Effects of quenching temperature and cooling conditions(water cooling and 10%NaCl cooling)on microstructure and mechanical properties of a 0.2%Ti low alloy martensitic wear-resistant steel used for die casting ejector...Effects of quenching temperature and cooling conditions(water cooling and 10%NaCl cooling)on microstructure and mechanical properties of a 0.2%Ti low alloy martensitic wear-resistant steel used for die casting ejector plate were investigated.The results show that lath martensite can be obtained after austenitizing in the range of 860-980℃and then water cooling.With an increase in austenitizing temperature,the precipitate content gradually decreases.The precipitates are mainly composed of TiC and Ti4C2S2,and their total content is between 1.15wt.%and 1.64wt.%.The precipitate phase concentration by water-cooling is higher than that by10%NaCl cooling due to the lower cooling rate of water cooling.As the austeniting temperature increases,the hardness and tensile strength of both water cooled and 10%NaCl cooled steels firstly increase and then decrease.The experimental steel exhibits the best comprehensive mechanical properties after being austenitized at 900℃,cooled by 10%NaCl,and then tempered at 200℃.Its hardness,ultimate tensile strength,and wear rate reach551.4 HBW,1,438.2 MPa,and 0.48×10^(-2)mg·m^(-1),respectively.展开更多
In the present paper, low carbon steel strips with different phosphorus contents were produced using a twin roll strip casting process. The solidification structure was studied and its features were analyzed in detail...In the present paper, low carbon steel strips with different phosphorus contents were produced using a twin roll strip casting process. The solidification structure was studied and its features were analyzed in detail. It was found that the strips possessed a fine microstructure compared with the mould cast steels. With increasing phosphorus content more ferrite has been formed with finer grains.展开更多
A novel diffusion couple method was used to investigate the interface diffusion of arsenic into a Nb-Ti microalloyed low carbon steel and its effects on phase transformation at the interface. It is discovered that the...A novel diffusion couple method was used to investigate the interface diffusion of arsenic into a Nb-Ti microalloyed low carbon steel and its effects on phase transformation at the interface. It is discovered that the content of arsenic has great effect on grain growth and phase transformation at high temperature. When the arsenic content is no more than lwt%, there is no obvious grain growth and no obvious ferrite transitional region formed at the diffusion interface. However, when the arsenic content is no less than 5wt%, the grain grows very rapidly. In addition, the arsenic-enriched ferrite transitional layer forms at the diffusion interface in the hot-rolling process, which results from a slower diffusion rate of arsenic atoms than that of carbon in ferrite.展开更多
The effects of Si content on combinations of important properties such as hardness, hardenability, and weldability in addition to strength increment were systematically investigated to develop a Mo and V free low allo...The effects of Si content on combinations of important properties such as hardness, hardenability, and weldability in addition to strength increment were systematically investigated to develop a Mo and V free low alloy cast steel for automobile cold pressing die insert. For the evaluation of the applicability as the die insert, the mechanical properties were measured after spheroidization annealing (SA), quenching and tempering (Q/T), and flame hardening (FH) treatments, respectively. The developed 0.8%-1.6%Si containing Mo and V free alloy cast steels showed excellent matrix strengthening effect, hardenability, and weldability, fulfilling the industrial criterion of the mechanical properties for the die insert.展开更多
The low stress abrasion behaviours of heat treated mild, medium carbon and high C - low Cr steels, which are generally used in making farm implements, have been investigated. The simple heat treatment greatly improves...The low stress abrasion behaviours of heat treated mild, medium carbon and high C - low Cr steels, which are generally used in making farm implements, have been investigated. The simple heat treatment greatly improves the hardness, tensile strength and abrasion resistance of medium carbon and high C - low Cr steels. The results indicate that the material removal during abrasion is controlled by a number of factors, such as hardness, chemical composition, microstructure and heat treatment conditions. The conclusion is that the heat treated high C - low Cr steel and mild steel carburized by using coaltar pitch provide the best hardness and abrasion resistance and thus appear to be the most suitable materials for making agricultural tools.展开更多
Understanding the weldability of steel in relation to the use of carbon equivalent is very necessary </span><span style="white-space:normal;font-family:"">for</span><span style...Understanding the weldability of steel in relation to the use of carbon equivalent is very necessary </span><span style="white-space:normal;font-family:"">for</span><span style="white-space:normal;font-family:""> the welding industry. The study was poised to unearth the fundamentals of carbon equivalent as applied in evaluating the weldability of steel. The study used </span><span style="white-space:normal;font-family:"">a </span><span style="white-space:normal;font-family:"">two-stage design approach to address the problem of carbon equivalence weldability of steel, thus, survey and experimental. Two different steels were tested to ascertain their chemical composition which could inform carbon equivalent calculation, and the results revealed microalloy and low alloy steels respectively. In subjecting the microalloy steel to carbon equivalent analyses of the AWS and IIW coefficients;revealed a value (CEV) = 0.11 each, suggesting that this microalloy steel has excellent weldability;no preheat</span><span style="white-space:normal;font-family:"">ing</span><span style="white-space:normal;font-family:""> is required. A successful welding operation on this steel does not depend on preheat</span><span style="white-space:normal;font-family:"">ing</span><span style="white-space:normal;font-family:"">.<b> </b>Also</span><span style="white-space:normal;font-family:"">,</span><span style="white-space:normal;font-family:""> the average results of the low alloy steel revealed a value (CEV) = 0.37 and 0.32 respectively, suggesting that this type of steel has very good weldability and may require </span><span style="white-space:normal;font-family:"">to </span><span style="white-space:normal;font-family:"">preheat. It is recommended that welders have </span><span style="white-space:normal;font-family:"">a </span><span style="white-space:normal;font-family:"">general idea about the weldability of steel with regard to carbon equivalent calculation. In addition</span><span style="white-space:normal;font-family:"">,</span><span style="white-space:normal;font-family:""> they should understand the chemical compositions of steels they are dealing with.展开更多
The influence of soaking time in deep cryogenic treatment on the tensile and impact properties of low-alloy medium-carbon HY-TUF steel was investigated in this study. Microstructural studies based on phase distributio...The influence of soaking time in deep cryogenic treatment on the tensile and impact properties of low-alloy medium-carbon HY-TUF steel was investigated in this study. Microstructural studies based on phase distribution mapping by electron backscatter diffraction show that the deep cryogenic process causes a decrease in the content of retained austenite and an increase in the volume fraction of η-carbide with increasing soaking time up to 48 h. The decrease in the content of retained austenite from ~1.23vol% to 0.48vol% suggests an isothermal martensitic transformation at 77 K. The η-type precipitates formed in deep cryogenic-treated martensite over 48 h have the Hirotsu and Nagakura orientation relation with the martensitic matrix. Furthermore, a high coherency between η-carbide and the martensitic matrix is observed by high-resolution transmission electron microscopy. The variations in macrohardness, yield strength, ultimate tensile strength, and ductility with soaking time in the deep cryogenic process show a peak/plateau trend.展开更多
The lath-or plate-shaped bainitic ferrite of low and medium carbon alloy steels consists of packets of ferrite sublaths which are composed of many finer and regular ferrite blocks.They are uniform shear growth units o...The lath-or plate-shaped bainitic ferrite of low and medium carbon alloy steels consists of packets of ferrite sublaths which are composed of many finer and regular ferrite blocks.They are uniform shear growth units of bainitic phase transformation.No carbide is precipitated from them.The bainitic O-carbides are precipitated from γ-α interface or carbon-rich austenite.The mode of arrangement of the units in ferrite sublath packet is in uni-or bi-di- rection.Single surface relief is produced by the accumulation of uniform shear strains with all the ferrite units arranged unidirectionally in a sublath packet,while tent-shaped surface relief is formed by the integration of the uniform shear strains of two groups with ferrite units piling up in two directions and growing face to face;whereas if they grow back to back,the integra- tion will be responsible for invert-tent-shaped surface relief.The interface trace between two groups of ferrite units in a sublath packet is shown as“midrib”.展开更多
For better processing performance of high carbon low alloy steel wire rod,an investigation about the influence of cementite lamellar spacing on wire 'easy drawing' performance is completed.It is pointed out th...For better processing performance of high carbon low alloy steel wire rod,an investigation about the influence of cementite lamellar spacing on wire 'easy drawing' performance is completed.It is pointed out that too thin cementite lamellar spacing(<80 um) reduces the strain hardening level of wire drawing, and reduce the torsion performance of drawn wire at same time.For the wire or wire rod from industrial production,compared with the micro-structure with troostite,the micro-structure with sorbite or sorbite mixed with pearlite is more suitable to the drawing process with high reduction ratio.展开更多
Corrosion behaviour of cast iron and low alloy steel in cocoa liquor and well water was investigated. The average weight losses of the specimens were measured using digital weighing balance. The results showed that th...Corrosion behaviour of cast iron and low alloy steel in cocoa liquor and well water was investigated. The average weight losses of the specimens were measured using digital weighing balance. The results showed that the weight losses of both cast iron and low alloy steel in both media increases with time. Corrosion rate of cast iron in cocoa liquor increases rapidly with time for up to 336 hours (1000 μm/yr), but in well water the rapid rate of corrosion only lasted up to 187 hours (1160 μm/yr) thereafter it continuously dropping until 264 hours (667 μm/yr) after which it remains constant. Low alloy steel corroded faster in cocoa liquor up to 264 hours (200 μm/yr), whereas the initial rapid corrosion rate only lasted up to 168 hours (180 μm/yr) in well water environment. The results revealed that low alloy steel exhibited better corrosion resistance in both media, with cocoa liquor been more aggressive. Thus, low alloy steel will be a better material for piping and pumping system in cocoa processing industries.展开更多
The key manufacturing technologies associated with composition, microstructure, mechanical properties, casting quality and key process control for large martensitic stainless steel castings are involved in this paper....The key manufacturing technologies associated with composition, microstructure, mechanical properties, casting quality and key process control for large martensitic stainless steel castings are involved in this paper. The achievements fully satisfeid the technical requirements of the large 700 MW stainless steel hydraulic turbine runner for the Three Gorges Hydropower Station, and become the major technical support for the design and manufacture of the largest 700 MW hydraulic turbine generator unit in the world developed through our own efforts. The characteristics of a new high yield to tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel with ultra low carbon and high cleanliness are also described. Over the next ten years, the large martensitic stainless steel castings and advanced manufacturing technologies will see a huge demand in clean energy industry such as nuclear power, hydraulic power at home and abroad. Therefore, the new high yield o tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel materials, the fast and flexible manufacturing technologies of large size castings, and new environment friendly sustainable process will face new challenges and opportunities.展开更多
Grey cast iron’s welding itself is a complex proble m.So proper welding materials must be selected,complex welding techniques such as preheating before weldingslow cooling after welding etc,should be taken. However t...Grey cast iron’s welding itself is a complex proble m.So proper welding materials must be selected,complex welding techniques such as preheating before weldingslow cooling after welding etc,should be taken. However the carbon component in low-carbon steel is comparatively low,the carbo n of welded joint will diffuse to the low-carbon steel when it is welded with gr ey cast iron,which will cause the component of carbon greatly increased at the low-carbon steel side in HAZ,high carbon martensite and cracks will occur.If p reheating before weldingslow cooling after welding and other welding procedure are taken,the grey cast iron side can probably be qualified.But the carbon wi ll diffuse to HAZ of the low-carbon steel side more easily.Therefore after stud ying the weldabilities of grey cast iron and low-carbon steel,the author develo ped a new type of cast iron electrode considering the demands of factories’prac tices,and the welding technology test of grey cast iron and low-carbon steel ar e carried out. In this paper,a new type of grey cast iron electrode is developed based on the practices in factories,its ingredients and properties are introduced.The w elding tests of grey cast iron and low-carbon steel are practiced.The joint str ucture of the dissimilar metal and the appearance of weld are observed.The hard ness distribution of the welded joint is tested.The results show that the elect rode can meet the welding requirements of the grey cast iron and low-carbon stee l.There are no cracksgas pores and other defects of metallurgy in welded join t,the appearance of welded joint are good.展开更多
In this study,morphological and microstructural analyses were conducted on net-shaped microcracks appearing on the surface of low-carbon steel manufactured via twin-roll strip casting. The fractograph and microscale d...In this study,morphological and microstructural analyses were conducted on net-shaped microcracks appearing on the surface of low-carbon steel manufactured via twin-roll strip casting. The fractograph and microscale distribution of elements in the cracked region were also analyzed. Results revealed that the cracked surfaces were characterized by slight pits,along with inclusions composed of manganese and silicon oxide distributed along both the sides of the cracks. Fractograph analysis revealed that the crack and smooth dendrite surfaces were oxidized. These phenomena indicate that microcracks on the cast strip surface form at the hightemperature stage of the solidification process during twin-roll casting and rolling. Microcracks were present in each region with pits in the cast strip and extended along the dendrite interface because of the combined effects of phasechange stress,thermal stress,mechanical stress,and fractional crystallization during the solidification process.展开更多
The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic micr...The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic microscpe, chemical analysis etc. The result shows that the technology of carburizing in liquid cast-iron can expedite caburization distinctly and changes the carburizing layer structure. The carburizing rate is 60~80 times of that of the traditional technology, and there is about 43% decrease in the activation energy compared with gas-carburization. In outer structure layer, cementite is formed simultaneously both on the crystal boundary reticularly and inside the crystal grains stripedly. In inner carburizing layer, there is undissolved blocky ferrite in reticular cementite. Besides, rare earth element can expedite carburization process.展开更多
Welded joint impact performances of low-alloy carbon steel plates welded by full-automatic gas metal arc welding (GMAW) were evaluated. To clarity the effect of impact temperature on impact properties of weld metal ...Welded joint impact performances of low-alloy carbon steel plates welded by full-automatic gas metal arc welding (GMAW) were evaluated. To clarity the effect of impact temperature on impact properties of weld metal (WM) and heat- affected zone ( HAZ), Charpy V impact tests at different temperatures and fracture surface analysis were carried out. The Charpy V impact energy decreases with the decreasing test temperature both for the WM and HAZ, while the proportion of crystal zone on WM and HAZ impact fracture surface increases with the decreasing test temperature. Research results indicate that the welding defects (void and slag) make the impact energy of WM more scattered and lower than that of HAZ.展开更多
Electrochemical impedance spectroscopy, cyclic potentiodynamic polarization measurements, and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy were used to investigate the influenc...Electrochemical impedance spectroscopy, cyclic potentiodynamic polarization measurements, and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy were used to investigate the influence of mill scale and rust layer on the passivation capability and chloride-induced corrosion behaviors of conventional low-carbon(LC) steel and low-alloy(LA) steel in simulated concrete pore solution. The results show that mill scale exerts different influences on the corrosion resistance of both steels at various electrochemical stages. We propose that the high long-term corrosion resistance of LA steel is mainly achieved through the synergistic effect of a gradually formed compact, adherent and well-distributed Cr-enriched inner rust layer and the physical barrier protection effect of mill scale.展开更多
The conventional middle and high carbon spring steels have some drawbacks in properties, production and application. In order to meet the demands of rapid development of automobile, a new low and middle carbon spring ...The conventional middle and high carbon spring steels have some drawbacks in properties, production and application. In order to meet the demands of rapid development of automobile, a new low and middle carbon spring steel 35Si2CrMnVB, C0.34, Sil.66, MnO.80, CrO.67, V0.13, B0.001, P0.011, S0.014 wt.%, has been developed. Comparison between the new spring steel 35Si2CrMnVB and the conventional spring steel 60Si2MnA, C0.61, Si 1.75, MnO.76, P0.021, S0.018 wt.%, shows that the new spring steel has not only high strength, good ductility, good comprehensive mechanical properties, but also low decarbonization tendency, sufficient hardenability and high elastic sag resistance, etc.. The microstructure change in quenched steel caused by the decreasing of carbon contents is detected through metallographic observation, the new low and middle carbon spring steel 35Si2CrMnVB after quenching is composed of almost lath martensite with high dislocation density and only a little martensite with twin structure. It is testified that to develop low carbon spring steel with more excellent properties for automobile is feasible.展开更多
In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carb...In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carburized layer was also analyzed. The results show that the carburizing rate of low-carbon steel at high-temperature and short-term is so fast, and the microstructure of carburized layer possess higher carbon content, and cementite, pearlite and ferrite exist in carburized layer structure simultaneously. Besides, the kinetic equations of permeating layer forming have been presented, and the carburizing mechanism was preliminary discussed also.展开更多
文摘Effects of quenching temperature and cooling conditions(water cooling and 10%NaCl cooling)on microstructure and mechanical properties of a 0.2%Ti low alloy martensitic wear-resistant steel used for die casting ejector plate were investigated.The results show that lath martensite can be obtained after austenitizing in the range of 860-980℃and then water cooling.With an increase in austenitizing temperature,the precipitate content gradually decreases.The precipitates are mainly composed of TiC and Ti4C2S2,and their total content is between 1.15wt.%and 1.64wt.%.The precipitate phase concentration by water-cooling is higher than that by10%NaCl cooling due to the lower cooling rate of water cooling.As the austeniting temperature increases,the hardness and tensile strength of both water cooled and 10%NaCl cooled steels firstly increase and then decrease.The experimental steel exhibits the best comprehensive mechanical properties after being austenitized at 900℃,cooled by 10%NaCl,and then tempered at 200℃.Its hardness,ultimate tensile strength,and wear rate reach551.4 HBW,1,438.2 MPa,and 0.48×10^(-2)mg·m^(-1),respectively.
基金This work was supported by the Major State Basic Research Development Program of China(973 Program)under the contract number of 2004CB619108the National Natural Science Foundation of China(No.50574018)the NECT-04-0278 Project of the Ministry of Education of China.
文摘In the present paper, low carbon steel strips with different phosphorus contents were produced using a twin roll strip casting process. The solidification structure was studied and its features were analyzed in detail. It was found that the strips possessed a fine microstructure compared with the mould cast steels. With increasing phosphorus content more ferrite has been formed with finer grains.
基金supported by the National Natural Science Foundation of China (No.50874083)the China Postdoctoral Science Foundation (No.201104493)the China International Scientific and Technological Cooperation Projects (No.2010DFA52130)
文摘A novel diffusion couple method was used to investigate the interface diffusion of arsenic into a Nb-Ti microalloyed low carbon steel and its effects on phase transformation at the interface. It is discovered that the content of arsenic has great effect on grain growth and phase transformation at high temperature. When the arsenic content is no more than lwt%, there is no obvious grain growth and no obvious ferrite transitional region formed at the diffusion interface. However, when the arsenic content is no less than 5wt%, the grain grows very rapidly. In addition, the arsenic-enriched ferrite transitional layer forms at the diffusion interface in the hot-rolling process, which results from a slower diffusion rate of arsenic atoms than that of carbon in ferrite.
文摘The effects of Si content on combinations of important properties such as hardness, hardenability, and weldability in addition to strength increment were systematically investigated to develop a Mo and V free low alloy cast steel for automobile cold pressing die insert. For the evaluation of the applicability as the die insert, the mechanical properties were measured after spheroidization annealing (SA), quenching and tempering (Q/T), and flame hardening (FH) treatments, respectively. The developed 0.8%-1.6%Si containing Mo and V free alloy cast steels showed excellent matrix strengthening effect, hardenability, and weldability, fulfilling the industrial criterion of the mechanical properties for the die insert.
文摘The low stress abrasion behaviours of heat treated mild, medium carbon and high C - low Cr steels, which are generally used in making farm implements, have been investigated. The simple heat treatment greatly improves the hardness, tensile strength and abrasion resistance of medium carbon and high C - low Cr steels. The results indicate that the material removal during abrasion is controlled by a number of factors, such as hardness, chemical composition, microstructure and heat treatment conditions. The conclusion is that the heat treated high C - low Cr steel and mild steel carburized by using coaltar pitch provide the best hardness and abrasion resistance and thus appear to be the most suitable materials for making agricultural tools.
文摘Understanding the weldability of steel in relation to the use of carbon equivalent is very necessary </span><span style="white-space:normal;font-family:"">for</span><span style="white-space:normal;font-family:""> the welding industry. The study was poised to unearth the fundamentals of carbon equivalent as applied in evaluating the weldability of steel. The study used </span><span style="white-space:normal;font-family:"">a </span><span style="white-space:normal;font-family:"">two-stage design approach to address the problem of carbon equivalence weldability of steel, thus, survey and experimental. Two different steels were tested to ascertain their chemical composition which could inform carbon equivalent calculation, and the results revealed microalloy and low alloy steels respectively. In subjecting the microalloy steel to carbon equivalent analyses of the AWS and IIW coefficients;revealed a value (CEV) = 0.11 each, suggesting that this microalloy steel has excellent weldability;no preheat</span><span style="white-space:normal;font-family:"">ing</span><span style="white-space:normal;font-family:""> is required. A successful welding operation on this steel does not depend on preheat</span><span style="white-space:normal;font-family:"">ing</span><span style="white-space:normal;font-family:"">.<b> </b>Also</span><span style="white-space:normal;font-family:"">,</span><span style="white-space:normal;font-family:""> the average results of the low alloy steel revealed a value (CEV) = 0.37 and 0.32 respectively, suggesting that this type of steel has very good weldability and may require </span><span style="white-space:normal;font-family:"">to </span><span style="white-space:normal;font-family:"">preheat. It is recommended that welders have </span><span style="white-space:normal;font-family:"">a </span><span style="white-space:normal;font-family:"">general idea about the weldability of steel with regard to carbon equivalent calculation. In addition</span><span style="white-space:normal;font-family:"">,</span><span style="white-space:normal;font-family:""> they should understand the chemical compositions of steels they are dealing with.
文摘The influence of soaking time in deep cryogenic treatment on the tensile and impact properties of low-alloy medium-carbon HY-TUF steel was investigated in this study. Microstructural studies based on phase distribution mapping by electron backscatter diffraction show that the deep cryogenic process causes a decrease in the content of retained austenite and an increase in the volume fraction of η-carbide with increasing soaking time up to 48 h. The decrease in the content of retained austenite from ~1.23vol% to 0.48vol% suggests an isothermal martensitic transformation at 77 K. The η-type precipitates formed in deep cryogenic-treated martensite over 48 h have the Hirotsu and Nagakura orientation relation with the martensitic matrix. Furthermore, a high coherency between η-carbide and the martensitic matrix is observed by high-resolution transmission electron microscopy. The variations in macrohardness, yield strength, ultimate tensile strength, and ductility with soaking time in the deep cryogenic process show a peak/plateau trend.
文摘The lath-or plate-shaped bainitic ferrite of low and medium carbon alloy steels consists of packets of ferrite sublaths which are composed of many finer and regular ferrite blocks.They are uniform shear growth units of bainitic phase transformation.No carbide is precipitated from them.The bainitic O-carbides are precipitated from γ-α interface or carbon-rich austenite.The mode of arrangement of the units in ferrite sublath packet is in uni-or bi-di- rection.Single surface relief is produced by the accumulation of uniform shear strains with all the ferrite units arranged unidirectionally in a sublath packet,while tent-shaped surface relief is formed by the integration of the uniform shear strains of two groups with ferrite units piling up in two directions and growing face to face;whereas if they grow back to back,the integra- tion will be responsible for invert-tent-shaped surface relief.The interface trace between two groups of ferrite units in a sublath packet is shown as“midrib”.
文摘For better processing performance of high carbon low alloy steel wire rod,an investigation about the influence of cementite lamellar spacing on wire 'easy drawing' performance is completed.It is pointed out that too thin cementite lamellar spacing(<80 um) reduces the strain hardening level of wire drawing, and reduce the torsion performance of drawn wire at same time.For the wire or wire rod from industrial production,compared with the micro-structure with troostite,the micro-structure with sorbite or sorbite mixed with pearlite is more suitable to the drawing process with high reduction ratio.
文摘Corrosion behaviour of cast iron and low alloy steel in cocoa liquor and well water was investigated. The average weight losses of the specimens were measured using digital weighing balance. The results showed that the weight losses of both cast iron and low alloy steel in both media increases with time. Corrosion rate of cast iron in cocoa liquor increases rapidly with time for up to 336 hours (1000 μm/yr), but in well water the rapid rate of corrosion only lasted up to 187 hours (1160 μm/yr) thereafter it continuously dropping until 264 hours (667 μm/yr) after which it remains constant. Low alloy steel corroded faster in cocoa liquor up to 264 hours (200 μm/yr), whereas the initial rapid corrosion rate only lasted up to 168 hours (180 μm/yr) in well water environment. The results revealed that low alloy steel exhibited better corrosion resistance in both media, with cocoa liquor been more aggressive. Thus, low alloy steel will be a better material for piping and pumping system in cocoa processing industries.
文摘The key manufacturing technologies associated with composition, microstructure, mechanical properties, casting quality and key process control for large martensitic stainless steel castings are involved in this paper. The achievements fully satisfeid the technical requirements of the large 700 MW stainless steel hydraulic turbine runner for the Three Gorges Hydropower Station, and become the major technical support for the design and manufacture of the largest 700 MW hydraulic turbine generator unit in the world developed through our own efforts. The characteristics of a new high yield to tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel with ultra low carbon and high cleanliness are also described. Over the next ten years, the large martensitic stainless steel castings and advanced manufacturing technologies will see a huge demand in clean energy industry such as nuclear power, hydraulic power at home and abroad. Therefore, the new high yield o tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel materials, the fast and flexible manufacturing technologies of large size castings, and new environment friendly sustainable process will face new challenges and opportunities.
文摘Grey cast iron’s welding itself is a complex proble m.So proper welding materials must be selected,complex welding techniques such as preheating before weldingslow cooling after welding etc,should be taken. However the carbon component in low-carbon steel is comparatively low,the carbo n of welded joint will diffuse to the low-carbon steel when it is welded with gr ey cast iron,which will cause the component of carbon greatly increased at the low-carbon steel side in HAZ,high carbon martensite and cracks will occur.If p reheating before weldingslow cooling after welding and other welding procedure are taken,the grey cast iron side can probably be qualified.But the carbon wi ll diffuse to HAZ of the low-carbon steel side more easily.Therefore after stud ying the weldabilities of grey cast iron and low-carbon steel,the author develo ped a new type of cast iron electrode considering the demands of factories’prac tices,and the welding technology test of grey cast iron and low-carbon steel ar e carried out. In this paper,a new type of grey cast iron electrode is developed based on the practices in factories,its ingredients and properties are introduced.The w elding tests of grey cast iron and low-carbon steel are practiced.The joint str ucture of the dissimilar metal and the appearance of weld are observed.The hard ness distribution of the welded joint is tested.The results show that the elect rode can meet the welding requirements of the grey cast iron and low-carbon stee l.There are no cracksgas pores and other defects of metallurgy in welded join t,the appearance of welded joint are good.
基金funded by Shanghai Engineering Research Center of Strip Casting and Rolling(No.11DZ2282300)
文摘In this study,morphological and microstructural analyses were conducted on net-shaped microcracks appearing on the surface of low-carbon steel manufactured via twin-roll strip casting. The fractograph and microscale distribution of elements in the cracked region were also analyzed. Results revealed that the cracked surfaces were characterized by slight pits,along with inclusions composed of manganese and silicon oxide distributed along both the sides of the cracks. Fractograph analysis revealed that the crack and smooth dendrite surfaces were oxidized. These phenomena indicate that microcracks on the cast strip surface form at the hightemperature stage of the solidification process during twin-roll casting and rolling. Microcracks were present in each region with pits in the cast strip and extended along the dendrite interface because of the combined effects of phasechange stress,thermal stress,mechanical stress,and fractional crystallization during the solidification process.
文摘The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic microscpe, chemical analysis etc. The result shows that the technology of carburizing in liquid cast-iron can expedite caburization distinctly and changes the carburizing layer structure. The carburizing rate is 60~80 times of that of the traditional technology, and there is about 43% decrease in the activation energy compared with gas-carburization. In outer structure layer, cementite is formed simultaneously both on the crystal boundary reticularly and inside the crystal grains stripedly. In inner carburizing layer, there is undissolved blocky ferrite in reticular cementite. Besides, rare earth element can expedite carburization process.
文摘Welded joint impact performances of low-alloy carbon steel plates welded by full-automatic gas metal arc welding (GMAW) were evaluated. To clarity the effect of impact temperature on impact properties of weld metal (WM) and heat- affected zone ( HAZ), Charpy V impact tests at different temperatures and fracture surface analysis were carried out. The Charpy V impact energy decreases with the decreasing test temperature both for the WM and HAZ, while the proportion of crystal zone on WM and HAZ impact fracture surface increases with the decreasing test temperature. Research results indicate that the welding defects (void and slag) make the impact energy of WM more scattered and lower than that of HAZ.
基金the support by the National Natural Science Foundation of China(Nos.51208098 and 51678144)the National Basic Research Program of China(No.2015CB655100)+1 种基金the Natural Science Foundation of Jiangsu Province(No.BK20161420)Industry-University Research Cooperative Innovation Fund of Jiangsu Province(No.BY2013091)
文摘Electrochemical impedance spectroscopy, cyclic potentiodynamic polarization measurements, and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy were used to investigate the influence of mill scale and rust layer on the passivation capability and chloride-induced corrosion behaviors of conventional low-carbon(LC) steel and low-alloy(LA) steel in simulated concrete pore solution. The results show that mill scale exerts different influences on the corrosion resistance of both steels at various electrochemical stages. We propose that the high long-term corrosion resistance of LA steel is mainly achieved through the synergistic effect of a gradually formed compact, adherent and well-distributed Cr-enriched inner rust layer and the physical barrier protection effect of mill scale.
基金supports from the Natural Science Foundation of Jiangxi Province,P.R.China under contracts No.0250024.
文摘The conventional middle and high carbon spring steels have some drawbacks in properties, production and application. In order to meet the demands of rapid development of automobile, a new low and middle carbon spring steel 35Si2CrMnVB, C0.34, Sil.66, MnO.80, CrO.67, V0.13, B0.001, P0.011, S0.014 wt.%, has been developed. Comparison between the new spring steel 35Si2CrMnVB and the conventional spring steel 60Si2MnA, C0.61, Si 1.75, MnO.76, P0.021, S0.018 wt.%, shows that the new spring steel has not only high strength, good ductility, good comprehensive mechanical properties, but also low decarbonization tendency, sufficient hardenability and high elastic sag resistance, etc.. The microstructure change in quenched steel caused by the decreasing of carbon contents is detected through metallographic observation, the new low and middle carbon spring steel 35Si2CrMnVB after quenching is composed of almost lath martensite with high dislocation density and only a little martensite with twin structure. It is testified that to develop low carbon spring steel with more excellent properties for automobile is feasible.
文摘In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carburized layer was also analyzed. The results show that the carburizing rate of low-carbon steel at high-temperature and short-term is so fast, and the microstructure of carburized layer possess higher carbon content, and cementite, pearlite and ferrite exist in carburized layer structure simultaneously. Besides, the kinetic equations of permeating layer forming have been presented, and the carburizing mechanism was preliminary discussed also.