Application of nuclear magnetic resonance technology to carbon capture,utilization and storage:A review

Carbon capture,utilization and storage (CCUS) is considered as a very important technology for mitigating global climate change.Carbon dioxide (CO2) injected into an underground reservoir will induce changes in its physical properties and the migration of CO2 will be affected by many factors.Accurately understanding these changes and migration characteristics of CO2 is crucial for selecting a CCUS project site,estimating storage capacity and ensuring storage security.In this paper,the basic principles of nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) technologies are briefly introduced in the context of laboratory experiments related to CCUS.The types of NMR apparatus,experimental samples and testing approaches applied worldwide are discussed and analyzed.Then two typical NMR core analysis systems used in CCUS field and a self-developed high-pressure,low-field NMR rock core flooding experimental system are compared.Finally,a summary of the current deficiencies related to NMR applied to CCUS field is given and future research plans are proposed.

Classification of different walnut varieties using low-field nuclear magnetic resonance technology and cluster analysis

To classify different walnut varieties based on water and oil content of walnut,and determine their storage conditions,the low-field nuclear magnetic resonance(LFNMR)technology was used to obtain the NMR transverse relaxation time(T 2)of the samples based on the physical and chemical indicators of the walnut quality.The relationship between the relaxation time and phase state of the internal material of the sample was investigated,and the characteristic parameters of the NMR spectrum signals were statistically analyzed using cluster analysis to determine the different walnut varieties,and three different components,as well as their contents,were detected by a LFNMR spectrometer:firmly bound water,weakly bound water,and weakly bound oil.Test results indicated that the oil peak was dominant in the overall signal intensity compared to the water peaks,in which the firmly bound water phase contributed more to the overall water signal between the water peaks.Using the analytic hierarchy process of cluster analysis,21 walnut samples were classified into three different classes,based on the characteristic parameters of the water-content and oil-content spectrum signals.The first class contains four walnut varieties characterized by least water and highest oil contents;the third class contains two walnut varieties,with the highest water content and least oil content;whereas,the second class contains 15 walnut varieties,with both water and oil contents at medium levels.The results showed that LFNMR led to a rapid detection of moisture and oil contents in walnuts,while cluster analysis classified different walnuts varieties based on these parameters.This study also provided the basis for optimizing the storage methods and storage conditions of walnuts.

Analysis of quality-related proteins in golden pompano(Trachinotus ovatus)fillets with modified atmosphere packaging under superchilling storage

Here,we aimed to study the changes in proteome of golden pompano fillets during post-mortem storage.Tandem mass tags(TMT)-labeled quantitative proteomic strategy was applied to investigate the relationships between protein changes and quality characteristics of modified atmosphere packaging(MAP)fillets during superchilling(-3°C)storage.Scanning electron microscopy was used to show that the muscle histology microstructure of fillets was damaged to varying degrees,and low-field nuclear magnetic resonance was used to find that the immobilized water and free water in the muscle of fillets changed significantly.Total sulfhydryl content,TCA-soluble peptides and Ca2+-ATPase activity also showed that the fillet protein had a deterioration by oxidation and denaturation.The Fresh(FS),MAP,and air packaging(AP)groups were set.Total of 150 proteins were identified as differential abundant proteins(DAPs)in MAP/FS,while 209 DAPs were in AP/FS group.The KEGG pathway analysis indicated that most DAPs were involved in binding proteins and protein turnover.Correlation analysis found that 52 DAPs were correlated with quality traits.Among them,8 highly correlated DAPs are expected to be used as potential quality markers for protein oxidation and water-holding capacity.These results provide a further understanding of the muscle deterioration mechanism of packaging golden pompano fillets during superchilling.

Further discussion of CO_(2) huff-n-puff mechanisms in tight oil reservoirs based on NMR monitored fluids spatial distributions

Due to the poor physical properties of tight reservoirs,CO_(2) huff-n-puff(HNP)is considered a potential enhanced oil recovery(EOR)method after primary depletion.Optimization plays a critical role in the effective implementation of CO_(2) huff-n-puff.But the optimization requires a good understanding of the EOR mechanisms.In this work,the spatial distribution of oil saturation under different experimental conditions was analyzed by the NMR method to further discuss the HNP mechanisms.According to the variation of 1D frequency signal amplitude,we divided the core into the hardly movable area and movable area,the region with the obvious signal decline was defined as the movable area,and the hardly movable area was the region with limited signal decline.Based on that the recovery characteristics of different scenarios were evaluated.Firstly,the necessity of the soaking stage was studied,where three scenarios with different soaking times were carried out.Secondly,the injection pressure was adjusted to investigate the effect of the pressure gradient.The T_(2) spectra show that soaking has significantly improved the production of crude oil in small pores,and higher oil recovery in a single cycle is observed,but it is lower when the elapsed time(total operation time)is the same.31.03% of oil can be recovered after 3 cycles HNP,which increases to 33.8% and 37.06% for the 4 cycles and 6 cycles cases.As the pressure gradient increases,more oil is removed out of the matrix,and the oil in the deep part of the reservoir can be effectively recovered.During the CO_(2) huff-n-puff process,the oil distributions are similar to the solution gas drive,the residual oil is distributed at the close end of the core and the range that the oil can be efficiently recovered is limited.

Effects of Water-cement Ratio and Hydration Heat Regulating Materials on Hydration Process of Early-age Cementitious Materials

By means of low-field nuclear magnetic resonance(LF-NMR),the transverse relaxation time(T_(2))signals of physically bound water in cement paste were monitored to indicate water content change and characterize the early-age hydration process.With the curves of the T_(2)signals and hydration time obtained,the hydration process could be divided into four typical periods using the null points of the second derivative curve,and the influences of water-cement ratio(w/c)and hydration heat regulating materials(HHRM)on hydration process were analyzed.The experimental results showed that the hydration rate of pure cement paste in accelerated period presented a positive correlation with w/c.Compared to pure cement paste,the addition of HHRM extended all four periods,and led to a much faster hydration rate in initial period as well as a slower rate in accelerated period.Finally,according to the LFNMR test results,the early-age hydration model of cementitious materials was proposed considering w/c and HHRM content.

κ-卡拉胶比例对明胶凝胶体系凝胶特性、水分分布及微观结构的影响

论文采用质地剖面(texture profile analysis,TPA)/穿刺分析、低场核磁场共振(low-field nuclear magnetic resonance,LF-NMR)、计算机断层扫描技术(computed tomography,CT)和流变仪研究了κ-卡拉胶的比例对明胶凝胶的凝胶强度、质构特性、水分分布、动态黏弹性和微观结构的影响,并分析了几者之间的相关性。结果表明:随κ-卡拉胶比例的增加,混合凝胶体系的凝胶强度、硬度、咀嚼性、胶凝温度及熔化温度相对增大,弹性及内聚性降低,黏性和回复性先下降后上升;凝胶网络结构趋向于致密、均匀;结合水比例(S_(21))下降,不易流动水比例(S_(22))相对增加,且当体系中κ-卡拉胶的比例逐渐增加至50%时,单组份弛豫时间(T_(2W))及不易流动水的弛豫时间(T_(22))的减小较为明显,而结合水的弛豫时间(T21)变化相对较小;相关性分析表明,凝胶强度、硬度、咀嚼性与S_(21)负相关,与S_(22)、T21正相关。弹性与S_(21)、T_(22)和T_(2W)正相关,与S_(22)负相关。内聚性与T_(22)和T_(2W)正相关。研究可为明胶-κ-卡拉胶复配胶在食品中的应用提供理论支持。

Effect of Content and Fineness of GGBS on Pore Structure of Cement Paste

The effect of the content and specific surface area of the ground granulated blast furnace slag (GGBS) on the pore structure of the cement paste was determined through the low-field nuclear magnetic resonance (NMR).The Pearson correlation analysis method was used to calculate the correlation coefficient between the porosity and age of cement paste,the specific surface area of GGBS and the content of GGBS.The test results exhibited that the porosity of the cement paste with different ageing durations gradually decreased on increasing the content and specific surface area of GGBS.The content and specific surface area of GGBS had a negligible effect on the 1-10 nm size gel pores in the cement paste,whereas,had a significant effect on the 10-100 nm size capillary pores.In addition,these parameters did not affect the final most probable pore size of the cement paste.The correlation between age and porosity was the largest,and the correlation between GGBS content and porosity was greater than that between GGBS specific surface area and porosity.Moreover,a modified pore structure model was successfully developed to effectively predict the pore structure of the GGBS based cement paste.

Simultaneous Determination of Oil and Water in Soybean by LF-NMR Relaxometry and Chemometrics

A fast, non-destructive and eco-friendly method was developed to simultaneously determine the oil and water contents of soybean based on low field nuclear magnetic resonance（LF-NMR） relaxometry combined with chemometrics, such as partial least squares regression（PLSR）. The Carr-Purcell-Meiboom-Gill（CPMG） magnetiza- tion decay data of ten soybean samples were acquired by LF-NMR and directly applied to the PLSR analysis. Cali- bration models were established via PLSR with full cross-validation based on the reference values obtained by the Soxhlet extraction method for measuring oil and oven-drying method for measuring water. The results indicate that the calibration models are satisfactory for both oil and water determinations; the root mean squared errors of cross-validation（RMSECV） for oil and water are 0.2285% and 0.0178%, respectively. Furthermore, the oil and water contents in unknown soybean samples were predicted by the PLSR models and the results were compared with the reference values. The relative errors of the predicted oil and water contents were in ranges of 1.25%---4.96% and 0.44%--2.49%, respectively. These results demonstrate that the combination of LF-NMR relaxometry with chemo- metrics shows great potential for the simultaneous determination of contents of oil and water in soybean with high accuracy.

Rapid and non-destructive detection method for water status and water distribution of rice seeds with different vigor

In this study,newly harvested and aged rice seeds were analyzed to determine their aging process,identify the difference between artificially and naturally aged seeds,and develop a rapid,accurate,and non-destructive detection method for water status and water distribution of rice seed with different vigor.To this end,an artificially accelerated aging test was conducted on the newly harvested rice seeds.Then,low-field nuclear magnetic resonance(LF-NMR)technology was applied to test the new(Shennong No.9816,2018),old(Shennong No.9816,2017),and artificially aged seeds(Shennong No.9816,2018).A standard germination test was conducted for three types of seeds.Finally,the differences of water status and distribution between rice seeds of different vigor were analyzed based on the standard germination test results and wave spectrometry information collected using LF-NMR.The results indicated that new seeds,old seeds,and the artificially accelerated aging rice seeds all exhibited two water phases,and the vigor of rice seeds after the artificial accelerated aging test was lower than that of new seeds.There were significant differences between the frequencies of bound water at the time of the peak and the time at the end of the peak for the three types of seeds.The two times showed an increasing trend for rice seeds with poor vigor,indicating that the ability of the water in the rice seeds having poor vigor to combine with other substances was weakened.There were significant differences between the distributions of free water peak end time for the three types of seeds.All the rice seeds with poor vigor exhibited a decreasing trend at this time,indicating that the freedom of free water inside the rice seed samples with poor vigor was weakened.The total water content of the artificially aged seeds and the aged seeds was higher than that of the new seeds,but the free water content increased from artificially aged seeds to new seeds to aged seeds.This indicates that LF-NMR technology is an effective detection method that can simply compare the differences in seed vitality with respect to water distribution as well as differentiate the seed internal water content of artificially aged and naturally aged seeds.