The uncertainty of nuclide libraries in the analysis of the gamma spectra of low-and intermediate-level radioactive waste(LILW)using existing methods produces unstable results.To address this problem,a novel spectral ...The uncertainty of nuclide libraries in the analysis of the gamma spectra of low-and intermediate-level radioactive waste(LILW)using existing methods produces unstable results.To address this problem,a novel spectral analysis method is proposed in this study.In this method,overlapping peaks are located using a continuous wavelet transform.An improved quadratic convolution method is proposed to calculate the widths of the peaks and establish a fourth-order filter model to estimate the Compton edge baseline with the overlapping peaks.Combined with the adaptive sensitive nonlinear iterative peak,this method can effectively subtracts the background.Finally,a function describing the peak shape as a filter is used to deconvolve the energy spectrum to achieve accurate qualitative and quantitative analyses of the nuclide without the aid of a nuclide library.Gamma spectrum acquisition experiments for standard point sources of Cs-137 and Eu-152,a segmented gamma scanning experiment for a 200 L standard drum,and a Monte Carlo simulation experiment for triple overlapping peaks using the closest energy of three typical LILW nuclides(Sb-125,Sb-124,and Cs-134)are conducted.The results of the experiments indicate that(1)the novel method and gamma vision(GV)with an accurate nuclide library have the same spectral analysis capability,and the peak area calculation error is less than 4%;(2)compared with the GV,the analysis results of the novel method are more stable;(3)the novel method can be applied to the activity measurement of LILW,and the error of the activity reconstruction at the equivalent radius is 2.4%;and(4)The proposed novel method can quantitatively analyze all nuclides in LILW without a nuclide library.This novel method can improve the accuracy and precision of LILW measurements,provide key technical support for the reasonable disposal of LILW,and ensure the safety of humans and the environment.展开更多
The southern part of the Eastern Desert of Egypt—about 30 km southwest of Abu-Ramad city—is mainly covered by ophiolitic rocks(Sul Hamed), island arc assemblage, younger granites(muscovite granites of Qash Amer and ...The southern part of the Eastern Desert of Egypt—about 30 km southwest of Abu-Ramad city—is mainly covered by ophiolitic rocks(Sul Hamed), island arc assemblage, younger granites(muscovite granites of Qash Amer and two mica granites of El Sela), and various acidic and basic dikes. Field, petrological, and geochemical studies indicate that the El Sela shear zone has been subject to hydrothermal and supergene alteration such as kaolinization, albitization, sericitization, and hematitization. It is invaded by quartz ENE–WSW veins associated with hydrothermal alteration accompanied by radioactive mineralization. The investigated younger granitic rocks had very low contents of compatible elements, such as Cr, Ni,and Co; and high contents of incompatible elements, such as Zr, and large ion lithophiles, such as Sr, especially in the El Sela shear zone. Major oxide and trace element analyses revealed calc-alkaline affinity and peraluminous character.These highly differentiated granitic rocks' lower Zr/Hf and higher Y/Ho than the normal ratio are consistent with hydrothermal alteration. Most samples had rare earth element(REE)-patterns with an M-type tetrad effect in the first and fourth segments and a W-type tetrad in the third segment. The average ∑REE in the studied granites was lower than the world granite average; the ratio of light to heavy REEs greater. The main radioactive, uranium-bearing, and uraniferous Fe and Mn minerals are uranothorite,autunite, uranophane and autunite as compounds, kasolite,columbite, xenotime, uranophane-bearing zircon and jarosite, silver-bearing pyrite, hematite, and autunite-bearing pyrolusite.展开更多
This paper describes a low-cost and fast method to evaluate gross α and β^(-) radioactivities in natural water based on an online high-purity germanium detector gamma measurement system.The major gamma activities in...This paper describes a low-cost and fast method to evaluate gross α and β^(-) radioactivities in natural water based on an online high-purity germanium detector gamma measurement system.The major gamma activities in natural water are provided by natural and artificial radionuclides such as ^(40) K,^(137)Cs,and radionuclides belonging to ^(238)U and ^(232)Th series.The main a emitters related to gamma emissions in natural water are ^(224)Ra(240.98 keV)and ^(226)Ra(186.21 keV),and the β^(-) emitters are ^(40) K(1460.85 keV),^(214)Bi(609.31 keV),^(208)Tl(583.19 keV),and ^(214)Pb(351.93 keV).The formula for gross α and β^(-) activity concentration is based on these radionuclides,and the short half-life decay products are considered in the calculation.The detection efficiency of the device across energy region(0–3 MeV)is obtained through Monte Carlo simulation,and a calibration experiment is conducted to verify the simulation results.Gamma radioactivity is measured continuously for 114 d in Pixian County and Dongfeng Canal located in the Zouma River,Chengdu,Sichuan Province,China.A comparison of the calculation results and monitoring data from the Sichuan Management and Monitoring Center Station of Radioactive Environment indicates that the percentage and absolute error of a activity concentration is lower than 53%and 0.02 Bq/L,respectively,and that of β-activity concentration is lower than 33.2%and 0.016 Bq/L,respectively.The method can rapidly determine gross α and β^(-) activity concentrations in natural water online.展开更多
Radioactivity measurements were carried out around Maumba and Nguluku villages, two of the proposed sites for titanium mining in the coastal area of Kenya. Samples of surface soils were analyzed using a HPGe gamma spe...Radioactivity measurements were carried out around Maumba and Nguluku villages, two of the proposed sites for titanium mining in the coastal area of Kenya. Samples of surface soils were analyzed using a HPGe gamma spectrometer. The average activity concentrations for 226Ra, 232Th and 40K are 20.9 ±7.6, 27.6 ± 9.1 and 69.5 ± 16.5 Bqkg–1, respectively. The absorbed dose rates in air, calculated on the basis of the measured activity concentrations, range from 9.8 to 50.0 nGyh-1, with an average of 29.2 nGyh-1. These values are below the global population-weighted mean, and they should be considered when planning appropriate monitoring and surveillance programmes during the mining operation, as well as the reclamation and restoration programmes after mining.展开更多
In experiments searching for rare signals,background events from the detector itself are some of the major factors limiting search sensitivity.Screening for ultra-low radioactive detector materials is becoming ever mo...In experiments searching for rare signals,background events from the detector itself are some of the major factors limiting search sensitivity.Screening for ultra-low radioactive detector materials is becoming ever more essential.We propose to develop a gaseous time projection chamber(TPC)with a Micromegas readout for radio screening.The TPC records three-dimensional trajectories of charged particles emitted from a flat sample placed in the active volume of the detector.The detector can distinguish the origin of an event and identify the particle types with information from trajectories,which significantly increases the screening sensitivity.For a particles from the sample surface,we observe that our proposed detector can reach a sensitivity higher than 100 l Bq m-2 within two days.展开更多
Liquid scintillator（LS） has been widely used in past and running neutrino experiments, and is expected also to be used in future experiments. Requirements on LS radio-purity have become higher and higher. Water extr...Liquid scintillator（LS） has been widely used in past and running neutrino experiments, and is expected also to be used in future experiments. Requirements on LS radio-purity have become higher and higher. Water extraction is a powerful method to remove soluble radioactive nuclei, and a mini-extraction station has been constructed. To evaluate the extraction efficiency and optimize the operation parameters, a setup to load radioactivity to LS and a laboratory scale setup to measure radioactivity using the ^212Bi-^212Po-^208Pb cascade decay have been developed. Experience from this laboratory study will be useful for the design of large scale water extraction plants and the optimization of working conditions in the future.展开更多
基金supported by the National Natural Science Foundation of China(Nos.12205190,11805121)the Science and Technology Commission of Shanghai Municipality(No.21ZR1435400).
文摘The uncertainty of nuclide libraries in the analysis of the gamma spectra of low-and intermediate-level radioactive waste(LILW)using existing methods produces unstable results.To address this problem,a novel spectral analysis method is proposed in this study.In this method,overlapping peaks are located using a continuous wavelet transform.An improved quadratic convolution method is proposed to calculate the widths of the peaks and establish a fourth-order filter model to estimate the Compton edge baseline with the overlapping peaks.Combined with the adaptive sensitive nonlinear iterative peak,this method can effectively subtracts the background.Finally,a function describing the peak shape as a filter is used to deconvolve the energy spectrum to achieve accurate qualitative and quantitative analyses of the nuclide without the aid of a nuclide library.Gamma spectrum acquisition experiments for standard point sources of Cs-137 and Eu-152,a segmented gamma scanning experiment for a 200 L standard drum,and a Monte Carlo simulation experiment for triple overlapping peaks using the closest energy of three typical LILW nuclides(Sb-125,Sb-124,and Cs-134)are conducted.The results of the experiments indicate that(1)the novel method and gamma vision(GV)with an accurate nuclide library have the same spectral analysis capability,and the peak area calculation error is less than 4%;(2)compared with the GV,the analysis results of the novel method are more stable;(3)the novel method can be applied to the activity measurement of LILW,and the error of the activity reconstruction at the equivalent radius is 2.4%;and(4)The proposed novel method can quantitatively analyze all nuclides in LILW without a nuclide library.This novel method can improve the accuracy and precision of LILW measurements,provide key technical support for the reasonable disposal of LILW,and ensure the safety of humans and the environment.
文摘The southern part of the Eastern Desert of Egypt—about 30 km southwest of Abu-Ramad city—is mainly covered by ophiolitic rocks(Sul Hamed), island arc assemblage, younger granites(muscovite granites of Qash Amer and two mica granites of El Sela), and various acidic and basic dikes. Field, petrological, and geochemical studies indicate that the El Sela shear zone has been subject to hydrothermal and supergene alteration such as kaolinization, albitization, sericitization, and hematitization. It is invaded by quartz ENE–WSW veins associated with hydrothermal alteration accompanied by radioactive mineralization. The investigated younger granitic rocks had very low contents of compatible elements, such as Cr, Ni,and Co; and high contents of incompatible elements, such as Zr, and large ion lithophiles, such as Sr, especially in the El Sela shear zone. Major oxide and trace element analyses revealed calc-alkaline affinity and peraluminous character.These highly differentiated granitic rocks' lower Zr/Hf and higher Y/Ho than the normal ratio are consistent with hydrothermal alteration. Most samples had rare earth element(REE)-patterns with an M-type tetrad effect in the first and fourth segments and a W-type tetrad in the third segment. The average ∑REE in the studied granites was lower than the world granite average; the ratio of light to heavy REEs greater. The main radioactive, uranium-bearing, and uraniferous Fe and Mn minerals are uranothorite,autunite, uranophane and autunite as compounds, kasolite,columbite, xenotime, uranophane-bearing zircon and jarosite, silver-bearing pyrite, hematite, and autunite-bearing pyrolusite.
基金the National Science Foundation of China(No.41774147)the National Key R&D Program of China(No.2017YFC0602105)+1 种基金the Science–Technology Support Plan Projects of Sichuan Province(No.2020YJ0334)the Sichuan Science and Technology Program(No.2020JDRC0108).
文摘This paper describes a low-cost and fast method to evaluate gross α and β^(-) radioactivities in natural water based on an online high-purity germanium detector gamma measurement system.The major gamma activities in natural water are provided by natural and artificial radionuclides such as ^(40) K,^(137)Cs,and radionuclides belonging to ^(238)U and ^(232)Th series.The main a emitters related to gamma emissions in natural water are ^(224)Ra(240.98 keV)and ^(226)Ra(186.21 keV),and the β^(-) emitters are ^(40) K(1460.85 keV),^(214)Bi(609.31 keV),^(208)Tl(583.19 keV),and ^(214)Pb(351.93 keV).The formula for gross α and β^(-) activity concentration is based on these radionuclides,and the short half-life decay products are considered in the calculation.The detection efficiency of the device across energy region(0–3 MeV)is obtained through Monte Carlo simulation,and a calibration experiment is conducted to verify the simulation results.Gamma radioactivity is measured continuously for 114 d in Pixian County and Dongfeng Canal located in the Zouma River,Chengdu,Sichuan Province,China.A comparison of the calculation results and monitoring data from the Sichuan Management and Monitoring Center Station of Radioactive Environment indicates that the percentage and absolute error of a activity concentration is lower than 53%and 0.02 Bq/L,respectively,and that of β-activity concentration is lower than 33.2%and 0.016 Bq/L,respectively.The method can rapidly determine gross α and β^(-) activity concentrations in natural water online.
文摘Radioactivity measurements were carried out around Maumba and Nguluku villages, two of the proposed sites for titanium mining in the coastal area of Kenya. Samples of surface soils were analyzed using a HPGe gamma spectrometer. The average activity concentrations for 226Ra, 232Th and 40K are 20.9 ±7.6, 27.6 ± 9.1 and 69.5 ± 16.5 Bqkg–1, respectively. The absorbed dose rates in air, calculated on the basis of the measured activity concentrations, range from 9.8 to 50.0 nGyh-1, with an average of 29.2 nGyh-1. These values are below the global population-weighted mean, and they should be considered when planning appropriate monitoring and surveillance programmes during the mining operation, as well as the reclamation and restoration programmes after mining.
基金Supported by the National Natural Science Foundation of China （Nos. 11105081, 11275110 and 11375103） and the National Energy Application Project For Research and Demonstration （No. 20131660315）.
基金the Ministry of Science and Technology of China(No.2016YFA0400302)the National Natural Sciences Foundation of China(Nos.11775142 and U1965201)the Chinese Academy of Sciences Center for Excellence in Particle Physics(CCEPP).
文摘In experiments searching for rare signals,background events from the detector itself are some of the major factors limiting search sensitivity.Screening for ultra-low radioactive detector materials is becoming ever more essential.We propose to develop a gaseous time projection chamber(TPC)with a Micromegas readout for radio screening.The TPC records three-dimensional trajectories of charged particles emitted from a flat sample placed in the active volume of the detector.The detector can distinguish the origin of an event and identify the particle types with information from trajectories,which significantly increases the screening sensitivity.For a particles from the sample surface,we observe that our proposed detector can reach a sensitivity higher than 100 l Bq m-2 within two days.
基金Supported by The Strategic Priority Research Program of the Chinese Academy of Sciences(XDA10010500)Natural Science Foundation of China(11390384)
文摘Liquid scintillator（LS） has been widely used in past and running neutrino experiments, and is expected also to be used in future experiments. Requirements on LS radio-purity have become higher and higher. Water extraction is a powerful method to remove soluble radioactive nuclei, and a mini-extraction station has been constructed. To evaluate the extraction efficiency and optimize the operation parameters, a setup to load radioactivity to LS and a laboratory scale setup to measure radioactivity using the ^212Bi-^212Po-^208Pb cascade decay have been developed. Experience from this laboratory study will be useful for the design of large scale water extraction plants and the optimization of working conditions in the future.
