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Technology for Manufacture of Xylene from Toluene and Methanol with Coproduction of Low-Carbon Olefins Passed Appraisal
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《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2019年第2期117-117,共1页
On November 30, 2018 “The technology for manufacture of xylene from toluene and methanol with coproduction of low-carbon olefins” jointly developed by the Yanchang Petroleum Group (YPG) and the CAS Dalian Institute ... On November 30, 2018 “The technology for manufacture of xylene from toluene and methanol with coproduction of low-carbon olefins” jointly developed by the Yanchang Petroleum Group (YPG) and the CAS Dalian Institute of Chemical Physics (DICP) had passed the appraisal of research achievements. In order to open up a new In order to open up a new technical route for alkylation of toluene to p-xylene, the technical personnel of YPG and DICP have been jointly engaging in the activities for tackling key problems to set up a 10 kt/a commercial unit for producing xylene through reaction of methanol with toluene along with coproduction of low-carbon olefins. 展开更多
关键词 XYLENE low-carbon olefins
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Commercial Demonstration Unit for Manufacture of Aromatics from Toluene and Methanol with Coproduction of Low-Carbon Olefins Will Be Set Up
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《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2014年第1期51-51,共1页
On November 29,2013 the Shaanxi Coal Chemicals Technology Engineering Center,Ltd.(SCCTEC),the CNOOC Huizhou Refining and Chemical Company and the SINOPEC Luoyang Engineering Company,Ltd.signed an agreement on cooperat... On November 29,2013 the Shaanxi Coal Chemicals Technology Engineering Center,Ltd.(SCCTEC),the CNOOC Huizhou Refining and Chemical Company and the SINOPEC Luoyang Engineering Company,Ltd.signed an agreement on cooperation in development of 展开更多
关键词 DMTO Commercial Demonstration Unit for Manufacture of Aromatics from Toluene and Methanol with Coproduction of low-carbon olefins Will Be Set Up BE
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Corrigendum to “TiO2 supported cobalt-manganese nano catalysts for light olefins production from syngas” [Journal of Energy Chemistry22(4)(2013) 645–652] 被引量:1
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作者 Mostafa Feyzi Asadollah Hassankhani 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第12期275-275,共1页
关键词 TiO2 supported cobalt-manganese nano catalysts for light olefins production from syngas Corrigendum to Journal of Energy Chemistry22
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Industrial Production of Catalyst for Removing Trace Olefins from Aromatics
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作者 Pu Xin Shi Li 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2012年第2期44-49,共6页
A novel additive incorporated into the catalyst for removing trace olefins from aromatics was proposed, and under the laboratory conditions the lifetime of the catalyst was increased from 5 h to 8 h upon specifying th... A novel additive incorporated into the catalyst for removing trace olefins from aromatics was proposed, and under the laboratory conditions the lifetime of the catalyst was increased from 5 h to 8 h upon specifying the conversion of the olefins equating to more than 55% as a criterion. Catalyst production, which was named ROC, has been successfully scaled up from laboratory formulations to commercial scale manufacture and over 100 tons of catalyst had been produced. The superiority in catalytic activity was identified by the evaluation tests of the ROC catalyst based on whatever kind of feedstocks (with their bromine index ranging from 400 mgBr/100g to 1 200 mgBr/100g) being used as the feedstock. The X-ray diffraction patterns had verified that the additive was highly dispersed on the surface of catalyst; the GC-FID analysis results showed that the ROC catalyst could increase the xylene content; the pyridine-FTIR spectroscopic analyses suggested that the additive could increase the amount of the weak L acids, which was the main cause leading to enhancement of the catalyst activity. 展开更多
关键词 催化剂 工业生产 烯烃 芳烃 实验室条件 GC-FID FTIR光谱 催化活性
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New Trends in Olefin Production 被引量:37
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作者 Ismael Amghizar Laurien A. Vandewalle Kevin M. Van Geem Guy B. Matin 《Engineering》 SCIE EI 2017年第2期171-178,共8页
Most olefins (e.g., ethylene and propylene) will continue to be produced through steam cracking (SC) ofhydrocarbons in the coming decade. In an uncertain commodity market, the chemical industry is investingvery li... Most olefins (e.g., ethylene and propylene) will continue to be produced through steam cracking (SC) ofhydrocarbons in the coming decade. In an uncertain commodity market, the chemical industry is investingvery little in alternative technologies and feedstocks because of their current lack of economic viability,despite decreasing crude oil reserves and the recognition of global warming. In this perspective, some of themost promising alternatives are compared with the conventional SC process, and the major bottlenecks ofeach of the competing processes are highlighted. These technologies emerge especially from the abundanceof cheap propane, ethane, and methane from shale gas and stranded gas. From an economic point of view,methane is an interesting starting material, if chemicals can be produced from it. The huge availability ofcrude oil and the expected substantial decline in the demand for fuels imply that the future for proventechnologies such as Fischer-Tropsch synthesis (FFS) or methanol to gasoline is not bright. The abundance ofcheap ethane and the large availability of crude oil, on the other hand, have caused the SC industry to shiftto these two extremes, making room for the on-purpose production of light olefins, such as by the catalyticdehydrogenation of orooane. 展开更多
关键词 olefin production STEAM CRACKING METHANE conversionShale gas CO2 EMISSIONS
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Current Situation and Development of Refractories for Clean Steel Production 被引量:4
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作者 LI Hongxia LIU Guoqi 《China's Refractories》 CAS 2013年第3期1-6,共6页
The low cost and high efficient clean steels metallur- gy has been focused much attention in China. Among the factors affecting the cleanliness and consequent quali- ty of steel products, refractories are one of the k... The low cost and high efficient clean steels metallur- gy has been focused much attention in China. Among the factors affecting the cleanliness and consequent quali- ty of steel products, refractories are one of the key fac- tors. Meanwhile the restriction of resource, energy and environment is getting stronger, thus the improvement of refractories becontes much more important. In this paper, refractories selection principle Jbr clean steel production according to their thermodynamic features was ex- plained; refractories for tundLsh and flow control in con- tinuous casting, which play important roles in prohibi- ring secondary contamination of molten steel, were intro- duced. Moreover, new development of low-carbon and carbon-free refractory materials was also described. 展开更多
关键词 clean steel production basic refractories low-carbon and carbon-free refractories design of re- fractory
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Operation Mechanism of Farmers' Professional Cooperatives from the Point of Low-Carbon Agricultural Products 被引量:1
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作者 HUANG Lei,CHENG Yu-gui Nanchang Hangkong University,Jiangxi 330063,China 《Asian Agricultural Research》 2012年第3期46-50,共5页
We firstly take a look at internal logic of cluster development of low-carbon agricultural products.In combination with operation features of farmers' professional cooperatives and actual requirements for cluster ... We firstly take a look at internal logic of cluster development of low-carbon agricultural products.In combination with operation features of farmers' professional cooperatives and actual requirements for cluster development of low-carbon agricultural products;we elaborate establishing benefit allocation mechanism,bearing education and training functions,forming low-carbon value,building low-carbon identification system,as well as realizing low-carbon value.According to these situations,we systematically analyze operation mechanism of farmers' professional cooperatives suitable for cluster development of low-carbon agricultural products.To promote cluster development of low-carbon agricultural products,we put forward following suggestions,including government guidance and encouragement,social acceptance and active cooperation,and integration into global low-carbon development system to share benefit of low-carbon development. 展开更多
关键词 CLUSTER of low-carbon AGRICULTURAL products FARMER
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一种基于甲醇制烯烃及其下游生产链的m-PIOT模型定量研究
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作者 刘丹竹 梁金强 +2 位作者 徐庶亮 叶茂 刘中民 《煤化工》 CAS 2024年第2期52-58,共7页
以我国西部某化工园区的规划数据为例,通过建立甲醇及其下游产业链实物型投入产出模型,对该产业链中不同产品部门之间的相互作用进行了定量分析。结果表明:该园区甲醇下游产业链中缺乏强拉动及强支撑作用的产品部门;丙烯酸异辛酯、混合C... 以我国西部某化工园区的规划数据为例,通过建立甲醇及其下游产业链实物型投入产出模型,对该产业链中不同产品部门之间的相互作用进行了定量分析。结果表明:该园区甲醇下游产业链中缺乏强拉动及强支撑作用的产品部门;丙烯酸异辛酯、混合C_(4)等对产业链发展具有较强的拉动作用;原材料甲醇的感应度系数高达21.808,对整条产业链具有较强的制约性。 展开更多
关键词 实物型投入产出模型 甲醇制烯烃 甲醇 产业链 物料流
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烯式吡虫啉(olefin IMI)光解及其光解产物研究 被引量:1
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作者 葛峰 单正军 +2 位作者 戴亦军 陈婷 袁生 《生态与农村环境学报》 CAS CSSCI CSCD 北大核心 2009年第2期103-106,共4页
烟碱类杀虫剂吡虫啉(imidacloprid,IMI)在环境中可代谢为生物活性提高10倍的烯式吡虫啉(olefin IMI)。研究了olefin IMI的光稳定性、光解动力学和光解代谢途径。结果表明:olefin IMI在避光条件下较为稳定,室温下放置400d后,olefin IMI... 烟碱类杀虫剂吡虫啉(imidacloprid,IMI)在环境中可代谢为生物活性提高10倍的烯式吡虫啉(olefin IMI)。研究了olefin IMI的光稳定性、光解动力学和光解代谢途径。结果表明:olefin IMI在避光条件下较为稳定,室温下放置400d后,olefin IMI含量仅减少3%;而在室内模拟日光条件下,olefin IMI易于分解,光解反应符合一级动力学方程(r>0.99),半衰期为4d。olefin IMI的光解反应存在2条主要途径:一是羟基化生成4,5-二羟基化吡虫啉,该产物进一步氧化断裂药效基团硝基亚胺基生成羰基化产物;二是直接脱去硝基基团生成胍基产物。 展开更多
关键词 烯式吡虫啉(olefin IMI) 光解 代谢途径
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2-丙基庚醇生产过程中的收率影响因素分析
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作者 刘洪伟 李毅超 《煤化工》 CAS 2024年第1期44-47,共4页
2-丙基庚醇是煤基甲醇制烯烃装置碳四组分的重要深加工产品,其产品收率和产量直接关乎企业的经济效益。介绍了国能包头煤化工有限责任公司2-丙基庚醇的生产工艺流程,分析了羰基合成戊醛过程中混合碳四组分组成、CO分压、催化剂浓度,缩... 2-丙基庚醇是煤基甲醇制烯烃装置碳四组分的重要深加工产品,其产品收率和产量直接关乎企业的经济效益。介绍了国能包头煤化工有限责任公司2-丙基庚醇的生产工艺流程,分析了羰基合成戊醛过程中混合碳四组分组成、CO分压、催化剂浓度,缩合反应过程中反应温度、停留时间、碱浓度,加氢反应过程中反应温度、氢气质量等因素对中间品戊醛、2-丙基庚烯醛和最终产品2-丙基庚醇收率、产量的影响,并针对性地进行了优化和操作参数调整,不断提高2-丙基庚醇的收率和产量。 展开更多
关键词 甲醇制烯烃 羰基合成 混合碳四组分 缩合反应 2-丙基庚醇 产品收率 影响因素
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Application of Olefin-Reducing Catalyst in FCC Unit at Daqing Petrochemical Company 被引量:1
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作者 LiuXinfeng YangDaoxue +1 位作者 ZhangGuojing YaoHua 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2003年第4期25-30,共6页
This article refers to the application of DOCO olefin-reducing catalyst developed by RIPP and manufactured by the Catalyst Factory of Changling Refining and Chemical Company in the 1.4 Mt/a RFCCU at Daqing Petrochemic... This article refers to the application of DOCO olefin-reducing catalyst developed by RIPP and manufactured by the Catalyst Factory of Changling Refining and Chemical Company in the 1.4 Mt/a RFCCU at Daqing Petrochemical Company. Results of operation over two months had revealed that this catalyst had good olefin-reducing ability and heavy oil converting ability adapted to paraffinic feedstock. The gasoline olefin yield had been reduced to 36.1 v% from 54.2 v% with gasoline RON rating decreased by 1.4 units. The induction period of gasoline had significantly increased to 952 mm, while the coke yield was increased by 0.05 percentage point with light oil yield dropping by only 0.02 percentage point. The FCC product distribution is favorable. 展开更多
关键词 石蜡 辛烷值 流化床催化裂化技术 大庆石油化工公司 催化剂 生产技术 炼油工业
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Low-carbon Economy and Eco-design of Commodity Packing 被引量:3
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作者 AN Li-li XUE Qiu 《Computer Aided Drafting,Design and Manufacturing》 2011年第1期52-55,共4页
Research situation of eco-design is analyzed, and then thoughts and methods of eco-design are discused. The eco-design includes packaging modularization, dematerialization, energy-saving and bio-simulation.
关键词 low-carbon economy packing of product ECO-DESIGN thoughtway
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Potentials and Challenges of Carbon Knowledge Graph in Sustainable Textile Production for Carbon Traceability:A Review
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作者 BAO Jinsong WU Tao LI Jie 《Journal of Donghua University(English Edition)》 CAS 2024年第4期349-364,共16页
Textile production has received considerable attention owing to its significance in production value,the complexity of its manufacturing processes and the extensive reach of its supply chains.However,textile industry ... Textile production has received considerable attention owing to its significance in production value,the complexity of its manufacturing processes and the extensive reach of its supply chains.However,textile industry consumes substantial energy and materials and emits greenhouse gases that severely harm the environment.In addressing this challenge,the concept of sustainable production offers crucial guidance for the sustainable development of the textile industry.Low-carbon manufacturing technologies provide robust technical support for the textile industry to transition to a low-carbon model by optimizing production processes,enhancing energy efficiency and minimizing material waste.Consequently,low-carbon manufacturing technologies have gradually been implemented in sustainable textile production scenarios.However,while research on low-carbon manufacturing technologies for textile production has advanced,these studies predominantly concentrate on theoretical methods,with relatively limited exploration of practical applications.To address this gap,a thorough overview of carbon emission management methods and tools in textile production,as well as the characteristics and influencing factors of carbon emissions in key textile manufacturing processes is presented to identify common issues.Additionally,two new concepts,carbon knowledge graph and carbon traceability,are introduced,offering strategic recommendations and application directions for the low-carbon development of sustainable textile production.Beginning with seven key aspects of sustainable textile production,the characteristics of carbon emissions and their influencing factors in key textile manufacturing process are systematically summarized.The aim is to provide guidance and optimization strategies for future emission reduction efforts by exploring the carbon emission situations and influencing factors at each stage.Furthermore,the potential and challenges of carbon knowledge graph technology are summarized in achieving carbon traceability,and several research ideas and suggestions are proposed. 展开更多
关键词 sustainable textile production carbon knowledge graph carbon traceability low-carbon development emission reduction
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Research on the transmission mechanism of low-carbon policies:an empirical study of agricultural companies
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作者 Hongxi Chen Cuituo Liu Yu Yuan 《Chinese Journal of Population,Resources and Environment》 2015年第2期155-161,共7页
Companies bear primary responsibility for low-carbon economy,thus relevant low-carbon policies should be set properly to guide them and to ensure their low-carbon production effectively.To solve the problems generated... Companies bear primary responsibility for low-carbon economy,thus relevant low-carbon policies should be set properly to guide them and to ensure their low-carbon production effectively.To solve the problems generated during low-carbon development,this article verifies the existence of the transmission path and strength.This verification includes mediating variables of companies'willingness and capacity to conduct low-carbon production,a transmission mechanism through incentive path and resources protection,and questionnaire data of agricultural companies.Conclusions show that the lowcarbon policies have obvious positive effects on willingness of corporation;the basic service-oriented policy has a significantly promoting effect on low-carbon production capacity;and low-carbon production performance is positively influenced by willingness as well as capability.Aiming at a better transmission path,some corresponding recommendations have been put forward in the end. 展开更多
关键词 low-carbon policy WILLINGNESS of COMPANIES to adopt low-carbon production low-carbon production capacity AGRICULTURAL COMPANIES
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Bottleneck on Supply Chain of Organic Agricultural Products and Countermeasures
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作者 ZHANG Xin-min 《Asian Agricultural Research》 2012年第9期57-59,共3页
Organic agriculture is one of successful models of low-carbon agriculture, and plays an important role in alleviating and adapting to climate change. However, the development of supply chain of organic agricultural pr... Organic agriculture is one of successful models of low-carbon agriculture, and plays an important role in alleviating and adapting to climate change. However, the development of supply chain of organic agricultural products lags behind, which seriously restricts development of organic agricultural product market. In this paper, major models and bottleneck of supply chain of organic agricultural products are analyzed, and finally countermeasures are put forward. 展开更多
关键词 ORGANIC AGRICULTURAL productS low-carbon agricultu
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Empirical Analysis on Factors Restricting Low-carbon Agricultural Development in Hubei Province
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作者 Li Qi Li Bianlian 《Meteorological and Environmental Research》 CAS 2014年第5期36-38,共3页
From the perspective of input into agricultural production, the growth of agricultural production from 1982 to 2010 in Hubei Province was analyzed by using multiple regression method. The results show that the quantit... From the perspective of input into agricultural production, the growth of agricultural production from 1982 to 2010 in Hubei Province was analyzed by using multiple regression method. The results show that the quantity of fertilizer and the total power of machinery used for farming have significantly contributed to agricultural growth in Hubei Province, but they are also main factors restricting low-carbon agricultural development in Hubei Province. Therefore, the key point to develop low-carbon agriculture in Hubei Province currently should be put on how to fertilize rationally, how to innovate the pattern of agricultural production, how to develop agricultural mechanization rationally and so on. 展开更多
关键词 low-carbon agriculture production function Influencing factor COUNTERMEASURES China
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烯芳类化工产品原料含消费税退税的税务争议分析与建议
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作者 于秀丽 张海桐 《化学工业》 CAS 2023年第3期75-81,共7页
结合我国成品油消费税税制功能定位,分析了我国烯芳类化工产品原料中含石脑油和燃料油的消费税免、退税政策延革和意义;指出了成品油消费税退税判定条件存在的争议及监管漏洞;提出了加强我国成品油消费税监管的几点建议。
关键词 消费税退税 政策延续及变革 燃料油 烯烃类化工品 监管漏洞 建议
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烯烃氢甲酰化技术工业化现状及展望 被引量:1
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作者 黄宁 《当代石油石化》 CAS 2023年第5期29-34,共6页
烯烃氢甲酰化技术是烯烃生产醛和其他高附加值化学品的重要手段,我国该领域自主技术尚处于起步阶段。通过研究国内外氢甲酰化技术工业化现状及特点,提出我国氢甲酰化技术的发展建议。当前,氢甲酰化技术正在向装置柔性化、产品多样化、... 烯烃氢甲酰化技术是烯烃生产醛和其他高附加值化学品的重要手段,我国该领域自主技术尚处于起步阶段。通过研究国内外氢甲酰化技术工业化现状及特点,提出我国氢甲酰化技术的发展建议。当前,氢甲酰化技术正在向装置柔性化、产品多样化、工艺低碳化的方向发展。在产业链升级和产品绿色低碳化的趋势下,建议国内研究机构以膦配体和非均相催化剂研发为突破,同时开发高碳醇等高附加值产品及替代性羰基源。 展开更多
关键词 烯烃氢甲酰化 高碳醇 柔性生产 绿色低碳
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C_(4)叠合产物加氢催化剂的制备及性能评价 被引量:1
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作者 杨国明 王连英 +1 位作者 张海洪 韩龙年 《精细石油化工》 CAS 2023年第6期34-37,共4页
以拟薄水铝石粉为载体制备原料,以Ni为活性金属组分,用等体积浸渍工艺制备了C_(4)叠合产物加氢催化剂,并对催化剂进行表征和性能评价。结果表明,C_(4)叠合产物加氢催化剂比表面积≥180 m^(2)/g,孔体积≥0.5 cm^(3)/g,侧压强度≥180 N/c... 以拟薄水铝石粉为载体制备原料,以Ni为活性金属组分,用等体积浸渍工艺制备了C_(4)叠合产物加氢催化剂,并对催化剂进行表征和性能评价。结果表明,C_(4)叠合产物加氢催化剂比表面积≥180 m^(2)/g,孔体积≥0.5 cm^(3)/g,侧压强度≥180 N/cm。在反应条件温度80~200℃、压力1~4 MPa、氢油比100∶1~500∶1以及空速1~2 h-1条件下,烯烃加氢饱和转化率可达99%以上。 展开更多
关键词 C_(4)叠合产物 镍系催化剂 性能评价 烯烃饱和
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车用汽油国标升级后的生产与技术分析 被引量:1
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作者 王菁 张浩 +1 位作者 张燕子 白春旭 《炼油与化工》 CAS 2023年第2期44-47,共4页
降低烯烃含量是国内车用汽油质量升级的关键,为确保炼油厂出产汽油从国Ⅴ92#顺利升级到国ⅥA再到ⅥB,符合清洁能源的要求,某炼油厂依据现有加工规模和生产条件,谋划汽油升级调和,优化装置工艺控制参数,降低汽油烯烃和精制汽油辛烷值损失... 降低烯烃含量是国内车用汽油质量升级的关键,为确保炼油厂出产汽油从国Ⅴ92#顺利升级到国ⅥA再到ⅥB,符合清洁能源的要求,某炼油厂依据现有加工规模和生产条件,谋划汽油升级调和,优化装置工艺控制参数,降低汽油烯烃和精制汽油辛烷值损失,控制添加剂费用,成功产出ⅥB汽油。 展开更多
关键词 车用汽油 产品调和 优化操作 烯烃控制
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