Fluid identification and tight oil layer classification for the southwestern Mahu Sag,Junggar Basin using NMR logging-based spectrum decomposition

The intricate distribution of oil and water in tight rocks makes pinpointing oil layers challenging.While conventional identification methods offer potential solutions,their limited accuracy precludes them from being effective in their applications to unconventional reservoirs.This study employed nuclear magnetic resonance(NMR)spectrum decomposition to dissect the NMR T_(2)spectrum into multiple subspectra.Furthermore,it employed laboratory NMR experiments to ascertain the fluid properties of these sub-spectra,aiming to enhance identification accuracy.The findings indicate that fluids of distinct properties overlap in the T_(2)spectra,with bound water,movable water,bound oil,and movable oil appearing sequentially from the low-value zone to the high-value zone.Consequently,an oil layer classification scheme was proposed,which considers the physical properties of reservoirs,oil-bearing capacity,and the characteristics of both mobility and the oil-water two-phase flow.When applied to tight oil layer identification,the scheme's outcomes align closely with actual test results.A horizontal well,deployed based on these findings,has produced high-yield industrial oil flow,underscoring the precision and dependability of this new approach.

Micro-geological causes and macro-geological controlling factors of low-resistivity oil layers in the Puao Oilfield

Low-resistivity oil layers are often missed in logging interpretation because of their resistivity close to or below the resistivity of nearby water layers. Typical low-resistivity oil layers have been found in the past few years in the Putaohua reservoir of the Puao Oilfield in the south of the Daqing placanticline by detailed exploration. Based on a study of micro-geological causes of low-resistivity oil layers, the macro-geological controlling factors were analyzed through comprehensive research of regional depositional background, geological structure, and oil-water relations combined with core, water testing, well logging, and scanning electron microscopy data. The results showed that the formation and distribution of Putaohua low-resistivity oil layers in the Puao Oilfield were controlled by depositional environment, sedimentary facies, diagenesis, motive power of hydrocarbon accumulation, and acidity and alkalinity of reservoir liquid. The low-resistivity oil layers caused by high bound-water saturation were controlled by deposition and diagenesis, those caused by high free-water saturation were controlled by structural amplitude and motive power of hydrocarbon accumulation. Those caused by formation water with high salinity were controlled by the ancient saline water depositional environment and faulted structure and those caused by additional conductivity of shale were controlled by paleoclimate and acidity and alkalinity of reservoir liquid. Consideration of both micro-geological causes and macro-geological controlling factors is important in identifying low-resistivity oil layers.

Characteristics of the active-layer under the China-Russia Crude Oil pipeline

Active layer is a key component for permafrost environment studies as many subsurface biological,biogeochemical,ecological,and pedogenic activities prevail in this layer.This study focuses on active layer temperature monitoring in an area with sporadic permafrost at two adjacent sites along China-Russia Crude Oil Pipeline(CRCOP),NorthEast China.Site T1 is located in disturbed ground on the right-of-way(on-ROW)2 m away from the center of the oil pipeline.T2 is located in a natural and undisturbed site,around 16.6 m off-ROW.Our objective was to study seasonal variability of the active layer depth and thermal regime from October 2017 to September 2018.The monitoring sites consist of soil temperature probes arranged in a vertical array at different depths at both sites.The following parameters were computed:number of isothermal days(ID),freezing days(FD),thawing days(TD),freezing degree days(FDD),thawing degree days(TDD),number of freeze-thaw days(FTD).The mean air temperature in the monitoring period reached-3.2℃.The temperature profile indicates that the maximum active layer thickness observed during the study period was 10 m at T1 and 2 m at T2.The majority of the soil temperatures were above or close to 0℃,resulting in great values of TDD,especially in the first 4 m depth.TDD for T1 were predominant and ranged between 600-1160℃·days(0-4 m depth)reflecting the influence of oil temperature from the pipeline.In T2 borehole FDD were predominant for all the soil layer depths resulting in less permafrost degradation.This comparison emphasizes the significant influence of vegetation removal and the dispersed heat from the pipeline on the active layer thickness.

Pore structure differences of the extra-low permeability sandstone reservoirs and the causes of low resistivity oil layers: A case study of Block Yanwumao in the middle of Ordos Basin, NW China

The influence of pore structure difference on rock electrical characteristics of reservoir and oil reservoir was analyzed taking Triassic Chang 6 reservoir in Block Yanwumao in the middle of Ordos Basin as an example. The relationship between the pore structure difference and the low resistivity oil layer was revealed and demonstrated through core observation, lab experiments, geological research, well log interpretation and trial production etc. The results show that there were two kinds of oil layers in Chang 6 oil layer set, normal oil layer and low resistivity oil layer in the region, corresponding to two types of pore structures, pore type mono-medium and micro-fracture-pore type double-medium; the development of micro-fracture changed greatly the micro-pore structure of the reservoir, and the pore structure difference had an important influence on the rock electrical characteristics of the extra-low permeability sandstone reservoir and oil reservoir; the normal oil layers had obvious characteristics of pore-type mono-medium, and were concentrated in Chang 61, Chang 6232 and Chang 62; the low resistivity oil layers had obvious characteristics of micro-fracture-pore type double-medium, which were mainly distributed in Chang 612 and Chang 63. The mud filtrate penetrated deep into the oil layers along the micro-cracks, leading to sharp reduction of resistivity, and thus low resistivity of the oil layer; the low resistivity oil layers had better storage capacity and higher productivity than the normal oil layers.

Zwitterionic monolayer grafted ceramic membrane with an antifouling performance for the efficient oil-water separation

Enormous demands on the separation of oil/water(O/W)emulsions in various industries,such as petrochemical,food and pharmaceutical industries,are looking for high performance and energy-efficient separation methods.Ceramic membranes have been used to deal with O/W emulsions,for its outstanding characteristics of easy-operation,high-flux,and long-term stability.However,membrane fouling is still a challenge in the industrial application of ceramic membranes.Herein,antifouling ceramic membranes were fabricated by grafting zwitterions on the membrane surface via an environment-friendly two-step grafting method,which improves the antifouling property and permeability.Successful grafting of such zwitterion on the ceramic surface was assessed by the combination of FTIR and XPS characterization.More importantly,the hydration can be formed by electrostatic interactions layer on the modified membrane,which was confirmed by TGA characterization.The antifouling performance of prepared zwitterionic ceramic membranes in the separation of O/W emulsions was systematically tested.The results suggested that zwitterion can significantly improve the flux of ceramic ultrafiltration membrane,and can also improve antifouling property dramatically by reducing the irreversible fouling in the separation of O/W emulsions.Therefore,zwitterionic ceramic membranes hold promising potentials as an antifouling,highly efficient and green method in the practical purification of the O/W emulsions.

The superhydrophobic sponge decorated with Ni-Co double layered oxides with thiol modification for continuous oil/water separation

In this paper, the superhydrophobic polyurethane sponge(SS-PU) was facilely fabricated by etching with Jones reagent to bind the nanoparticles of Ni-Co double layered oxides(LDOs) on the surface, and following modification with n-dodecyl mercaptan(DDT). This method provides a new strategy to fabricate superhydrophobic PU sponge with a water contact angle of 157° for absorbing oil with low cost and in large scale. It exhibits the strong absorption capacity and highly selective characteristic for various kinds of oils which can be recycled by simple squeezing. Besides, the as-prepared sponge can deal with the floating and underwater oils, indicating its application value in handling oil spills and domestic oily wastewater. The good self-cleaning ability shows the potential to clear the pollutants due to the ultralow adhesion to water. Especially, the most important point is that the superhydrophobic sponge can continuously and effectively separate the oil/water mixture against the condition of turbulent disturbance by using our designed device system, which exhibit its good superhydrophobicity, strong stability.Furthermore, the SS-PU still maintained stable absorption performance after 150 cycle tests without losing capacity obviously, showing excellent durability in long-term operation and significant potential as an efficient absorbent in large-scale dispose of oily water.

Palm Oil Microencapsulation by Coacervation, Thin Layer Drying, and Silica Dioxide Absorption Technique

Indonesia is the largest palm oil producer in the world. The content of β-carotene in palm oil, which can act as pro-vitamin A, is relatively high, so it has great potential for overcoming cases of vitamin A deficiency. By microencapsulation process of palm oil, β-carotene content in palm oil will be more stable and have a longer shelf life. There are three methods of microencapsulation used in this study, namely coacervation, thin-layer drying, and SiO2 absorption technique, which theoretically are suitable for encapsulating β-carotene in palm oil. The aim of this research is to compare and find the most suitable method of microencapsulation process of palm oil to obtain the highest β-carotene content and retention. Results show that those three methods are significantly different in affecting water absorption, solubility in water, yield, microencapsulation efficiency, β-carotene content, and retention of microencapsulated palm oil. The microencapsulated palm oil made from thin layer drying method has the highest β-carotene content at 200.16 μg/g and β-carotene retention of 68.89%. It also has low water absorption and high water solubility, so it can be applied as a powder premix in food as vitamin A supplement.

Seismic identification of channel sandbodies in the Fuyang oil layer in North Songliao Basin, China

The Fuyang oil-layer in North Songliao Basin is characterized by thin interbedded sands and shales, strong lateral variation, strong reservoir heterogeniety, and so on. The thickness of individual sand layers is generally 3 - 5 m. Identifying the channel sand-bodies of the Fuyang oil layer using seismic techniques is very difficult due to the low seismic resolution. Taking the GTZ area as an example, we discuss the genetic characteristics of the channel sand-bodies and point out the real difficulty in using seismic techniques to predict the channel sand-bodies. Two methods for the identification of channels are presented： frequency spectrum imaging and pre-stack azimuthal anisotropy. Identifying the channel sand-bodies in Fuyu oil-layer using the two seismic methods results in a success rate up to 80% compared with well data.

Application of Thin Layer Chromatography in Preparation of Drug Containing Serum of Eucalyptus Oil

[Objectives] To explore whether the thin layer chromatography( TLC) can be used to guide the preparation of drug containing serum of eucalyptus oil. [Methods]Eucalyptus oil samples with different dilution ratio were detected by TLC. Eucalyptus oil was intragastrically administered to mice,serum samples of different eucalyptus oil doses,different intragastric administration methods and different blood sampling times were collected. The above samples were detected by TLC,and the above results were verified by gas chromatography. [Results] TLC can detect concentration difference of eucalyptus oil samples with different dilution ratio. TLC can provide qualitative and semi-quantitative detection of eucalyptus oil in serum. High,medium and low dose of eucalyptus oil in serum had different effects on the growth of MCF-7 cells in the SD rats( P < 0. 05). [Conclusions] TLC can be used to guide the preparation of drug containing serum of eucalyptus oil.

Development of Layered Treatment Technique for Multiple Heavy Oil Reservoirs

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Deepwater and Deep Layers： the Strategic Choices for China＇s Oil and Gas Resources Development

On December 2, 2017, the 2nd Seminar on the Development Strategy of China＇s Oil and Gas Resources was held in Beijing. This seminar was hosted by the Strategic Research Center for Oil and Gas Resources, Ministry of Land （MLR） and Resources and sponsored by both the CNOOC Exploration Department and the School of Ocean and Earth Sciences of Tongji University. With the theme of ＂deepwater and deep-layer oil and gas resources and development strategy＂,

Layered injection technology for chemical flooding of Class-Ⅲ oil reservoirs in the Daqing Oil Fields complex,Songliao Basin,Northeast China

The Class-Ⅲ oil reservoirs of Lasaxing oilfield in the Daqing Oil Fields complex have geological oil reserves of 1.86 billion tonnes,an oil recovery of 39%,with remaining reserves accounting for more than 45%of the total geological reserves of the oilfield.Therefore,they have considerable potential for future oil production.The current layered injection technologies fail to achieve effective control over the low single-layer injection rates since they can only produce low throttle differential pressure under low injection rates(5-20 m^(3)/d).In this study,a symmetrically-structured double-offset-hole injection allocator and a novel throttling component were developed.Their spatial layout was constructed and mechanical parameters were optimized using finite element analysis,which allows for expanding the flow rate range at low injection rates.According to experimental results,the throttle differential pressure increased from 0.2 MPa to 0.8 MPa at an injection rate of 5 m^(3)/d,and the range of the single-layer flow rates expanded from 20-70 m^(3)/d to 5-70 m3/d.The field test results show that the effective production of oil layers with medium and low permeability was achieved and that the ratio of producing oil layer thickness to the total reservoir thickness increased by 9.7%on average.Therefore,this study provides valuable technical support for the effective chemical-flooding-based development of Class-Ⅲ oil reservoirs.

Stress corrosion cracking behavior of buried oil and gas pipeline steel under the coexistence of magnetic field and sulfate-reducing bacteria

Magnetic field and microorganisms are important factors influencing the stress corrosion cracking(SCC)of buried oil and gas pipelines. Once SCC occurs in buried pipelines, it will cause serious hazards to the soil environment. The SCC behavior of X80 pipeline steel under the magnetic field and sulfate-reducing bacteria(SRB) environment was investigated by immersion tests, electrochemical tests, and slow strain rate tensile(SSRT) tests. The results showed that the corrosion and SCC sensitivity of X80 steel decreased with increasing the magnetic field strength in the sterile environment. The SCC sensitivity was higher in the biotic environment inoculated with SRB, but it also decreased with increasing magnetic field strength, which was due to the magnetic field reduces microbial activity and promotes the formation of dense film layer. This work provided theoretical guidance on the prevention of SCC in pipeline steel under magnetic field and SRB coexistence.

Quantitative prediction model for the depth limit of oil accumulation in the deep carbonate rocks:A case study of Lower Ordovician in Tazhong area of Tarim Basin

With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration field.Hence,the extent to which oil exploration can be extended,and the prediction of the depth limit of oil accumulation(DLOA),are issues that have attracted significant attention in petroleum geology.Since it is difficult to characterize the evolution of the physical properties of the marine carbonate reservoir with burial depth,and the deepest drilling still cannot reach the DLOA.Hence,the DLOA cannot be predicted by directly establishing the relationship between the ratio of drilling to the dry layer and the depth.In this study,by establishing the relationships between the porosity and the depth and dry layer ratio of the carbonate reservoir,the relationships between the depth and dry layer ratio were obtained collectively.The depth corresponding to a dry layer ratio of 100%is the DLOA.Based on this,a quantitative prediction model for the DLOA was finally built.The results indicate that the porosity of the carbonate reservoir,Lower Ordovician in Tazhong area of Tarim Basin,tends to decrease with burial depth,and manifests as an overall low porosity reservoir in deep layer.The critical porosity of the DLOA was 1.8%,which is the critical geological condition corresponding to a 100%dry layer ratio encountered in the reservoir.The depth of the DLOA was 9,000 m.This study provides a new method for DLOA prediction that is beneficial for a deeper understanding of oil accumulation,and is of great importance for scientific guidance on deep oil drilling.

Calculating single layer production contribution of heavy oil commingled wells by analysis of aromatic parameters in whole-oil GC-MS

Traditional fluid production profile logging is not usually suitable for heavy-viscous crude oil wells.Biodegradation of heavy oil can lead to the loss of n-alkanes,and the use of chromatogram fingerprint techniques in studying the production contributions of single layers in heavy oil commingled wells has limitations.However,aromatic compounds are relatively well preserved.We took the heavy oil commingled wells of small layers NG55 and NG61 in the ninth area of the Gudong oil field as examples.Based on the principle of chromatography,the whole-oil GC-MS was used,and the aromatic parameters which have a strongly linear relationship with the ratio of mixed two end member oils were verified and selected in laboratory.Studies showed that the ratio of （1,4,6-＋ 2,3,6-trimethylnaphthalene） to 1,2,5-trimethylnaphthalene has a strongly linear relationship with the ratio of the mixed two end member oils （R2=0.992）.The oil contributions from single layers NG55 and NG61 in six commingled heavy oil wells were calculated using established charts and this relationship.The calculated results are consistent with the results of long period dynamic monitoring and logging interpretation in the study area and can provide a scientific basis for monitoring production performance and hierarchical management of reservoirs.The study provides a new geochemical method for calculation of the contributions of single layers in heavy oil commingled wells when conventional fluid production profile logging is not suitable.

Ultrastructural Studies on the Development of Oil Cells in Litsea pungens

The developmental process of oil cells in the shoot of Litsea pungens Hemsl. has been studied with transmission electron microscopy. According to the development of the three layers of cell wall, the developmental process could be divided into 4 stages. In stage 1, the cell wall consisted only of a primary (the outmost) cellulose layer, which might further be divided into two substages, the oil cell initial, and the vacuolizing oil cell. During this stage, there were some small electron translucent vesicles and dark osmiophilic droplets of variant sizes in the different-shaped plastids. It was observed that some dark and gray osmiophilic materials coalesced to vacuoles in the cytoplasm. In stage 2, a lamellated suberin layer accumulated inside the primary cellulose layer. In stage 3, a thicker and looser inner cellulose wall layer was formed gradually inside the suberin layer. Some dark osmiophilic droplets have been observed in this loose inner cellulose wall layer. The plasmodesmata were blocked up and became a special structure. Then, the big vacuole, which is the oil sac, was full of osmiophilic oil. In stage 4, the oil cell became matured and the cytoplasm disintegrated. The oil sac enveloped from plasmalemma was attached to the cupule, which was formed by the protuberance of the inner cellulose wall layer into the lumen. After the maturity of oil cell, the ground cytoplasm began to disintegrate and became electron opaque or exhibited in a disordered state, and the osmiophilic oil appeared light gray.

Seismic Technique for Studying Sedimentary Layer: Bohai Basin as an Example

The upper tertiary to quaternary is the main target layer for oil and gas exploitation in China's Mainland, especially crude oil production in the Bohai Basin accounts for approximately 40% of China’s crude oil production. Therefore, a study of the Upper Tertiary to Quaternary has important significance for science and practical applications. In this study, using the receiver function method, Ps and later phase extraction, the sedimentary thickness and an accurate estimate of velocity ratio can be obtained. The technique is simple, its calculation results are unique, and it can be applied to a study of the sedimentary layer. The technique is promising for oil and gas exploration.

Residual oil evolution based on displacement characteristic curve

The purpose of this study was to determine the displacement and dynamic distribution characteristics of the remaining oil in the two development stages of water flooding and subsequent alkaline surfactant polymer(ASP) flooding. The well pattern types in the water and ASP flooding stages are a longdistance determinant well pattern and short-distance five-point well pattern, respectively. The type A displacement characteristic curve can be obtained using the production data, and the slope of the straight-line section of the curve can reflect the displacement strength of the oil displacement agent. A numerical simulation was carried out based on the geological model. The results revealed that the injected water advances steadily with a large-distance determinant water-flooding well pattern. The single-well water production rate increases monotonically during water flooding. There is a significant positive correlation between the cumulative water-oil ratio and the formation parameter. Differential seepage between the oil and water phases is the main factor causing residual oil formation after water flooding, while the residual oil is still relatively concentrated. The effect of the chemical oildisplacement agent on improving the oil-water two-phase seepage flow has distinct stages during ASP flooding. The remaining oil production is extremely sporadic after ASP flooding.

Experimental Study on Heavy Oil Drag Reduction in Horizontal Pipelines by Water Annular Conveying

Transportation of heavy oil by the so-called water-ring technique is a very promising method by which pressure drop and pollution can be significantly reduced.Dedicated experiments have been carried out by changing the phase’s density,viscosity,velocity and interfacial tension to systematically analyze the characteristics of the water ring.On the basis of such experimental data,a mathematical model for pressure drop prediction has been introduced.This research shows that as long as the density of oil and water remains the same,a concentric water ring can effectively be formed.In such conditions,the oil-water viscosity difference has little effect on the shape of water ring,and it only affects the pressure drop.The greater the viscosity of heavy oil,the smaller the pressure drop of the oil-water ring transportation system.The influence of phases’interfacial tension on the characteristics and pressure drop of the heavy oil-water ring can be considered negligible.The pressure drop prediction model introduced on the basis of the Buckingham’s principle provides values in good agreement(95%)with the experimental data.