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Production of super-high strength aluminum alloy billets by low frequency electromagnetic casting 被引量:6
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作者 张海涛 崔建忠 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第10期2134-2139,共6页
The effects of low frequency electromagnetic field on the macro-physical fields in the semi-continuous casting process of aluminum alloys and the microstructure and crack in the billets were studied and analyzed by th... The effects of low frequency electromagnetic field on the macro-physical fields in the semi-continuous casting process of aluminum alloys and the microstructure and crack in the billets were studied and analyzed by the numerical and experimental methods.Comparison of the results for the macro-physical fields in the low frequency electromagnetic casting(LFEC) process with the conventional DC casting process indicates the following characters due to the application of electromagnetic field:an entirely changed direction and remarkably increased velocity of melt flow;a uniform distribution and a decreased gradient of temperature;elevated isothermal lines;a reduced sump depth;decreased stress and plastic deformation.Further,the microstructure of the billets is refined remarkably and the crack in the billets is eliminated in LFEC process because of modification of the macro-physical fields induced by the application of low frequency electromagnetic field. 展开更多
关键词 super-high strength aluminum alloy low frequency electromagnetic casting DC casting macro-physical field CRACK MICROSTRUCTURE
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Gating system optimization of low pressure casting A356 aluminum alloy intake manifold based on numerical simulation 被引量:14
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作者 Jiang Wenming Fan Zitian 《China Foundry》 SCIE CAS 2014年第2期119-124,共6页
To eliminate the shrinkage porosity in low pressure casting of an A356 aluminum alloy intake manifold casting, numerical simulation on fi lling and solidifi cation processes of the casting was carried out using the Pr... To eliminate the shrinkage porosity in low pressure casting of an A356 aluminum alloy intake manifold casting, numerical simulation on fi lling and solidifi cation processes of the casting was carried out using the ProCAST software. The gating system of the casting is optimized according to the simulation results. Results show that when the gating system consists of only one sprue, the fi lling of the molten metal is not stable; and the casting does not follow the sequence solidifi cation, and many shrinkage porosities are observed through the casting. After the gating system is improved by adding one runner and two in-gates, the fi lling time is prolonged from 4.0 s to 4.5 s, the fi lling of molten metal becomes stable, but this casting does not follow the sequence solidifi cation either. Some shrinkage porosity is also observed in the hot spots of the casting. When the gating system was further improved by adding risers and chill to the hot spots of the casting, the shrinkage porosity defects were eliminated completely. Finally, by using the optimized gating system the A356 aluminum alloy intake manifold casting with integrated shape and smooth surface as well as dense microstructure was successfully produced. 展开更多
关键词 low pressure casting A356 aluminum alloy numerical simulation OPTIMIZATION intake manifold
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Properties of Cross-Rolled Low Alloy White Cast Iron Grinding Ball 被引量:9
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作者 CHANG Li-min LIU Lin LIU Jian-hua 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2007年第5期47-51,共5页
The low-energy, multi-impact fracture resistance and the abrasiveness of the cross-rolled low alloy white cast iron grinding balls were studied after heat treatments at residual rolling temperature. Moreover, the mean... The low-energy, multi-impact fracture resistance and the abrasiveness of the cross-rolled low alloy white cast iron grinding balls were studied after heat treatments at residual rolling temperature. Moreover, the means by which they are damaged and characters of the wear surface were analyzed. The results show that high resistance to impact fracture and high abrasiveness can be achieved after appropriate heat treatment at residual rolling temperature. This kind of heat treatment technology has several advantages under low impact and hard abrasive. These results are very useful for determining the optimized heat treatment technology at residual rolling temperatures. 展开更多
关键词 low alloy white cast iron grinding ball cross rolling impact fracture resistance ABRASIVENESS
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Effect of pressurizing speed on filling behavior of gradual expansion structure in low pressure casting of ZL205A alloy 被引量:7
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作者 Shan-guang Liu Chuan-biao Luo +3 位作者 Guo-ai Li Wen-lin Gao Zheng Lu Sheng-long 《China Foundry》 SCIE 2018年第4期276-282,共7页
The mold filling behavior of gradual expansion structure in low pressure casting was studied by two phase flow model using the Volume of Fluid method, and was verified by water simulation with a Plexiglas mold. To get... The mold filling behavior of gradual expansion structure in low pressure casting was studied by two phase flow model using the Volume of Fluid method, and was verified by water simulation with a Plexiglas mold. To get smooth mold filling process and provide a guide for the pressurizing speed design in the producing practice, the mathematical model with the pressurizing speed, expansion angle and height of the gradual expansion structure was established. For validation experiments, ZL205 A alloy castings were produced under two different pressurizing speeds. Weibull probability plots were used to assess the fracture mechanisms under different pressurizing speeds. Mechanical properties of ZL205 A alloy were applied to assess the entrainment of oxide film. The results show that the filling process of a gradual expansion structure in a low pressure casting can be divided into the spreading stage and filling stage by gate velocity. The gate velocity continues to increase in the gradual expansion structure, and increases with the increase of pressurizing speed or expansion angle. Under the effect of the falling fluid raised by the jet flow along the sidewall, the fluid velocity decreases in the jet zone from ingate to free surface. As such, oxide film entrainment does not occur when the gate velocity is greater than the critical velocity, andthe gate velocity no longer reflects the real state of the free surface. The scatter of the mechanical properties is strongly affected by the entrainment of oxide films. 展开更多
关键词 low pressure casting two phase flow water simulation oxide film ZL205A alloy
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Production of A356 aluminum alloy wheels by thixo-forging combined with a low superheat casting process 被引量:5
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作者 Wang Shuncheng Cai Chang +1 位作者 Zheng Kaihong Qi Wenjun 《China Foundry》 SCIE CAS 2013年第5期299-303,共5页
The A356 aluminum alloy wheels were produced by thixo-forging combined with a low superheat casting process. The as-cast microstructure, microstructure evolution during reheating and the mechanical properties of thixo... The A356 aluminum alloy wheels were produced by thixo-forging combined with a low superheat casting process. The as-cast microstructure, microstructure evolution during reheating and the mechanical properties of thixo-forged wheels made from the A356 aluminum alloy were studied. The results show that the A356 aluminum alloy round billet with fine, uniform and non-dendritic grains can be obtained when the melt is cast at 635 ℃ When the round billet is reheated at 600 ℃ for 60 min, the non-dendritic grains are changed into spherical ones and the round billet can be easily thixo-forged into wheels. The tensile strength, yield strength and elongation of the thixo-forged wheels with T6 heat treatment are 327.6 MPa, 228.3 MPa and 7.8%, respectively, which are higher than those of a cast wheel. It is suggested that the thixo-forging combined with the low superheat casting process is an effective technique to produce aluminum alloy wheels with high mechanical properties. 展开更多
关键词 semisolid metal THIXO-FORGING low superheat casting aluminum alloy wheel
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Influence of T6 heat treatment on A356 and A380 aluminium alloys manufactured by thixoforging combined with low superheat casting 被引量:2
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作者 Ridvan GECU Serhat ACAR +2 位作者 Alptekin KISASOZ Kerem ALTUG GULER Ahmet KARAASLAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第3期385-392,共8页
The effects of T6 heat treatment on thixoforged A356 and A380 aluminium alloys were studied.Low superheat casting(LSC)technique was carried out to prepare proper specimens for thixoforging process.The samples were pou... The effects of T6 heat treatment on thixoforged A356 and A380 aluminium alloys were studied.Low superheat casting(LSC)technique was carried out to prepare proper specimens for thixoforging process.The samples were poured at 20°C above their liquidus temperatures which provided the formation of equiaxed grains instead of dendritic growth.Produced billets were reheated for varied time from 20 to 80 min and thixoforged with 50%deformation rate.After thixoforging process,the samples were T6 heat treated for both A356 and A380 alloys.The microstructural evaluation and hardness alteration of thixoforged,solution treated and aged specimens were examined comparatively by using optical microscopy,scanning electron microscopy with energy-dispersive X-ray spectroscopy and Brinell hardness equipment.T6 heat treatment provided relatively uniform microstructure with newly formed precipitates that are Mg2Si and Al2Cu for A356 and A380 billets,respectively.Accordingly,hardness after artificial aging was increased considerably and reached HB 93 for A356 and HB 120 for A380 alloys. 展开更多
关键词 T6 heat treatment THIXOFORGING low superheat casting aluminium alloy
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Pressurization control system for low pressure crucible casting 被引量:2
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作者 Li Qiang Hao Qitang Jie Wanqi 《China Foundry》 SCIE CAS 2011年第4期376-379,共4页
A new compact pressurization control system of the low pressure casting machine for crucible pressure casting has been developed. It is especially designed for the production of high-quality aluminum or magnesium allo... A new compact pressurization control system of the low pressure casting machine for crucible pressure casting has been developed. It is especially designed for the production of high-quality aluminum or magnesium alloy parts with low input cost. This machine with such a system has the virtue of economical and compact, and combines the Fuzzy-PID technology and achieves accuracies of ±2.5 mbar. At present, this machine has been adopted by several users in China for the production of aluminum alloy castings with high property requirements. Furthermore, for magnesium alloy castings, this machine can be used with the gas protect unit. 展开更多
关键词 crucible pressure casting low pressure casting pressurization control system
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Effect of Si Content on Mechanical Properties of a Mo and V Free Low Alloy Cast Steel for Automobile Cold Pressing Die 被引量:1
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作者 B.H.Kim J.S.Shin +4 位作者 S.M.Lee B.M.Moon H.D.Kim S.Y.Ju O.Y.Choi 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2008年第3期313-316,共4页
The effects of Si content on combinations of important properties such as hardness, hardenability, and weldability in addition to strength increment were systematically investigated to develop a Mo and V free low allo... The effects of Si content on combinations of important properties such as hardness, hardenability, and weldability in addition to strength increment were systematically investigated to develop a Mo and V free low alloy cast steel for automobile cold pressing die insert. For the evaluation of the applicability as the die insert, the mechanical properties were measured after spheroidization annealing (SA), quenching and tempering (Q/T), and flame hardening (FH) treatments, respectively. The developed 0.8%-1.6%Si containing Mo and V free alloy cast steels showed excellent matrix strengthening effect, hardenability, and weldability, fulfilling the industrial criterion of the mechanical properties for the die insert. 展开更多
关键词 low alloy cast steel Cold pressing die Die insert Matrix hardening Flame hardening
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Solidification Structure of Low Carbon Steel Strips with Different Phosphorus Contents Produced by Strip Casting 被引量:8
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作者 Na LI Zhenyu LIU Yiqing QIU Zhaosen LIN Xianghua LIU Guodong WANG 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2006年第6期755-758,共4页
In the present paper, low carbon steel strips with different phosphorus contents were produced using a twin roll strip casting process. The solidification structure was studied and its features were analyzed in detail... In the present paper, low carbon steel strips with different phosphorus contents were produced using a twin roll strip casting process. The solidification structure was studied and its features were analyzed in detail. It was found that the strips possessed a fine microstructure compared with the mould cast steels. With increasing phosphorus content more ferrite has been formed with finer grains. 展开更多
关键词 PHOSPHORUS Solidification structure Strip casting low carbon steel
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基于ProCAST的摩托车架低压铸造方案分析与优化 被引量:1
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作者 单爱丽 鲍培玮 +4 位作者 邢书明 闫光远 高文静 欧黎明 姜加兴 《铸造》 CAS 北大核心 2023年第10期1329-1335,共7页
采用ProCAST软件对摩托车架低压铸造过程进行数值模拟。通过研究金属液充型过程中的汇流与卷气现象,凝固过程可能出现的缩松、氧化渣以及整个过程铸件产生的变形量等,以验证车架成形方案设计的合理性。初步仿真结果表明车架整体设计符... 采用ProCAST软件对摩托车架低压铸造过程进行数值模拟。通过研究金属液充型过程中的汇流与卷气现象,凝固过程可能出现的缩松、氧化渣以及整个过程铸件产生的变形量等,以验证车架成形方案设计的合理性。初步仿真结果表明车架整体设计符合要求,但存在氧化渣集中、部分缩松尺寸较大等问题,并预报了变形量的大小,为反变形措施提供了依据。为解决这些问题对模具结构、工艺参数等制定了优化方案并再次进行仿真,改进方案模拟结果表明:在砂芯附近增加2个渣包、将充型一、二阶段的压力降低3~4kPa等,能减小缩松概率、降低氧化渣含量. 展开更多
关键词 摩托车架 低压铸造 数值模拟 充型 凝固 变形量 优化方案
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Principles and practice of low pressure-expendable pattern casting process for magnesium alloys 被引量:1
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作者 LI Ji-qiang FAN Zi-tian +3 位作者 WU He-bao DONG Xuan-pu ZHANG Da-fu HUANG Nai-yu 《China Foundry》 SCIE CAS 2006年第4期293-296,共4页
A newly developed low-pressure expendable pattern casting (LP-EPC) process was introduced and its basic principles or effect factors were further analyzed. According to theoretical calculation and experimental results... A newly developed low-pressure expendable pattern casting (LP-EPC) process was introduced and its basic principles or effect factors were further analyzed. According to theoretical calculation and experimental results, the major casting parameters that are of great and critical importance on the process include pressure and flux of filling gas, decomposition characteristic and density of foam pattern, thickness and permeability of coating, pouring temperature, vacuum degree and their combination. Most of casting defects can be effectively avoided by choosing the suitable parameters. The success achieved in pouring motor housing and exhaust manifold castings demonstrates the advantages of LP-EPC process in the production of high-complicated castings with high dimension accuracy. 展开更多
关键词 MAGNESIUM alloys vacuum SUCKING castING low-PRESSURE castING expendable pattern castING
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Effect of low frequency electromagnetic field on microstructures and macrosegregation of horizontal direct chill casting aluminum alloy 被引量:5
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作者 赵志浩 崔建忠 +2 位作者 董杰 张海涛 张北江 《中国有色金属学会会刊:英文版》 CSCD 2004年第6期1095-1099,共5页
The influences of low frequency electromagnetic field on cast surface, microstructures and macrosegregation in horizontal direct chill(HDC) casting process were investigated experimentally. The cast surfaces, microstr... The influences of low frequency electromagnetic field on cast surface, microstructures and macrosegregation in horizontal direct chill(HDC) casting process were investigated experimentally. The cast surfaces, microstructures and macrosegregation of the ingots manufactured by conventional HDC and low frequency electromagnetic HDC casting were compared. The results show that low frequency electromagnetic field significantly improves the surface quality, refines the microstructures and reduces macrosegregation. Further more, increasing electromagnetic intensity or decreasing frequency is beneficial to the improvement. In the range of ampere-turns and frequency employed in the experiments, the optimum ampere-turns is found to be 10 000 A·turn and the frequency to be 30 Hz. 展开更多
关键词 微观结构 宏观偏析 电磁场 水平冷硬铸造
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EFFECT OF LOW-FREQUENCY ELECTROMAGNETIC FIELD ON THE AS-CASTING MICROSTRUCTURES AND MECHANICAL PROPERTIES OF HDC 2024 ALUMINUM ALLOY 被引量:4
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作者 Q.F. Zhu Z.H. Zhao J.Z. Cui Y.B. Zuo F. Qu 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2008年第3期205-210,共6页
The influences of the low frequency electromagnetic field on the horizontal direct chill casting process were investigated experimentally. Ingots of 2024 aluminum alloy with a cross size of 40 mm× 200 mm were pro... The influences of the low frequency electromagnetic field on the horizontal direct chill casting process were investigated experimentally. Ingots of 2024 aluminum alloy with a cross size of 40 mm× 200 mm were produced by the conventional horizontal chill casting process and low frequency electromagnetic horizontal chill casting processre- spectively. The as-cast structures and the mechanical property of the ingots were examined. The results showed that the low frequency electromagnetic field could sub- stantially refine the microstructures and pronouncedly reduce the macrosegregation in the horizontal direct chill casting process. Moreover, the surface quality of the ingot was prominently improved by the low frequency electromagnetic field. The fracture strength and elongation percentage of the ingot was increased with the low frequency electromagnetic field. 展开更多
关键词 Horizontal direct chill casting low frequency electromagnetic field 2024 aluminum alloy MICROSTRUCTURES MACROSEGREGATION
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Efects of low frequency electromagnetic ield on surface quality, microstructure and hot-tearing tendency of semi-continuous casting ZK60 magnesium alloy billets 被引量:3
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作者 Zhang Zhiqiang Le Qichi +1 位作者 Bao Lei Cui Jianzhong 《China Foundry》 SCIE CAS 2013年第6期351-354,共4页
The low frequency electromagnetic field was applied during direct chill(DC) semi-continuous casting of the ZK60 magnesium alloy billets. Effects of low frequency electromagnetic field on surface quality, microstructur... The low frequency electromagnetic field was applied during direct chill(DC) semi-continuous casting of the ZK60 magnesium alloy billets. Effects of low frequency electromagnetic field on surface quality, microstructure and hot-tearing tendency of Φ500 mm ZK60 magnesium alloy billets were investigated. The results showed that with the application of the low frequency electromagnetic field, the surface quality of the ZK60 magnesium alloy billets is markedly improved and the depth of cold fold is decreased. The microstructure of the billets is also significantly refined. Besides, the distribution of the grain size is relatively uniform from the billet surface towards its center, where the average grain size is 42 μm at surface and 50 μm at center. It also shows that the hot-tearing tendency of DC semi-continuous casting ZK60 magnesium alloy billets is significantly reduced under low frequency electromagnetic field. 展开更多
关键词 ZK60 magnesium alloy billets direct chill casting low frequency electromagnetic field REFINEMENT
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Formation mechanism of spheroidal carbide in ultra-low carbon ductile cast iron 被引量:2
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作者 Bin-guo Fu Zhuo-qing Li +3 位作者 Xue-bo Zhao Zhen Shen Guo-lu Li Jin-hai Liu 《China Foundry》 SCIE 2016年第5期346-351,共6页
The formation mechanism of the spheroidal carbide in the ultra-low carbon ductile cast iron fabricated by the metal mold casting technique was systematically investigated. The results demonstrated that the spheroidal ... The formation mechanism of the spheroidal carbide in the ultra-low carbon ductile cast iron fabricated by the metal mold casting technique was systematically investigated. The results demonstrated that the spheroidal carbide belonged to eutectic carbide and crystallized in the isolated eutectic liquid phase area. The formation process of the spheroidal carbide was related to the contact and the intersection between the primary dendrite and the secondary dendrite of austenite. The oxides of magnesium, rare earths and other elements can act as heterogeneous nucleation sites for the spheroidal carbide. It was also found that the amount of the spheroidal carbide would increase with an increase in carbon content. The cooling rate has an important influence on the spheroidal carbide under the same chemical composition condition. 展开更多
关键词 ultra-low carbon ductile cast iron cooling rate nucleation core spheroidal carbides formation mechanism
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MODELING AND EXPERIMENTAL RESEARCH OF FOUR-STRAND LOW-FREQUENCY ELECTROMAGNETIC CASTING ALUMINUM ALLOY 被引量:1
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作者 J.C. Li B.F. Wang J.Z. Cui 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2007年第3期157-166,共10页
With the aid of ANSYS software, the effect of different mould external part materials on magnetic flux density in the aluminum melt and magnetic field interaction of four coils applied with same currents were investig... With the aid of ANSYS software, the effect of different mould external part materials on magnetic flux density in the aluminum melt and magnetic field interaction of four coils applied with same currents were investigated. Calculating results showed that magnetic flux density in the aluminum melt was greatly improved and the magnetic field interaction among different coils was decreased when external part of mould is made of soft magnetic material. Based on the finding, a four-strand low-frequency electromagnetic casting 6063 aluminum alloy experiment was carried out in the laboratory . The experiment showed that the surface of the billet was smooth and had no exudations and cold shuts, the as-cast microstructures were fine, uniform, equiaxed, net-globular or globular under low-frequency electromagnetic field. The microstructure becomes finer with increased current value. 展开更多
关键词 low-frequency electromagnetic casting finite element method aluminum alloy MOULD
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Effect of Cooling Rate on Structure and Properties of Wear-Resistant Low Chromium Cast Iron after Hot Deformation
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作者 CHANGLi-min WANGHai-yan +2 位作者 HUANGYa-dian XUHong ZHOUXiao-guang 《Journal of Iron and Steel Research International》 SCIE CAS CSCD 2005年第2期52-55,63,共5页
The effect of cooling rate on structure and properties of wear-resistant low chromium cast iron after 40% hot deformation was investigated by metallographic and scanning electron microscope. The results show that the ... The effect of cooling rate on structure and properties of wear-resistant low chromium cast iron after 40% hot deformation was investigated by metallographic and scanning electron microscope. The results show that the cooling rate is closely related to the structure and properties, and for the cast iron, the best comprehensive mechanical properties were obtained by forced air cooling with a cooling rate as about 7 ℃/s. The reason and regularity for the change of mechanical properties were analyzed. 展开更多
关键词 cooling rate hot deformation structure property wear resistance low chromium cast iron
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A Comparison Study between Suspension Casting Process and Low Superheat Casting Process
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作者 Yan Yu Qijie Thai +1 位作者 Libo Zhang Hanqi Hu (Materials Science and Engineering School, University of Science and Technology Beliing, Beding 100083, China)(Shenyang Research Institute of Foundry, Shenyang 110021, China) 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 1999年第1期31-34,共4页
Taking GCr15 bearing steel as experiment material, the effects of suspension casting process and low superheat casting process on the solidification of ingot were studied comparehvely. The results show that both suspe... Taking GCr15 bearing steel as experiment material, the effects of suspension casting process and low superheat casting process on the solidification of ingot were studied comparehvely. The results show that both suspension casting process and low superheat casting process can improve the censeal segregation and crystal structure of ingot. As the acting mechanism is different between the two kinds of processes, it is found that suspension casting process is more effective than low superheat casting process in improving the quality of ingot. 展开更多
关键词 suspension casting process low superheat casting process SOLIDIFICATION
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Coupled Modeling of Electromagnetic Fleld,Fluid Flow,Heat Transfer and Solidification During Conventional DC Casting and Low Ftequency Electrmagnetic Casting of 7xxx Aluminum Alloys
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作者 Nagaum Hiromi 《特种铸造及有色合金》 CAS CSCD 北大核心 2008年第S1期485-490,共6页
A comprehensive mathematical model has been developed to describe the interaction of the multiple physics fields during the conventional DC casting and LFEC (low frequency electromagnetic casting) process. The model i... A comprehensive mathematical model has been developed to describe the interaction of the multiple physics fields during the conventional DC casting and LFEC (low frequency electromagnetic casting) process. The model is based on a combination of the commercial finite element package ANSYS and the commercial finite volume package FLUENT, with the former for the calculation of the electromagnetic field and the latter for the calculation of the magnetic driven fluid flow, heat transfer and solidification. Moreover, the model has been verified against the temperature measurements obtained from two 7XXX aluminum alloy billets of 200mm diameter, cast during the conventional DC casting and the LFEC casting processes. In addition, a measurement of the sump shape of the billets were carried out by using addition melting metal of Al-30%Cu alloy into the billets during casting process. There was a good agreement between the calculated results and the measured results. Further, comparison of the calculated results during the LFEC process with that during the conventional DC casting process indicated that velocity patterns, temperature profiles and the sump depth are strongly modified by the application of a low frequency electromagnetic field during the DC casting. 展开更多
关键词 low frequency electromagnetic casting DC casting coupled modeling temperature field fluid flow solidification.
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Low-Energy Multi-Impact Fracture Resistance of Cross Rolled Low Chromium Cast Semi-Steel Containing Rare Earth Grinding Ball
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作者 王海燕 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第S1期154-156,共3页
The low-energy multi-impact fracture resistance of the cross rolled low chromium cast semi-steel containing RE grinding balls was studied. Moreover, its damage mode was analyzed by means of metallographic examination,... The low-energy multi-impact fracture resistance of the cross rolled low chromium cast semi-steel containing RE grinding balls was studied. Moreover, its damage mode was analyzed by means of metallographic examination, scanning electron microscopic examination and drop ball test. The results show that it can obtain extractive impact fracture resistance after proper heat treatment. More advantages were obtained for the ball worked in the condition of low-imp ductility act. The main reasons are the function of RE and the change in morphology of eutectic carbide network. 展开更多
关键词 cross rolled low chromium cast semi-steel grinding ball impact fracture resistance rare earths
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