Low melting point metals（Ga, In, Sn） as alloy elements were used to prepare Al-In-Sn and Al-Ga-In-Sn alloys through mechanical ball milling method. The effects of mass ratio of In to Sn and Ga content on the hydroly...Low melting point metals（Ga, In, Sn） as alloy elements were used to prepare Al-In-Sn and Al-Ga-In-Sn alloys through mechanical ball milling method. The effects of mass ratio of In to Sn and Ga content on the hydrolysis properties of aluminum alloys were investigated. X-ray diffraction（XRD） and scanning electron microscopy（SEM） with energy disperse spectroscopy（EDS） were used to analyze the compositions and morphologies of the obtained Al alloys. The results show that the phase compositions of Al-In-Sn ternary alloys are Al and two intermetallic compounds, In3 Sn and In Sn4. All Al-In-Sn ternary alloys exhibit poor hydrolysis activity at room temperature. Al-In-Sn alloy with the mass ratio of In to Sn equaling 1：4 has the highest hydrogen yield. After Ga is introduced to the ternary alloys, the hydrolysis activity of aluminum alloys at room temperature is greatly improved. It is speculated that the addition of Ga element promotes the formation of defects inside the Al alloys and Ga-In3Sn-In Sn4 eutectic alloys on the alloys surface. Al atoms can be dissolved in this eutectic phase and become the active spots during the hydrolysis process. The small size and uniform distribution of this eutectic phase may be responsible for the enhancement of hydrolysis activity.展开更多
Thermal resistance of low-melting-temperature alloy （LMTA） thermal interface materials （TIMs） was measured by laser flash method before and after different stages of heating. The results showed that the thermal pe...Thermal resistance of low-melting-temperature alloy （LMTA） thermal interface materials （TIMs） was measured by laser flash method before and after different stages of heating. The results showed that the thermal performance of the LMTA TIMs was degraded during the heating process. It is suggested that the degradation may mainly be attributed to the interfacial reaction between the Cu and the molten LMTAs. Due to the fast growth rate of intermetallic compound （IMC） at the solid-liquid interface, a thick brittle IMC is layer formed at the interface, which makes cracks easy to initiate and expand. Otherwise, the losses of indium and tin contents in the LMTA during the interfacial reaction will make the melting point of the TIM layer increase, and so, the TIM layer will not melt at the operating temperature.展开更多
The effects of homogenization treatment on microstructure, overburnt temperature and hot rolling plasticity of high strength 7B04 aluminium alloy were investigated. Under the condition of homogenization at 470 ℃, the...The effects of homogenization treatment on microstructure, overburnt temperature and hot rolling plasticity of high strength 7B04 aluminium alloy were investigated. Under the condition of homogenization at 470 ℃, the starting melting temperature of the primary eutectics in ingot of non-equilibium solidified 7B04 alloy is 478 ℃. Using two-step homogenization processing at ultra-high temperature which comprises heating the ingots to 470 ℃ at 10 ℃/ h and holding for 64 h, and then heating to 500 ℃ at 1 ℃ /h and holding for 10 h, the ingots of 7B04 aluminium alloy could safely pass the sensitive overburnt zone between 480 ℃ and 495 ℃, and the ordinary burnt phenomena of the ingots between 480 ℃ and 495 ℃ does not occur because the excess low-melting point eutectic phases in the as-cast alloy dissolve into the matrix during the two-step homogenization processing. Consequently, the hot rolling plasticity of ingot of 7B04 aluminium alloy is greatly improved.展开更多
Experimental studies to demonstrate self healing potentials of Al-Mg-Si alloy were undertaken in this research work. Self healing exploring secondary precipitation in the Al-Mg-Si alloy and use of low melting metallic...Experimental studies to demonstrate self healing potentials of Al-Mg-Si alloy were undertaken in this research work. Self healing exploring secondary precipitation in the Al-Mg-Si alloy and use of low melting metallic alloy reinforcement (60Sn-40Pb alloy) were used as basis for the investigation. For the precipitation study, the Al-Mg-Si alloy was under-aged at temperature of 160oC for 10 minutes and then subjected to second step ageing treatment at four different temperatures within the range of 25oC and 70oC. In the 60Sn-40Pb alloy reinforced Al-Mg-Si alloy study, the samples were prepared in pre-cracked state and then subjected to healing heat-treatment at 250oC. For all cases tensile test and healing efficiency was used to analyze the results generated. It was observed that a second step thermal ageing at 50oC resulted in peak improvement in tensile strength, yield strength, toughness and percent elongation while ageing above this temperature lead to a drop in the tensile properties in comparison to that of the sample not subjected to a second ageing treatment. Also the use of 60Sn-40Pb alloy as reinforcement in the Al-Mg-Si alloy resulted in a healing efficiency of 91% after pre-cracking and heat-treatment. The satisfactory bonding between the 60Sn-40Pb alloy and the Al-Mg-Si alloy matrix contributed to the high healing efficiency observed.展开更多
In order to remove hydrogen and inclusions from A356 alloy melt, a low melting point glass flux, JDN Ⅱ, was developed. The results indicated that JDN Ⅱ flux has distinct effect of purification and protection on A356...In order to remove hydrogen and inclusions from A356 alloy melt, a low melting point glass flux, JDN Ⅱ, was developed. The results indicated that JDN Ⅱ flux has distinct effect of purification and protection on A356 alloy melt. When the dosage of the flux was 3%, the content of hydrogen in A356 melt was only 2.6?mL/kg at 857?℃ and 0.7?mL/kg even at 750?℃. In the meantime, the mechanical properties of the alloy increase greatly with the covering of 3% JDN Ⅱ flux. Compared with no flux, the tensile strength of A356 alloy increases by 9.42% and the elongation increases by 22%. The purification mechanism of JDN Ⅱ glass flux was discussed too.展开更多
基金Project(2010CB635107) supported by the Major State Basic Research Development Program of ChinaProjects(51202064,51472081) supported by the National Natural Science Foundation of China+2 种基金Project(2013CFA085) supported by the Natural Science Foundation of Hubei Province,ChinaProject(2013070104010016) supported by Wuhan Youth Chenguang Program of Science and Technology,ChinaProject([2013]2-22) supported by the Open Fund of Key Laboratory of Green Materials for Light Industry of Hubei Province,China
文摘Low melting point metals（Ga, In, Sn） as alloy elements were used to prepare Al-In-Sn and Al-Ga-In-Sn alloys through mechanical ball milling method. The effects of mass ratio of In to Sn and Ga content on the hydrolysis properties of aluminum alloys were investigated. X-ray diffraction（XRD） and scanning electron microscopy（SEM） with energy disperse spectroscopy（EDS） were used to analyze the compositions and morphologies of the obtained Al alloys. The results show that the phase compositions of Al-In-Sn ternary alloys are Al and two intermetallic compounds, In3 Sn and In Sn4. All Al-In-Sn ternary alloys exhibit poor hydrolysis activity at room temperature. Al-In-Sn alloy with the mass ratio of In to Sn equaling 1：4 has the highest hydrogen yield. After Ga is introduced to the ternary alloys, the hydrolysis activity of aluminum alloys at room temperature is greatly improved. It is speculated that the addition of Ga element promotes the formation of defects inside the Al alloys and Ga-In3Sn-In Sn4 eutectic alloys on the alloys surface. Al atoms can be dissolved in this eutectic phase and become the active spots during the hydrolysis process. The small size and uniform distribution of this eutectic phase may be responsible for the enhancement of hydrolysis activity.
基金supported by the National Basic Research Program of China (No.2010CB631006)the National Natural Science Foundation of China (No.51171191)
文摘Thermal resistance of low-melting-temperature alloy （LMTA） thermal interface materials （TIMs） was measured by laser flash method before and after different stages of heating. The results showed that the thermal performance of the LMTA TIMs was degraded during the heating process. It is suggested that the degradation may mainly be attributed to the interfacial reaction between the Cu and the molten LMTAs. Due to the fast growth rate of intermetallic compound （IMC） at the solid-liquid interface, a thick brittle IMC is layer formed at the interface, which makes cracks easy to initiate and expand. Otherwise, the losses of indium and tin contents in the LMTA during the interfacial reaction will make the melting point of the TIM layer increase, and so, the TIM layer will not melt at the operating temperature.
基金Project(MKPT-2004-17ZD) supported by the National 10th Five-Year Plan of China
文摘The effects of homogenization treatment on microstructure, overburnt temperature and hot rolling plasticity of high strength 7B04 aluminium alloy were investigated. Under the condition of homogenization at 470 ℃, the starting melting temperature of the primary eutectics in ingot of non-equilibium solidified 7B04 alloy is 478 ℃. Using two-step homogenization processing at ultra-high temperature which comprises heating the ingots to 470 ℃ at 10 ℃/ h and holding for 64 h, and then heating to 500 ℃ at 1 ℃ /h and holding for 10 h, the ingots of 7B04 aluminium alloy could safely pass the sensitive overburnt zone between 480 ℃ and 495 ℃, and the ordinary burnt phenomena of the ingots between 480 ℃ and 495 ℃ does not occur because the excess low-melting point eutectic phases in the as-cast alloy dissolve into the matrix during the two-step homogenization processing. Consequently, the hot rolling plasticity of ingot of 7B04 aluminium alloy is greatly improved.
文摘Experimental studies to demonstrate self healing potentials of Al-Mg-Si alloy were undertaken in this research work. Self healing exploring secondary precipitation in the Al-Mg-Si alloy and use of low melting metallic alloy reinforcement (60Sn-40Pb alloy) were used as basis for the investigation. For the precipitation study, the Al-Mg-Si alloy was under-aged at temperature of 160oC for 10 minutes and then subjected to second step ageing treatment at four different temperatures within the range of 25oC and 70oC. In the 60Sn-40Pb alloy reinforced Al-Mg-Si alloy study, the samples were prepared in pre-cracked state and then subjected to healing heat-treatment at 250oC. For all cases tensile test and healing efficiency was used to analyze the results generated. It was observed that a second step thermal ageing at 50oC resulted in peak improvement in tensile strength, yield strength, toughness and percent elongation while ageing above this temperature lead to a drop in the tensile properties in comparison to that of the sample not subjected to a second ageing treatment. Also the use of 60Sn-40Pb alloy as reinforcement in the Al-Mg-Si alloy resulted in a healing efficiency of 91% after pre-cracking and heat-treatment. The satisfactory bonding between the 60Sn-40Pb alloy and the Al-Mg-Si alloy matrix contributed to the high healing efficiency observed.
文摘In order to remove hydrogen and inclusions from A356 alloy melt, a low melting point glass flux, JDN Ⅱ, was developed. The results indicated that JDN Ⅱ flux has distinct effect of purification and protection on A356 alloy melt. When the dosage of the flux was 3%, the content of hydrogen in A356 melt was only 2.6?mL/kg at 857?℃ and 0.7?mL/kg even at 750?℃. In the meantime, the mechanical properties of the alloy increase greatly with the covering of 3% JDN Ⅱ flux. Compared with no flux, the tensile strength of A356 alloy increases by 9.42% and the elongation increases by 22%. The purification mechanism of JDN Ⅱ glass flux was discussed too.
