Multiple regression equations of liquidus temperature, electrical conductivity and bath density of the Na_3AlF_6-AlF_3-BaC1_2-NaCl system were obtained from experiments by using orthogonal regression method. The exper...Multiple regression equations of liquidus temperature, electrical conductivity and bath density of the Na_3AlF_6-AlF_3-BaC1_2-NaCl system were obtained from experiments by using orthogonal regression method. The experiments were carried out in 100A cell with low melting point electrolyte, the influences of cathodic current density, electrolytic temperature, density differences of bath and liquid aluminum on current efficiency (CE) were studied; when the electrolyte cryolite ratio was 2.5, w(BaC1_2) and w(NaCl) were 48% and 10%, respectively, CE reached 90% and specific energy consumption was 10.97k Wb/kg/kg. Because of the fact that aluminum metal obtained floated on the surface of molten electrolyte, this electrolysis method was then defined as low temperature aluminum floating electrolysis. The results showed that the new low temperature aluminum electrolysis process in the Na_3AlF_6-AlF_3-BaC1_2-NaCl bath system was practical and promising.展开更多
Mixed culture fermentation(MCF)is challenged by the unqualified activity of enriched bacteria and unwanted methane dissolution under low temperatures.In this work,caproate production from xylose was investigated by MC...Mixed culture fermentation(MCF)is challenged by the unqualified activity of enriched bacteria and unwanted methane dissolution under low temperatures.In this work,caproate production from xylose was investigated by MCF at a low temperature(20°C).The results showed that a 9 d long hydraulic retention time(HRT)in a continuously stirred tank reactor was necessary for caproate production(~0.3 g/L,equal to 0.6 g COD/L)from xylose(10 g/L).The caproate concentration in the batch mode was further increased to 1.6 g/L.However,changing the substrate to ethanol did not promote caproate production,resulting in~1.0 g/L after 45 d of operation.Four genera,Bifidobacterium,Caproiciproducens,Actinomyces,and Clostridium_sensu_stricto_12,were identified as the enriched caproate-producing bacteria.The enzymes in the fatty acid biosynthesis(FAB)pathway for caproate production were identified via metagenomic analysis.The enzymes for the conversion of(C_(n+2))-2,3-Dehydroxyacyl-CoA to(C_(n+2))-Acyl-CoA(i.e.,EC 1.3.1.8 and EC 1.3.1.38)in the reverseβ-oxidation(RBO)pathway were not identified.These results could extend the understanding of low-temperature caproate production.展开更多
为了阐明低盐虾酱在低温发酵过程中的代谢物特点,采用气相色谱-质谱联用技术对低盐虾酱在低温发酵过程中的代谢物进行监测;结合t检验和变量投影重要性(variable importance in projection,VIP)分析等多元统计分析,筛选出差异代谢物。结...为了阐明低盐虾酱在低温发酵过程中的代谢物特点,采用气相色谱-质谱联用技术对低盐虾酱在低温发酵过程中的代谢物进行监测;结合t检验和变量投影重要性(variable importance in projection,VIP)分析等多元统计分析,筛选出差异代谢物。结果表明,正交偏最小二乘判别分析模型显示,不同温度下发酵低盐虾酱之间的代谢物能够明显分离。2组低盐虾酱中共有44种主要代谢物,包括氨基酸类16种、脂肪酸类6种、胺类2种、有机酸类8种、醇类3种、核苷酸类3种、其他类化合物6种。以P<0.05和VIP>1为筛选条件,得到30种差异代谢物,主要包括氨基酸类7种、酯类2种、嘌呤类2种、有机酸类8种、醇类2种和其他代谢物9种;其中,与对照组(20℃)相比,低温组(10℃)中L-丝氨酸、L-苏氨酸、黄嘌呤、次黄嘌呤和L-谷氨酰胺显著增加,乙酸橙花酯、樱黄素和褪黑素显著减少(P<0.01)。研究结果为进一步改善低盐虾酱生产工艺提供一定的理论依据。展开更多
Room temperature sputtered inorganic nickel oxide(NiO_(x))is one of the most promising hole transport layers(HTL)for perovskite-sillion 2-terminal tandem solar cells with the aid of ultrathin and compact organic layer...Room temperature sputtered inorganic nickel oxide(NiO_(x))is one of the most promising hole transport layers(HTL)for perovskite-sillion 2-terminal tandem solar cells with the aid of ultrathin and compact organic layers to passivate the surface defects.In this study,the aromatic solvent with different substituent groups was used to regulate the conformation of poly[bis(4-phenyl)(2,4,6-trimethylphenyl)am ine](PTAA)layer.As a result,the single-junction perovskite solar cell(PSC)gained a power conversion efficiency(PCE)of 20.63%,contributing to a 27.21%efficiency for monolithic perovskite/silicon(double-side polished)2-terminal tandem solar cell,by applying the alkyl aromatic solvent to enhance theπ-πstacking of PTAA molecular chains.The tandem solar cell can maintain 95%initial efficiency after aging over 1000 h.This study provides a universal approach for improving the photovoltaic performance of NiO_(x)/polymer-based perovskite/silicon tandem solar cells and other single junction inverted PSCs.展开更多
基金The project was financially supported by the National Natural Science Foundation of China! (Gmnt No.59574018)China Postdocto
文摘Multiple regression equations of liquidus temperature, electrical conductivity and bath density of the Na_3AlF_6-AlF_3-BaC1_2-NaCl system were obtained from experiments by using orthogonal regression method. The experiments were carried out in 100A cell with low melting point electrolyte, the influences of cathodic current density, electrolytic temperature, density differences of bath and liquid aluminum on current efficiency (CE) were studied; when the electrolyte cryolite ratio was 2.5, w(BaC1_2) and w(NaCl) were 48% and 10%, respectively, CE reached 90% and specific energy consumption was 10.97k Wb/kg/kg. Because of the fact that aluminum metal obtained floated on the surface of molten electrolyte, this electrolysis method was then defined as low temperature aluminum floating electrolysis. The results showed that the new low temperature aluminum electrolysis process in the Na_3AlF_6-AlF_3-BaC1_2-NaCl bath system was practical and promising.
基金the National Natural Science Foundation of China(Nos.51808120 and 52170127)China Postdoctoral Science Foundation(No.2019M652235)the Program for Innovative Research Team in Science and Technology in Fujian Province University(China)(IRTSTFJ).
文摘Mixed culture fermentation(MCF)is challenged by the unqualified activity of enriched bacteria and unwanted methane dissolution under low temperatures.In this work,caproate production from xylose was investigated by MCF at a low temperature(20°C).The results showed that a 9 d long hydraulic retention time(HRT)in a continuously stirred tank reactor was necessary for caproate production(~0.3 g/L,equal to 0.6 g COD/L)from xylose(10 g/L).The caproate concentration in the batch mode was further increased to 1.6 g/L.However,changing the substrate to ethanol did not promote caproate production,resulting in~1.0 g/L after 45 d of operation.Four genera,Bifidobacterium,Caproiciproducens,Actinomyces,and Clostridium_sensu_stricto_12,were identified as the enriched caproate-producing bacteria.The enzymes in the fatty acid biosynthesis(FAB)pathway for caproate production were identified via metagenomic analysis.The enzymes for the conversion of(C_(n+2))-2,3-Dehydroxyacyl-CoA to(C_(n+2))-Acyl-CoA(i.e.,EC 1.3.1.8 and EC 1.3.1.38)in the reverseβ-oxidation(RBO)pathway were not identified.These results could extend the understanding of low-temperature caproate production.
文摘为了阐明低盐虾酱在低温发酵过程中的代谢物特点,采用气相色谱-质谱联用技术对低盐虾酱在低温发酵过程中的代谢物进行监测;结合t检验和变量投影重要性(variable importance in projection,VIP)分析等多元统计分析,筛选出差异代谢物。结果表明,正交偏最小二乘判别分析模型显示,不同温度下发酵低盐虾酱之间的代谢物能够明显分离。2组低盐虾酱中共有44种主要代谢物,包括氨基酸类16种、脂肪酸类6种、胺类2种、有机酸类8种、醇类3种、核苷酸类3种、其他类化合物6种。以P<0.05和VIP>1为筛选条件,得到30种差异代谢物,主要包括氨基酸类7种、酯类2种、嘌呤类2种、有机酸类8种、醇类2种和其他代谢物9种;其中,与对照组(20℃)相比,低温组(10℃)中L-丝氨酸、L-苏氨酸、黄嘌呤、次黄嘌呤和L-谷氨酰胺显著增加,乙酸橙花酯、樱黄素和褪黑素显著减少(P<0.01)。研究结果为进一步改善低盐虾酱生产工艺提供一定的理论依据。
基金supported by the National Key R&D Program of China(2018YFB1500103)the National Natural Science Foundation of China(62104082)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(2022A1515010746,2022A1515011228)the Science and Technology Program of Guangzhou(202201010458)。
文摘Room temperature sputtered inorganic nickel oxide(NiO_(x))is one of the most promising hole transport layers(HTL)for perovskite-sillion 2-terminal tandem solar cells with the aid of ultrathin and compact organic layers to passivate the surface defects.In this study,the aromatic solvent with different substituent groups was used to regulate the conformation of poly[bis(4-phenyl)(2,4,6-trimethylphenyl)am ine](PTAA)layer.As a result,the single-junction perovskite solar cell(PSC)gained a power conversion efficiency(PCE)of 20.63%,contributing to a 27.21%efficiency for monolithic perovskite/silicon(double-side polished)2-terminal tandem solar cell,by applying the alkyl aromatic solvent to enhance theπ-πstacking of PTAA molecular chains.The tandem solar cell can maintain 95%initial efficiency after aging over 1000 h.This study provides a universal approach for improving the photovoltaic performance of NiO_(x)/polymer-based perovskite/silicon tandem solar cells and other single junction inverted PSCs.
