Synergistic anionic/zwitterionic mixed surfactant system with high emulsification efficiency for enhanced oil recovery in low permeability reservoirs

Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant sodium alkyl glucosyl hydroxypropyl sulfonate(APGSHS) and zwitterionic surfactant octadecyl betaine(BS-18) is proposed. The performance of APGSHS/BS-18 mixed surfactant system was evaluated in terms of interfacial tension, emulsification capability, emulsion size and distribution, wettability alteration, temperature-resistance and salt-resistance. The emulsification speed was used to evaluate the emulsification ability of surfactant systems, and the results show that mixed surfactant systems can completely emulsify the crude oil into emulsions droplets even under low energy conditions. Meanwhile,the system exhibits good temperature and salt resistance. Finally, the best oil recovery of 25.45% is achieved for low permeability core by the mixed surfactant system with a total concentration of 0.3 wt%while the molar ratio of APGSHS:BS-18 is 4:6. The current study indicates that the anionic/zwitterionic mixed surfactant system can improve the oil flooding efficiency and is potential candidate for application in low permeability reservoirs.

A novel profile modification HPF-Co gel satisfied with fractured low permeability reservoirs in high temperature and high salinity

Conformance control and water plugging are a widely used EOR method in mature oilfields.However,majority of conformance control and water plugging agents are unavoidable dehydrated situation in high-temperature and high-salinity low permeability reservoirs.Consequently,a novel conformance control system HPF-Co gel,based on high-temperature stabilizer(CoCl_(2)·H_(2)O,CCH)is developed.The HPF-Co bulk gel has better performances with high temperature(120℃)and high salinity(1×10^(5)mg/L).According to Sydansk coding system,the gel strength of HPF-Co with CCH is increased to code G.The dehydration rate of HPF-Co gel is 32.0%after aging for 150 d at 120℃,showing excellent thermal stability.The rheological properties of HPF gel and HPF-Co gel are also studied.The results show that the storage modulus(G′)of HPF-Co gel is always greater than that of HPF gel.The effect of CCH on the microstructure of the gel is studied.The results show that the HPF-Co gel with CCH has a denser gel network,and the diameter of the three-dimensional network skeleton is 1.5-3.5μm.After 90 d of aging,HPF-Co gel still has a good three-dimensional structure.Infrared spectroscopy results show that CCH forms coordination bonds with N and O atoms in the gel amide group,which can suppress the vibration of cross-linked sites and improve the stability at high temperature.Fractured core plugging test determines the optimized polymer gel injection strategy and injection velocity with HPF-Co bulk gel system,plugging rate exceeding 98%.Moreover,the results of subsequent waterflooding recovery can be improved by 17%.

Modeling of multiphase flow in low permeability porous media:Effect of wettability and pore structure properties

Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the effects of complex pore structures and wettability.To address this issue,based on the digital rock of low permeability sandstone,a direct numerical simulation is performed considering the interphase drag and boundary slip to clarify the microscopic water-oil displacement process.In addition,a dual-porosity pore network model(PNM)is constructed to obtain the water-oil relative permeability of the sample.The displacement efficiency as a recovery process is assessed under different wetting and pore structure properties.Results show that microscopic displacement mechanisms explain the corresponding macroscopic relative permeability.The injected water breaks through the outlet earlier with a large mass flow,while thick oil films exist in rough hydrophobic surfaces and poorly connected pores.The variation of water-oil relative permeability is significant,and residual oil saturation is high in the oil-wet system.The flooding is extensive,and the residual oil is trapped in complex pore networks for hydrophilic pore surfaces;thus,water relative permeability is lower in the water-wet system.While the displacement efficiency is the worst in mixed-wetting systems for poor water connectivity.Microporosity negatively correlates with invading oil volume fraction due to strong capillary resistance,and a large microporosity corresponds to low residual oil saturation.This work provides insights into the water-oil flow from different modeling perspectives and helps to optimize the development plan for enhanced recovery.

Development of Superhydrophobic Nano-SiO_(2)and Its Field Application in Low-permeability,High-temperature,and High-salinity Oil Reservoirs

In this study,to meet the stringent requirements on the hydrophobicity of nano-SiO_(2)particles for use in depressurization and enhanced injection operations in high-temperature and high-salinity oil reservoirs,secondary chemical grafting modification of nano-SiO_(2)is performed using a silane coupling agent to prepare superhydrophobic nano-SiO_(2) particles.Using these superhydrophobic nano-SiO_(2)particles as the core agent,and liquid paraffin or diesel as the dispersion medium,a uniform dispersion of nano-SiO_(2)particles is achieved under high-speed stirring,and a chemically enhanced water injection system with colloidal stability that can be maintained for more than 60 d is successfully developed.Using this system,a field test of depressurization and enhanced injection is carried out on six wells in an oilfield,and the daily oil production level is increased by 11 t.The cumulative increased water injection is 58784 m^(3),the effective rate of the measures was 100%,and the average validity period is 661 d.

Characteristics of water alternating CO_(2)injection in low-permeability beach-bar sand reservoirs

Water flooding can be ineffective in highly heterogeneous low-permeability beach-bar sand reservoirs.The introduction of CO_(2)flooding helps boost the oil production of the reservoirs but only in an early stage.During the late stage of flooding,gas channeling would occur.Water alternating gas(CO_(2))(WAG)process can be used to delay gas channeling and improve the effect of CO_(2)injection,though its adaptability to beach-bar sand reservoirs remains unclear.In order to clarify CO_(2)injection characteristics in these reservoirs,experiments were carried out in high-temperature high-pressure NMR on-line displacement experiment apparatus to simulate different flooding modes on synthetic cores that can reflect the vertical heterogeneity of beach-bar reservoirs.Different CO_(2)injection modes were implemented on these cores and the displacement characteristics and residual oil distribution features during both WAG injection and continuous CO_(2)injection were analyzed quantitatively and qualitatively.The results show that the scheme of WAG injection after continuous CO_(2)injection can obtain better oil displacement efficiency than that of the scheme of continuous CO_(2)injection after WAG injection,but there is no significant difference in respect of oil displacement efficiency of WAG flooding between the mode of bar-injection e beach-production(injection into bar sand e production from beach sand)and the mode of beach-injection e beach-production(injection into and production from beach sand),with the former mode having a higher oil recovery rate.The wider pore-size distribution range of microscopic residual oil after WAG injection shows great potential of enhancing oil recovery from subsequent continuous gas injection.When WAG injection is implemented prior to continuous CO_(2)injection,the displacement effect of the latter is more significant.This research may provide a theoretical basis for CO_(2)EOR in this type of reservoirs.

Numerical Simulation of Oil-Water Two-Phase Flow in Low Permeability Tight Reservoirs Based on Weighted Least Squares Meshless Method

In response to the complex characteristics of actual low-permeability tight reservoirs,this study develops a meshless-based numerical simulation method for oil-water two-phase flow in these reservoirs,considering complex boundary shapes.Utilizing radial basis function point interpolation,the method approximates shape functions for unknown functions within the nodal influence domain.The shape functions constructed by the aforementioned meshless interpolation method haveδ-function properties,which facilitate the handling of essential aspects like the controlled bottom-hole flow pressure in horizontal wells.Moreover,the meshless method offers greater flexibility and freedom compared to grid cell discretization,making it simpler to discretize complex geometries.A variational principle for the flow control equation group is introduced using a weighted least squares meshless method,and the pressure distribution is solved implicitly.Example results demonstrate that the computational outcomes of the meshless point cloud model,which has a relatively small degree of freedom,are in close agreement with those of the Discrete Fracture Model(DFM)employing refined grid partitioning,with pressure calculation accuracy exceeding 98.2%.Compared to high-resolution grid-based computational methods,the meshless method can achieve a better balance between computational efficiency and accuracy.Additionally,the impact of fracture half-length on the productivity of horizontal wells is discussed.The results indicate that increasing the fracture half-length is an effective strategy for enhancing production from the perspective of cumulative oil production.

Experimental study of the mechanism of nanofluid in enhancing the oil recovery in low permeability reservoirs using microfluidics

Due to the low porosity and low permeability in unconventional reservoirs,a large amount of crude oil is trapped in micro-to nano-sized pores and throats,which leads to low oil recovery.Nanofluids have great potential to enhance oil recovery(EOR)in low permeability reservoirs.In this work,the regulating ability of a nanofluid at the oil/water/solid three-phase interface was explored.The results indicated that the nanofluid reduced the oil/water interfacial tension by two orders of magnitude,and the expansion modulus of oil/water interface was increased by 77% at equilibrium.In addition,the solid surface roughness was reduced by 50%,and the three-phase contact angle dropped from 135(oil-wet)to 48(water-wet).Combining the displacement experiments using a 2.5D reservoir micromodel and a microchannel model,the remaining oil mobilization and migration processes in micro-to nano-scale pores and throats were visualized.It was found that the nanofluid dispersed the remaining oil into small oil droplets and displaced them via multiple mechanisms in porous media.Moreover,the high strength interface film formed by the nanofluid inhibited the coalescence of oil droplets and improved the flowing ability.These results help to understand the EOR mechanisms of nanofluids in low permeability reservoirs from a visual perspective.

An overview of efficient development practices at low permeability sandstone reservoirs in China

Low permeability sandstone reservoirs in China typically have more complicated geological conditions, pore structures, and flow characteristics as compared to medium-to-high-permeability sandstone reservoirs. Traditional geological and seepage theories, and engineering methods are not applicable to the development of these low permeability reservoirs, and wells drilled into them often produce oil and gas at very low rates. Recent breakthroughs in reservoir exploitation technology have greatly improved the productivity of low permeability reservoirs, making them the primary target for oil exploration and extraction in China. The development theories and practices applied to low permeability reservoirs in China are reviewed in this study— based on relevant geological and engineering practices, including drilling, fracturing, recovery, and surface engineering. A unique series of technological advances that aid the development of low permeability reservoirs in China are summarized here. This study may serve as a meaningful guide in achieving scale efficiency for the development of low permeability reservoirs.

Pilot Test for Nitrogen Foam Flooding in Low Permeability Reservoir

Due to the characteristics of reservoir formation,the producing level of low permeability reservoir is relatively very low.It is hard to obtain high recovery through conventional development schemes.Considering the tight matrix,complex fracture system,low production level of producers,and low recovery factor ofMblock in Xinjiang oilfield,it is selected for on-site pilot test of nitrogen foam flooding.Detailed flooding scheme is made and the test results are evaluated respectively both for producers and injectors.The pressure index,filling degree,and fluid injection profile are found to be all improved in injectors after injection of nitrogen foam.The oil production,water cut and liquid production file are also improved in most of the producers,with the natural decline rate in the test area become slow.Results show that nitrogen foam flooding technology can be good technical storage for enhanced oil recovery in low permeability reservoir.

Research on Well Testing Interpretation of Low Permeability Deformed Dual Medium Reservoir

Considering the influence of quadratic gradient term and medium deformation on the seepage equation, a well testing interpretation model for low permeability and deformation dual medium reservoirs was derived and established. The difference method was used to solve the problem, and pressure and pressure derivative double logarithmic curves were drawn to analyze the seepage law. The research results indicate that the influence of starting pressure gradient and medium deformation on the pressure characteristic curve is mainly manifested in the middle and late stages. The larger the value, the more obvious the upward warping of the pressure and pressure derivative curve;the parameter characterizing the dual medium is the crossflow coefficient. The channeling coefficient determines the time and location of the appearance of the “concave”. The smaller the value, the later the appearance of the “concave”, and the more to the right of the “concave”.

Numerical study on gas production via a horizontal well from hydrate reservoirs with different slope angles in the South China Sea

It is important to study the effect of hydrate production on the physical and mechanical properties of low-permeability clayey–silty reservoirs for the largescale exploitation of hydrate reservoirs in the South China Sea.In this study,a multiphysical-field coupling model,combined with actual exploration drilling data and the mechanical experimental data of hydrate cores in the laboratory,was established to investigate the physical and mechanical properties of low-permeability reservoirs with different slope angles during 5-year hydrate production by the depressurization method via a horizontal well.The result shows that the permeability of reservoirs severely affects gas production rate,and the maximum gas production amount of a 20-m-long horizontal well can reach186.8 m3/day during the 5-year hydrate production.Reservoirs with smaller slope angles show higher gas production rates.The depressurization propagation and hydrate dissociation mainly develop along the direction parallel to the slope.Besides,the mean effective stress of reservoirs is concentrated in the near-wellbore area with the on-going hydrate production,and gradually decreases with the increase of the slope angle.Different from the effective stress distribution law,the total reservoir settlement amount first decreases and then increases with the increase of the slope angle.The maximum settlement of reservoirs with a 0°slope angle is up to 3.4 m,and the displacement in the near-wellbore area is as high as2.2 m after 5 years of hydrate production.It is concluded that the pore pressure drop region of low-permeability reservoirs in the South China Sea is limited,and various slope angles further lead to differences in effective stress and strain of reservoirs during hydrate production,resulting in severe uneven settlement of reservoirs.

Advances in enhanced oil recovery technologies for low permeability reservoirs

Low permeability oil and gas resources are rich and have great potential all over the world, which has gradually become the main goal of oil and gas development. However, after traditional primary and secondary exploitation, there is still a large amount of remaining oil that has not been recovered.Therefore, in recent years, enhanced oil recovery(EOR) technologies for low permeability reservoirs have been greatly developed to further improve crude oil production. This study presents a comprehensive review of EOR technologies in low permeability reservoirs with an emphasis on gas flooding, surfactant flooding, nanofluid flooding and imbibition EOR technologies. In addition, two kinds of gel systems are introduced for conformance control in low permeability reservoirs with channeling problems. Finally,the technical challenges, directions and outlooks of EOR in low permeability reservoirs are addressed.

Pore network modeling of water block in low permeability reservoirs

A pore network model was used in this paper to investigate the factors, in particular, throat radius, wettability and initial water saturation, causing water block in low permeability reservoirs. A new term - ＇relative permeability number＇ （RPN） was firstly defined, and then used to describe the degree of water block. Imbibition process simulations show that the RPN drops in accordance with the extension of the averaged pore throat radius from 0.05 to 1.5 μm, and yet once beyond that point of 1.5 μm, the RPN reaches a higher value, indicating the existence of a critical pore throat radius where water block is the maximum. When the wettability of the samples changes from water-wet to weakly water-wet, weakly gas-wet, or gas（oil）-wet, the gas RPN increases consistently, but this consistency is disturbed by the RPN dropping for weakly water-wet samples for water saturations less than 0.4, which means weakly waterwet media are more easily water blocked than water-wet systems. In the situation where the initial water saturation exceeds 0.05, water block escalates along with an increase in initial water saturation.

The coupling of dynamics and permeability in the hydrocarbon accumulation period controls the oil-bearing potential of low permeability reservoirs:a case study of the low permeability turbidite reservoirs in the middle part of the third member of Shahejie

The relationships between permeability and dynamics in hydrocarbon accumulation determine oil- bearing potential （the potential oil charge） of low perme- ability reservoirs. The evolution of porosity and permeability of low permeability turbidite reservoirs of the middle part of the third member of the Shahejie Formation in the Dongying Sag has been investigated by detailed core descriptions, thin section analyses, fluid inclusion analyses, carbon and oxygen isotope analyses, mercury injection, porosity and permeability testing, and basin modeling. The cutoff values for the permeability of the reservoirs in the accumulation period were calculated after detailing the accumulation dynamics and reservoir pore structures, then the distribution pattern of the oil-bearing potential of reservoirs controlled by the matching relationship between dynamics and permeability during the accumulation period were summarized. On the basis of the observed diagenetic features and with regard to the paragenetic sequences, the reservoirs can be subdivided into four types of diagenetic facies. The reservoirs experienced two periods of hydro- carbon accumulation. In the early accumulation period, the reservoirs except for diagenetic facies A had middle to high permeability ranging from 10 × 10-3 gm2 to 4207 × 10-3 lain2. In the later accumulation period, the reservoirs except for diagenetic facies C had low permeability ranging from 0.015 × 10-3 gm2 to 62× 10-3 -3m2. In the early accumulation period, the fluid pressure increased by the hydrocarbon generation was 1.4-11.3 MPa with an average value of 5.1 MPa, and a surplus pressure of 1.8-12.6 MPa with an average value of 6.3 MPa. In the later accumulation period, the fluid pressure increased by the hydrocarbon generation process was 0.7-12.7 MPa with an average value of 5.36 MPa and a surplus pressure of 1.3-16.2 MPa with an average value of 6.5 MPa. Even though different types of reservoirs exist, all can form hydrocarbon accumulations in the early accumulation per- iod. Such types of reservoirs can form hydrocarbon accumulation with high accumulation dynamics; however, reservoirs with diagenetic facies A and diagenetic facies B do not develop accumulation conditions with low accumu- lation dynamics in the late accumulation period for very low permeability. At more than 3000 m burial depth, a larger proportion of turbidite reservoirs are oil charged due to the proximity to the source rock, Also at these depths, lenticular sand bodies can accumulate hydrocarbons. At shallower depths, only the reservoirs with oil-source fault development can accumulate hydrocarbons. For flat surfaces, hydrocarbons have always been accumulated in the reservoirs around the oil-source faults and areas near the center of subsags with high accumulation dynamics.

Effect of absorption boundary layer on nonlinear flow in low permeability porous media

Taking low permeability cores of Daqing oilfield for example,the flow characteristics at low velocity were studied with the self-designed micro-flux measuring instrument.Considering the throat distribution and capillary model,the thickness of fluid boundary layer under different pressure gradients was calculated,and the mechanism and influencing factors of nonlinear percolation were discussed.The results show that the percolation curve of ultra-low rocks is nonlinear,and apparent permeability is not a constant which increases with pressure gradient.The absorption boundary layer decreases with the increase of pressure gradient,and changes significantly especially in low pressure gradient,which is the essence of nonlinear percolation.The absorption boundary layer is also found to be impacted by the surface property of rocks.

Analytical solution of a double moving boundary problem for nonlinear flows in one-dimensional semi-infinite long porous media with low permeability

Based on Huang＇s accurate tri-sectional nonlin- ear kinematic equation （1997）, a dimensionless simplified mathematical model for nonlinear flow in one-dimensional semi-infinite long porous media with low permeability is presented for the case of a constant flow rate on the inner boundary. This model contains double moving boundaries, including an internal moving boundary and an external mov- ing boundary, which are different from the classical Stefan problem in heat conduction： The velocity of the external moving boundary is proportional to the second derivative of the unknown pressure function with respect to the distance parameter on this boundary. Through a similarity transfor- mation, the nonlinear partial differential equation （PDE） sys- tem is transformed into a linear PDE system. Then an ana- lytical solution is obtained for the dimensionless simplified mathematical model. This solution can be used for strictly checking the validity of numerical methods in solving such nonlinear mathematical models for flows in low-permeable porous media for petroleum engineering applications. Finally, through plotted comparison curves from the exact an- alytical solution, the sensitive effects of three characteristic parameters are discussed. It is concluded that with a decrease in the dimensionless critical pressure gradient, the sensi- tive effects of the dimensionless variable on the dimension- less pressure distribution and dimensionless pressure gradi- ent distribution become more serious; with an increase in the dimensionless pseudo threshold pressure gradient, the sensi- tive effects of the dimensionless variable become more serious; the dimensionless threshold pressure gradient （TPG） has a great effect on the external moving boundary but has little effect on the internal moving boundary.

An overview on nonlinear porous flow in low permeability porous media

This paper gives an overview on nonlinear porous flow in low permeability porous media, reveals the microscopic mechanisms of flows, and clarifies properties of porous flow fluids. It shows that, deviating from Darcy＇s linear law, the porous flow characteristics obey a nonlinear law in a low-permeability porous medium, and the viscosity of the porous flow fluid and the permeability values of water and oil are not constants. Based on these characters, a new porous flow model, which can better describe low permeability reservoir~ is established. This model can describe various patterns of porous flow, as Darcy＇s linear law does. All the parameters involved in the model, having definite physical meanings, can be obtained directly from the experiments.

Numerical simulation and experiment analysis of improving permeability by deep-hole presplitting explosion in high gassy and low permeability coal seam

Created a new damage model for explosive for LS-DYNA3D,taking advantageof the Taylor method aimed at the high gassy and low permeability coal seam,and numericallysimulated and analyzed the deep-hole presplitting explosion.The entire processof explosion was represented,including cracks caused by dynamic pressure,transmissionand vibration superposition of stress waves,as well as cracks growth driven by gas generatedby explosion.The influence of the cracks generated in the process of explosion andthe performance of improving permeability caused by the difference of interval between.explosive holes were analyzed.A reasonable interval between explosive holes of deepholepresplitting explosions in high gassy and low permeability coal seams was proposed,and the resolution of gas drainage in high gassy and low permeability coal seam was putforward.

Characterization and prevention of formation damage for fractured carbonate reservoir formations with low permeability

Stress sensitivity and water blocking in fractured carbonate reservoir formations with low permeability were determined as the main potential damage mechanisms during drilling and completion operations in the ancient buried hill Ordovician reservoirs in the Tarim Basin. Geological structure, lithology, porosity, permeability and mineral components all affect the potential for formation damage. The experimental results showed that the permeability loss was 83.8%-98.6% caused by stress sensitivity, and was 27.9%-48.1% caused by water blocking. Based on the experimental results, several main conclusions concerning stress sensitivity can be drawn as follows： the lower the core permeability and the smaller the core fracture width, the higher the stress sensitivity. Also, stress sensitivity results in lag effect for both permeability recovery and fracture closure. Aimed at the mechanisms of formation damage, a modified low-damage mixed metal hydroxide （MMH） drilling fluid system was developed, which was mainly composed of low-fluorescence shale control agent, filtration control agent, lowfluorescence lubricant and surfactant. The results of experimental evaluation and field test showed that the newly-developed drilling fluid and engineering techniques provided could dramatically increase the return permeability （over 85%） of core samples. This drilling fluid had such advantages as good rheological and lubricating properties, high temperature stability, and low filtration rate （API filtration less than 5 ml after aging at 120 ℃ for 4 hours）. Therefore, fractured carbonate formations with low permeability could be protected effectively when drilling with the newly-developed drilling fluid. Meanwhile, field test showed that both penetration rate and bore stability were improved and the soaking time of the drilling fluid with formation was sharply shortened, indicating that the modified MMH drilling fluid could meet the requirements of drilling engineering and geology.

Study on Reducing Injection Pressure of Low Permeability Reservoirs Characterized by High Temperature and High Salinity

In view of the problems of high injection pressure and low water injection rate in water injection wells of low permeability reservoirs featuring high temperature and high salinity,two new surfactants were synthesized,including a quaternary ammonium surfactant and a betaine amphoteric surfactant.The composite surfactant system BYJ-1 was formed by mixing two kinds of surfactants.The minimum interfacial tension between BYJ-1 solution and the crude oil could reach 1.4×10^(-3) mN/m.The temperature resistance was up to 140℃,and the salt resistance could reach up to 120 g/L.For the low permeability core fully saturated with water phase,BYJ-1 could obviously reduce the starting pressure gradient of low permeability core.While for the core with residual oil,BYJ-1 could obviously reduce the injection pressure and improve the oil recovery.Moreover,the field test showed that BYJ-1 could effectively reduce the injection pressure of the water injection well,increase the injection volume,and increase the liquid production and oil production of the corresponding production well.