Nanocellulose,a natural polymeric nanomaterial,has attracted significant attention in enhanced oil recovery(EOR)applications due to its abundance,nanoscale,high oil-water interfacial adsorption ef-ficiency.In this stu...Nanocellulose,a natural polymeric nanomaterial,has attracted significant attention in enhanced oil recovery(EOR)applications due to its abundance,nanoscale,high oil-water interfacial adsorption ef-ficiency.In this study,surface-functionalized cellulose nanocrystals(SF-CNCs)were prepared via hy-drochloric acid hydrolysis and chemical modification,with adaptable nanosize and considerable dispersion stability in low-permeability reservoirs.The SF-CNCs were structurally characterized by FT-IR,Cryo-TEM,which have a diameter of 5-10 nm and a length of 100-200 nm.The SF-CNC dispersions possessed higher stability and stronger salt-tolerance than those of corresponding CNC dispersions,due to the strong hydrophilicity of the sulfonic acid group.It was synergistically used with a non-ionic surfactant(APG1214)to formulate a combined flooding system(0.1 wt%SF-CNC+0.2 wt%APG1214).The combined flooding system exhibits strong emulsification stability,low oil-water interfacial tension of o.03 mN/m,and the ability to alter the wettability for oil-wetting rocks.Furthermore,the combined system was_able to provide an optimum EOR efficiency of 20.2%in low-permeability cores with 30.13×10^(-3)μm^(2).Notably.it can enlarge the sweep volume and increase the displacement efficiency simultaneously.Overall,the newly formulated nanocellulose/surfactant combined system exhibits a remarkable EoR performance in low-permeability reservoirs.展开更多
In recent years,supercritical CO_(2)flooding has become an effective method for developing lowpermeability reservoirs.In supercritical CO_(2)flooding different factors influence the mechanism of its displacement proce...In recent years,supercritical CO_(2)flooding has become an effective method for developing lowpermeability reservoirs.In supercritical CO_(2)flooding different factors influence the mechanism of its displacement process for oil recovery.Asynchronous injection-production modes can use supercritical CO_(2)to enhance oil recovery but may also worsen the injection capacity.Cores with high permeability have higher oil recovery rates and better injection capacity,however,gas channeling occurs.Supercritical CO_(2)flooding has a higher oil recovery at high pressure levels,which delays the occurrence of gas channeling.Conversely,gas injection has lower displacement efficiency but better injection capacity at the high water cut stage.This study analyzes the displacement characteristics of supercritical CO_(2)flooding with a series of experiments under different injection and production parameters.Experimental results show that the gas breakthrough stage has the fastest oil production and the supercritical CO_(2)injection capacity variation tendency is closely related to the gas-oil ratio.Further experiments show that higher injection rates represent significant ultimate oil recovery and injection index,providing a good reference for developing low-permeability reservoirs.展开更多
The segmented water control technology for bottom water reservoirs can effectively delay the entry of bottom water and adjust the production profile.To clarify the impact of different methods on horizontal well produc...The segmented water control technology for bottom water reservoirs can effectively delay the entry of bottom water and adjust the production profile.To clarify the impact of different methods on horizontal well production with different reservoir conditions and to provide theoretical support for the scientific selection of methods for bottom water reservoirs,a numerical simulation method is presented in this study,which is able to deal with wellbore reservoir coupling under screen tube,perforation,and ICD(Inflow Control Device)completion.Assuming the geological characteristics of the bottom-water conglomerate reservoir in the Triassic Formation of the Tahe Block 9 as a test case,the three aforementioned completion methods are tested to predict the transient production characteristics.The impact of completion parameters,reservoir permeability,bottom-water energy,and individual well control on the time to encounter water in horizontal wells(during a water-free production period)is discussed.A boundary chart for the selection of completion methods is introduced accordingly.The results show that the optimized ICD completion development effect for heterogeneous reservoirs is the best,followed by optimized perforation completion.Permeability is the main factor affecting the performances of completion methods,while bottom water energy and single well controlled reserves have a scarce impact.The average permeability of the reservoir is less than 500 mD,and ICD has the best water control effect.If the permeability is greater than 500 mD,the water control effect of perforation completion becomes a better option.展开更多
By using drilling,high-precision 3 D seismic data,data of geochemistry,logging and testing,the reservoir characteristics and accumulation conditions of the KL6-1 lithologic oilfield in the Laibei Low Uplift in the Boh...By using drilling,high-precision 3 D seismic data,data of geochemistry,logging and testing,the reservoir characteristics and accumulation conditions of the KL6-1 lithologic oilfield in the Laibei Low Uplift in the Bohai Sea are examined comprehensively.The study shows that:KL6-1 oilfield is a monolithic,high-quality,large-scale Neogene lithologic oilfield featuring shallow reservoir depth,high productivity,concentrated oil-bearing intervals,large oil-bearing area,and high reserve abundance;hydrocarbon source supply from two directions provides a sufficient material basis for the formation of large oil field;two types of"inherited structural ridge"developed under the effect of block rotation,late active faults formed by Neotectonic movement,and widely distributed contiguous sand bodies provide an efficient oil and gas transportation system for the large-scale accumulation of oil and gas;contiguous channel and lacustrine lowstand system sand bodies developed in low accommodation condition provide the basic condition for the formation of large-scale lithologic traps;deep formations structural ridge,faults(dominant migration pathways)and large-scale superimposed contiguous sand bodies constitute a"vine type"oil and gas migration and accumulation system in the Laibei Low Uplift,which is conducive to the formation of large-scale and high-abundance lithologic reservoir in this area.The successful discovery of KL6-1,100 million ton reserve order lithologic oil field,has revealed the exploration potential of Neogene large lithologic reservoirs in Bohai Sea,expanded the exploration field,and also has certain reference significance for the exploration of large lithologic reservoirs in similar areas.展开更多
Natural gas hydrates(NGHs)are globally recognized as an important type of strategic alternative energy due to their high combustion efficiency,cleanness,and large amounts of resources.The NGHs reservoirs in the South ...Natural gas hydrates(NGHs)are globally recognized as an important type of strategic alternative energy due to their high combustion efficiency,cleanness,and large amounts of resources.The NGHs reservoirs in the South China Sea(SCS)mainly consist of clayey silts.NGHs reservoirs of this type boast the largest distribution range and the highest percentage of resources among NGHs reservoirs in the world.However,they are more difficult to exploit than sandy reservoirs.The China Geological Survey successfully carried out two NGHs production tests in the Shenhu Area in the northern SCS in 2017 and 2020,setting multiple world records,such as the longest gas production time,the highest total gas production,and the highest average daily gas production,as well as achieving a series of innovative theoretical results.As suggested by the in-depth research on the two production tests,key factors that restrict the gas production efficiency of hydrate dissociation include reservoir structure characterization,hydrate phase transition,multiphase seepage and permeability enhancement,and the simulation and regulation of production capacity,among which the hydrate phase transition and seepage mechanism are crucial.Study results reveal that the hydrate phase transition in the SCS is characterized by low dissociation temperature,is prone to produce secondary hydrates in the reservoirs,and is a complex process under the combined effects of the seepage,stress,temperature,and chemical fields.The multiphase seepage is controlled by multiple factors such as the physical properties of unconsolidated reservoirs,the hydrate phase transition,and exploitation methods and is characterized by strong methane adsorption,abrupt changes in absolute permeability,and the weak flow capacity of gas.To ensure the long-term,stable,and efficient NGHs exploitation in the SCS,it is necessary to further enhance the reservoir seepage capacity and increase gas production through secondary reservoir stimulation based on initial reservoir stimulation.With the constant progress in the NGHs industrialization,great efforts should be made to tackle the difficulties,such as determining the micro-change in temperature and pressure,the response mechanisms of material-energy exchange,the methods for efficient NGHs dissociation,and the boundary conditions for the formation of secondary hydrates in the large-scale,long-term gas production.展开更多
A smart response fluid was designed and developed to overcome the challenges of gas channeling during CO_(2)flooding in low-permeability,tight oil reservoirs.The fluid is based on Gemini surfactant with self-assembly ...A smart response fluid was designed and developed to overcome the challenges of gas channeling during CO_(2)flooding in low-permeability,tight oil reservoirs.The fluid is based on Gemini surfactant with self-assembly capabilities,and the tertiary amine group serves as the response component.The responsive characteristics and corresponding mechanism of the smart fluid during the interaction with CO_(2)/oil were studied,followed by the shear characteristics of the thickened aggregates obtained by the smart fluid responding to CO_(2).The temperature and salt resistance of the smart fluid and the aggregates were evaluated,and their feasibility and effectiveness in sweep-controlling during the CO_(2)flooding were confirmed.This research reveals:(1)Thickened aggregates could be assembled since the smart fluid interacted with CO_(2).When the mass fraction of the smart fluid ranged from 0.05%to 2.50%,the thickening ratio changed from 9 to 246,with viscosity reaching 13 to 3100 mPas.As a result,the sweep efficiency in low-permeability core models could be increased in our experiments.(2)When the smart fluid(0.5%to 1.0%)was exposed to simulated oil,the oil/fluid interfacial tension decreased to the level of 1×10^(-2)mN/m.Furthermore,the vesicle-like micelles in the smart fluid completely transformed into spherical micelles when the fluid was exposed to simulated oil with the saturation greater than 10%.As a result,the smart fluid could maintain low oil/fluid interfacial tension,and would not be thickened after oil exposure.(3)When the smart fluid interacted with CO_(2),the aggregates showed self-healing properties in terms of shear-thinning,static-thickening,and structural integrity after several shear-static cycles.Therefore,this fluid is safe to be placed in deep reservoirs.(4)The long-term temperature and salt resistance of the smart fluid and thickened aggregates have been confirmed.展开更多
基金the China National Postdoctoral Program for Innovative Talents(Bx20200386)China Postdoctoral Science Foundation(2021M703586)+1 种基金Key Program of National Natural Science Foundation of China(52130401)National Natural Science Foundation of China(52204064,52104055)for financial support.
文摘Nanocellulose,a natural polymeric nanomaterial,has attracted significant attention in enhanced oil recovery(EOR)applications due to its abundance,nanoscale,high oil-water interfacial adsorption ef-ficiency.In this study,surface-functionalized cellulose nanocrystals(SF-CNCs)were prepared via hy-drochloric acid hydrolysis and chemical modification,with adaptable nanosize and considerable dispersion stability in low-permeability reservoirs.The SF-CNCs were structurally characterized by FT-IR,Cryo-TEM,which have a diameter of 5-10 nm and a length of 100-200 nm.The SF-CNC dispersions possessed higher stability and stronger salt-tolerance than those of corresponding CNC dispersions,due to the strong hydrophilicity of the sulfonic acid group.It was synergistically used with a non-ionic surfactant(APG1214)to formulate a combined flooding system(0.1 wt%SF-CNC+0.2 wt%APG1214).The combined flooding system exhibits strong emulsification stability,low oil-water interfacial tension of o.03 mN/m,and the ability to alter the wettability for oil-wetting rocks.Furthermore,the combined system was_able to provide an optimum EOR efficiency of 20.2%in low-permeability cores with 30.13×10^(-3)μm^(2).Notably.it can enlarge the sweep volume and increase the displacement efficiency simultaneously.Overall,the newly formulated nanocellulose/surfactant combined system exhibits a remarkable EoR performance in low-permeability reservoirs.
基金financial support from the National Natural Science Foundation of China(No.51904324,51974348,U19B6003)
文摘In recent years,supercritical CO_(2)flooding has become an effective method for developing lowpermeability reservoirs.In supercritical CO_(2)flooding different factors influence the mechanism of its displacement process for oil recovery.Asynchronous injection-production modes can use supercritical CO_(2)to enhance oil recovery but may also worsen the injection capacity.Cores with high permeability have higher oil recovery rates and better injection capacity,however,gas channeling occurs.Supercritical CO_(2)flooding has a higher oil recovery at high pressure levels,which delays the occurrence of gas channeling.Conversely,gas injection has lower displacement efficiency but better injection capacity at the high water cut stage.This study analyzes the displacement characteristics of supercritical CO_(2)flooding with a series of experiments under different injection and production parameters.Experimental results show that the gas breakthrough stage has the fastest oil production and the supercritical CO_(2)injection capacity variation tendency is closely related to the gas-oil ratio.Further experiments show that higher injection rates represent significant ultimate oil recovery and injection index,providing a good reference for developing low-permeability reservoirs.
文摘The segmented water control technology for bottom water reservoirs can effectively delay the entry of bottom water and adjust the production profile.To clarify the impact of different methods on horizontal well production with different reservoir conditions and to provide theoretical support for the scientific selection of methods for bottom water reservoirs,a numerical simulation method is presented in this study,which is able to deal with wellbore reservoir coupling under screen tube,perforation,and ICD(Inflow Control Device)completion.Assuming the geological characteristics of the bottom-water conglomerate reservoir in the Triassic Formation of the Tahe Block 9 as a test case,the three aforementioned completion methods are tested to predict the transient production characteristics.The impact of completion parameters,reservoir permeability,bottom-water energy,and individual well control on the time to encounter water in horizontal wells(during a water-free production period)is discussed.A boundary chart for the selection of completion methods is introduced accordingly.The results show that the optimized ICD completion development effect for heterogeneous reservoirs is the best,followed by optimized perforation completion.Permeability is the main factor affecting the performances of completion methods,while bottom water energy and single well controlled reserves have a scarce impact.The average permeability of the reservoir is less than 500 mD,and ICD has the best water control effect.If the permeability is greater than 500 mD,the water control effect of perforation completion becomes a better option.
基金Supported by the China National Science and Technology Major Project(2016ZX05024-003)。
文摘By using drilling,high-precision 3 D seismic data,data of geochemistry,logging and testing,the reservoir characteristics and accumulation conditions of the KL6-1 lithologic oilfield in the Laibei Low Uplift in the Bohai Sea are examined comprehensively.The study shows that:KL6-1 oilfield is a monolithic,high-quality,large-scale Neogene lithologic oilfield featuring shallow reservoir depth,high productivity,concentrated oil-bearing intervals,large oil-bearing area,and high reserve abundance;hydrocarbon source supply from two directions provides a sufficient material basis for the formation of large oil field;two types of"inherited structural ridge"developed under the effect of block rotation,late active faults formed by Neotectonic movement,and widely distributed contiguous sand bodies provide an efficient oil and gas transportation system for the large-scale accumulation of oil and gas;contiguous channel and lacustrine lowstand system sand bodies developed in low accommodation condition provide the basic condition for the formation of large-scale lithologic traps;deep formations structural ridge,faults(dominant migration pathways)and large-scale superimposed contiguous sand bodies constitute a"vine type"oil and gas migration and accumulation system in the Laibei Low Uplift,which is conducive to the formation of large-scale and high-abundance lithologic reservoir in this area.The successful discovery of KL6-1,100 million ton reserve order lithologic oil field,has revealed the exploration potential of Neogene large lithologic reservoirs in Bohai Sea,expanded the exploration field,and also has certain reference significance for the exploration of large lithologic reservoirs in similar areas.
基金funded by a key project of the National Natural Science Foundation of China entitled“Multi-Field Spatio-Temporal Evolutionary Pattern of Hydrate Phase Transition and Seepage of NGHs Reservoirs”(51991365)。
文摘Natural gas hydrates(NGHs)are globally recognized as an important type of strategic alternative energy due to their high combustion efficiency,cleanness,and large amounts of resources.The NGHs reservoirs in the South China Sea(SCS)mainly consist of clayey silts.NGHs reservoirs of this type boast the largest distribution range and the highest percentage of resources among NGHs reservoirs in the world.However,they are more difficult to exploit than sandy reservoirs.The China Geological Survey successfully carried out two NGHs production tests in the Shenhu Area in the northern SCS in 2017 and 2020,setting multiple world records,such as the longest gas production time,the highest total gas production,and the highest average daily gas production,as well as achieving a series of innovative theoretical results.As suggested by the in-depth research on the two production tests,key factors that restrict the gas production efficiency of hydrate dissociation include reservoir structure characterization,hydrate phase transition,multiphase seepage and permeability enhancement,and the simulation and regulation of production capacity,among which the hydrate phase transition and seepage mechanism are crucial.Study results reveal that the hydrate phase transition in the SCS is characterized by low dissociation temperature,is prone to produce secondary hydrates in the reservoirs,and is a complex process under the combined effects of the seepage,stress,temperature,and chemical fields.The multiphase seepage is controlled by multiple factors such as the physical properties of unconsolidated reservoirs,the hydrate phase transition,and exploitation methods and is characterized by strong methane adsorption,abrupt changes in absolute permeability,and the weak flow capacity of gas.To ensure the long-term,stable,and efficient NGHs exploitation in the SCS,it is necessary to further enhance the reservoir seepage capacity and increase gas production through secondary reservoir stimulation based on initial reservoir stimulation.With the constant progress in the NGHs industrialization,great efforts should be made to tackle the difficulties,such as determining the micro-change in temperature and pressure,the response mechanisms of material-energy exchange,the methods for efficient NGHs dissociation,and the boundary conditions for the formation of secondary hydrates in the large-scale,long-term gas production.
基金Supported by the PetroChina Science and Technology Major Project(2019-E2607)PetroChina Exploration and Production Company Science and Technology Project(KS2020-01-09).
文摘A smart response fluid was designed and developed to overcome the challenges of gas channeling during CO_(2)flooding in low-permeability,tight oil reservoirs.The fluid is based on Gemini surfactant with self-assembly capabilities,and the tertiary amine group serves as the response component.The responsive characteristics and corresponding mechanism of the smart fluid during the interaction with CO_(2)/oil were studied,followed by the shear characteristics of the thickened aggregates obtained by the smart fluid responding to CO_(2).The temperature and salt resistance of the smart fluid and the aggregates were evaluated,and their feasibility and effectiveness in sweep-controlling during the CO_(2)flooding were confirmed.This research reveals:(1)Thickened aggregates could be assembled since the smart fluid interacted with CO_(2).When the mass fraction of the smart fluid ranged from 0.05%to 2.50%,the thickening ratio changed from 9 to 246,with viscosity reaching 13 to 3100 mPas.As a result,the sweep efficiency in low-permeability core models could be increased in our experiments.(2)When the smart fluid(0.5%to 1.0%)was exposed to simulated oil,the oil/fluid interfacial tension decreased to the level of 1×10^(-2)mN/m.Furthermore,the vesicle-like micelles in the smart fluid completely transformed into spherical micelles when the fluid was exposed to simulated oil with the saturation greater than 10%.As a result,the smart fluid could maintain low oil/fluid interfacial tension,and would not be thickened after oil exposure.(3)When the smart fluid interacted with CO_(2),the aggregates showed self-healing properties in terms of shear-thinning,static-thickening,and structural integrity after several shear-static cycles.Therefore,this fluid is safe to be placed in deep reservoirs.(4)The long-term temperature and salt resistance of the smart fluid and thickened aggregates have been confirmed.