Effects of coating constituent, coating density, coating layer thickness and temperature on coating sorption capacity for polystyrene decomposition products have been studied systematically. It has been found that the...Effects of coating constituent, coating density, coating layer thickness and temperature on coating sorption capacity for polystyrene decomposition products have been studied systematically. It has been found that the effect of attapulgite clay on sorption capacity is the largest among coating constituents. The sorption capacity of the coating with 2% attapulgite clay is elevated by 81%. The relationship between casting porosity and coating sorption capacity has been studied. It has been pointed out that higher coating sorption capacity for polystyrene decomposition products is helpful to decrease the casting porosity. Results also show that the sorption capacity of self-developed HW-1 coating for polystyrene decomposition products is as good as that of Ashland coating from America.展开更多
The effects of modification, grain refinement, polystyrene pattern, pouring temperature and reduced pressure degree on aluminum alloy porosity in lost foam casting (LFC) process were studied. The results show that the...The effects of modification, grain refinement, polystyrene pattern, pouring temperature and reduced pressure degree on aluminum alloy porosity in lost foam casting (LFC) process were studied. The results show that the solidification rate of LFC process is slower than that of resin sand process or clay sand process. The effect of modification and grain refinement on the aluminum alloy casting density in LFC is greater than that on resin sand process. Through α Al phase refinement process with 0.2%Ti for aluminum melt, the subversive effect of Sr modification in LFC process is decreased greatly, and the aluminum casting density in LFC process is nearly equal to that in resin sand process. To decrease the porosity of aluminum castings in LFC process, lower density of polystyrene pattern, higher pouring temperature (760~780 ℃) and lower reduced pressure degree (≤20 kPa) should be applied.[展开更多
By using ICP spectroscopy, energy dispersive spectroscopy (EDS) analysis, X-ray diffraction, SEM and microscope analysis, the effects of Mn on the structure of B319 aluminum alloy are studied. The results show that wi...By using ICP spectroscopy, energy dispersive spectroscopy (EDS) analysis, X-ray diffraction, SEM and microscope analysis, the effects of Mn on the structure of B319 aluminum alloy are studied. The results show that without the addition of Mn, there are coral-like Al_2Cu phase and needle-like β-Fe (Al_5FeSi)in the structure of casting with lost foam casting (LFC). Precipitation of Al_2Cu can take place along the long sides of the β needles. Under the rapid cooling rates, such as ones in metallic mold, the Fe phase appears in the form of Chinese script α-Fe. With the addition of Mn, there are Chinese script α-Fe phases(Al_(15) (Mn, Fe)_3Si_2)in the structure of LFC casting. When Fe/Mn≤1.5, the needle-like β-Fe phases transform to Chinese script α-Fe completely. With the decrease of Fe/Mn ratio, the tensile strength σ_b and elongation δ increase, especially the elongation δ increases greatly. When Fe/Mn ratio decreases from 2.5 to 1, the δ increases from 1.2% to 1.9% by 58%.展开更多
The dynamic mechanical properties of open-cell aluminum alloy foams with different relative densities and cell sizes have been investigated by compressive tests. The strain rates varied from 700 s-1 to 2600 s-1. The e...The dynamic mechanical properties of open-cell aluminum alloy foams with different relative densities and cell sizes have been investigated by compressive tests. The strain rates varied from 700 s-1 to 2600 s-1. The experimental results showed that the dynamic compressive stress-strain curves exhibited a typical three-stage behavior: elastic, plateau and densification. The dynamic compressive strength of foams is affected not only by the relative density but also by the strain rate and cell size. Aluminum alloy foams with higher relative density or smaller cell size are more sensitive to the strain rate than foams with lower relative density or larger cell size.展开更多
The microstructure and mechanical properties of Mg-10.1Gd-3.74Y-0.25Zr (mass fraction, %) alloy (GW104 alloy) cast by metal mould casting (MMC) and lost foam casting (LFC) were evaluated, respectively. It is r...The microstructure and mechanical properties of Mg-10.1Gd-3.74Y-0.25Zr (mass fraction, %) alloy (GW104 alloy) cast by metal mould casting (MMC) and lost foam casting (LFC) were evaluated, respectively. It is revealed that different forming modes do not influence the phase composition of as-cast alloy. In the as-cast specimens, the microstructures are similar and composed of α-Mg solid solution, eutectic compound of α-Mg+Mg 24 (Gd, Y) 5 and cuboid-shaped Mg 5 (Gd, Y) phase; whereas the average grain size of the alloy produced by metal mould casting is smaller than that by lost foam casting. The eutectic compound of the alloy is completely dissolved after solution treatment at 525 ℃for 6 h, while the Mg 5 (Gd, Y) phase still exists after solution treatment. After peak-ageing, the lost foam cast alloy exhibits the maximum ultimate tensile strength of 285 MPa, and metal mould cast specimen 325 MPa at room temperature, while the tensile yield strengths of them are comparable. It can be concluded that GW104 alloy cast by lost foam casting possesses similar microstructure and evidently lower mechanical strength compared with metal mould cast alloy, due to slow solidification rate and proneness to form shrinkage porosities during lost foam casting process.展开更多
Porosity is thought to be severe in aluminum alloy castings produced by lost foam process due to the pyrolysis of the polystyrene foam pattern during pouring, which results in detrimental effect in mechanical property...Porosity is thought to be severe in aluminum alloy castings produced by lost foam process due to the pyrolysis of the polystyrene foam pattern during pouring, which results in detrimental effect in mechanical property. The slow solidification rate promotes the formation of gassing pin holes, and relative weakness of the thermal gradients can cause micro-shrinkage if the outline of the part complicates feeding in the lost foam casting. One of the methods to eliminate the porosity is to apply high pressure to the molten metal like an isostatic forging during solidification. Fundamental experiments were carried out to evaluate the effect of the external pressure on the porosity and mechanical properties of A356.2 alloy bar in the lost foam casting. Solidification time and porosity decreased with increasing the applied pressure during solidification. Applying external pressure was effective in decreasing the porosity and increasing the elongation of the lost foam casting.展开更多
Controlling process parameters of lost foam casting (LFC) enables this process to produce defect-free complex shape castings. An experimental investigation on lost foam casting of an A1-Si-Cu cast alloy was carried ...Controlling process parameters of lost foam casting (LFC) enables this process to produce defect-free complex shape castings. An experimental investigation on lost foam casting of an A1-Si-Cu cast alloy was carried out. The effects of pouting temperature, slurry viscosity, vibration time and sand size on surface finish, shrinkage porosity and eutectic silicon spacing of thin-wall casting were investigated. A full two-level factorial design of experimental technique was used to identify the significant manufacturing factors affecting the properties of casting. Pouring temperature was found as the most significant factor affecting A1-Si-Cu lost foam casting quality. It was shown that flask vibration time interacted with pouring temperature influenced euteetic silicon spacing and porosity percentage significantly. The results also revealed that the surface quality of the samples cast in fine sand moulds at higher pouring temperatures was almost unchanged, while those cast in coarse sand moulds possessed lower surface qualities. Furthermore, variation in slurry viscosity showed no significant effect on the evaluated properties compared to other parameters.展开更多
The hole defects can easily occur in magnesium alloy castings that are prepared by low pressure lost foam casting(LP-LFC)process when the process parameters such as vacuum,pouring temperature and f illing velocity are...The hole defects can easily occur in magnesium alloy castings that are prepared by low pressure lost foam casting(LP-LFC)process when the process parameters such as vacuum,pouring temperature and f illing velocity are not properly selected.In this study,the forming mechanism of the hole defects in AZ91D magnesium castings by LP-LFC process was investigated.The shape,location and surface appearance of the hole defects were observed using optical microscopy and scanning electron microscopy,and the chemical composition on the surface of the holes was analyzed using energy spectrometer.The result indicates that there are two types of hole defects,i.e.,the pyrolysis products related hole defects,including concentrative hole and blow hole defects,and slag related hole defects.The concentrative hole and the blow-hole defects were formed either by the liquidEPS degradation products entrapped in the molten metal under the condition that the pouring temperature is equal to or lower than 730℃,or by the hindered transport of EPS pyrolysis products.Some irregular shape hole defects were caused by slag or by coating slough entrapment when the pouring temperature is equal to 750℃and the f illing velocity is equal to or greater than 100 mm·s-1.To reduce or eliminate the hole defects,the vacuum and f illing velocity must be properly chosen to ensure that the metal front prof ile exhibits convex shape and in laminar current state,and the pouring temperature should be just high enough to ensure that the molten melt has adequate heat energy to complete the foam pyrolysis and to fully occupy the mould.For AZ91D magnesium castings in this study,the parameters should be 730℃pouring temperature,0.02-0.03 MPa vacuum and 80mm·s-1f illing velocity.展开更多
By use of ICP spectroscopy,energy spectrum analysis,hydrogen tester,image analyzer,the differential scanning calorimetric(DSC)and microscope analysis,the effects of RE on the Porosity,structure and properties of B319 ...By use of ICP spectroscopy,energy spectrum analysis,hydrogen tester,image analyzer,the differential scanning calorimetric(DSC)and microscope analysis,the effects of RE on the Porosity,structure and properties of B319 aluminum alloy were studied.The results show that under the 0.3°C/s slow cooling rate in lost foam casting,the effect of RE on modification and grain size of B319 aluminum alloy is little.With the increase of RE master alloy,the tensile strength and elongation increase.When RE>0.15%,block like La_(2)Si_(2)Al_(3)phase appear,and the tensile strength and elongation decrease.The results also show that the melt hydrogen content and casting porosity can be decreased greatly by adding 0.15%RE to aluminum melt.This is the important reason why RE improves the mechanical properties of casting under lost foam casting condition.展开更多
The nearly equiaxed grains of Mg9AlZnY alloy were obtained by vibrating solidification in lost foam casting(LFC) and the microstructure of Mg9AlZnY alloy was analyzed.On this basis,the morphology and size of α-Mg gra...The nearly equiaxed grains of Mg9AlZnY alloy were obtained by vibrating solidification in lost foam casting(LFC) and the microstructure of Mg9AlZnY alloy was analyzed.On this basis,the morphology and size of α-Mg grains fabricated by semi-solid isothermal heat treatment(SSIT) at 530 ℃ and 570 ℃ holding different time were studied.The results show that the main constituent phases of Mg9AlZnY alloy are α-Mg,β-Mg17Al12 and Al2Y,and the Y can greatly refine α-Mg grains.The distribution of α-Mg grains equivalent diameters between 20 and 100 μm is up to 87%,and the average roundness of α-Mg grains reaches 1.37 in the specimen obtained at 570 ℃ and holding time 60 min.According to the analysis of solidification kinetics and thermodynamic,binary eutectic with low melting point melts firstly on SSIT process.As the liquid fraction increases with the solute diffusibility,both of the shape and size of α-Mg grains change ceaselessly.When the liquid fraction reaches equilibrium,the α-Mg grains are gradually spheroidized under the interfacial tension,and then the α-Mg grains begin to combine and grow.Evolution of α-Mg dendritic grains on SSIT process is obviously different from that of equiaxed grains.展开更多
Effects of vacuum, pouring temperature and pattern thickness on the heat transfer of magnesium alloy lost foam casting(LFC) process were explored. The results indicate that without vacuum a positive thermal gradient f...Effects of vacuum, pouring temperature and pattern thickness on the heat transfer of magnesium alloy lost foam casting(LFC) process were explored. The results indicate that without vacuum a positive thermal gradient from the gate to the end of the casting was formed immediately after the mold filling. The average temperature of the casting, the temperature gradient and solidification times increase significantly with pouring temperature and pattern thickness. Vacuum plays a quite different role in the heat transfer during mould filling and solidification periods: it significantly increases the cooling rate of the filling melt, but decreases the cooling rate of the casting during solidification period. The temperature of the liquid metal drops sharply and varies greatly with no apparent mode in the casting after the mold filling. The amplitude of temperature fluctuations in the casting increases with vacuum, pouring temperature and pattern thickness. The average temperature increases with pouring temperature and pattern thickness, but less rapidly than that without vacuum. The effect of vacuum on the solidification times of castings is found to depend on pouring temperature, vacuum makes solidification times increase greatly at high pouring temperature, while decreases slightly at low pouring temperature.展开更多
The microstructure and mechanical properties of AZ91 alloy prepared by lost foam casting(LFC) and various heat treatments have been investigated. The microstructure of the AZ91 alloy via LFC consists of dominant α-...The microstructure and mechanical properties of AZ91 alloy prepared by lost foam casting(LFC) and various heat treatments have been investigated. The microstructure of the AZ91 alloy via LFC consists of dominant α-Mg and β-Mg17Al12 as well as a new phase Al32Mn25 with size of about 550 μm, which has not been detected in AZ91 alloy prepared by other casting processes. The tests demonstrate that the as-cast mechanical properties are higher than those of sand gravity casting because of chilling and cushioning effect of foam pattern during the mould filling. The solution kinetics and the aging processes at different temperatures were also investigated by hardness and electrical resistivity measurements. The kinetics of aging are faster at the high temperature due to enhanced diffusion of atoms in the matrix, so the hardness peak at 380 ℃ occurs after 10 h; while at the lower aging temperature(150 ℃), the peak is not reached in the time(24 h) considered.展开更多
Lost foam casting(LFC)technology has been widely applied to cast iron and cast steel.However,the development of LFC for Al and Mg alloys was relatively slower than that for cast iron and cast steel.The application of ...Lost foam casting(LFC)technology has been widely applied to cast iron and cast steel.However,the development of LFC for Al and Mg alloys was relatively slower than that for cast iron and cast steel.The application of LFC to Al and Mg alloys needs more effort,especially in China.In this paper,the development history of LFC is reviewed,and the application situations of LFC to Al and Mg alloys are mainly discussed.Meanwhile,the key problems of LFC for Al and Mg alloys are also pointed out.Finally,the prospects for LFC technology are discussed,and some special new LFC technologies are introduced for casting Al and Mg alloys.In future,the development trends of green LFC technology mainly focus on the special new LFC methods,metal material,coating,heat treatment,new foam materials as well as purification technology of tail gas,etc.展开更多
Surface composite layer was fabricated on the AZ91D substrate using the lost foam casting (LFC) process. The pre-coating layer reacted with melt substrate and formed the composite layer, and the coating was mainly c...Surface composite layer was fabricated on the AZ91D substrate using the lost foam casting (LFC) process. The pre-coating layer reacted with melt substrate and formed the composite layer, and the coating was mainly consist of alloying aluminum powder and low-temperature glass powder (PbO-ZnO-Na20). The vacuum degree, pouring temperature, mold filling process of melt, and pre-coating thickness played an important role during the formation process of composite layer. The results show that surface morphology of composite layer can be divided into three categories: alloying effect of bad and good ceramic layer, alloying effect of good and bad ceramic layer, composite layer of good quality. The main reason for bad alloying layer is that alloying pre-coating thickness is so thin that it is scoured easily and involved in the melt, in addition, it is difficult for melt to infiltrate into the alloying coating owing to the surface tension of coating when the vacuum degree is excessively low. Bad ceramic layer is because of somewhat lower pouring temperature and the thicker alloying coating, due to the absorption of heat from the melt, making low temperature glass powder pre-coating layer fuse inadequate. Thus, to get good quality composite layer, the process conditions must be appropriate, the result shows that the optimum process parameters are as follows: at a pouring temperature of 800 ~C, vacuum degree of -0.06 MPa, alloying pre-coating thickness ofO.4 mm, and low glass powder pre-coating layer thickness ofl mm.展开更多
Vacuum pressurizing casting technique, providing better mould filling and inter-dendritic feeding, can reduce the porosity greatly in cast aluminum alloys, and improve the fatigue properties. The rotary bending fatigu...Vacuum pressurizing casting technique, providing better mould filling and inter-dendritic feeding, can reduce the porosity greatly in cast aluminum alloys, and improve the fatigue properties. The rotary bending fatigue properties of A356-T6 alloys prepared by vacuum pressurizing casting were investigated. The S-N curve and limit strength 90 MPa under fatigue life of 107 cycles were obtained. The analyses on the fatigue fractography and microstructure of specimens showed that the fatigue fracture mainly occurs at the positions with casting defects in the subsurface, especially at porosities regions, which attributed to the crack propagation during the fatigue fracture process. Using the empirical crack propagation law of Pairs-Erdogon, the quantitative relationship among the initial crack size, fatigue life and applied stress was established. The fatigue life decreases with an increase in initial crack size. Two constants in the Pairs-Erdogon equation of aluminum alloy A356-T6 were calculated using the experimental data.展开更多
This study investigated whether the pouring ladle's outlet shape could reduce the porosity of aluminum alloy casting products and whether it could be applied to mass production of automotive brackets based on comp...This study investigated whether the pouring ladle's outlet shape could reduce the porosity of aluminum alloy casting products and whether it could be applied to mass production of automotive brackets based on computer simulations and experiment.The filling behaviors of the melt were simulated to compare the flow characteristics of the molten metal poured from the conventional ladle and the proposed ladle.Results show that for the conventional ladle,the pouring metal is V-shaped,while it is relatively circular and poured at a more constant rate in the proposed ladle.CT scans reveal that the proposed ladle reduces the porosity of the cast product.The proposed ladle resulted in an average of 30 fewer pores,a 299.56 mm3 smaller average total pore volume,and a 0.041% lower difference in average porosity.It is concludes that the proposed ladle can be used in the gravity casting process.By changing the ladle outlet shape can reduce the casting failure rate of massproduced automobile bracket.展开更多
An experimental study on lost foam casting of an Al-Si-Cu alloy was conducted. The main objective was to study the effect of pattern coating thickness on casting imperfection and porosity percentage as well as eutecti...An experimental study on lost foam casting of an Al-Si-Cu alloy was conducted. The main objective was to study the effect of pattern coating thickness on casting imperfection and porosity percentage as well as eutectic silicon spacing of the alloy. The results showed that increasing slurry viscosity and flask dipping time influenced the casting integrity and microstructural characteristics. It was found that thinner pattern coating produced improved mould filling, refined microstructure and higher quality castings containing less porosity.展开更多
Mechanical vibration was applied to the solidification of a lost foam cast(LFC) 356 aluminum alloy.Effects of mechanical vibration,with different peak acceleration,on the size and morphology of α-Al phase,and also on...Mechanical vibration was applied to the solidification of a lost foam cast(LFC) 356 aluminum alloy.Effects of mechanical vibration,with different peak acceleration,on the size and morphology of α-Al phase,and also on the mechanical properties of the castings were studied.Results indicated that α-Al dendrites gradually grow into equiaxed grains as the peak acceleration of vibration is increased.When the peak acceleration is between about 1 to 4 g,α-Al phase distribution is uniform and is refined obviously.α-Al dendrites are reduced and the mechanical properties of the castings are improved significantly when compared to those of the castings that are produced without vibration.However,when the peak acceleration is higher than 4 g,strong vibration will lead to defects formation,such as sand adhesion,while the amount and size of pores will be increased.And due to the turbulent flow that caused by strong vibration,the chance of forming large pores in the matrix has been increased significantly.The increase in defects will result in the deterioration of mechanical properties.展开更多
Microstructure and mechanical properties of lost foam cast aluminum alloys have been investigated in both primary A356(0.13% Fe) and secondary 356(0.47%). As expected, secondary 356 shows much higher content of Fe-ric...Microstructure and mechanical properties of lost foam cast aluminum alloys have been investigated in both primary A356(0.13% Fe) and secondary 356(0.47%). As expected, secondary 356 shows much higher content of Fe-rich intermetallic phases, and in particular the porosity in comparison with primary A356. The average area percent and size(length) of Fe-rich intermetallics change from about 0.5% and 6 μm in A356 to 2% and 25 μm in 356 alloy. The average area percent and maximum size of porosity also increase from about 0.4% and 420 μm to 1.4% and 600 μm, respectively. As a result, tensile ductility decreases about 60% and ultimate tensile strength declines about 8%. Lower fatigue strength was also experienced in the secondary 356 alloy. Low cycle fatigue(LCF) strength decreased from 187 MPa in A356 to 159 MPa in 356 and high cycle fatigue(HCF) strength also declined slightly from 68 MPa to 64 MPa.展开更多
Contrastive research was carried out to study the thermal properties of open-celled aluminum foams prepared by counter-gravity infiltration casting system and the traditional process respectively.The experimental resu...Contrastive research was carried out to study the thermal properties of open-celled aluminum foams prepared by counter-gravity infiltration casting system and the traditional process respectively.The experimental results show that the thermal conductivity coefficients of aluminum foams prepared by two different infiltration methods have similar increasing trend with the increase of particle size;along with the reducing porosity,the thermal conductivity coefficients will be enhanced oppositely.However,with the same particle size,the open-celled aluminum foam prepared by the former method has a higher thermal conductivity coefficient obviously.It is largely because that the sample prepared by counter-gravity infiltration casting has a lower void content and better dense crystallization of metal-matrix after the constant pressure process.展开更多
文摘Effects of coating constituent, coating density, coating layer thickness and temperature on coating sorption capacity for polystyrene decomposition products have been studied systematically. It has been found that the effect of attapulgite clay on sorption capacity is the largest among coating constituents. The sorption capacity of the coating with 2% attapulgite clay is elevated by 81%. The relationship between casting porosity and coating sorption capacity has been studied. It has been pointed out that higher coating sorption capacity for polystyrene decomposition products is helpful to decrease the casting porosity. Results also show that the sorption capacity of self-developed HW-1 coating for polystyrene decomposition products is as good as that of Ashland coating from America.
文摘The effects of modification, grain refinement, polystyrene pattern, pouring temperature and reduced pressure degree on aluminum alloy porosity in lost foam casting (LFC) process were studied. The results show that the solidification rate of LFC process is slower than that of resin sand process or clay sand process. The effect of modification and grain refinement on the aluminum alloy casting density in LFC is greater than that on resin sand process. Through α Al phase refinement process with 0.2%Ti for aluminum melt, the subversive effect of Sr modification in LFC process is decreased greatly, and the aluminum casting density in LFC process is nearly equal to that in resin sand process. To decrease the porosity of aluminum castings in LFC process, lower density of polystyrene pattern, higher pouring temperature (760~780 ℃) and lower reduced pressure degree (≤20 kPa) should be applied.[
文摘By using ICP spectroscopy, energy dispersive spectroscopy (EDS) analysis, X-ray diffraction, SEM and microscope analysis, the effects of Mn on the structure of B319 aluminum alloy are studied. The results show that without the addition of Mn, there are coral-like Al_2Cu phase and needle-like β-Fe (Al_5FeSi)in the structure of casting with lost foam casting (LFC). Precipitation of Al_2Cu can take place along the long sides of the β needles. Under the rapid cooling rates, such as ones in metallic mold, the Fe phase appears in the form of Chinese script α-Fe. With the addition of Mn, there are Chinese script α-Fe phases(Al_(15) (Mn, Fe)_3Si_2)in the structure of LFC casting. When Fe/Mn≤1.5, the needle-like β-Fe phases transform to Chinese script α-Fe completely. With the decrease of Fe/Mn ratio, the tensile strength σ_b and elongation δ increase, especially the elongation δ increases greatly. When Fe/Mn ratio decreases from 2.5 to 1, the δ increases from 1.2% to 1.9% by 58%.
基金This work was supported by the Natural Science Foundation of CAEP under grant No.10076020.
文摘The dynamic mechanical properties of open-cell aluminum alloy foams with different relative densities and cell sizes have been investigated by compressive tests. The strain rates varied from 700 s-1 to 2600 s-1. The experimental results showed that the dynamic compressive stress-strain curves exhibited a typical three-stage behavior: elastic, plateau and densification. The dynamic compressive strength of foams is affected not only by the relative density but also by the strain rate and cell size. Aluminum alloy foams with higher relative density or smaller cell size are more sensitive to the strain rate than foams with lower relative density or larger cell size.
基金Project(2007CB613704)supported by the National Basic Research Program of China
文摘The microstructure and mechanical properties of Mg-10.1Gd-3.74Y-0.25Zr (mass fraction, %) alloy (GW104 alloy) cast by metal mould casting (MMC) and lost foam casting (LFC) were evaluated, respectively. It is revealed that different forming modes do not influence the phase composition of as-cast alloy. In the as-cast specimens, the microstructures are similar and composed of α-Mg solid solution, eutectic compound of α-Mg+Mg 24 (Gd, Y) 5 and cuboid-shaped Mg 5 (Gd, Y) phase; whereas the average grain size of the alloy produced by metal mould casting is smaller than that by lost foam casting. The eutectic compound of the alloy is completely dissolved after solution treatment at 525 ℃for 6 h, while the Mg 5 (Gd, Y) phase still exists after solution treatment. After peak-ageing, the lost foam cast alloy exhibits the maximum ultimate tensile strength of 285 MPa, and metal mould cast specimen 325 MPa at room temperature, while the tensile yield strengths of them are comparable. It can be concluded that GW104 alloy cast by lost foam casting possesses similar microstructure and evidently lower mechanical strength compared with metal mould cast alloy, due to slow solidification rate and proneness to form shrinkage porosities during lost foam casting process.
文摘Porosity is thought to be severe in aluminum alloy castings produced by lost foam process due to the pyrolysis of the polystyrene foam pattern during pouring, which results in detrimental effect in mechanical property. The slow solidification rate promotes the formation of gassing pin holes, and relative weakness of the thermal gradients can cause micro-shrinkage if the outline of the part complicates feeding in the lost foam casting. One of the methods to eliminate the porosity is to apply high pressure to the molten metal like an isostatic forging during solidification. Fundamental experiments were carried out to evaluate the effect of the external pressure on the porosity and mechanical properties of A356.2 alloy bar in the lost foam casting. Solidification time and porosity decreased with increasing the applied pressure during solidification. Applying external pressure was effective in decreasing the porosity and increasing the elongation of the lost foam casting.
基金the Ministry of Higher Education of Malaysia (MOHE) for the financial support under the vote GUP-Q.J130000.2501.04H18
文摘Controlling process parameters of lost foam casting (LFC) enables this process to produce defect-free complex shape castings. An experimental investigation on lost foam casting of an A1-Si-Cu cast alloy was carried out. The effects of pouting temperature, slurry viscosity, vibration time and sand size on surface finish, shrinkage porosity and eutectic silicon spacing of thin-wall casting were investigated. A full two-level factorial design of experimental technique was used to identify the significant manufacturing factors affecting the properties of casting. Pouring temperature was found as the most significant factor affecting A1-Si-Cu lost foam casting quality. It was shown that flask vibration time interacted with pouring temperature influenced euteetic silicon spacing and porosity percentage significantly. The results also revealed that the surface quality of the samples cast in fine sand moulds at higher pouring temperatures was almost unchanged, while those cast in coarse sand moulds possessed lower surface qualities. Furthermore, variation in slurry viscosity showed no significant effect on the evaluated properties compared to other parameters.
基金financially supported by the National High Technology Research and Development Program of China(Project No.2007AA03Z113)the Zhejiang Province Natural Science Foundation of China(Project Nos.LY12E05015 and Y1110106)
文摘The hole defects can easily occur in magnesium alloy castings that are prepared by low pressure lost foam casting(LP-LFC)process when the process parameters such as vacuum,pouring temperature and f illing velocity are not properly selected.In this study,the forming mechanism of the hole defects in AZ91D magnesium castings by LP-LFC process was investigated.The shape,location and surface appearance of the hole defects were observed using optical microscopy and scanning electron microscopy,and the chemical composition on the surface of the holes was analyzed using energy spectrometer.The result indicates that there are two types of hole defects,i.e.,the pyrolysis products related hole defects,including concentrative hole and blow hole defects,and slag related hole defects.The concentrative hole and the blow-hole defects were formed either by the liquidEPS degradation products entrapped in the molten metal under the condition that the pouring temperature is equal to or lower than 730℃,or by the hindered transport of EPS pyrolysis products.Some irregular shape hole defects were caused by slag or by coating slough entrapment when the pouring temperature is equal to 750℃and the f illing velocity is equal to or greater than 100 mm·s-1.To reduce or eliminate the hole defects,the vacuum and f illing velocity must be properly chosen to ensure that the metal front prof ile exhibits convex shape and in laminar current state,and the pouring temperature should be just high enough to ensure that the molten melt has adequate heat energy to complete the foam pyrolysis and to fully occupy the mould.For AZ91D magnesium castings in this study,the parameters should be 730℃pouring temperature,0.02-0.03 MPa vacuum and 80mm·s-1f illing velocity.
文摘By use of ICP spectroscopy,energy spectrum analysis,hydrogen tester,image analyzer,the differential scanning calorimetric(DSC)and microscope analysis,the effects of RE on the Porosity,structure and properties of B319 aluminum alloy were studied.The results show that under the 0.3°C/s slow cooling rate in lost foam casting,the effect of RE on modification and grain size of B319 aluminum alloy is little.With the increase of RE master alloy,the tensile strength and elongation increase.When RE>0.15%,block like La_(2)Si_(2)Al_(3)phase appear,and the tensile strength and elongation decrease.The results also show that the melt hydrogen content and casting porosity can be decreased greatly by adding 0.15%RE to aluminum melt.This is the important reason why RE improves the mechanical properties of casting under lost foam casting condition.
基金Project(2007AA03Z113) supported by the National High-Tech Research and Development Program of ChinaProject (50775085) supported by the National Natural Science Foundation of China
文摘The nearly equiaxed grains of Mg9AlZnY alloy were obtained by vibrating solidification in lost foam casting(LFC) and the microstructure of Mg9AlZnY alloy was analyzed.On this basis,the morphology and size of α-Mg grains fabricated by semi-solid isothermal heat treatment(SSIT) at 530 ℃ and 570 ℃ holding different time were studied.The results show that the main constituent phases of Mg9AlZnY alloy are α-Mg,β-Mg17Al12 and Al2Y,and the Y can greatly refine α-Mg grains.The distribution of α-Mg grains equivalent diameters between 20 and 100 μm is up to 87%,and the average roundness of α-Mg grains reaches 1.37 in the specimen obtained at 570 ℃ and holding time 60 min.According to the analysis of solidification kinetics and thermodynamic,binary eutectic with low melting point melts firstly on SSIT process.As the liquid fraction increases with the solute diffusibility,both of the shape and size of α-Mg grains change ceaselessly.When the liquid fraction reaches equilibrium,the α-Mg grains are gradually spheroidized under the interfacial tension,and then the α-Mg grains begin to combine and grow.Evolution of α-Mg dendritic grains on SSIT process is obviously different from that of equiaxed grains.
基金Project(2005037697) supported by China Postdoctoral Science Foundation Project(Y04850-61) supported by Creative Program of Nanjing University of Aeronautics and Astronautics
文摘Effects of vacuum, pouring temperature and pattern thickness on the heat transfer of magnesium alloy lost foam casting(LFC) process were explored. The results indicate that without vacuum a positive thermal gradient from the gate to the end of the casting was formed immediately after the mold filling. The average temperature of the casting, the temperature gradient and solidification times increase significantly with pouring temperature and pattern thickness. Vacuum plays a quite different role in the heat transfer during mould filling and solidification periods: it significantly increases the cooling rate of the filling melt, but decreases the cooling rate of the casting during solidification period. The temperature of the liquid metal drops sharply and varies greatly with no apparent mode in the casting after the mold filling. The amplitude of temperature fluctuations in the casting increases with vacuum, pouring temperature and pattern thickness. The average temperature increases with pouring temperature and pattern thickness, but less rapidly than that without vacuum. The effect of vacuum on the solidification times of castings is found to depend on pouring temperature, vacuum makes solidification times increase greatly at high pouring temperature, while decreases slightly at low pouring temperature.
基金Project(50275058) supported by the National Natural Science Foundation of China
文摘The microstructure and mechanical properties of AZ91 alloy prepared by lost foam casting(LFC) and various heat treatments have been investigated. The microstructure of the AZ91 alloy via LFC consists of dominant α-Mg and β-Mg17Al12 as well as a new phase Al32Mn25 with size of about 550 μm, which has not been detected in AZ91 alloy prepared by other casting processes. The tests demonstrate that the as-cast mechanical properties are higher than those of sand gravity casting because of chilling and cushioning effect of foam pattern during the mould filling. The solution kinetics and the aging processes at different temperatures were also investigated by hardness and electrical resistivity measurements. The kinetics of aging are faster at the high temperature due to enhanced diffusion of atoms in the matrix, so the hardness peak at 380 ℃ occurs after 10 h; while at the lower aging temperature(150 ℃), the peak is not reached in the time(24 h) considered.
基金supported by the National Nature Science Foundation of China(NFSC)(No.50275058,50775085,51204124,51375187)the National High Technology Research and Development Program of China(No.2007AA03Z113)
文摘Lost foam casting(LFC)technology has been widely applied to cast iron and cast steel.However,the development of LFC for Al and Mg alloys was relatively slower than that for cast iron and cast steel.The application of LFC to Al and Mg alloys needs more effort,especially in China.In this paper,the development history of LFC is reviewed,and the application situations of LFC to Al and Mg alloys are mainly discussed.Meanwhile,the key problems of LFC for Al and Mg alloys are also pointed out.Finally,the prospects for LFC technology are discussed,and some special new LFC technologies are introduced for casting Al and Mg alloys.In future,the development trends of green LFC technology mainly focus on the special new LFC methods,metal material,coating,heat treatment,new foam materials as well as purification technology of tail gas,etc.
基金the National Natural Science Foundation of China (No.50775085)
文摘Surface composite layer was fabricated on the AZ91D substrate using the lost foam casting (LFC) process. The pre-coating layer reacted with melt substrate and formed the composite layer, and the coating was mainly consist of alloying aluminum powder and low-temperature glass powder (PbO-ZnO-Na20). The vacuum degree, pouring temperature, mold filling process of melt, and pre-coating thickness played an important role during the formation process of composite layer. The results show that surface morphology of composite layer can be divided into three categories: alloying effect of bad and good ceramic layer, alloying effect of good and bad ceramic layer, composite layer of good quality. The main reason for bad alloying layer is that alloying pre-coating thickness is so thin that it is scoured easily and involved in the melt, in addition, it is difficult for melt to infiltrate into the alloying coating owing to the surface tension of coating when the vacuum degree is excessively low. Bad ceramic layer is because of somewhat lower pouring temperature and the thicker alloying coating, due to the absorption of heat from the melt, making low temperature glass powder pre-coating layer fuse inadequate. Thus, to get good quality composite layer, the process conditions must be appropriate, the result shows that the optimum process parameters are as follows: at a pouring temperature of 800 ~C, vacuum degree of -0.06 MPa, alloying pre-coating thickness ofO.4 mm, and low glass powder pre-coating layer thickness ofl mm.
基金financially supported by the National Basic Research"973"Program of China(2011CB610406)the National Natural Science Foundation for the Major International(Regional)Joint Research Project(51420105005)
文摘Vacuum pressurizing casting technique, providing better mould filling and inter-dendritic feeding, can reduce the porosity greatly in cast aluminum alloys, and improve the fatigue properties. The rotary bending fatigue properties of A356-T6 alloys prepared by vacuum pressurizing casting were investigated. The S-N curve and limit strength 90 MPa under fatigue life of 107 cycles were obtained. The analyses on the fatigue fractography and microstructure of specimens showed that the fatigue fracture mainly occurs at the positions with casting defects in the subsurface, especially at porosities regions, which attributed to the crack propagation during the fatigue fracture process. Using the empirical crack propagation law of Pairs-Erdogon, the quantitative relationship among the initial crack size, fatigue life and applied stress was established. The fatigue life decreases with an increase in initial crack size. Two constants in the Pairs-Erdogon equation of aluminum alloy A356-T6 were calculated using the experimental data.
基金supported by the National Research Foundation of Korea(NRF)(2015R1A5A1037668)the Ministry of Trade,Industry and Energy(Grant N0002310)
文摘This study investigated whether the pouring ladle's outlet shape could reduce the porosity of aluminum alloy casting products and whether it could be applied to mass production of automotive brackets based on computer simulations and experiment.The filling behaviors of the melt were simulated to compare the flow characteristics of the molten metal poured from the conventional ladle and the proposed ladle.Results show that for the conventional ladle,the pouring metal is V-shaped,while it is relatively circular and poured at a more constant rate in the proposed ladle.CT scans reveal that the proposed ladle reduces the porosity of the cast product.The proposed ladle resulted in an average of 30 fewer pores,a 299.56 mm3 smaller average total pore volume,and a 0.041% lower difference in average porosity.It is concludes that the proposed ladle can be used in the gravity casting process.By changing the ladle outlet shape can reduce the casting failure rate of massproduced automobile bracket.
基金Ministry of Science and Technology of Malaysia for funding the research project under E-science Fund Vote No. 79352
文摘An experimental study on lost foam casting of an Al-Si-Cu alloy was conducted. The main objective was to study the effect of pattern coating thickness on casting imperfection and porosity percentage as well as eutectic silicon spacing of the alloy. The results showed that increasing slurry viscosity and flask dipping time influenced the casting integrity and microstructural characteristics. It was found that thinner pattern coating produced improved mould filling, refined microstructure and higher quality castings containing less porosity.
基金supported by the National High Technology Research and Development Program of China (Grant No.2007AA03Z113)The National Natural Science Foundation of China (Grant No.50775085)
文摘Mechanical vibration was applied to the solidification of a lost foam cast(LFC) 356 aluminum alloy.Effects of mechanical vibration,with different peak acceleration,on the size and morphology of α-Al phase,and also on the mechanical properties of the castings were studied.Results indicated that α-Al dendrites gradually grow into equiaxed grains as the peak acceleration of vibration is increased.When the peak acceleration is between about 1 to 4 g,α-Al phase distribution is uniform and is refined obviously.α-Al dendrites are reduced and the mechanical properties of the castings are improved significantly when compared to those of the castings that are produced without vibration.However,when the peak acceleration is higher than 4 g,strong vibration will lead to defects formation,such as sand adhesion,while the amount and size of pores will be increased.And due to the turbulent flow that caused by strong vibration,the chance of forming large pores in the matrix has been increased significantly.The increase in defects will result in the deterioration of mechanical properties.
文摘Microstructure and mechanical properties of lost foam cast aluminum alloys have been investigated in both primary A356(0.13% Fe) and secondary 356(0.47%). As expected, secondary 356 shows much higher content of Fe-rich intermetallic phases, and in particular the porosity in comparison with primary A356. The average area percent and size(length) of Fe-rich intermetallics change from about 0.5% and 6 μm in A356 to 2% and 25 μm in 356 alloy. The average area percent and maximum size of porosity also increase from about 0.4% and 420 μm to 1.4% and 600 μm, respectively. As a result, tensile ductility decreases about 60% and ultimate tensile strength declines about 8%. Lower fatigue strength was also experienced in the secondary 356 alloy. Low cycle fatigue(LCF) strength decreased from 187 MPa in A356 to 159 MPa in 356 and high cycle fatigue(HCF) strength also declined slightly from 68 MPa to 64 MPa.
基金Project(51304254) supported by the National Natural Science Foundation of ChinaProject(2013GK4064) supported by the Strategic Emerging Industry Program of the Ministry of Science and Technology of Hunan Province,China
文摘Contrastive research was carried out to study the thermal properties of open-celled aluminum foams prepared by counter-gravity infiltration casting system and the traditional process respectively.The experimental results show that the thermal conductivity coefficients of aluminum foams prepared by two different infiltration methods have similar increasing trend with the increase of particle size;along with the reducing porosity,the thermal conductivity coefficients will be enhanced oppositely.However,with the same particle size,the open-celled aluminum foam prepared by the former method has a higher thermal conductivity coefficient obviously.It is largely because that the sample prepared by counter-gravity infiltration casting has a lower void content and better dense crystallization of metal-matrix after the constant pressure process.