),Lanzhou University(LU),Peking University(PU)and Sichuan University(SU)from 1989 to 1994 for generation of long-lived radionuclides of im-portance in fusion reactor technology.The cross sections are measured for the reactions <sup>109</sup>Ag(n,2n)<sup>108</sup>Ag<sup>m</sup>,<sup>151</sup>Eu(n,2n)<sup>150</sup>Eu<sup>m</sup>,<sup>153</sup>Eu(n,2n)<sup>152</sup>Eu<sup>8</sup>,<sup>159</sup>Tb(n,2n)<sup>158</sup>Tb,<sup>179</sup>Hf(n,2n )<sup>178</sup>Hf<sup>m2</sup>,<sup>182</sup>W(n,n′α)<sup>178</sup>Hf<sup>m2</sup>,<sup>187</sup>Re(n,2n)<sup>186</sup>Re<sup>m</sup> and <sup>193</sup>Ir(n,2n)<sup>192</sup>Ir<sup>m2</sup>at 14 MeV,<sup>109</sup>Ag(n,2n)<sup>108</sup>Ag<sup>m</sup>,<sup>151</sup>Eu(n,2n)<sup>150</sup>Eu<sup>m</sup>,<sup>159</sup>Tb(n,2n)<sup>158</sup>Tb and <sup>179</sup>Hf(n,2n)<sup>178</sup>Hf<sup>m2</sup>at 9.5 and 9.9 MeV,and<sup>98</sup>Mo(n,γ)<sup>199</sup>Mo(β<sup>-</sup>)→<sup>99</sup>Tc,<sup>165</sup>Ho(n.γ)<sup>166</sup>Ho<sup>m</sup> and <sup>151</sup>Eu(n,γ)<sup>152</sup>Eu<sup>8</sup> in the energy range of20~1100 keV.Some of them were calculated by systematic and HFTT code,which was basedon the compound nucleus evaporation and the preequilibrium exciton model.展开更多
Effective engineering asset management(EAM)is critical to economic development and improving livability in society,but its complexity often impedes optimal asset functionalities.Digital twins(DTs)could revolutionize t...Effective engineering asset management(EAM)is critical to economic development and improving livability in society,but its complexity often impedes optimal asset functionalities.Digital twins(DTs)could revolutionize the EAM paradigm by bidirectionally linking the physical and digital worlds in real time.There is great industrial and academic interest in DTs for EAM.However,previous review studies have predominately focused on technical aspects using limited life-cycle perspectives,failing to holistically synthesize DTs for EAM from the managerial point of view.Based on a systematic literature review,we introduce an analytical framework for describing DTs for EAM,which encompasses three levels:DT 1.0 for technical EAM,DT 2.0 for technical-human EAM,and DT 3.0 for technical-environmental EAM.Using this framework,we identify what is known,what is unknown,and future directions at each level.DT 1.0 addresses issues of asset quality,progress,and cost management,generating technical value.It lacks multi-objective self-adaptive EAM,however,and suffers from high application cost.It is imperative to enable closed-loop EAM in order to provide various functional services with affordable DT 1.0.DT 2.0 accommodates issues of human-machine symbiosis,safety,and flexibility management,generating managerial value beyond the technical performance improvement of engineering assets.However,DT 2.0 currently lacks the automation and security of human-machine interactions and the managerial value related to humans is not prominent enough.Future research needs to align technical and managerial value with highly automated and secure DT 2.0.DT 3.0 covers issues of participatory governance,organization management,sustainable development,and resilience enhancement,generating macro social value.Yet it suffers from organizational fragmentation and can only address limited social governance issues.Numerous research opportunities exist to coordinate different stakeholders.Similarly,future research opportunities exist to develop DT 3.0 in a more open and complex system.展开更多
Asset-backed securities are developed through complex processes such as asset restructuring and credit enhancement.Therefore,the information asymmetry between issuers and investors is greater compared to traditional s...Asset-backed securities are developed through complex processes such as asset restructuring and credit enhancement.Therefore,the information asymmetry between issuers and investors is greater compared to traditional securities,which imposes higher requirements on information disclosure for asset-backed securities.Asset-backed securities have characteristics such as diversified disclosers,differentiated disclosure content,and specialized risk factors.China has already formulated a series of rules and regulations regarding information disclosure of asset-backed securities.It is imperative to develop specialized laws and regulations for asset-backed securities,encompass original equity holders and credit enhancement agencies as information disclosers,incorporate information such as underlying asset details,cash flow projections,and credit ratings and enhancements into the disclosure content,and improve the legal liability rules to effectively address false disclosures.展开更多
As climate change draws more attention globally,the development of low-carbon economy has become an inevitable choice for mankind to achieve sustainable development.The increasingly strict control of carbon emission i...As climate change draws more attention globally,the development of low-carbon economy has become an inevitable choice for mankind to achieve sustainable development.The increasingly strict control of carbon emission is making carbon emission rights a scarce resource and endowing the rights with the attributes of assets and commodities.China has announced the goal of“carbon emission peaking before 2030 and carbon neutralization before 2060”.Responding to this goal,as major carbon emitters,oil companies play the role of a driving force for green and low-carbon development.Carbon assets management is a key path for oil companies to achieve emission reduction goals and low-carbon transformation.However,the carbon assets management of China’s oil companies is still in the initial stage,with the system and regulations not yet sound,and the management process not yet closed loop.First the modes and experiences of carbon assets management in major international oil companies is introduced.Then the objective logical relationship and linkage laws between carbon assets management and enterprise value creation are comprehensively analyzed by integrating the basic theories of economics and management.On this basis,a value-creation oriented carbon assets management system for oil companies is constructed,mainly covering aspects such as enterprise strategy,control mechanisms,carbon inventory,and management modes.展开更多
As educational activities realize value transmission and value realization through a digital form, the Digital transformation of universities continues to advance. The quantity of asset data continues to grow, with in...As educational activities realize value transmission and value realization through a digital form, the Digital transformation of universities continues to advance. The quantity of asset data continues to grow, with internal value reflected in education, management, and services, while external value is reflected in policies, resources and reputation. Therefore, effective management of university assets is particularly important. Blockchain is an important infrastructure for Digital transformation, which provides a trusted environment for the occurrence of various collaborations and will reshape many collaboration mechanisms. This paper discusses the current situation and problems faced by universities in the process of Digital transformation. We analyze the development opportunities brought about by Digital transformation and the specific problems faced by physical asset management in detail. We discuss the data platform optimization, asset data application, digital asset security, planning strategy, and construction path of digital transformation involved in the physical asset management of universities.展开更多
This paper explores the audit risks associated with the recognition of data assets on financial statements,focusing on the complexities arising from their replicability,unique valuation patterns,and contextual depende...This paper explores the audit risks associated with the recognition of data assets on financial statements,focusing on the complexities arising from their replicability,unique valuation patterns,and contextual dependencies.It identifies major misstatement risks at both the financial statement and assertion levels,including the potential for management to exaggerate data asset values,uncertainties in valuation methods,and deficiencies in data governance and internal controls.Additionally,auditors’lack of professional knowledge and inappropriate audit methods can lead to inspection risks.The paper emphasizes the urgent need for enhanced accounting standards for data assets,effective guidelines for their recognition and measurement,and robust internal controls.Furthermore,it advocates for the exploration of effective valuation methods and the incorporation of advanced technologies,such as big data and AI,into auditing practices.By improving auditor training and methodologies,organizations can better manage the inherent risks associated with data asset auditing.展开更多
Based on field visit and interview,the current situation of snow village in China is summarized from four aspects:core scenic spots in snow village,skiing industry in snow village,film and television industry in snow ...Based on field visit and interview,the current situation of snow village in China is summarized from four aspects:core scenic spots in snow village,skiing industry in snow village,film and television industry in snow village,and ice and snow agritainment.The investigation found that there are still significant problems in homogenization,scenic area infrastructure,and government regulation in snow village.Targeted solutions are proposed from four aspects:tapping internal advantages,strengthening top-level design and infrastructure construction,promoting tourism industry upgrading,and collaborating to innovate the ice and snow tourism supply chain,in order to further promote the economic development of snow village.展开更多
Fixed assets in universities occupy an important position in university management due to their wide coverage and large amount of money.Due to insufficient funding supply,private universities mainly focus on the alloc...Fixed assets in universities occupy an important position in university management due to their wide coverage and large amount of money.Due to insufficient funding supply,private universities mainly focus on the allocation and utilization of fixed assets,which reflects the overall characteristics of cautious allocation,maximum utilization,and delayed elimination in the actual management of fixed assets.This article aims to conduct research and analysis on the entire lifecycle process of the allocation,use,and disposal of fixed assets in private universities,summarize the problems existing in the internal control of fixed assets in private universities,and propose corresponding countermeasures and suggestions in a targeted manner.展开更多
基金supported by the National Natural Science Foundation of China(No.11875328).
文摘The transmutation of long-lived fission products through spallation induced by light nuclides was investi-gated for the purpose of determining the feasibility of this approach for long-lived fission products,in both economic and environmental terms.The cross-section data were obtained from the TALYS Evaluated Nuclear Data Library(TENDL).A thick target model was used to study the consumption of the target isotopes in the transmutation process.The transmutation yield was calculated using the highest beam intensity available with the China initiative accelerator-driven system.It was found that the light nuclide-induced spallation reaction can significantly reduce the radio toxicity of the investigated long-lived fission products.Using the transmutation target made of elemental LLFP and the proton beam with an intensity of 5 mA,the consumption of 90 Sr,93 Zr,107 Pd,or 137 Cs can reach approximately 500 g per year.
基金This work was supported by the National Natural Science Foundation of China(No.11605296)the Natural Science Foundation of Guangdong Province,China(No.2016A030310208)Fundamental Research Funds for Central Universities(No.18lgpy87).
文摘Background The accelerator-driven subcritical transmutation system(ADS)is an advanced technology for the harmless disposal of nuclear waste.A theoretical analysis of the ingredients and content of nuclear waste,particularly long-lived waste in a pressurized water reactor(PWR),will provide important information for future spent fuel disposal.Purpose The present study is an attempt to investigate the yields of isotopes in the neutron-induced fission process and estimate the content of long-lived ingredients of nuclear waste in a PWR.Method We combined an approximation of the mass distribution of five Gaussians with the most probable charge model(Zp model)to obtain the isotope yields in the^(235)U(n,f)and^(239)Pu(n,f)processes.The potential energy surface based on the concept of a di-nuclear system model was applied to an approximation using five Gaussian functions.A mathematical formula for the neutron spectrum in a PWR was established,and sets of differential equations were solved to calculate the content of long-lived nuclides in a PWR.Results The calculated isotopic fission yields were in good agreement with the experimental data.Except for 238U,the contents of^(239)Pu,^(240)Pu,^(241)Pu,^(242)Pu,^(237)Np,^(235)U,and^(236)U are predominant in the PWR after reaching a discharge burnup.In addition,some isotope pairs of heavy nuclei reach a similar value after stabilization,which can be explained by the decay chain and effective fission crosssections.For fission fragments,we simulated the content evolution of some long-lived nuclides^(90)Sr,^(107)Pd,^(135)Cs,and their isobars^(90)Rb,^(107)Rh,and^(135)Xe during a fuel cycle in a PWR.The variations in the inventories of uranium and plutonium were in good agreement with the data in Daya Bay.Conclusion A new method is proposed for the prediction of the isotopic fission yield.The inventory of long-lived nuclides was analyzed and predicted after reaching a discharge burnup.
基金Supported by the National Magnetic Confinement Fusion Science Program of China under Grant Nos 2013GB112004 and 2015GB103002the Natural Science Research Key Project of Education Department of Anhui Province under Grant No KJ2016A434+3 种基金the Doctoral Scientific Research Foundation of Anqing Normal University under Grant No 044-140001000024the National Natural Science Foundation of China under Grant Nos 11275231,11305212,11405212 and 11261140328the Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology under Grant No 2014FXCX003the Hefei Science Center CAS Users with Potential Project under Grant No 2015HSC-UP007
文摘We observe the spectra of molybdenum for the first time since the first wall of our experimental advanced superconducting tokamak (EAST) was changed mainly to molybdenum tiles. A large amount of molybdenum accumulated in the central plasma where the long-lived m = 1 mode instability bursts is shown. Molybdenum is proved to be the main impurity species observed during the formation and lifetime of impurity-induced long-lived m= 1 mode. This may indicate that a close relationship exists between the high-Z impurity accumulation and the occurrence of long-lived m = 1 mode in EAST plasmas.
基金supported by NSFC for Creative Research Groups (21421004)Distinguished Young Scholars (21325625)+4 种基金NSFC/China (21636002)Oriental ScholarshipFundamental Research Funds for the Central Universities (WJ1416005)Scientific Committee of Shanghai (15XD1501400)Programme of Introducing Talents of Discipline to Universities (B16017)
文摘Bulk thanks to their characteristics of being environmentally benign,easily fabricated and relatively stable,dyesensitized solar cells(DSSCs)have attracted attention over decades as a potential alternative to solar energy conversion[1].However,as L.M.Peter pointed out in 2011,'although much more is now known about the physical and chemical processes taking place during operation of the DSSCs,the exponential increase in research effort during this period has not been matched by large increases in efficiency'[2].To date,
基金This work was supported by the Science Foundation of Jinan University (639)
文摘The B3LYP/6-31G^* level of theory was used for the optimization of nonclassical platinum drugs with planar aromatic heterocycle ligands in addition to their monoaqua species, diaqua species and monofunctional adducts. Single point calculations were performed on optimized geometries using the MP2/6-31G^** method, and the Lanl2dz pseudo potential for the Pt atom remained constant in all calculations. It can be easily seen that the trans effect can influence both geometrical structures and bond dissociating energies (BDEs). On the basis of our calculation, we get that the long-lived monofunctional adducts with chloride ligand may be in existence, because they possessed higher stability energies, easily dissociated chloride compared with the monoaqua species dissociating chloride and that replacement of the first chloride by bases became exothermic in solution. Our calculated results also demonstrate that the strongest H-bonds appear in the complexes of q-wG and t-wG using different methods. In comparison with adenine complexes, the corresponding guanine complexes possess larger interaction energies as well as higher stability energies either corrected by basis set superposition error (bsse) of Boys-Bernardi counterpoise method or uncorrected both in gas phase and in solution with one exception that the stability energy of q-CIA complex in solution is larger than that of q,CIG complex. Finally, the nature of bond was analyzed in terms of partial charges distribution based on NBO population.
文摘For the Na + I2 collision system, theoretical study is performed on the QCISD(T) level by using ab initio method. The ab initio potential energy surfaces are got and on them the long-lived complexes are found and optimized. These results verify the crossed molecule beam experimental phenomenon and the detailed geometry structures are given for the first time. The role of the complexes in the reaction path is also described in detail.
文摘Systematization for the maintenance of buildings enables their supporting system to be more practical than before. This study aims to make the maintenance and the long-term repairs for the buildings to be easier. In Japan, 30-40-year-old buildings seem to have been planned and built with little thought about their future maintenances, which have made them very difficult to be repaired on a large scale. This is why effective management systems about dealing with the data should be strongly suggested. Since the Building Standard Law was amended on April 1, 2008, in Japan, the regular investigation and report for particular buildings are legally obligated every three years, thus a variety of useful data can be obtained through Kitakyushu City cases as well as former data personally obtained. With those data used usefully, systematization for the maintenance of the buildings will produce satisfactory results by building up a connection between those data and the long-term repair planning.
文摘An intense 14 MeV neutron source facility named OKTAVIAN was installed in the A15 building,Osaka University in 1981.Along the operation period,new radioisotopes with various half-life have been produced as neutron activation products in its concrete wall shield.In this work,we investigated the concrete wall in the heavy irradiation room of OKTAVIAN using gamma spectrometry method to discover the presence of radioisotope having large half-life value(long-lived radioisotope)as neutron activation products.Computational simulations were performed prior to measurement to predict the presence of long-lived radioisotopes by employing MCNP5 and FISPACT codes.A pre-calibrated Germanium detector with high energy resolution was employed to measure the concrete.Several long-lived activation products have been observed such as 152 Eu,54 Mn,65 Zn,22 Na and 60 Co.The activity of each radioisotope was derived after estimating the detector efficiency using MCNP5.As a result of the measurement and analysis,the followings are concluded:(1)Though presence of activation products represents radiological risk to everyone who performs an experimental activity in the irradiation room of the OKTAVIAN facility,the present result shows that past experiments were carried out safely without any significant additional exposure dose coming from the wall for the last 38 years.(2)The approximated total fluence of D-T neutrons to the wall was successfully estimated from the produced radioisotope,152 Eu,because it has the longest half-life of 13.5 years among the observed radioisotopes.(3)From the results of(1)and(2),it could be possible to estimate the total activity of the concrete wall in the OKTAVIAN facility,which is very essential and important information,because this would be very valuable for decommissioning or disposal of the facility in the future.
文摘There is presented the review of publications connecting with creation of matrices for the immobilization of long-lived radionuclides and radioactive waste for storage and disposal, as well as for the transmutation. This paper substantiates the practicability and feasibility of obtaining the carbon matrces by carbonization of imidoderivatives.
文摘<strong>Introduction</strong>.<span><span><span style="font-family:;" "=""><span style="font-family:Verdana;"> The molecular biological mechanism of the increased incidence of the various types of cancer in obesity or type 2 diabetes in rodents or humans has largely been resolved in recent years. By contrast, the molecular biological mechanism of the decreased, not increased, incidence of the various types of cancer in the homozygous long-lived Ames dwarf mice still remains unresolved. </span><b><span style="font-family:Verdana;">Objective.</span></b><span style="font-family:Verdana;"> The first objective of the present study was to investigate whether the decrease in the incidence of cancer in the homozygous long-lived Ames dwarf mice is due to the increase, not decrease, in the expression of p27Kip1, a cell cycle repressor protein. The second objective was to investigate whether the decrease in the incidence of cancer in the homozygous long-lived Ames dwarf mice is due to the decrease, not increase, in the levels of glucose or insulin. </span><b><span style="font-family:Verdana;">Methods.</span></b><span style="font-family:Verdana;"> To achieve these objectives, we first performed western immunoblot analysis of the hepatic expression of p27Kip1 protein. We then performed, using a human breast cancer cell line </span><i><span style="font-family:Verdana;">in</span></i> <i><span style="font-family:Verdana;">vitro</span></i><span style="font-family:Verdana;">, the luciferase reporter plasmid assay to determine whether the translation initiation activity of the p27Kip1 mRNA is increased when the concentrations of either glucose or insulin are decreased. </span><b><span style="font-family:Verdana;">Results and Conclusion. </span></b><span style="font-family:Verdana;">The results of the first objective indicated that the hepatic expression of p27Kip1 protein was up-regulated in the homozygous long-lived Ames dwarf mice as expected. We also found that the lower concentrations of glucose or insulin increased the translation initiation activity of the p27Kip1 mRNA.</span></span></span></span>
文摘The iconic image of a giant radiating dyke swarm subsequently fragmented into three pieces via supercontinental breakup was produced by Paul May in1971(see next page).That figure presented a large part of
基金The project cartied OHt under IAEA Research Agreement No 5060/CF
文摘A summary is given on the activation cross section measurements performed byChina Institute of Atomic Energy(CIAE),Lanzhou University(LU),Peking University(PU)and Sichuan University(SU)from 1989 to 1994 for generation of long-lived radionuclides of im-portance in fusion reactor technology.The cross sections are measured for the reactions <sup>109</sup>Ag(n,2n)<sup>108</sup>Ag<sup>m</sup>,<sup>151</sup>Eu(n,2n)<sup>150</sup>Eu<sup>m</sup>,<sup>153</sup>Eu(n,2n)<sup>152</sup>Eu<sup>8</sup>,<sup>159</sup>Tb(n,2n)<sup>158</sup>Tb,<sup>179</sup>Hf(n,2n )<sup>178</sup>Hf<sup>m2</sup>,<sup>182</sup>W(n,n′α)<sup>178</sup>Hf<sup>m2</sup>,<sup>187</sup>Re(n,2n)<sup>186</sup>Re<sup>m</sup> and <sup>193</sup>Ir(n,2n)<sup>192</sup>Ir<sup>m2</sup>at 14 MeV,<sup>109</sup>Ag(n,2n)<sup>108</sup>Ag<sup>m</sup>,<sup>151</sup>Eu(n,2n)<sup>150</sup>Eu<sup>m</sup>,<sup>159</sup>Tb(n,2n)<sup>158</sup>Tb and <sup>179</sup>Hf(n,2n)<sup>178</sup>Hf<sup>m2</sup>at 9.5 and 9.9 MeV,and<sup>98</sup>Mo(n,γ)<sup>199</sup>Mo(β<sup>-</sup>)→<sup>99</sup>Tc,<sup>165</sup>Ho(n.γ)<sup>166</sup>Ho<sup>m</sup> and <sup>151</sup>Eu(n,γ)<sup>152</sup>Eu<sup>8</sup> in the energy range of20~1100 keV.Some of them were calculated by systematic and HFTT code,which was basedon the compound nucleus evaporation and the preequilibrium exciton model.
基金supported by the National Natural Science Foundation of China(72001160)the National Social Science Fund of China(19VDL001 and 18ZDA043)+2 种基金the National Key Research and Development(R&D)Program of China(2022YFC3801700)the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement(101034337)the Support Program for Young and Middle-Tech Leading Talents of Tongji University.
文摘Effective engineering asset management(EAM)is critical to economic development and improving livability in society,but its complexity often impedes optimal asset functionalities.Digital twins(DTs)could revolutionize the EAM paradigm by bidirectionally linking the physical and digital worlds in real time.There is great industrial and academic interest in DTs for EAM.However,previous review studies have predominately focused on technical aspects using limited life-cycle perspectives,failing to holistically synthesize DTs for EAM from the managerial point of view.Based on a systematic literature review,we introduce an analytical framework for describing DTs for EAM,which encompasses three levels:DT 1.0 for technical EAM,DT 2.0 for technical-human EAM,and DT 3.0 for technical-environmental EAM.Using this framework,we identify what is known,what is unknown,and future directions at each level.DT 1.0 addresses issues of asset quality,progress,and cost management,generating technical value.It lacks multi-objective self-adaptive EAM,however,and suffers from high application cost.It is imperative to enable closed-loop EAM in order to provide various functional services with affordable DT 1.0.DT 2.0 accommodates issues of human-machine symbiosis,safety,and flexibility management,generating managerial value beyond the technical performance improvement of engineering assets.However,DT 2.0 currently lacks the automation and security of human-machine interactions and the managerial value related to humans is not prominent enough.Future research needs to align technical and managerial value with highly automated and secure DT 2.0.DT 3.0 covers issues of participatory governance,organization management,sustainable development,and resilience enhancement,generating macro social value.Yet it suffers from organizational fragmentation and can only address limited social governance issues.Numerous research opportunities exist to coordinate different stakeholders.Similarly,future research opportunities exist to develop DT 3.0 in a more open and complex system.
文摘Asset-backed securities are developed through complex processes such as asset restructuring and credit enhancement.Therefore,the information asymmetry between issuers and investors is greater compared to traditional securities,which imposes higher requirements on information disclosure for asset-backed securities.Asset-backed securities have characteristics such as diversified disclosers,differentiated disclosure content,and specialized risk factors.China has already formulated a series of rules and regulations regarding information disclosure of asset-backed securities.It is imperative to develop specialized laws and regulations for asset-backed securities,encompass original equity holders and credit enhancement agencies as information disclosers,incorporate information such as underlying asset details,cash flow projections,and credit ratings and enhancements into the disclosure content,and improve the legal liability rules to effectively address false disclosures.
文摘As climate change draws more attention globally,the development of low-carbon economy has become an inevitable choice for mankind to achieve sustainable development.The increasingly strict control of carbon emission is making carbon emission rights a scarce resource and endowing the rights with the attributes of assets and commodities.China has announced the goal of“carbon emission peaking before 2030 and carbon neutralization before 2060”.Responding to this goal,as major carbon emitters,oil companies play the role of a driving force for green and low-carbon development.Carbon assets management is a key path for oil companies to achieve emission reduction goals and low-carbon transformation.However,the carbon assets management of China’s oil companies is still in the initial stage,with the system and regulations not yet sound,and the management process not yet closed loop.First the modes and experiences of carbon assets management in major international oil companies is introduced.Then the objective logical relationship and linkage laws between carbon assets management and enterprise value creation are comprehensively analyzed by integrating the basic theories of economics and management.On this basis,a value-creation oriented carbon assets management system for oil companies is constructed,mainly covering aspects such as enterprise strategy,control mechanisms,carbon inventory,and management modes.
文摘As educational activities realize value transmission and value realization through a digital form, the Digital transformation of universities continues to advance. The quantity of asset data continues to grow, with internal value reflected in education, management, and services, while external value is reflected in policies, resources and reputation. Therefore, effective management of university assets is particularly important. Blockchain is an important infrastructure for Digital transformation, which provides a trusted environment for the occurrence of various collaborations and will reshape many collaboration mechanisms. This paper discusses the current situation and problems faced by universities in the process of Digital transformation. We analyze the development opportunities brought about by Digital transformation and the specific problems faced by physical asset management in detail. We discuss the data platform optimization, asset data application, digital asset security, planning strategy, and construction path of digital transformation involved in the physical asset management of universities.
文摘This paper explores the audit risks associated with the recognition of data assets on financial statements,focusing on the complexities arising from their replicability,unique valuation patterns,and contextual dependencies.It identifies major misstatement risks at both the financial statement and assertion levels,including the potential for management to exaggerate data asset values,uncertainties in valuation methods,and deficiencies in data governance and internal controls.Additionally,auditors’lack of professional knowledge and inappropriate audit methods can lead to inspection risks.The paper emphasizes the urgent need for enhanced accounting standards for data assets,effective guidelines for their recognition and measurement,and robust internal controls.Furthermore,it advocates for the exploration of effective valuation methods and the incorporation of advanced technologies,such as big data and AI,into auditing practices.By improving auditor training and methodologies,organizations can better manage the inherent risks associated with data asset auditing.
文摘Based on field visit and interview,the current situation of snow village in China is summarized from four aspects:core scenic spots in snow village,skiing industry in snow village,film and television industry in snow village,and ice and snow agritainment.The investigation found that there are still significant problems in homogenization,scenic area infrastructure,and government regulation in snow village.Targeted solutions are proposed from four aspects:tapping internal advantages,strengthening top-level design and infrastructure construction,promoting tourism industry upgrading,and collaborating to innovate the ice and snow tourism supply chain,in order to further promote the economic development of snow village.
文摘Fixed assets in universities occupy an important position in university management due to their wide coverage and large amount of money.Due to insufficient funding supply,private universities mainly focus on the allocation and utilization of fixed assets,which reflects the overall characteristics of cautious allocation,maximum utilization,and delayed elimination in the actual management of fixed assets.This article aims to conduct research and analysis on the entire lifecycle process of the allocation,use,and disposal of fixed assets in private universities,summarize the problems existing in the internal control of fixed assets in private universities,and propose corresponding countermeasures and suggestions in a targeted manner.