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Reliability and sensitivity analysis of loop-designed security and stability control system in interconnected power systems 被引量:5
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作者 Shenghu Li Huimin Zhou +2 位作者 Yunsong Yan Wei Han Jianfeng Ren 《Global Energy Interconnection》 EI CAS CSCD 2022年第5期501-511,共11页
Security and stability control system(SSCS)in power systems involves collecting information and sending the decision from/to control stations at different layers;the tree structure of the SSCS requires more levels.Fai... Security and stability control system(SSCS)in power systems involves collecting information and sending the decision from/to control stations at different layers;the tree structure of the SSCS requires more levels.Failure of a station or channel can cause all the execution stations(EXs)to be out of control.The randomness of the controllable capacity of the EXs increases the difficulty of the reliability evaluation of the SSCS.In this study,the loop designed SSCS and reliability analysis are examined for the interconnected systems.The uncertainty analysis of the controllable capacity based on the evidence theory for the SSCS is proposed.The bidirectional and loop channels are introduced to reduce the layers and stations of the existing SSCS with tree configuration.The reliability evaluation and sensitivity analysis are proposed to quantify the controllability and vulnerable components for the SSCS in different configurations.By aiming at the randomness of the controllable capacity of the EXs,the uncertainty analysis of the controllable capacity of the SSCS based on the evidence theory is proposed to quantify the probability of the SSCS for balancing the active power deficiency of the grid. 展开更多
关键词 Security and stability control system(SSCS) loop design CONTROLLABILITY VULNERABILITY Interconnected power systems Evidence theory Uncertainty controllable capacity.
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INTEGRATION OF CELL FORMATION AND LAYOUT DESIGN IN THE UNIDIRECTIONAL LOOP MATERIAL HANDLING ENVIRONMENT 被引量:3
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作者 LeiDeming WuZhiming 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2005年第2期286-289,共4页
A two-phase approach is proposed to deal with the integration problem in theloop layout. Tabu search is applied to cell construction in phase 1 to minimize the inter-cell flow,and the heuristic for layout design is us... A two-phase approach is proposed to deal with the integration problem in theloop layout. Tabu search is applied to cell construction in phase 1 to minimize the inter-cell flow,and the heuristic for layout design is used as phase 2 to optimize the sum of intra-cell andinter-cell transportation cost. The final computational results demonstrate the validation of thetwo-phase approach. 展开更多
关键词 Unidirectiona loop Cell formation Layout design Tabu search
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Literature Review on Network Design Problems in Closed Loop and Reverse Supply Chains 被引量:1
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作者 Muthusamy Aravendan Ramasamy Panneerselvam 《Intelligent Information Management》 2014年第3期104-117,共14页
The productivity of an organization is very much affected by non-value adding activity like logistics, which moves the resources from suppliers to factory, raw materials/semi-finished items within the factory and fini... The productivity of an organization is very much affected by non-value adding activity like logistics, which moves the resources from suppliers to factory, raw materials/semi-finished items within the factory and finished goods from factory to customers via a designated distribution channel called as forward logistics. In some cases, parts of the products such as automobiles, computers, cameras, mobile phones, washing machines, refrigerators, garments, footwear and empty glass bottles of beverages, etc. will be brought back to the factories as a product recovery strategy through reverse logistics network which is integrated in a sustainable closed loop supply chain network. So, it is highly essential to optimize the movement of the items in the reverse logistics network. This paper gives a comprehensive review of literature of the design of networks for the reverse logistics as well as for the reverse logistics coupled with forward logistics. The contributions of the researchers are classified into nine categories based on the methods used to design the logistics network. 展开更多
关键词 Supply CHAIN Network design CLOSED-loop REVERSE LOGISTICS Models HEURISTICS Algorithms
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An Integrated Multi-Echelon Model for a Sustainable Closed Loop Supply Chain Network Design 被引量:1
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作者 Muthusamy Aravendan Ramasamy Panneerselvam 《Intelligent Information Management》 2014年第6期257-279,共23页
The integration of entire supply and value chain into a closed loop network is gaining more importance in recent times in order to ensure a business to be economically and environmentally sustainable with the changing... The integration of entire supply and value chain into a closed loop network is gaining more importance in recent times in order to ensure a business to be economically and environmentally sustainable with the changing trends in business and social environments, growing environmental consciousness in the society and government legislations to protect the environment as well as the business. In this context, this paper considers a multi-echelon closed loop supply chain network design with forward and reverse logistics components. An attempt has been made to develop a mixed integer non-linear programming model for this problem with different costs so that the sum of the total cost is minimized subject to different constraints pertaining to capacities of the entities of the system, demands of first customers and second customers. A generalized model is presented and then its application is illustrated using an example problem by solving the model using LINGO14. This model forms as a tool to compare future meta-heuristics to check the closeness of their solutions with corresponding optimal solutions. 展开更多
关键词 Closed loop Forward INTEGRATED MODEL MULTI-ECHELON MINLP Network design RESPONSIVENESS Reverse SUSTAINABLE
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Development and Comparison of Hybrid Genetic Algorithms for Network Design Problem in Closed Loop Supply Chain 被引量:1
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作者 Muthusamy Aravendan Ramasamy Panneerselvam 《Intelligent Information Management》 2015年第6期313-338,共26页
This paper presents four different hybrid genetic algorithms for network design problem in closed loop supply chain. They are compared using a complete factorial experiment with two factors, viz. problem size and algo... This paper presents four different hybrid genetic algorithms for network design problem in closed loop supply chain. They are compared using a complete factorial experiment with two factors, viz. problem size and algorithm. Based on the significance of the factor “algorithm”, the best algorithm is identified using Duncan’s multiple range test. Then it is compared with a mathematical model in terms of total cost. It is found that the best hybrid genetic algorithm identified gives results on par with the mathematical model in statistical terms. So, the best algorithm out of four algorithm proposed in this paper is proved to be superior to all other algorithms for all sizes of problems and its performance is equal to that of the mathematical model for small size and medium size problems. 展开更多
关键词 CLOSED loop Supply CHAIN GENETIC Algorithms HGA META-HEURISTICS MINLP Model Network design Optimization
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淡水鱼类线粒体DNA D-loop基因的引物设计和应用 被引量:18
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作者 黄志坚 徐晓鹏 +4 位作者 唐晶晶 张飓 郑锦卿 李桂峰 何建国 《中山大学学报(自然科学版)》 CAS CSCD 北大核心 2009年第4期84-88,共5页
线粒体DNA测序已广泛应用于鉴定和区分种类以及解决系统进化关系问题。本文选取已测定的主要淡水鱼类的线粒体DNA D-loop基因序列进行同源性比较,寻找保守序列,利用简并性原则设计一对通用的简并引物。利用设计的引物对广东省珠江流域... 线粒体DNA测序已广泛应用于鉴定和区分种类以及解决系统进化关系问题。本文选取已测定的主要淡水鱼类的线粒体DNA D-loop基因序列进行同源性比较,寻找保守序列,利用简并性原则设计一对通用的简并引物。利用设计的引物对广东省珠江流域主要的淡水鱼类线粒体DNA D-loop控制区基因进行扩增,均能获得单一的目的DNA片断,特异性扩增产物大小为1 kb左右。经测序及与GenBank同源序列的比较,证实为包含线粒体控制区全序列的扩增产物。本研究所设计的引物和应用的方法可以快速地同时对多种鱼类进行大规模的遗传背景分析,鉴定某些难于鉴别的近缘物种,为我国鱼类的种类鉴定、地理种群鉴别及种质资源的评估提供重要的工具。 展开更多
关键词 淡水鱼类 线粒体DNA D-loop 引物设计 遗传分析
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活性位点邻近的?-loop对胰蛋白酶热稳定性和活性的影响 被引量:3
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作者 杜坤 甘一如 黄鹤 《高校化学工程学报》 EI CAS CSCD 北大核心 2017年第3期657-662,共6页
以猪源胰蛋白酶作为研究对象,尝试利用删除猪源胰蛋白酶活性位点邻近?-loop的方法来提高其热稳定性和活性。首先通过Gromacs v4.5.5分子动力学模拟软件,预测出了胰蛋白酶的柔性区Fragment 41~46(即?-loop所在区域)。然后根据删除?-loop... 以猪源胰蛋白酶作为研究对象,尝试利用删除猪源胰蛋白酶活性位点邻近?-loop的方法来提高其热稳定性和活性。首先通过Gromacs v4.5.5分子动力学模拟软件,预测出了胰蛋白酶的柔性区Fragment 41~46(即?-loop所在区域)。然后根据删除?-loop结构中不同的氨基酸数目,确立了三个突变R1Q、K3Q及C5Q;通过重叠延伸PCR技术构建突变菌株,发酵表达后,进行了酶热稳定性和活性分析。结果表明,R1Q、K3Q及C5Q的活性在一定程度上均有提高,在热稳定性上R1Q和K3Q有所提高,C5Q有所下降,其中R1Q突变体酶的最高活性较野生型提高了1.42倍,同时,失活半衰期和最适反应温度较野生型也分别提高了213.3 min和11.8℃。实验结果证明,在删除该?-loop中的异亮氨酸后,得到了突变型R1Q酶,成功实现酶双功能的共同进化。该策略有潜力应用于其他工业酶分子的热稳定性和活性改造,为推动生物酶的工业化应用奠定基础。 展开更多
关键词 猪源胰蛋白酶 Ω-loop 理性设计 热稳定性 活性
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RELIABILITY-BASED DESIGN OF COMPOSITES UNDER THE MIXED UNCERTAINTIES AND THE OPTIMIZATION ALGORITHM 被引量:6
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作者 Rui Ge Jianqiao Chen Junhong Wei 《Acta Mechanica Solida Sinica》 SCIE EI 2008年第1期19-27,共9页
This paper proposed a reliability design model for composite materials under the mixture of random and interval variables. Together with the inverse reliability analysis technique, the sequential single-loop optimizat... This paper proposed a reliability design model for composite materials under the mixture of random and interval variables. Together with the inverse reliability analysis technique, the sequential single-loop optimization method is applied to the reliability-based design of composites. In the sequential single-loop optimization, the optimization and the reliability analysis are decoupled to improve the computational efficiency. As shown in examples, the minimum weight problems under the constraint of structural reliability are solved for laminated composites. The Particle Swarm Optimization (PSO) algorithm is utilized to search for the optimal solutions. The design results indicate that, under the mixture of random and interval variables, the method that combines the sequential single-loop optimization and the PSO algorithm can deal effectively with the reliability-based design of composites. 展开更多
关键词 laminated composites inverse reliability analysis reliability-based design sequential single-loop optimization method PSO
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无人集群体系设计与仿真评估方法 被引量:1
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作者 杨松 王维平 +2 位作者 李小波 周鑫 井田 《国防科技大学学报》 EI CAS CSCD 北大核心 2024年第3期126-136,共11页
无人集群作战正在成为一种改变战争形态的新型作战样式。针对当前无人装备试验相对独立、缺乏一体化闭环设计与集成验证手段的问题,提出了一种体系设计与仿真评估方法。该方法包含了作战概念建模与需求分析、体系设计理念与体系设计、... 无人集群作战正在成为一种改变战争形态的新型作战样式。针对当前无人装备试验相对独立、缺乏一体化闭环设计与集成验证手段的问题,提出了一种体系设计与仿真评估方法。该方法包含了作战概念建模与需求分析、体系设计理念与体系设计、内场仿真实验与方案探索、体系原型研发与评估优化、外场集成试验与综合决策五个阶段,创新发展了体系设计、仿真试验、评估优化的理论方法、工具链路、集成环境,为无人集群的体系化、智能化、实战化提供了一定的理论与技术支撑。 展开更多
关键词 无人集群 体系设计 仿真评估 一体化闭环设计 集成验证
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A Rework Reduction Mechanism in Complex Projects Using Design Structure Matrix Clustering Methods 被引量:1
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作者 XU Haiyan ZHAO Shinan +1 位作者 Amin MAHMOUDI Mohammad Reza FEYLIZADEH 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2019年第2期264-279,共16页
To reduce the uncertainty and reworks in complex projects,a novel mechanism is systematically developed in this paper based on two classical design structure matrix(DSM)clustering methods:Loop searching method(LSM)and... To reduce the uncertainty and reworks in complex projects,a novel mechanism is systematically developed in this paper based on two classical design structure matrix(DSM)clustering methods:Loop searching method(LSM)and function searching method(FSM).Specifically,the optimal working areas for the two clustering methods are first obtained quantitatively in terms of non-zero fraction(NZF)and singular value modularity index(SMI),in which the whole working area is divided into six sub-zones.Then,a judgement procedure is proposed for conveniently choosing the optimal DSM clustering method,which makes it easy to determine which DSM clustering method performs better for a given case.Subsequently,a conceptual model is constructed to assist project managers in effectively analyzing the network of projects and greatly reducing reworks in complex projects by defining preventive actions.Finally,the aircraft design process is presented to show how the proposed judgement mechanism can be utilized to reduce the reworks in actual projects. 展开更多
关键词 project management design structure MATRIX loop SEARCHING METHOD FUNCTION SEARCHING METHOD reworks
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Optimization of three-loop missile autopilot gain under crossover frequency constraint 被引量:1
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作者 M.A.ABD-ELATIF Long-jun QIAN Yu-ming BO 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2016年第1期32-38,共7页
The open-loop crossover frequency is pointed as an important parameter for practical autopilot design. Since different gain designs may achieve the same open-loop crossover frequency, it should be neither considered a... The open-loop crossover frequency is pointed as an important parameter for practical autopilot design. Since different gain designs may achieve the same open-loop crossover frequency, it should be neither considered as a performance objective of the optimal autopilot design-schemes nor neglected. Besides, the main assignment of the autopilot is to drive the missile to track the acceleration commands, so the autopilot gain design should be evaluated directly according to the resultant tracking performance. For this purpose, an optimal design methodology of the three-loop missile autopilot is introduced based on constraint optimization technique, where the tracking performance is established analytically as the design objective and the open-loop crossover frequency is formed as inequality constraint function, both are manipulated in terms of stable characteristic parameters of the autopilot closed-loop. The proposed technique is implemented with the assistance of a numerical optimization algorithm which automatically adjusts the design parameters. Finally, numerical simulation results are provided to demonstrate the effectiveness and feasibility of the proposed approach compared with that in some references. 展开更多
关键词 导弹自动驾驶仪 频率约束 优化技术 三回路 增益 设计方法 跟踪性能 数值模拟
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GNSS测量与数据处理课程思政闭环设计
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作者 匡翠林 余文坤 蔡昌盛 《高教学刊》 2024年第25期189-192,共4页
GNSS测量与数据处理是测绘工程专业核心专业课。在我国北斗系统走向世界的背景下,该课程开展课程思政具有诸多先天优势。该文从思政目标、思政切入点、思政元素生成路径、思政教学方法和思政效果评价等方面进行该课程的思政全闭环设计,... GNSS测量与数据处理是测绘工程专业核心专业课。在我国北斗系统走向世界的背景下,该课程开展课程思政具有诸多先天优势。该文从思政目标、思政切入点、思政元素生成路径、思政教学方法和思政效果评价等方面进行该课程的思政全闭环设计,以期将课程的思政建设落地落实、见功见效,与思政课程同向同行,形成协同效应,同时也为同行课程思政教学改革提供实操参考。 展开更多
关键词 GNSS测量与数据处理 课程思政 思政元素 课程设计 全闭环设计
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自动控制辅助设计软件Auto-Design
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作者 陈继 《石油化工自动化》 CAS 2004年第6期10-12,共3页
就自动控制辅助设计软件Auto-Design的功能和使用方法做了较为详细的描述,该软件的使用主要是为了提高自控人员的工作效率,减少重复性劳动。
关键词 工程辅助设计 索引模块 数据模块 电缆模块 回路模块
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兆瓦级高效紧凑型核动力系统运行特性研究
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作者 张明辉 苟军利 +1 位作者 王政 单建强 《核技术》 EI CAS CSCD 北大核心 2024年第2期93-108,共16页
为研究兆瓦级高效紧凑型核动力系统的运行特性,使用自主开发的热管堆瞬态分析程序TAPIRS(Transient Analysis code for heat Pipe and AMTEC power conversion space Reactor power System)和超临界二氧化碳布雷顿循环的瞬态分析程序SCT... 为研究兆瓦级高效紧凑型核动力系统的运行特性,使用自主开发的热管堆瞬态分析程序TAPIRS(Transient Analysis code for heat Pipe and AMTEC power conversion space Reactor power System)和超临界二氧化碳布雷顿循环的瞬态分析程序SCTRAN/CO_(2)(Super Critical reactors Transient Analysis code/Carbon Dioxide)的耦合程序对其反应性、负荷、冷却水温度和流量等扰动进行了开环动态响应分析,并据此进行了控制系统设计。在此基础上,对线性变负荷、阶梯式变负荷以及甩负荷这三种变负荷运行工况进行了计算分析。结果表明:该核动力系统的转速对扰动的变化较为敏感,需要加以控制;低负荷下旁通会使压缩机流量上升,需对压缩机流量加以控制;系统在控制方案下能以6%FP(Full Power)·min^(−1)的速度实现0%~100%的负荷变动,且可以在任意负荷水平下运行;甩负荷下系统的波动时间变长,但是仍可达到新的稳态进行工作,且各参数处于安全范围内。本研究可为新型核动力系统的概念设计提供参考。 展开更多
关键词 兆瓦级高效紧凑新型核动力系统 开环动态响应 控制系统设计 变负荷运行
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基于区段的地下空间环路通风排烟设计方法
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作者 王洁 赵炳欣 姜学鹏 《隧道建设(中英文)》 CSCD 北大核心 2024年第1期155-162,共8页
为实现多匝道、多地块、内部空间复杂的地下空间环路烟气控制,提出一种区段式排烟方法:将地下空间环路与地块通过防火门分隔,形成独立的构筑物,结合隧道结构,确定风机房位置,划分区段,使烟气在一定区域内排出。以滨江地下环路为例,在隧... 为实现多匝道、多地块、内部空间复杂的地下空间环路烟气控制,提出一种区段式排烟方法:将地下空间环路与地块通过防火门分隔,形成独立的构筑物,结合隧道结构,确定风机房位置,划分区段,使烟气在一定区域内排出。以滨江地下环路为例,在隧道主线上均匀布置6个排烟风机房,并以此为节点,将隧道划分为8个区段。当火灾发生时,开启所在区段两端的风机进行排烟。由于各区段不设置固定分隔,整个风道是贯通的,因而各个风机房里的风机可互相作为备用排烟风机,以降低成本。采用数值模拟软件建立模型,对排烟口开启数量和间距进行模拟,确定排烟量为90 m^(3)/s、排烟口间距为30 m、开启8个排烟口的排烟方案。从人员疏散环境以及排烟效率对典型区段进行分析,结果表明:烟气控制在一定的范围内,人员疏散环境安全,排烟效率达到90%,证明方案合理可行。 展开更多
关键词 火灾烟气控制 地下空间环路 通风排烟设计方法 区段划分
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基于大创项目的应用技术开发实践——以数字电源教具设计为例
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作者 韩冬林 闫婧 梁坤仪 《天津中德应用技术大学学报》 2024年第2期70-75,共6页
针对教学环节中的难点和重点内容,基于dsPIC33CK256MP505数字信号控制器芯片,为开发新型的数字电源教具,在降压转换器的电路拓扑结构基础上,利用MplabPowerSmart开发软件,完成了电压控制型数字环路补偿器的设计,实现3P3Z数字补偿器的实... 针对教学环节中的难点和重点内容,基于dsPIC33CK256MP505数字信号控制器芯片,为开发新型的数字电源教具,在降压转换器的电路拓扑结构基础上,利用MplabPowerSmart开发软件,完成了电压控制型数字环路补偿器的设计,实现3P3Z数字补偿器的实时算法功能。 展开更多
关键词 数字电源 环路补偿器 数字信号控制器 教具设计
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实物在环实时仿真教学法研究
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作者 刘丽 《高教学刊》 2024年第2期106-110,共5页
新工科背景下,为培养学生创新实践能力,建设国家级一流本科课程,提出了一种新型的适用于电子技术基础课程的教学方法——实物在环实时仿真教学法,应用于北航数字电子技术基础课程。通过口袋仪器和实际硬件进行数字电路设计,可解决虚拟... 新工科背景下,为培养学生创新实践能力,建设国家级一流本科课程,提出了一种新型的适用于电子技术基础课程的教学方法——实物在环实时仿真教学法,应用于北航数字电子技术基础课程。通过口袋仪器和实际硬件进行数字电路设计,可解决虚拟仿真的真实性问题,培养学生解决复杂工程问题的能力;通过虚拟仪器展示波形,使知识难点可视化,有助于学生更快、更深刻理解。实践表明,这种方法取得了良好的教学效果,提高了教学质量。通过该教学方法学生获得了更丰富的学习体验,培养了创新实践能力。 展开更多
关键词 实物在环仿真 口袋仪器 数字电路设计 虚拟仪器 知识难点可视化
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闪色效果针织面料工艺设计与应用
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作者 陈红娟 《针织工业》 北大核心 2024年第8期22-26,共5页
在进行纬编横向夹色编织的基础上,通过分析并利用双反面组织、变线圈织物、集圈组织线圈结构的特征,设计一系列具有闪色提花效果针织织物。分析3种针织组织的三维立体结构各部分空间遮盖的特点,结合织物闪色形成的原理,总结不同组织闪... 在进行纬编横向夹色编织的基础上,通过分析并利用双反面组织、变线圈织物、集圈组织线圈结构的特征,设计一系列具有闪色提花效果针织织物。分析3种针织组织的三维立体结构各部分空间遮盖的特点,结合织物闪色形成的原理,总结不同组织闪色规律。根据图案设计需求,采用不同显色区域、不同组织结构比例分配进行编织,可以形成图案形态灵活、不同角度色彩变化的闪色织物效果。探讨基于不同组织结构的闪色针织面料设计案例,分析其织物风格特点,同时给出在针织服装上应用的建议。 展开更多
关键词 闪色 针织织物 夹色编织 双反面组织 变线圈织物 集圈组织 工艺设计
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Computer-assisted anti-AIDS drug development: cyclophilin B against the HIV-1 subtype A V3 loop
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作者 Alexander M. Andrianov Ivan V. Anishchenko 《Health》 2010年第7期661-671,共11页
Aim: The objects of this study originated from the experimental observations, whereby the HIV -1 gp120 V3 loop is a high-affinity ligand for immunophilins, and consisted in generating the structural complex of cycloph... Aim: The objects of this study originated from the experimental observations, whereby the HIV -1 gp120 V3 loop is a high-affinity ligand for immunophilins, and consisted in generating the structural complex of cyclophilin (Cyc) B belonging to immunophilins family with the virus subtype A V3 loop (SA-V3 loop) as well as in specifying the Cyc B segment forming the binding site for V3 synthetic copy of which, on the assumption of keeping the 3D peptide structure in the free state, may present a forwardlooking basic structure for anti-AIDS drug development. Methods: To reach the objects of view, molecular docking of the HIV-1 SA-V3 loop structure determined previously with the X-ray conformation of Cyc B was put into practice by Hex 4.5 program (http://www.loria.fr/~ritchied/ hex/) and the immunophilin stretch responsible for binding to V3 (Cyc B peptide) was identified followed by examination of its 3D structure and dynamic behavior in the unbound status. To design the Cyc B peptide, the X-ray conformation for the identical site of the native protein was involved in the calculations as a starting model to find its best energy structural variant. The search for this most preferable structure was carried out by consecutive use of the molecular mechanics and simulated annealing methods. The molecular dynamics computations were implemented for the Cyc B peptide by the GROMACS computer package (http:// www.gromacs.org/). Results: The overmolecular structure of Cyc B with V3 was built by computer modeling tools and the immunophilinderived peptide able to mask effectively the structurally invariant V3 segments embracing the functionally crucial amino acids of the HIV-1 gp120 envelope protein was constructed and analyzed. Conclusions: Starting from the joint analysis of the results derived with those of the literature, the generated peptide was suggested to offer a promising basic structure for making a reality of the protein engineering projects aimed at developing the anti-AIDS drugs able to stop the HIV’s spread. 展开更多
关键词 HIV-1 V3 loop Cyclophilin B Computer Modeling Molecular Docking Anti-Aids Drug design
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化学链燃烧中载氧体结构设计对抗磨性的影响研究
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作者 赵一凡 刘敦禹 金晶 《动力工程学报》 CAS CSCD 北大核心 2024年第4期509-519,共11页
在化学链反应过程中,载氧体作为氧和热量的载体起着至关重要的作用,载氧体设计一直是化学链技术研究的重点和难点。化学链燃烧通常发生在流化床反应器中,由于化学反应带来的化学应力对载氧体磨损贡献率最大,导致载氧体寿命大大缩短,有... 在化学链反应过程中,载氧体作为氧和热量的载体起着至关重要的作用,载氧体设计一直是化学链技术研究的重点和难点。化学链燃烧通常发生在流化床反应器中,由于化学反应带来的化学应力对载氧体磨损贡献率最大,导致载氧体寿命大大缩短,有效成分流失。从载氧体结构设计角度出发,定性评价了不同复合载氧体的抗磨损机理:核壳结构抑制了活性组分的相分离现象,避免了由于活性组分表面磨损带来的载氧体失活;添加Al_(2)O_(3)纤维和“铆钉”抑制了裂纹扩展,减缓了材料的磨损;添加燃料灰改善了复合载氧体的骨架强度,提高了载氧体抗磨性和抗结渣团聚性;利用复合载氧体的协同增效提高了反应活性,减缓了烧结团聚现象。从磨损动力学和使用寿命角度出发,定量比较了不同载氧体的磨损情况:通过对数拟合Gwyn磨损动力学方程,求出不同载氧体拟合参数K和n,可以反映磨损机制和磨损变化规律。 展开更多
关键词 化学链燃烧 结构设计 载氧体 磨损
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