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Enhancing Low-Frequency Microwave Absorption Through Structural Polarization Modulation of MXenes
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作者 Bo Shan Yang Wang +1 位作者 Xinyi Ji Yi Huang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期435-452,共18页
Two-dimensional carbon-based materials have shown promising electromagnetic wave absorption capabilities in mid-and high-frequency ranges,but face challenges in low-frequency absorption due to limited control over pol... Two-dimensional carbon-based materials have shown promising electromagnetic wave absorption capabilities in mid-and high-frequency ranges,but face challenges in low-frequency absorption due to limited control over polarization response mecha-nisms and ambiguous resonance behavior.In this study,we pro-pose a novel approach to enhance absorption efficiency in aligned three-dimensional(3D)MXene/CNF(cellulose nanofibers)cavities by modifying polarization properties and manipulating resonance response in the 3D MXene architecture.This controlled polarization mechanism results in a significant shift of the main absorption region from the X-band to the S-band,leading to a remarkable reflection loss value of-47.9 dB in the low-frequency range.Furthermore,our findings revealed the importance of the oriented electromagnetic coupling in influencing electromagnetic response and microwave absorption properties.The present study inspired us to develop a generic strategy for low-frequency tuned absorption in the absence of magnetic element participation,while orientation-induced polarization and the derived magnetic resonance coupling are the key controlling factors of the method. 展开更多
关键词 Hierarchical structure MXene Microwave absorption low-frequency
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Low-frequency bandgap and vibration suppression mechanism of a novel square hierarchical honeycomb metamaterial
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作者 Xingjian DONG Shuo WANG +5 位作者 Anshuai WANG Liang WANG Zhaozhan ZHANG Yuanhao TIE Qingyu LIN Yongtao SUN 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第10期1841-1856,共16页
The suppression of low-frequency vibration and noise has always been an important issue in a wide range of engineering applications.To address this concern,a novel square hierarchical honeycomb metamaterial capable of... The suppression of low-frequency vibration and noise has always been an important issue in a wide range of engineering applications.To address this concern,a novel square hierarchical honeycomb metamaterial capable of reducing low-frequency noise has been developed.By combining Bloch’s theorem with the finite element method,the band structure is calculated.Numerical results indicate that this metamaterial can produce multiple low-frequency bandgaps within 500 Hz,with a bandgap ratio exceeding 50%.The first bandgap spans from 169.57 Hz to 216.42 Hz.To reveal the formation mechanism of the bandgap,a vibrational mode analysis is performed.Numerical analysis demonstrates that the bandgap is attributed to the suppression of elastic wave propagation by the vibrations of the structure’s two protruding corners and overall expansion vibrations.Additionally,detailed parametric analyses are conducted to investigate the effect ofθ,i.e.,the angle between the protruding corner of the structure and the horizontal direction,on the band structures and the total effective bandgap width.It is found that reducingθis conducive to obtaining lower frequency bandgaps.The propagation characteristics of elastic waves in the structure are explored by the group velocity,phase velocity,and wave propagation direction.Finally,the transmission characteristics of a finite periodic structure are investigated experimentally.The results indicate significant acceleration amplitude attenuation within the bandgap range,confirming the structure’s excellent low-frequency vibration suppression capability. 展开更多
关键词 wave propagation vibration suppression METAMATERIAL low-frequency bandgap
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Dynamic characteristics of coal specimens with varying static preloading levels under low-frequency disturbance load
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作者 WEN Xiao-ze FENG Guo-rui +5 位作者 GUO Jun YU Lu-yang QIAN Rui-peng ZHANG Jie ZHANG Peng-fei FENG Wen-ming 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第8期2644-2657,共14页
The mechanical properties of residual coal pillars under the influence of upward mining disturbances significantly affect the safety of residual mining activities on working faces.This study conducted low-frequency di... The mechanical properties of residual coal pillars under the influence of upward mining disturbances significantly affect the safety of residual mining activities on working faces.This study conducted low-frequency disturbance dynamic uniaxial compression tests on coal specimens using a self-developed dynamic-static load coupling electro-hydraulic servo system,and studied the strength evolutions,surface deformations,acoustic emission(AE)characteristic parameters,and the failure modes of coal specimens with different static preloading levels were studied.The disturbance damage is positively correlated with the coal specimen static preload level.Specifically,the cumulative AE count rates of the initial accelerated damage stage for the coal specimens with static preloading level of 60%and 70%of the uniaxial compressive strength(UCS)were 2.66 and 3.19 times that of the 50%UCS specimens,respectively.Macroscopically,this behaviour manifested as a decrease in the compressive strength,and the mean strengths of the disturbance-damaged coal specimens with 60%and 70%of UCS static preloading decreased by 8.53%and 9.32%,respectively,compared to those of the specimens under pure static loading.The crack sources,such as the primary fissures,strongly control the dynamic response of the coal specimen.The difference between the dynamic responses of the coal specimens and that of dense rocks is significant. 展开更多
关键词 low-frequency disturbance dynamic response coal specimens static preloading level
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Suppression of low-frequency ultrasound broadband vibration using star-shaped single-phase metamaterials
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作者 Rui Zhao Jian Zheng +4 位作者 Jin Guo Yunbo Shi Hengzhen Feng Jun Tang Jun Liu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第4期217-224,共8页
In order to suppress the low-frequency ultrasound vibration in the broadband range of 20 k Hz—100 k Hz,this paper proposes and discusses an acoustic metamaterial with low-frequency ultrasound vibration attenuation pr... In order to suppress the low-frequency ultrasound vibration in the broadband range of 20 k Hz—100 k Hz,this paper proposes and discusses an acoustic metamaterial with low-frequency ultrasound vibration attenuation properties,which is configured by hybrid arc and sharp-angle convergent star-shaped lattices.The effect of the dispersion relation and the bandgap characteristic for the scatterers in star-shaped are simulated and analyzed.The target bandgap width is extended by optimizing the geometry parameters of arc and sharp-angle convergent lattices.The proposed metamaterial configured by optimized hybrid lattices exhibits remarkable broad bandgap characteristics by bandgap complementarity,and the simulation results verify a 99%vibration attenuation amplitude can be obtained in the frequency of20 k Hz—100 k Hz.After the fabrication of the proposed hybrid configurational star-shaped metamaterial by 3D printing technique,the transmission loss experiments are performed,and the experimental results indicate that the fabricated metamaterial has the characteristics of broadband vibration attenuation and an amplitude greater than 85%attenuation for the target frequency.These results demonstrate that the hybrid configurational star-shaped metamaterials can effectively widen the bandgap and realize high efficiency attenuation,which has capability for the vibration attenuation in the application of highprecise equipment. 展开更多
关键词 Star-shaped metamaterials BROADBAND Vibration attenuation low-frequency ultrasound vibration Transmission loss
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A seismic elastic moduli module for the measurements of low-frequency wave dispersion and attenuation of fluid-saturated rocks under different pressures
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作者 Yan-Xiao He Shang-Xu Wang +9 位作者 Gen-Yang Tang Chao Sun Hong-Bing Li San-Yi Yuan Xian Wei Li-Deng Gan Xiao-Feng Dai Qiang Ge Peng-Peng Wei Hui-Qing Zhang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期162-181,共20页
Knowledge about the seismic elastic modulus dispersion,and associated attenuation,in fluid-saturated rocks is essential for better interpretation of seismic observations taken as part of hydrocarbon identification and... Knowledge about the seismic elastic modulus dispersion,and associated attenuation,in fluid-saturated rocks is essential for better interpretation of seismic observations taken as part of hydrocarbon identification and time-lapse seismic surveillance of both conventional and unconventional reservoir and overburden performances.A Seismic Elastic Moduli Module has been developed,based on the forced-oscillations method,to experimentally investigate the frequency dependence of Young's modulus and Poisson's ratio,as well as the inferred attenuation,of cylindrical samples under different confining pressure conditions.Calibration with three standard samples showed that the measured elastic moduli were consistent with the published data,indicating that the new apparatus can operate reliably over a wide frequency range of f∈[1-2000,10^(6)]Hz.The Young's modulus and Poisson's ratio of the shale and the tight sandstone samples were measured under axial stress oscillations to assess the frequency-and pressure-dependent effects.Under dry condition,both samples appear to be nearly frequency independent,with weak pressure dependence for the shale and significant pressure dependence for the sandstone.In particular,it was found that the tight sandstone with complex pore microstructure exhibited apparent dispersion and attenuation under brine or glycerin saturation conditions,the levels of which were strongly influenced by the increased effective pressure.In addition,the measured Young's moduli results were compared with the theoretical predictions from a scaled poroelastic model with a reasonably good agreement,revealing that the combined fluid flow mechanisms at both mesoscopic and microscopic scales possibly responsible for the measured dispersion. 展开更多
关键词 low-frequency measurements Dispersion and attenuation Rock physics Fluid flow
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Low-frequency oscillation of train-network system considering traction power supply mode
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作者 Yuchen Liu Xiaoqin Lyu +1 位作者 Mingyuan Chang Qiqi Yang 《Railway Engineering Science》 EI 2024年第2期244-256,共13页
The low-frequency oscillation(LFO)has occurred in the train-network system due to the introduction of the power electronics of the trains.The modeling and analyzing method in current researches based on electrified ra... The low-frequency oscillation(LFO)has occurred in the train-network system due to the introduction of the power electronics of the trains.The modeling and analyzing method in current researches based on electrified railway unilateral power supply system are not suitable for the LFO analysis in a bilateral power supply system,where the trains are supplied by two traction substations.In this work,based on the single-input and single-output impedance model of China CRH5 trains,the node admittance matrices of the train-network system both in unilateral and bilateral power supply modes are established,including three-phase power grid,traction transformers and traction network.Then the modal analysis is used to study the oscillation modes and propagation characteristics of the unilateral and bilateral power supply systems.Moreover,the influence of the equivalent inductance of the power grid,the length of the transmission line,and the length of the traction network are analyzed on the critical oscillation mode of the bilateral power supply system.Finally,the theoretical analysis results are verified by the time-domain simulation model in MATLAB/Simulink. 展开更多
关键词 low-frequency oscillation Train-network system Modal analysis Bilateral power supply Participation factor
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High-order Bragg forward scattering and frequency shift of low-frequency underwater acoustic field by moving rough sea surface
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作者 莫亚枭 张朝金 +2 位作者 鹿力成 孙启航 马力 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期459-470,共12页
Acoustic scattering modulation caused by an undulating sea surface on the space-time dimension seriously affects underwater detection and target recognition.Herein,underwater acoustic scattering modulation from a movi... Acoustic scattering modulation caused by an undulating sea surface on the space-time dimension seriously affects underwater detection and target recognition.Herein,underwater acoustic scattering modulation from a moving rough sea surface is studied based on integral equation and parabolic equation.And with the principles of grating and constructive interference,the mechanism of this acoustic scattering modulation is explained.The periodicity of the interference of moving rough sea surface will lead to the interference of the scattering field at a series of discrete angles,which will form comb-like and frequency-shift characteristics on the intensity and the frequency spectrum of the acoustic scattering field,respectively,which is a high-order Bragg scattering phenomenon.Unlike the conventional Doppler effect,the frequency shifts of the Bragg scattering phenomenon are multiples of the undulating sea surface frequency and are independent of the incident sound wave frequency.Therefore,even if a low-frequency underwater acoustic field is incident,it will produce obvious frequency shifts.Moreover,under the action of ideal sinusoidal waves,swells,fully grown wind waves,unsteady wind waves,or mixed waves,different moving rough sea surfaces create different acoustic scattering processes and possess different frequency shift characteristics.For the swell wave,which tends to be a single harmonic wave,the moving rough sea surface produces more obvious high-order scattering and frequency shifts.The same phenomena are observed on the sea surface under fully grown wind waves,however,the frequency shift slightly offsets the multiple peak frequencies of the wind wave spectrum.Comparing with the swell and fully-grown wind waves,the acoustic scattering and frequency shift are not obvious for the sea surface under unsteady wind waves. 展开更多
关键词 high-order Bragg scattering frequency shift low-frequency acoustic field moving rough sea surface
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Current optimization-based control of dual three-phase PMSM for low-frequency temperature swing reduction
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作者 Linlin Lu Xueqing Wang +3 位作者 Luhan Jin Qiong Liu Yun Zhang Yao Mao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第4期238-246,共9页
In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperatur... In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperature swing can be equivalent to reducing maximum instantaneous phase copper loss in this paper.First,a two-level optimization aiming at minimizing maximum instantaneous phase copper loss at each electrical angle is proposed.Then,the optimization is transformed to a singlelevel optimization by introducing the auxiliary variable for easy solving.Considering that singleobjective optimization trades a great total copper loss for a small reduction of maximum phase copper loss,the optimization considering both instantaneous total copper loss and maximum phase copper loss is proposed,which has the same performance of temperature swing reduction but with lower total loss.In this way,the proposed control scheme can reduce maximum junction temperature by 11%.Both simulation and experimental results are presented to prove the effectiveness and superiority of the proposed control scheme for low-frequency temperature swing reduction. 展开更多
关键词 Dual three-phase PMSM low-frequency temperature swing Copper loss Current optimization Connected neutral points
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Altered spontaneous brain activity patterns in hypertensive retinopathy using fractional amplitude of low-frequency fluctuations:a functional magnetic resonance imaging study
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作者 Xue-Lin Wang Xu-Jun Zheng +8 位作者 Li-Juan Zhang Jin-Yu Hu Hong Wei Qian Ling Liang-Qi He Cheng Chen Yi-Xin Wang Xu Chen Yi Shao 《International Journal of Ophthalmology(English edition)》 SCIE CAS 2024年第9期1665-1674,共10页
AIM:To study functional brain abnormalities in patients with hypertensive retinopathy(HR)and to discuss the pathophysiological mechanisms of HR by fractional amplitude of low-frequency fluctuations(fALFFs)method.METHO... AIM:To study functional brain abnormalities in patients with hypertensive retinopathy(HR)and to discuss the pathophysiological mechanisms of HR by fractional amplitude of low-frequency fluctuations(fALFFs)method.METHODS:Twenty HR patients and 20 healthy controls(HCs)were respectively recruited.The age,gender,and educational background characteristics of the two groups were similar.After functional magnetic resonance imaging(fMRI)scanning,the subjects’spontaneous brain activity was evaluated with the fALFF method.Receiver operating characteristic(ROC)curve analysis was used to classify the data.Further,we used Pearson’s correlation analysis to explore the relationship between fALFF values in specific brain regions and clinical behaviors in patients with HR.RESULTS:The brain areas of the HR group with lower fALFF values than HCs were the right orbital part of the middle frontal gyrus(RO-MFG)and right lingual gyrus.In contrast,the values of fALFFs in the left middle temporal gyrus(MTG),left superior temporal pole(STP),left middle frontal gyrus(MFG),left superior marginal gyrus(SMG),left superior parietal lobule(SPL),and right supplementary motor area(SMA)were higher in the HR group.The results of a t-test showed that the average values of fALFFs were statistically significantly different in the HR group and HC group(P<0.001).The fALFF values of the left middle frontal gyrus in HR patients were positively correlated with anxiety scores(r=0.9232;P<0.0001)and depression scores(r=0.9682;P<0.0001).CONCLUSION:fALFF values in multiple brain regions of HR patients are abnormal,suggesting that these brain regions in HR patients may be dysfunctional,which may help to reveal the pathophysiological mechanisms of HR. 展开更多
关键词 hypertensive retinopathy fractional amplitude of low-frequency fluctuation brain region magnetic resonance imaging
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A low-frequency pure metal metamaterial absorber with continuously tunable stiffness
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作者 Xingzhong WANG Shiteng RUI +2 位作者 Shaokun YANG Weiquan ZHANG Fuyin MA 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第7期1209-1224,共16页
To address the incompatibility between high environmental adaptability and deep subwavelength characteristics in conventional local resonance metamaterials,and overcome the deficiencies in the stability of existing ac... To address the incompatibility between high environmental adaptability and deep subwavelength characteristics in conventional local resonance metamaterials,and overcome the deficiencies in the stability of existing active control techniques for band gaps,this paper proposes a design method of pure metal vibration damping metamaterial with continuously tunable stiffness for wideband elastic wave absorption.We design a dual-helix narrow-slit pure metal metamaterial unit,which possesses the triple advantage of high spatial compactness,low stiffness characteristics,and high structural stability,enabling the opening of elastic flexural band gaps in the low-frequency range.Similar to the principle of a sliding rheostat,the introduction of continuously sliding plug-ins into the helical slits enables the continuous variation of the stiffness of the metamaterial unit,achieving a continuously tunable band gap effect.This successfully extends the effective band gap by more than ten times.The experimental results indicate that this metamaterial unit can be used as an additional vibration absorber to absorb the low-frequency vibration energy effectively.Furthermore,it advances the metamaterial absorbers from a purely passive narrowband design to a wideband tunable one.The pure metal double-helix metamaterials retain the subwavelength properties of metamaterials and are suitable for deployment in harsh environments.Simultaneously,by adjusting its stiffness,it substantially broadens the effective band gap range,presenting promising potential applications in various mechanical equipment operating under adverse conditions. 展开更多
关键词 elastic metamaterial absorber continuously tunable stiffness low-frequency vibration damping variable stiffness design pure metal structure
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Diagnosing ratio of electron density to collision frequency of plasma surrounding scaled model in a shock tube using low-frequency alternating magnetic field phase shift
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作者 吴明兴 谢楷 +3 位作者 刘艳 徐晗 张宝 田得阳 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期519-530,共12页
A non-contact low-frequency(LF)method of diagnosing the plasma surrounding a scaled model in a shock tube is proposed.This method utilizes the phase shift occurring after the transmission of an LF alternating magnetic... A non-contact low-frequency(LF)method of diagnosing the plasma surrounding a scaled model in a shock tube is proposed.This method utilizes the phase shift occurring after the transmission of an LF alternating magnetic field through the plasma to directly measure the ratio of the plasma loop average electron density to collision frequency.An equivalent circuit model is used to analyze the relationship of the phase shift of the magnetic field component of LF electromagnetic waves with the plasma electron density and collision frequency.The applicable range of the LF method on a given plasma scale is analyzed.The upper diagnostic limit for the ratio of the electron density(unit:m^(-3))to collision frequency(unit:Hz)exceeds 1×10^(11),enabling an electron density to exceed 1×10^(20)m^(-3)and a collision frequency to be less than 1 GHz.In this work,the feasibility of using the LF phase shift to implement the plasma diagnosis is also assessed.Diagnosis experiments on shock tube equipment are conducted by using both the electrostatic probe method and LF method.By comparing the diagnostic results of the two methods,the inversion results are relatively consistent with each other,thereby preliminarily verifying the feasibility of the LF method.The ratio of the electron density to the collision frequency has a relatively uniform distribution during the plasma stabilization.The LF diagnostic path is a loop around the model,which is suitable for diagnosing the plasma that surrounds the model.Finally,the causes of diagnostic discrepancy between the two methods are analyzed.The proposed method provides a new avenue for diagnosing high-density enveloping plasma. 展开更多
关键词 low-frequency alternating magnetic field phase shift shock-tube plasma diagnosis electron density collision frequency
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Unveiling the origin of anomalous low-frequency Raman mode in CVD-grown monolayer WS_(2) 被引量:2
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作者 Qian Xiang Xiaofei Yue +8 位作者 Yanlong Wang Bin Du Jiajun Chen Shaoqian Zhang Gang Li Chunxiao Cong Ting Yu Qingwei Li Yuqi Jin 《Nano Research》 SCIE EI CSCD 2021年第11期4314-4320,共7页
Substrates provide the necessary support for scientific explorations of numerous promising features and exciting potential applications in two-dimensional (2D) transition metal dichalcogenides (TMDs). To utilize subst... Substrates provide the necessary support for scientific explorations of numerous promising features and exciting potential applications in two-dimensional (2D) transition metal dichalcogenides (TMDs). To utilize substrate engineering to alter the properties of 2D TMDs and avoid introducing unwanted adverse effects, various experimental techniques, such as high-frequency Raman spectroscopy, have been used to understand the interactions between 2D TMDs and substrates. However, sample-substrate interaction in 2D TMDs is not yet fully understood due to the lack of systematic studies by techniques that are sensitive to 2D TMD-substrate interaction. This work systematically investigates the interaction between tungsten disulfide (WS_(2)) monolayers and substrates by low-frequency Raman spectroscopy, which is very sensitive to WS_(2)-substrate interaction. Strong coupling with substrates is clearly revealed in chemical vapor deposition (CVD)-grown monolayer WS_(2) by its low-wavenumber interface mode. It is demonstrated that the enhanced sample-substrate interaction leads to tensile strain on monolayer WS_(2), which is induced during the cooling process of CVD growth and could be released for monolayer WS_(2) sample after transfer or fabricated by an annealing-free method such as mechanical exfoliation. These results not only suggest the effectiveness of low-frequency Raman spectroscopy for probing sample-substrate interactions in 2D TMDs, but also provide guidance for the design of high-performance devices with the desired sample-substrate coupling strength based on 2D TMDs. 展开更多
关键词 interface mode monolayer tungsten disulfide low-frequency raman spectroscopy sample-substrate interaction strain chemical vapor deposition
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不同变质程度煤中镜质组的元素分布特征:基于Raman和原位微区XRF分析
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作者 刘超 谢鹏鸿 +1 位作者 孙蓓蕾 常洋梅 《地质学报》 EI CAS CSCD 北大核心 2024年第8期2472-2485,共14页
为明确煤中元素与有机质之间的关系,本文选择山西太原西山煤田6个矿区石炭系—二叠系太原组8号煤层煤样(镜质体最大反射率为1.26%~2.03%)为研究对象,挑选其中的镜煤条带,利用激光共聚焦拉曼光谱仪(Raman)选出镜质组,结合微区X射线荧光... 为明确煤中元素与有机质之间的关系,本文选择山西太原西山煤田6个矿区石炭系—二叠系太原组8号煤层煤样(镜质体最大反射率为1.26%~2.03%)为研究对象,挑选其中的镜煤条带,利用激光共聚焦拉曼光谱仪(Raman)选出镜质组,结合微区X射线荧光光谱仪(μ-XRF)对镜质组中元素含量和分布特征进行分析,试图探讨不同变质程度煤中镜质组的拉曼光谱和元素的耦合关系。研究发现,镜质组中仍然存在着大量的纳米级矿物,在实验操作过程中即使Raman光谱的结果限定了有机组分,但是由于束斑大小的差异,μ-XRF测试时不可避免的受到了煤中纳米级矿物的影响;Al、Si、K、Ti、V、Fe、Co、Ca主要赋存于镜质组中的纳米级矿物中,Ni、Zn、Ga、Ge、Br、S则主要以有机结合态的形式存在。 展开更多
关键词 西山煤田8号煤 不同变质程度煤 镜质组 raman μ-XRF
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盐湖卤水中硼酸盐化学形态及Raman光谱定量分析
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作者 彭姣玉 杨克利 +3 位作者 董亚萍 冯海涛 张波 李武 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2024年第9期2514-2522,共9页
我国青藏盐湖以富含硼锂而著称,卤水中硼化学赋存状态随湖水化学类型的不同而发生变化,其中以硫酸盐型盐湖卤水中硼酸盐的存在形式变化最为复杂,卤水蒸发过程一般不以固体盐形式结晶析出,而是以多硼物种形式富集于氯化镁饱和老卤中,表... 我国青藏盐湖以富含硼锂而著称,卤水中硼化学赋存状态随湖水化学类型的不同而发生变化,其中以硫酸盐型盐湖卤水中硼酸盐的存在形式变化最为复杂,卤水蒸发过程一般不以固体盐形式结晶析出,而是以多硼物种形式富集于氯化镁饱和老卤中,表现出严重的过饱和性,对后续锂盐和镁盐的分离提取影响较大。开展盐湖卤水体系中硼酸盐化学形态、分布规律及离子间作用机制等溶液化学研究对盐湖资源高效开发具有重要的意义。相比常规拉曼光谱技术,拉曼积分球基于拉曼散射原理可极大地提高激发光的使用效率和拉曼散射信号,对硼酸盐溶液结构检测具有拉曼响应信号强、检出限低、信噪比高等优点,为盐卤复杂体系硼酸盐化学形态的定量分析奠定了基础。利用拉曼积分球开展了盐湖卤水硼酸盐化学形态研究,阐述了卤水蒸发过程多硼酸根离子的变化规律;同时借助响应曲面法进行实验设计与优化,建立了共存盐类干扰回归模型用于盐湖卤水中单硼物种B(OH)_(3)的准确测定。结果表明,盐湖卤水浓缩过程中硼不断聚合生成多聚度硼酸根离子如B_(3)O_(3)(OH)_(4)^(-)和B_(6)O_(7)(OH)_(7)^(2-)等,硼的化学形态变化规律与碱土金属如MgCl_(2)-MgO-2B_(2)O_(3)-H_(2)O体系中硼物种变化一致,但与碱金属溶液体系物种变化差别较大。回归模型对卤水中正硼酸B(OH)_(3)定量分析的相对误差小于5%,准确度较高;阐明了蒸发浓缩过程中B(OH)_(3)物种分布的变化规律,从定量视角初步阐述了卤水富集过程硼酸根离子间的聚合作用关系,可为后续开展盐卤体系多硼物种分布及作用机制研究提供新思路、新方法。 展开更多
关键词 卤水 硼酸盐:响应曲面 拉曼光谱 定量分析
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基于Raman光谱的3,5-二氨基-1,2,4-三唑(DAT)合成反应在线监测与反应机理探究——推荐一个仪器分析综合实验
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作者 张天龙 张容玲 +2 位作者 汤宏胜 李延 李华 《大学化学》 CAS 2024年第6期303-311,共9页
本实验介绍了一个仪器分析综合性实验——基于Raman光谱的3,5-二氨基-1,2,4-三唑(DAT)合成的在线监测与反应机理探究。该实验是一个科研转化的仪器分析综合实验,内容包括DAT的合成、基于Raman光谱的合成反应过程在线监测以及合成反应机... 本实验介绍了一个仪器分析综合性实验——基于Raman光谱的3,5-二氨基-1,2,4-三唑(DAT)合成的在线监测与反应机理探究。该实验是一个科研转化的仪器分析综合实验,内容包括DAT的合成、基于Raman光谱的合成反应过程在线监测以及合成反应机理解析。在实验中,采用化学计量学方法对Raman光谱数据进行处理和分析,以更深入地理解合成反应的机理。通过本实验,可以巩固学生的化学专业知识,提高学生的综合实验操作技能,激发学生对科学研究的兴趣,培养学生的科研探究能力。 展开更多
关键词 拉曼光谱 在线监测 合成反应机理 综合实验
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基于Raman的复方柳安咖注射液主要成分分析
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作者 张川云 李伦 +2 位作者 司民真 徐选盼 张德清 《光散射学报》 北大核心 2024年第2期122-133,共12页
本文应用拉曼光谱技术对复方柳安咖注射液的主要成分及含量进行了分析。首先测试分析了62个复方柳安咖注射液样品的拉曼光谱,结果表明62个注射液样品的拉曼光谱主要由水杨酸钠、安替比林和咖啡因的水溶液拉曼谱带组成;进一步利用密度泛... 本文应用拉曼光谱技术对复方柳安咖注射液的主要成分及含量进行了分析。首先测试分析了62个复方柳安咖注射液样品的拉曼光谱,结果表明62个注射液样品的拉曼光谱主要由水杨酸钠、安替比林和咖啡因的水溶液拉曼谱带组成;进一步利用密度泛函理论(DFT)计算了其主要成分的理论拉曼光谱和红外光谱,与实验测定的固体粉末光谱和溶液光谱进行比较分析,进而对复方柳安咖注射液拉曼光谱谱峰的振动模式进行了归属;最后利用水杨酸钠和安替比林浓度梯度溶液拉曼光谱特征峰的峰高和峰面积,分别建立定量分析模型,对62个复方柳安咖注射液样品中主要成分水杨酸钠和安替比林的含量进行预测,并与液相色谱法测试值进行了对比,结果显示预测值与液相色谱法测试值相近,得到了较好的主要成分含量预测结果。研究结果可为复方柳安咖注射液药剂的生产、药品质量的监控、药品光谱分析研究等方面提供参考。 展开更多
关键词 拉曼光谱 复方柳安咖注射液 密度泛函理论 定量分析
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A bio-inspired spider-like structure isolator for low-frequency vibration 被引量:2
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作者 Guangdong SUI Shuai HOU +5 位作者 Xiaofan ZHANG Xiaobiao SHAN Chengwei HOU Henan SONG Weijie HOU Jianming LI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第8期1263-1286,共24页
This paper proposes a quasi-zero stiffness(QZS)isolator composed of a curved beam(as spider foot)and a linear spring(as spider muscle)inspired by the precise capturing ability of spiders in vibrating environments.The ... This paper proposes a quasi-zero stiffness(QZS)isolator composed of a curved beam(as spider foot)and a linear spring(as spider muscle)inspired by the precise capturing ability of spiders in vibrating environments.The curved beam is simplified as an inclined horizontal spring,and a static analysis is carried out to explore the effects of different structural parameters on the stiffness performance of the QZS isolator.The finite element simulation analysis verifies that the QZS isolator can significantly reduce the first-order natural frequency under the load in the QZS region.The harmonic balance method(HBM)is used to explore the effects of the excitation amplitude,damping ratio,and stiffness coefficient on the system’s amplitude-frequency response and transmissibility performance,and the accuracy of the analytical results is verified by the fourth-order Runge-Kutta integral method(RK-4).The experimental data of the QZS isolator prototype are fitted to a ninth-degree polynomial,and the RK-4 can theoretically predict the experimental results.The experimental results show that the QZS isolator has a lower initial isolation frequency and a wider isolation frequency bandwidth than the equivalent linear isolator.The frequency sweep test of prototypes with different harmonic excitation amplitudes shows that the initial isolation frequency of the QZS isolator is 3 Hz,and it can isolate 90%of the excitation signal at 7 Hz.The proposed biomimetic spider-like QZS isolator has high application prospects and can provide a reference for optimizing low-frequency or ultra-low-frequency isolators. 展开更多
关键词 bionic isolation structure curved beam nonlinear stiffness quasi-zero stiffness(QzS) low-frequency vibration isolator
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LiF-ZrF_(4)熔盐体系离子结构的Raman光谱
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作者 康红光 胡宪伟 +1 位作者 赵婉婷 于江玉 《东北大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第6期823-828,共6页
采用Raman光谱和量子化学计算相结合的方法,研究了803~1 086 K下,ZrF_(4)摩尔分数为10%~60%的LiF-ZrF_(4)熔盐体系的离子结构特征及变化规律.研究结果表明:熔体中含有ZrF_(5)^(-),ZrF_(6)^(2-),ZrF_(7)^(3-)和ZrF_(8)^(4-)四种络合阴离... 采用Raman光谱和量子化学计算相结合的方法,研究了803~1 086 K下,ZrF_(4)摩尔分数为10%~60%的LiF-ZrF_(4)熔盐体系的离子结构特征及变化规律.研究结果表明:熔体中含有ZrF_(5)^(-),ZrF_(6)^(2-),ZrF_(7)^(3-)和ZrF_(8)^(4-)四种络合阴离子团,其中以ZrF_(7)^(3-)和ZrF_(8)^(4-)为主,二者摩尔分数之和高达90%~94%,ZrF_(5)^(-)和ZrF_(6)^(2-)含量较少.在熔盐升温初始阶段,熔盐中发生ZrF_(7)^(3-)与ZrF_(6)^(2-)生成ZrF_(8)^(4-)和ZrF_(5)^(-)的反应(ZrF_(7)^(3-)+ZrF_(6)^(2-)→ZrF_(8)^(4-)+ZrF_(5)^(-));到达一定温度后,熔盐中发生ZrF_(8)^(4-)与ZrF_(6)^(2-)生成ZrF_(7)^(3-),ZrF_(5)^(-)和F-的反应(ZrF_(8)^(4-)+ZrF_(6)^(2-)→ZrF_(7)^(3-)+ZrF_(5)^(-)+2F-).随着ZrF_(4)质量分数增加,熔盐中ZrF_(5)^(-)含量增加,ZrF_(6)^(2-),ZrF_(7)^(3-)和ZrF_(8)^(4-)的含量减少. 展开更多
关键词 LiF-ZrF_(4) 络合离子团 离子结构 raman光谱 量子化学计算
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A core-satellite self-assembled SERS aptasensor containing a“biological-silent region”Raman tag for the accurate and ultrasensitive detection of histamine 被引量:1
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作者 Chen Chen Yingfang Zhang +3 位作者 Ximo Wang Xuguang Qiao Geoffrey I.N.Waterhouse Zhixiang Xu 《Food Science and Human Wellness》 SCIE CSCD 2024年第2期1029-1039,共11页
Herein,a novel interference-free surface-enhanced Raman spectroscopy(SERS)strategy based on magnetic nanoparticles(MNPs)and aptamer-driven assemblies was proposed for the ultrasensitive detection of histamine.A core-s... Herein,a novel interference-free surface-enhanced Raman spectroscopy(SERS)strategy based on magnetic nanoparticles(MNPs)and aptamer-driven assemblies was proposed for the ultrasensitive detection of histamine.A core-satellite SERS aptasensor was constructed by combining aptamer-decorated Fe_(3)O_(4)@Au MNPs(as the recognize probe for histamine)and complementary DNA-modified silver nanoparticles carrying 4-mercaptobenzonitrile(4-MBN)(Ag@4-MBN@Ag-c-DNA)as the SERS signal probe for the indirect detection of histamine.Under an applied magnetic field in the absence of histamine,the assembly gave an intense Raman signal at“Raman biological-silent”region due to 4-MBN.In the presence of histamine,the Ag@4-MBN@Ag-c-DNA SERS-tag was released from the Fe_(3)O_(4)@Au MNPs,thus decreasing the SERS signal.Under optimal conditions,an ultra-low limit of detection of 0.65×10^(-3)ng/mL and a linear range 10^(-2)-10^5 ng/mL on the SERS aptasensor were obtained.The histamine content in four food samples were analyzed using the SERS aptasensor,with the results consistent with those determined by high performance liquid chromatography.The present work highlights the merits of indirect strategies for the ultrasensitive and highly selective SERS detection of small biological molecules in complex matrices. 展开更多
关键词 Surface-enhanced raman spectroscopy raman biological-silent region APTAMER Histamine detection Universal SERS-tag
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Observation of low-frequency oscillation in argon helicon discharge
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作者 朱婉莹 崔瑞林 +2 位作者 韩若愚 何锋 欧阳吉庭 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第2期86-94,共9页
We present here a kind of low-frequency oscillation in argon helicon discharge with a half helical antenna.This time-dependent instability shows a global quasi-periodic oscillation of plasma density and electron tempe... We present here a kind of low-frequency oscillation in argon helicon discharge with a half helical antenna.This time-dependent instability shows a global quasi-periodic oscillation of plasma density and electron temperature,with a typical frequency of a few tens of Hz which increases with external magnetic field as well as radiofrequency(RF)power.The relative oscillation amplitude decreases with magnetic field and RF power,but the rising time and pulse width do not change significantly under different discharge conditions.The oscillation can only be observed in some specific conditions of low magnetic fields and low RF power when the gas flows in from one end of the discharge area and out from another end.This global instability is suggested to be attributed to the pressure instability of neutral depletion,which is the result of compound action of gas depletion by heating expansion and gas replenishment from upstream.There are two kinds of oscillations,large and small amplitude oscillations,occurring in different discharge modes.This study could be a good verification of and complement to earlier experiments.This kind of spontaneous pulse phenomenon is also helpful in realizing a pulsing plasma source without a pulsed power supply. 展开更多
关键词 helicon plasma low-frequency oscillation global instability neutral depletion
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