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Maize straw application as an interlayer improves organic carbon and total nitrogen concentrations in the soil profile: A four-year experiment in a saline soil
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作者 CHANG Fang-di WANG Xi-quan +7 位作者 SONG Jia-shen ZHANG Hong-yuan YU Ru WANG Jing LIU Jian WANG Shang JI Hong-jie LI Yu-yi 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2023年第6期1870-1882,共13页
Soil salinization is a critical environmental issue restricting agricultural production.Deep return of straw to the soil as an interlayer (at 40 cm depth) has been a popular practice to alleviate salt stress.However,t... Soil salinization is a critical environmental issue restricting agricultural production.Deep return of straw to the soil as an interlayer (at 40 cm depth) has been a popular practice to alleviate salt stress.However,the legacy effects of straw added as an interlayer at different rates on soil organic carbon (SOC) and total nitrogen (TN) in saline soils still remain inconclusive.Therefore,a four-year (2015–2018) field experiment was conducted with four levels (i.e.,0,6,12and 18 Mg ha~(–1)) of straw returned as an interlayer.Compared with no straw interlayer (CK),straw addition increased SOC concentration by 14–32 and 11–57%in the 20–40 and 40–60 cm soil layers,respectively.The increases in soil TN concentration (8–22 and 6–34%in the 20–40 and 40–60 cm soil layers,respectively) were lower than that for SOC concentration,which led to increased soil C:N ratio in the 20–60 cm soil depth.Increases in SOC and TN concentrations in the 20–60 cm soil layer with straw addition led to a decrease in stratification ratios (0–20 cm:20–60 cm),which promoted uniform distributions of SOC and TN in the soil profile.Increases in SOC and TN concentrations were associated with soil salinity and moisture regulation and improved sunflower yield.Generally,compared with other treatments,the application of 12 Mg ha~(–1) straw had higher SOC,TN and C:N ratio,and lower soil stratification ratio in the2015–2017 period.The results highlighted that legacy effects of straw application as an interlayer were maintained for at least four years,and demonstrated that deep soil straw application had a great potential for improving subsoil fertility in salt-affected soils. 展开更多
关键词 straw addition InTERLAYER soil organic carbon soil nitrogen c:n ratio saline soil
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Characteristics of Soil Organic Carbon, Total Nitrogen, and C/N Ratio in Chinese Apple Orchards 被引量:6
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作者 Shunfeng Ge Haigang Xu +1 位作者 Mengmeng Ji Yuanmao Jiang 《Open Journal of Soil Science》 2013年第5期213-217,共5页
Soil organic carbon and nitrogen are used as indexes of soil quality assessment and sustainable land use management. At the same time, soil C/N ratio is a sensitive indicator of soil quality and for assessing the carb... Soil organic carbon and nitrogen are used as indexes of soil quality assessment and sustainable land use management. At the same time, soil C/N ratio is a sensitive indicator of soil quality and for assessing the carbon and nitrogen nutrition balance of soils. We studied the characteristics of soil organic carbon and total nitrogen by investigating a large number of apple orchards in major apple production areas in China. High apple orchard soil organic carbon content was observed in the provinces of Heilongjiang, Xinjiang, and Yunnan, whereas low content was found in the provinces of Shandong, Henan, Hebei, and Shaanxi, with the values ranging between 6.44 and 7.76 g·kg-1. Similar to soil organic carbon, soil total nitrogen content also exhibited obvious differences in the 12 major apple producing provinces. Shandong apple orchard soil had the highest total nitrogen content (1.26 g·kg-1), followed by Beijing (1.23 g·kg-1). No significant difference was noted between these two regions, but their total nitrogen content was significantly higher than the other nine provinces, excluding Yunnan. The soil total nitrogen content for Xinjiang, Heilongjiang, Hebei, Henan, and Gansu was between 0.87 and 1.03 g·kg-1, which was significantly lower than that in Shandong and Beijing, but significantly higher than that in Liaoning, Shanxi, and Shaanxi. Six provinces exhibited apple orchard soil C/N ratio higher than 10, including Heilongjiang (15.42), Xinjiang (13.38), Ningxia (14.45), Liaoning (12.24), Yunnan (11.03), and Gansu (10.63). The soil C/N ratio was below 10 in the remaining six provinces, in which the highest was found in Shaanxi (9.47), followed by Beijing (8.98), Henan (7.99), and Shanxi (7.62), and the lowest was found in Hebei (6.80) and Shandong (6.05). Therefore, the improvement of soil organic carbon should be given more attention to increase the steady growth of soil C/N ratio. 展开更多
关键词 cHInESE APPLE ORcHARD Soil Organic carbon Total nitrogen c/n ratio
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藻-菌颗粒污泥处理低C/N生活污水的研究
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作者 张夏 陈红兵 +4 位作者 胡惠秩 汪锐 陈乐言 万仁辉 徐芳 《湖北大学学报(自然科学版)》 CAS 2024年第1期60-67,共8页
在光暗交替、零曝气条件下建立两组不同进水C/N(chemical oxygen demand,COD/total nitrogen,TN)(R_(1):10.0,R 2:5.6)的序批式反应器并运行了70 d,研究微藻-细菌颗粒污泥(microalgal-bacterial granular sludge,MBGS)在低C/N进水条件... 在光暗交替、零曝气条件下建立两组不同进水C/N(chemical oxygen demand,COD/total nitrogen,TN)(R_(1):10.0,R 2:5.6)的序批式反应器并运行了70 d,研究微藻-细菌颗粒污泥(microalgal-bacterial granular sludge,MBGS)在低C/N进水条件下的污染物去除效果、颗粒组成及稳定性的变化。研究发现,R^(1)组颗粒形态稳定,结构紧密,而R^(2)组颗粒形态出现差异化,结构略松散。R^(2)的COD去除率无显著变化,并且有更好的NH_(4)^(+)-N去除效果(94.68±7.24)%,但其PO_(4)^(3-)-P的去除效果不佳(50.69±13.64)%。通过元素分析进一步发现低C/N条件使MBGS中细菌的比例增加36%,并证明低C/N生活污水中的COD和PO_(4)^(3-)-P主要依靠MBGS的同化作用去除,NH_(4)^(+)-N主要被细菌的硝化作用转化。此外,低C/N组中蛋白质含量显著增加,并分泌更多的松散结合EPS(loosely bound EPS,LB-EPS)来提高颗粒稳定性。 展开更多
关键词 藻-菌颗粒污泥 c/n 零曝气 同化作用 硝化作用
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Transformation of Carbon and Nitrogen by Earthworms in the Decomposition Processes of Broad-leaved Litters 被引量:13
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作者 DONG Weihua YIN Xiuqin 《Chinese Geographical Science》 SCIE CSCD 2007年第2期166-172,共7页
Earthworms are the important constituents in the decayed food web and the main ecological conditioners in the process of decomposition and nutrient mineralization. The transformation of organic carbon (C) and total ni... Earthworms are the important constituents in the decayed food web and the main ecological conditioners in the process of decomposition and nutrient mineralization. The transformation of organic carbon (C) and total nitrogen (N) in the broad-leaved litters ingested by earthworms was researched by means of a laboratory experiment. Experimental samples were collected from broad-leaved Korea Pine mixed forest in Liangshui National Natural Reserve (47°10′50″N, 128°53′20″E) in the northeastern Xiao Hinggan Mountains of Northeast China. The contents of organic C and total N in earthworms, leaf litters and earthworm faeces were analyzed. Results show that the organic C content was in the fol- lowing order: leaf litters>faeces>earthworms, while total N content was contrary to that of the organic C. The organic C contents in the different leaf litters were in the following order: Tilia amurensis>Betula costata>Acer mono, whereas the total N contents in the different leaf litters were: Betula costata>Tilia amurensis>Acer mono. The contents of organic C and total N in the faeces from the different leaf litters were almost consistent with the contents of the leaf litters. After the leaf litters were ingested by earthworms, the organic C, which was transformed to increase earthworms' weights, ac- counted for 3.90%-13.31% of the total ingestion by earthworms, while that in the earthworm faeces accounted for 6.14%-13.70%. The transformed organic C through the other metabolism (e.g., respiration) of earthworms accounted for 75.04%-89.92%. The ingested organic C by earthworms was mostly used for metabolic activities. The N ingested by earthworms was less than organic C. It is estimated that 37.08% of total N was transformed to increase the earthworm's weight, 19.97% into earthworm faeces and 47.86% for the consumption of the earthworm's activities. The earthworms not only increased the content of organic C and total N in the soil, but also decreased the values of C/N in the soil and leaf litters. Earthworms play a major role in the leaf litters' decomposition and transformation. 展开更多
关键词 阔叶落叶林 有机碳 蚯蚓 碳转化 氮转化
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Evaluation on nitrogen isotopes analysis in high-C/N-ratio plants using elemental analyzer/isotope ratio mass spectrometry 被引量:2
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作者 胡婧 刘卫国 《Nuclear Science and Techniques》 SCIE CAS CSCD 2014年第2期36-39,共4页
Elemental analyzer/isotope ratio mass spectrometry(EA/TRMS) has been widely applied to analyze the^(15)N/^(14)N isotope composition(δ^(15)N) of plants and soils,but the δ^(15)N results may be inaccurate due to incom... Elemental analyzer/isotope ratio mass spectrometry(EA/TRMS) has been widely applied to analyze the^(15)N/^(14)N isotope composition(δ^(15)N) of plants and soils,but the δ^(15)N results may be inaccurate due to incomplete combustion of the high-C/N-ratio plant samples by EA.Therefore,it is necessary to develop a method to solve the problem of imperfect combustion.In this study,we used two methods:1) adding copper oxide powder to the samples,and 2) increasing the O_2 flow(from 100 mL min^(-1) to 200 mL min^(-1)) for the auto sampler inlet purge line of the EA.The δ^(15)N values of the plant samples became more positive and tended to be stable after complete combustion.Also,the required blank samples for each plant sample decreased with increasing amount of the added CuO powder.However,at 200 mL min^(-1) of the oxygen flow in the EA,complete combustion could not be achieved without adding copper oxide,but this was done with decreased amount of CuO powder.Therefore,mixing cupric oxide into the high-C/N-ratio samples was an efficient,simple and convenient way to solve the problem of imperfect combustion in the EA. 展开更多
关键词 同位素分析 植物样品 元素分析仪 质谱仪 同位素比值 不完全燃烧 评价 铜粉末
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Growing Cover Crops to Improve Biomass Accumulation and Carbon Sequestration: A Phytotron Study 被引量:1
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作者 Qingren Wang Yuncong Li Ashok Alva 《Journal of Environmental Protection》 2010年第2期73-84,共12页
Cover crop system has shown a potential approach to improving carbon sequestration and environmental quality. Six of each winter and summer cover crops were subsequently grown in two soils, Krome gravelly loam soil (K... Cover crop system has shown a potential approach to improving carbon sequestration and environmental quality. Six of each winter and summer cover crops were subsequently grown in two soils, Krome gravelly loam soil (KGL), and Quincy fine sandy soil (QFS), in phytotrons at 3 temperatures (10/20, 15/25, 25/30oC for winter/summer cover crops) to investigate their contributions for carbon (C) sequestration. Among winter cover crops, the highest and the lowest amounts of C accumulated were by bellbean (Vicia faba L.), 597 g/m2 and white clover (Trifolium repens), 149 g/m2, respectively, in the QFS soil. Among summer cover crops, sunn hemp (Crotalaria juncea L.) accumulated the largest quantity of C (481 g/m2), while that by castorbean (Ricinus communis) was 102 g/m2 at 30oC in the KGL soil. The mean net C remained in the residues following the 127 d decomposition were 187 g/m2 of C (73% of the total) and 91 g/m2 (52% of the total) for the winter and summer cover crops, respectively. Following a whole cycle of winter and summer cover crops grown, the mean soil organic C (SOC) increased by 13.8 and 39.1% in the KGL and QFS soil, respectively, compared to the respective soils before. The results suggest that triticale, ryegrass, and bellbean are the promising winter cover crops in the QFS soil, while sunn hemp, velvetbean (Mucuna pruriens), and sorghum sudangrass (Sorghum bicolor &#215;S. bicolor) are recommended summer cover crops for both soils under favorable temperatures. 展开更多
关键词 carbon to nitrogen ratio (c:n) GREEnHOUSE Gas (GHG) Krome Gravelly LOAM (KGL) Quincy Fine Sand (QFS) Soil Organic carbon (SOc)
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Effects of Soil C/N Ratio on Apple Growth and Nitrogen Utilization,Residue and Loss
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作者 Shunfeng GE Yihua REN +4 位作者 Ling PENG Haigang XU Mengmeng JI Shaochong WEI Yuanmao JIANG 《Asian Agricultural Research》 2014年第2期69-72,76,共5页
Soil C /N ratio is an important influencing factor in soil nitrogen cycling. Two-year old apple trees( Borkh. cv. ‘Fuji'/Malus hupehensis) were used to understand the effect of soil C/N ratio [6. 52( CK),10,15,20... Soil C /N ratio is an important influencing factor in soil nitrogen cycling. Two-year old apple trees( Borkh. cv. ‘Fuji'/Malus hupehensis) were used to understand the effect of soil C/N ratio [6. 52( CK),10,15,20,25,30,35 and 40]on apple growth and nitrogen utilization and loss by using15N trace technique. The results showed that,with the increasing of soil C/N ratio,apple shoot length and fresh weight increased at first,and then decreased; the higher apple shoot length and fresh weight appeared in C/N = 15,20 and 25 treatments,and there were no significant differences among these three treatments,but significantly higher than the other treatments. Statistical analysis revealed that there was significant difference in nitrogen utilization rate between the different treatments,the highest N utilization rate was occurred in soil C/N = 25 treatment which value was 22. 87%,and there was no significant difference between soil C/N = 25 and C/N = 20 treatments,but both the two treatments were significantly higher than the other treatments; Soil C/N = 40 had the lowest N utilization rate which value was 15. 43%,and this value was less than CK( 16. 65%). The proportion of plant absorption nitrogen from fertilizer was much higher when the value of soil C/N ratio in the range of 15- 25,but the percentage of plant absorption nitrogen from soil was much higher when the soil C/N ratio was too low( < 15) or high( < 25). Amount of residual nitrogen in soil increased gradually with the soil C/N ratio increasing,the amount of residual nitrogen in C/N = 40 treatment was 1. 32 times than that in CK. With the increasing of soil C/N ratio,fertilizer nitrogen loss decreased at first,and then increased,fertilizer nitrogen loss was the minimum in C/N = 25 treatments( 49. 87%) and the maximum were occurred in CK( 61. 54%). Therefore,regarding the apple growth and nitrogen balance situation,the value of soil C/N ratio in the range of 15- 25 would be favorable for apple growth and could increase effectively nitrogen fixed by soil,reduce nitrogen loss,and improve the nitrogen utilization ratio. 展开更多
关键词 SOIL c/n ratio APPLE 15n nitrogen UTILIZATIOn nitr
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Effect of Ti(C,N) on Properties of Low-carbon MgO-C Bricks
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作者 QIN Xianpeng LI Yuanbing +1 位作者 YANG Zhenghong LI Yawei 《China's Refractories》 CAS 2008年第2期16-21,共6页
The effect of Ti(C,N) on properties of low-carbon MgO-C bricks was investigated.The phase composition and the microstructure of the matrix of low-carbon MgO-C brick containing Ti(C,N) were studied by XRD and SEM analy... The effect of Ti(C,N) on properties of low-carbon MgO-C bricks was investigated.The phase composition and the microstructure of the matrix of low-carbon MgO-C brick containing Ti(C,N) were studied by XRD and SEM analysis together with EDS.The results showed that Ti(C,N) distributed in the matrix of low-carbon MgO-C brick uniformly after being treated at 1 600 ℃ for 3 h in coke powder bed,and Ti(C,N) and MgO formed a solid solution.After the treatment at 1 600 ℃ for 3 h in coke powder bed,the bulk density and cold crushing strength of low-carbon MgO-C brick with Ti(C,N) decreased,and the apparent porosity and linear change rate of specimens increased.The oxidation resistance of low-carbon MgO-C brick with Ti(C,N) was superior to that of low-carbon MgO-C brick with no additives,but inferior to that of low-carbon MgO-C brick with Al powder.The slag resistance of the specimen with Ti(C,N) was excellent as well. 展开更多
关键词 MGO-c 氧化强度 耐火材料 建筑材料
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序批式MPR反应器处理低C/N城市污水运行方式优化研究 被引量:1
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作者 郭海燕 奚志鹏 +3 位作者 艾胜书 沈国 李劲松 边德军 《水处理技术》 CAS CSCD 北大核心 2023年第9期107-112,共6页
微压内循环生物反应器(Micro-Pressure Inner-Loop Bioreactor,MPR)是一种新型的污水处理工艺,在处理低C/N城市污水方面具有潜在优势。本实验考察了不同曝气量和进水方式下序批式MPR反应器对模拟城市污水处理效果,分析了污染物去除过程... 微压内循环生物反应器(Micro-Pressure Inner-Loop Bioreactor,MPR)是一种新型的污水处理工艺,在处理低C/N城市污水方面具有潜在优势。本实验考察了不同曝气量和进水方式下序批式MPR反应器对模拟城市污水处理效果,分析了污染物去除过程和污泥特性。研究结果表明,一次进方式下,在进水TN和TP浓度分别为79.52、4.1mg/L,进水C/N约为3.9的进水条件下,曝气量为7.5 L/h时,反应器TN和TP去除率分别达到70.26%和97.76%;采用二次进水方式后出水TN降至13.95 mg/L,TN的去除率提高至81.71%;两种进水方式下,反应器对COD和TP平均去除率保持在88.67%和95.03%。典型周期内污染物历时表明,和一次进水方式相比,分次进水优化了碳源分配,使更多碳源用于反硝化,系统内酸碱环境较一次进水更稳定,活性污泥浓度MLSS和污泥SOUR高于一次进水。 展开更多
关键词 微压内循环生物反应器(MPR) c/n城市污水 同步脱氮除磷 运行方式优化
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不同调理剂对尾菜低C/N堆肥腐殖化效果的影响 被引量:1
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作者 牛明芬 刘振民 +2 位作者 马建 秦美玲 赵明会 《土壤与作物》 2023年第3期314-325,共12页
针对尾菜碳氮比(C/N)低自身无法堆肥,现有好氧堆肥工艺下尾菜堆肥需要大量调理剂,不同调理剂组分对尾菜堆肥过程的腐殖化进程影响差异不清的问题,本研究以番茄藤蔓尾菜为主要原料,选用小麦秸秆、椰糠和蘑菇渣三种不同的调理剂进行好氧堆... 针对尾菜碳氮比(C/N)低自身无法堆肥,现有好氧堆肥工艺下尾菜堆肥需要大量调理剂,不同调理剂组分对尾菜堆肥过程的腐殖化进程影响差异不清的问题,本研究以番茄藤蔓尾菜为主要原料,选用小麦秸秆、椰糠和蘑菇渣三种不同的调理剂进行好氧堆肥,明确不同调理剂添加情况下,尾菜低碳氮比(C/N=14)好氧堆肥过程中腐殖质的产生与变化趋势。采用温度、pH、电导率(EC)和发芽指数(GI)进行堆肥腐熟度评判,通过腐殖质组分的变化,明确不同调理剂添加情况下的尾菜堆肥腐殖化效果及变化规律。结果表明,相较于尾菜无法自身堆肥完成腐殖化,添加不同调理剂均能使尾菜发生腐殖化,且不同处理腐殖化程度相似,堆肥结束腐殖质含量均在28%左右,但不同处理堆肥产物的胡敏酸含量差异较大,蘑菇渣处理(T3)含量最高达到11.9%,添加椰糠处理(T2)最少仅为4.8%;对不同处理堆肥产物红外光谱分析表明,相较于其他两个处理,添加椰糠处理的芳香族伸缩振动改变量最少,腐殖化程度较低。堆肥结果表明,小麦秸秆、椰糠和蘑菇渣三种调理剂均能使尾菜在低C/N条件下进行好氧堆肥,温度、pH、EC和GI值都能达到相关有机肥标准。添加小麦秸秆更易促进腐植酸产生,促进腐殖质的形成;添加椰糠处理,腐殖化效果较差。 展开更多
关键词 低碳氮比 尾菜堆肥 腐殖化 红外光谱
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低C/N比污水脱氮除磷技术应用研究进展 被引量:1
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作者 郝建军 王薪惠 +3 位作者 丁佳琪 李妍妍 解澍帆 赵荣兴 《辽宁化工》 CAS 2023年第1期94-97,共4页
人类的生存依赖水资源,工业的快速进步发展对水体产生负面影响,氮、磷过度排放使得水体持续恶化,随之而来的水污染成为不可小觑的重大环境问题,干扰人类正常生命活动,毁坏生态平衡,是国民经济绿色长远发展停滞的根源。现已通过多种技术... 人类的生存依赖水资源,工业的快速进步发展对水体产生负面影响,氮、磷过度排放使得水体持续恶化,随之而来的水污染成为不可小觑的重大环境问题,干扰人类正常生命活动,毁坏生态平衡,是国民经济绿色长远发展停滞的根源。现已通过多种技术对水环境进行改善修复,其中低C/N比污水脱氮除磷是解决环境问题的重要方法和研究热点。以传统工艺和新型工艺为切入点,以应用型和改进型为分类方法,对现今低C/N比污水脱氮除磷处理工艺进行总结,旨在为低C/N比污水脱氮除磷技术的发展提供新参考和新思路。 展开更多
关键词 c/n 污水 脱氮除磷技术
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Ti(C,N)基金属陶瓷成分对抗热震性能的影响
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作者 赵玉玲 但成 +1 位作者 余海洲 丰平 《硬质合金》 CAS 2023年第5期329-334,共6页
制备了不同碳氮比Ti(C,N)固溶体和分别加入NbC、TaC、VC、Cr_(3)C_(2)的Ti(C,N)基金属陶瓷,采用水淬冷热震方法研究了不同成分对Ti(C,N)基金属陶瓷抗热震性能的影响。结果表明:金属陶瓷在热冲击过程中,陶瓷相在热应力的作用下会发生开... 制备了不同碳氮比Ti(C,N)固溶体和分别加入NbC、TaC、VC、Cr_(3)C_(2)的Ti(C,N)基金属陶瓷,采用水淬冷热震方法研究了不同成分对Ti(C,N)基金属陶瓷抗热震性能的影响。结果表明:金属陶瓷在热冲击过程中,陶瓷相在热应力的作用下会发生开裂现象,在裂纹扩展路径上产生的微裂纹能促进裂纹扩展;在不同碳氮比的Ti(C_(x),N_(y))固溶体金属陶瓷中,碳氮比7/3的Ti(C_(0.7),N_(0.3))金属陶瓷的抗热震性能最好,本文研究中其热震临界温度为240℃;在添加的四种碳化物(NbC、TaC、VC和Cr_(3)C_(2))中,NbC和TaC能显著提升金属陶瓷的抗热震性,且TaC更优于NbC,而VC和Cr_(3)C_(2)的加入不利于改善金属陶瓷抗热冲击性能。 展开更多
关键词 TI(c n)基金属陶瓷 抗热震性能 碳氮比 碳化物
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活性污泥-悬浮生物膜系统处理低C/N污水深度脱氮性能 被引量:1
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作者 冯琪瑞 唐玉朝 +4 位作者 伍昌年 黄显怀 王坤 薛莉娉 蔡丽丽 《环境化学》 CAS CSCD 北大核心 2023年第5期1697-1707,共11页
通过农业废弃物玉米芯悬浮生长生物膜的载体,构建了活性污泥-悬浮生物膜混合系统,以SBR工艺运行方式对低浓度低C/N污水的深度脱氮性能进行了研究.探究了挂膜启动阶段系统脱氮效果;在工艺稳定运行后,考察了温度、HRT、DO、进水C/N、进水p... 通过农业废弃物玉米芯悬浮生长生物膜的载体,构建了活性污泥-悬浮生物膜混合系统,以SBR工艺运行方式对低浓度低C/N污水的深度脱氮性能进行了研究.探究了挂膜启动阶段系统脱氮效果;在工艺稳定运行后,考察了温度、HRT、DO、进水C/N、进水pH等参数对工艺脱氮性能的影响.经过24 d挂膜后,结合污染物去除情况及镜检显示生物膜挂膜成功.运行结果表明,以预处理后的生活污水作为模拟原水,控制反应温度为26—30℃,HRT=8 h,COD/TN为(4.0±0.1),DO=(2.2±0.1)mg·L^(-1),进水pH=(8.0±0.1)的条件下,系统达到最佳运行条件,COD、NH_(4)^(+)-N、TN平均去除率分别为70.2%、94.8%和80.8%,平均出水COD、NH_(4)^(+)-N、TN浓度分别为14.89 mg·L^(-1)、0.57 mg·L^(-1)和2.40 mg·L^(-1).好氧阶段DO浓度对TN去除率有一定的影响,当好氧阶段DO浓度为(2.2±0.1)mg·L^(-1)时,TN去除率达到峰值84.38%.结果表明,活性污泥-悬浮生物膜混合系统处理低浓度低C/N污水具有优良性能,为低浓度低C/N污水的深度脱氮及玉米芯的资源化利用提供新的思路. 展开更多
关键词 玉米芯 悬浮生物膜 混合系统 低浓度 c/n 深度脱氮
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双金属ZIF衍生的ZnxCoy/N-C催化剂及其高效电催化还原CO_(2)制CO的性能研究 被引量:1
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作者 张爱红 杨勇 +3 位作者 何安帮 杨名 杜军 陶长元 《低碳化学与化工》 CAS 北大核心 2023年第3期62-68,共7页
电催化CO_(2)还原是实现CO_(2)资源化利用的重要方法,其关键在于高效催化剂的合成。以双金属有机骨架化合物(ZnxCoy-ZIF)为前驱体,经高温热解得到ZnxCoy/N-C催化剂,研究了前驱体中双金属的物质的量之比及热解过程对ZnxCoy/N-C催化剂的... 电催化CO_(2)还原是实现CO_(2)资源化利用的重要方法,其关键在于高效催化剂的合成。以双金属有机骨架化合物(ZnxCoy-ZIF)为前驱体,经高温热解得到ZnxCoy/N-C催化剂,研究了前驱体中双金属的物质的量之比及热解过程对ZnxCoy/N-C催化剂的碳载体形成、N掺杂程度、Co电子结构变化及电催化还原CO_(2)制CO的反应性能的影响。结果表明,前驱体中Zn的存在有利于碳载体活性面积的提高,并且促进Co-Nx活性位点的形成,实现对Co位点电子结构的有效调节。900℃热解获得的ZnxCoy/N-C催化剂具有高活性及高导电性,在电还原CO_(2)制CO反应中,电流密度最高可达135 mA/cm2,且CO分电流密度为59 mA/cm2,CO法拉第效率达56.1%,在40 h的性能测试中,ZnxCoy/N-C催化剂的催化活性未出现下降,在电催化CO_(2)中具有工业化的潜力。 展开更多
关键词 Znxcoy/n-c Zn 氮掺杂碳 电催化还原cO_(2)
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混合营养脱氮在低C/N工业废水处理中的研究进展
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作者 鄢子鹏 郑梦启 +4 位作者 王成业 陈国炜 王伟 袁守军 苏馈足 《化工进展》 EI CAS CSCD 北大核心 2023年第12期6567-6575,共9页
富氮工业废水中难降解的氮杂环化合物加剧了碳氮比失衡,抑制了生物脱氮工艺中硝化反硝化过程,因而探究新型处理工艺是高效处理低C/N工业废水的必由之路。混合营养脱氮技术结合异养脱氮和自养脱氮的代谢路径,优化低C/N工业废水脱氮性能,... 富氮工业废水中难降解的氮杂环化合物加剧了碳氮比失衡,抑制了生物脱氮工艺中硝化反硝化过程,因而探究新型处理工艺是高效处理低C/N工业废水的必由之路。混合营养脱氮技术结合异养脱氮和自养脱氮的代谢路径,优化低C/N工业废水脱氮性能,进而实现低C/N工业废水处理提质增效。本文综述了混合营养脱氮工艺中铁介导生物脱氮、硫介导生物脱氮和菌藻共生脱氮工艺的作用机理、研究进展与影响因素,阐述了三种工艺特点及不同类型低C/N工业废水的适用性,并就三种混合营养脱氮工艺中存在的问题并结合当前研究方向,从优化电子供受体和代谢路径的角度提出增大电子容量、提高电子转移速率,结合电化学体系与Fe-S耦合增强协同代谢从而提升污染物代谢性能的建议。 展开更多
关键词 c/n 工业废水 氮杂环化合物 混合营养
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全氟辛酸对好氧颗粒污泥处理低C/N废水的影响
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作者 文晓敏 楼朝刚 +2 位作者 古永红 肖玲玲 刘君子 《水处理技术》 CAS CSCD 北大核心 2023年第8期92-97,共6页
开展了不同温度下新污染物全氟辛酸(PFOA)含量对好氧颗粒污泥(AGS)处理低C/N废水过程中运行效能及微生物群落特征的影响。结果表明,PFOA对AGS系统的影响具有浓度依赖性。低浓度PFOA(低于0.5 mg/L)对COD、NH_(4)^(+)-N及总氮(TN)去除无... 开展了不同温度下新污染物全氟辛酸(PFOA)含量对好氧颗粒污泥(AGS)处理低C/N废水过程中运行效能及微生物群落特征的影响。结果表明,PFOA对AGS系统的影响具有浓度依赖性。低浓度PFOA(低于0.5 mg/L)对COD、NH_(4)^(+)-N及总氮(TN)去除无明显影响,但提高磷酸盐去除。超过0.5 mg/L PFOA降低AGS对污染物和营养盐的去除。温度升高(25℃提高至35℃)利于提高AGS活性,且提高PFOA在AGS系统内的去除。高浓度PFOA降低了污泥浓度和有机质占比,刺激胞外聚合物(EPS)分泌,提高蛋白质(PN)和多糖(PS)含量。在2 mg/L,25℃下,EPS含量为73.6 mg/g,PN和PS占比提高至39.5 mg/g和26.6 mg/g。温度升高能降低PFOA的生物毒性。微生物群落特征分析揭示高浓度PFOA降低了变形菌门(Proteobacteria)、绿弯菌门(Chloroflexi)占比,在属水平上,降低了与生物脱氮相关微生物的相对丰度。研究结果AGS处理含PFOA的低C/N废水提供一定理论依据和强化策略。 展开更多
关键词 全氟辛酸 c/n废水 生物脱氮 微生物群落
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菘蓝碳氮代谢与基质C/N对氮处理的动态响应
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作者 崔英静 孙莉琼 +5 位作者 师建玲 李晓帆 鲍婷婷 王峰峰 唐晓清 王康才 《核农学报》 CAS CSCD 北大核心 2023年第11期2278-2287,共10页
为研究施氮后基质C/N和菘蓝(Isatis indigotica Fort.)碳氮代谢的动态变化,以河北居群的菘蓝为试验材料,播种后施用0、5、15、20 g·L^(-1)CO(NH_(2))_(2),分别记为CK、N1、N2、N3。利用重铬酸钾外加热法和碳氮分析仪测定基质及菘... 为研究施氮后基质C/N和菘蓝(Isatis indigotica Fort.)碳氮代谢的动态变化,以河北居群的菘蓝为试验材料,播种后施用0、5、15、20 g·L^(-1)CO(NH_(2))_(2),分别记为CK、N1、N2、N3。利用重铬酸钾外加热法和碳氮分析仪测定基质及菘蓝碳、氮元素含量;实时荧光定量PCR(qRT-PCR)法测定菘蓝碳氮代谢酶基因的表达;超高效液相色谱(UPLC)法测定菘蓝指标成分含量。结果表明,菘蓝碳氮代谢对不同浓度氮营养的响应不同。随着处理时间延长,N1、N2、N3叶与根的可溶性糖含量先增加后减少,与磷酸烯醇式丙酮酸羧化酶(PEPC)基因表达量变化趋势相反,与蔗糖磷酸合成酶(SPS)活性变化趋势相似。菘蓝碳氮代谢产物与碳氮代谢关键酶的活性及基因表达量密切相关。N1靛蓝含量与硝酸还原酶(NR)基因表达量变化趋势相似,靛玉红含量与谷氨酰胺合成酶(GS)基因表达量、谷氨酸合成酶(GOGAT)活性变化趋势相似,与GOGAT基因表达量、GS活性变化趋势相反。N2靛蓝含量与NR活性变化趋势相反,与GOGAT基因表达量变化趋势相似,靛玉红含量与NR、GS基因表达量、GOGAT活性变化趋势相似。N3靛蓝、靛玉红含量与NR、GS基因表达量、GOGAT活性变化趋势相似。GS、GOGAT活性和其相应酶基因表达量的变化趋势相反。随着菘蓝的生长,基质中的碳元素含量逐渐增加,氮元素含量逐渐减少,C/N升高。菘蓝碳、氮元素含量的变化趋势与基质相反。施氮后,菘蓝叶、根中累积的氮素含量增多,基质中的氮素减少,碳元素含量的变化与氮相反。N2处理各种酶的活性及基因表达量较高,同时累积更高的活性成分。综上,15 g·L^(-1)CO(NH_(2))_(2)处理更有助于菘蓝指标成分的累积。本研究结果为菘蓝氮营养高效利用提供了理论参考。 展开更多
关键词 菘蓝 碳氮代谢 c/n 动态响应
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处理低C/N废水的反硝化细菌及生物脱氮工艺的研究进展
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作者 沈洁 杨国 +3 位作者 廖庆 罗伟锋 夏斌 董华平 《山东化工》 CAS 2023年第20期83-86,共4页
目前,我国大部分生活污水、城市污水和部分工业废水中有机物含量偏低,呈现低C/N的特征,不利于大多数异养反硝化细菌的生物脱氮。因此,需要筛选适应低C/N废水的反硝化细菌,并应用于实际低C/N废水的脱氮处理。本文着重介绍了适应低C/N反... 目前,我国大部分生活污水、城市污水和部分工业废水中有机物含量偏低,呈现低C/N的特征,不利于大多数异养反硝化细菌的生物脱氮。因此,需要筛选适应低C/N废水的反硝化细菌,并应用于实际低C/N废水的脱氮处理。本文着重介绍了适应低C/N反硝化细菌的脱氮性能和适应机制,以及利用反硝化与其他技术相耦合的组合脱氮技术在处理实际低C/N废水中的应用。最后,探讨了处理低C/N废水面临的挑战和发展前景。 展开更多
关键词 c/n 异养反硝化 自养反硝化 组合脱氮工艺
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多点进水AAO-A+MBR工艺在低C/N污水处理厂的工程应用 被引量:2
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作者 沈超 任玉辉 《净水技术》 CAS 2023年第1期168-173,共6页
海宁丁桥污水处理厂四期工程处理规模为5×10^(4)m^(3)/d,进水中工业废水占比高达50%,进水C/N较低。根据现有用地、进水指标及工艺运行情况,新建初沉发酵池+多点进水AAO-A+MBR工艺系统,采用多点进水耦合乙酸钠投加的多碳源分配脱氮... 海宁丁桥污水处理厂四期工程处理规模为5×10^(4)m^(3)/d,进水中工业废水占比高达50%,进水C/N较低。根据现有用地、进水指标及工艺运行情况,新建初沉发酵池+多点进水AAO-A+MBR工艺系统,采用多点进水耦合乙酸钠投加的多碳源分配脱氮保障方法,同时采用了将曝气池溶解氧控制在较低水平的策略。投入运行一年多,在进水COD_(Cr)、氨氮、TP、TN、SS平均质量浓度分别为254.0、29.30、3.09、31.60、126.3 mg/L的情况下,出水COD_(Cr)、氨氮、TP、TN、SS平均质量浓度分别为26.2、0.31、0.23、7.72、5.1 mg/L,出水水质稳定达到《城镇污水处理厂污染物排放标准》(GB 18918—2002)中的一级A标准,单位直接运行成本为0.5330元/m^(3),具有良好的环境效益和经济效益。 展开更多
关键词 污水处理厂 低碳氮比 多点进水 溶解氧 MBR工艺 工程设计
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低C/N比CANON工艺脱氮机制分析
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作者 田亮 黄锐 +1 位作者 杜冬云 吴晨捷 《环境科学与技术》 CAS CSCD 北大核心 2023年第10期104-111,共8页
该文在微氧升流反应器中构建颗粒-絮体污泥体系,以乙酸钠作为碳源,探究了C/N对CANON工艺脱氮效率的影响,并分析了低C/N下该工艺的脱氮机制。当C/N=0.75时,TN和NH_(4)^(+)-N去除率达到了最高值92%和95%。而当C/N从0.75增长至1时,TN和NH_(... 该文在微氧升流反应器中构建颗粒-絮体污泥体系,以乙酸钠作为碳源,探究了C/N对CANON工艺脱氮效率的影响,并分析了低C/N下该工艺的脱氮机制。当C/N=0.75时,TN和NH_(4)^(+)-N去除率达到了最高值92%和95%。而当C/N从0.75增长至1时,TN和NH_(4)^(+)-N去除率分别下降至80%和85%;C/N回调至0.75后,10 d左右反应器性能恢复至91%TN去除率。C/N=0.75时脱氮贡献分析和粒度分布表明AnAOB对NO_(2)^(-)-N的摄取处于优势地位,反应器内主要发生Anammox反应和短程反硝化反应,合适的C/N并不会导致异养菌取代AnAOB的优势地位,且Anammox反应的脱氮贡献在56%~62%之间。 展开更多
关键词 微氧升流反应器 cAnOn工艺 颗粒-絮体污泥 脱氮机制 c/n
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