Evaluation of the coupled impact of silicon oxide nanoparticles and low-salinity water on the wettability alteration of Berea sandstones

This study investigated experimentally the coupled effects of hydrophilic SiO_(2) nanoparticles(NPs)and low-salinity water(LSW)on the wettability of synthetic clay-free Berea sandstone.Capillary pressure,interfacial tension(IFT),contact angle,Zeta potential,and dynamic displacement measurements were performed at various NP mass fractions and brine salinities.The U.S.Bureau of Mines(USBM)index was used to quantify the wettability alteration.Furthermore,the NP stability and retention and the effect of enhanced oil recovery by nanofluid were examined.The results showed that LSW immiscible displacement with NPs altered the wettability toward more water wet.With the decreasing brine salinity and increasing NP mass fraction,the IFT and contact angle decreased.The wettability alteration intensified most as the brine salinity decreased to 4000 mg/L and the NP mass fraction increased to 0.075%.Under these conditions,the resulting incremental oil recovery factor was approximately 13 percentage points.When the brine salinity was 4000 mg/L and the NP mass fraction was 0.025%,the retention of NPs caused the minimum damage to permeability.

Effect of CO_(2)flooding in an oil reservoir with strong bottom-water drive in the Tahe Oilfield,Tarim Basin,Northwest China

The dissolution and diffusion of CO_(2)in oil and water and its displacement mechanism were investigated by laboratory experiment and numerical simulation for Block 9 in the Tahe oilfield,a sandstone oil reservoir with strong bottom-water drive in Tarim Basin,Northwest China.Such parameters were analyzed as solubility ratio of CO_(2)in oil,gas and water,interfacial tension,in-situ oil viscosity distribution,remaining oil saturation distribution,and oil compositions.The results show that CO_(2)flooding could control water coning and increase oil production.In the early stage of the injection process,CO_(2)expanded vertically due to gravity differentiation,and extended laterally under the action of strong bottom water in the intermediate and late stages.The CO_(2)got enriched and extended at the oil-water interface,forming a high interfacial tension zone,which inhibited the coning of bottom water to some extent.A miscible region with low interfacial tension formed at the gas injection front,which reduced the in-situ oil viscosity by about 50%.The numerical simulation results show that enhanced oil recovery(EOR)is estimated at 5.72%and the oil exchange ratio of CO_(2)is 0.17 t/t.

Combined imbibition system with black nanosheet and low-salinity water for improving oil recovery in tight sandstone reservoirs

Nanomaterials and low-salinity water(LSW)are two popular enhanced oil recovery(EOR)methods that have been widely studied in recent years.The former is used for in-depth conformance improvement and the latter for microscopic oil displacement(by altering the potential and contact angle).However,there are few literature on combining them to achieve synergistic effects,especially for tight sandstone res-ervoirs.Based on the reservoir conditions of the Jimusar Oilfield,this study investigated the oil recovery mechanism of the combined imbibition system,which was composed of black nanosheet(BN)and LSW.Its performances including decreasing interfacial tension,emulsification,and wettability alterations were evaluated.The imbibition differences between the single system of BN and LSW and the combined BN-LsW imbibition system were then compared.Results showed that the combined imbibition system had a better emulsification effect on the crude oil and could also alter the wettability of the core surface.Moreover,the combined system could increase both the imbibition rate and the ultimate oil recovery.The nuclear magnetic T2 spectrum also indicated that the addition of black nanosheets could divert more fluid into small pores and thus improve the microscopic sweep efficiency.

Performance of low-salinity water flooding for enhanced oil recovery improved by SiO_2 nanoparticles

Low-salinity water injection has been utilized as a promising method for oil recovery in recent years. Low-salinity water flooding changes the ion composition or brine salinity for improving oil recovery. Recently, the application of nanoparticles with low-salinity water flooding has shown remarkable results in enhanced oil recovery(EOR). Many studies have been performed on the effect of nanofluids on EOR mechanisms. Their results showed that nanofluids can improve oil recovery when used in low-salinity water flooding. In this work, the effects of injection of low-salinity water and low-salinity nanofluid(prepared by adding SiO_2 nanoparticles to low-salinity water) on oil recovery were investigated. At first, the effects of ions were investigated with equal concentrations in low-salinity water flooding. The experimental results showed that the monovalent ions had better performance than the divalent ions because of them having more negative zeta potential and less ionic strength. Also, low-salinity water flooding recovered 6.1% original oil in place(OOIP) more than the high-salinity flooding. Contact angle measurements demonstrated that low-salinity water could reduce the contact angle between oil and water. Then in the second stage, experiments were continued by adding SiO_2 nanoparticles to the K+ solution which had the highest oil recovery at the first stage. The experimental results illustrated that the addition of Si02 nanoparticles up to 0.05 wt% increased oil recovery by about 4% OOIP more than the low-salinity water flooding.

How much would silica nanoparticles enhance the performance of low-salinity water flooding?

Nanofluids and low-salinity water(LSW)flooding are two novel techniques for enhanced oil recovery.Despite some efforts on investigating benefits of each method,the pros and cons of their combined application need to be evaluated.This work sheds light on performance of LSW augmented with nanoparticles through examining wettability alteration and the amount of incremental oil recovery during the displacement process.To this end,nanofluids were prepared by dispersing silica nanoparticles(0.1 wt%,0.25 wt%,0.5 wt% and 0.75 wt%)in 2,10,20 and 100 times diluted samples of Persian Gulf seawater.Contact angle measurements revealed a crucial role of temperature,where no wettability alteration occurred up to 80 ℃.Also,an optimum wettability state(with contact angle 22°)was detected with a 20 times diluted sample of seawater augmented with 0.25 wt% silica nanoparticles.Also,extreme dilution(herein 100 times)will be of no significance.Throughout micromodel flooding,it was found that in an oil-wet condition,a combination of silica nanoparticles dispersed in 20 times diluted brine had the highest displacement efficiency compared to silica nanofluids prepared with deionized water.Finally,by comparing oil recoveries in both water-and oil-wet micromodels,it was concluded that nanoparticles could enhance applicability of LSW via strengthening wettability alteration toward a favorable state and improving the sweep efficiency.

Efficiency of enhanced oil recovery by injection of low-salinity water in barium-containing carbonate reservoirs

When low-salinity water containing sulfate ions is injected into carbonate reservoirs, rock dissolution and in situ precipitation occur, altering rock permeability and wettability. Particularly, when barium ions are present in formation water,they react chemically with SO;, and BaSO;is precipitated. These reactions can cause a serious impact on the efficiency of enhanced oil recovery（EOR）. Therefore, the main purpose of this study was to identify EOR efficiency induced by lowsalinity waterflooding（LSWF） when Ba;is present in carbonate reservoirs. From the experimental results, it was confirmed that the permeability calculated by the measured pressure difference was improved because of rock dissolution predominating over in situ precipitation for the case of low Ba;concentrations. In the analysis of wettability alteration through the measurements of relative permeabilities before and after LSWF, the higher Ba;concentration case consumed more SO;in precipitating the BaSO;, resulting in weaker wettability alteration due to the reduction of sulfate activity.These phenomena ultimately influenced EOR efficiency, i.e., the oil recovery was greater for the lower Ba;concentration.

Stochastic and upscaled analytical modeling of fines migration in porous media induced by low-salinity water injection

Fines migration induced by injection of low-salinity water(LSW) into porous media can lead to severe pore plugging and consequent permeability reduction. The deepbed filtration(DBF) theory is used to model the aforementioned phenomenon, which allows us to predict the effluent concentration history and the distribution profile of entrapped particles. However, the previous models fail to consider the movement of the waterflood front. In this study, we derive a stochastic model for fines migration during LSW flooding, in which the Rankine-Hugoniot condition is used to calculate the concentration of detached particles behind and ahead of the moving water front. A downscaling procedure is developed to determine the evolution of pore-size distribution from the exact solution of a large-scale equation system. To validate the proposed model,the obtained exact solutions are used to treat the laboratory data of LSW flooding in artificial soil-packed columns. The tuning results show that the proposed model yields a considerably higher value of the coefficient of determination, compared with the previous models, indicating that the new model can successfully capture the effect of the moving water front on fines migration and precisely match the effluent history of the detached particles.

Systematic improvement in Tong's B-type water drive method

Tong's B-type water drive method was proposed as early as the 1970s and has been widely applied in the dynamic prediction and effective evaluation of oilfield development.Through extensive applications and studies,many researchers found that the statistical constants in the formula of the Tong's B-type water drive method(also referred to as the Tong's B-type formula)are not applicable to multiple types of reservoirs,especially low-permeability ones,due to the limited range of reservoir types when the formula was conceived.Moreover,they put forward suggestions to improve the Tong's B-type formula,most of which focused on the research and calculation of the first constant in the formula.For oilfields in the development stages of high or ultra-high water cuts,it is widely accepted that different types of reservoirs have different limit water cuts.This understanding naturally makes it necessary to further modify the Tong's B-type formula.It is practically significant to establish the water drive formula and cross plot considering that the two constants in the formula vary with reservoir type.By analyzing the derivation process and conditions of the Tong's B-type formula,this study points out two key problems,i.e.,the two constants 7.5 and 1.69 in the formula are not applicable to all types of reservoir.Given this,this study establishes a function between key reservoir parameters and the first constant and another function between key reservoir parameters and recovery efficiency.Based on the established two functions and considering that different types of oil reservoir have different limit water cuts,this study develops an improved Tong's B-type formula and prepares the corresponding improved cross plot.The results of this study will improve the applicability and accuracy of Tong's B-type water drive method in predicting the trend of water cut increasing for different types of oil reservoirs.

Long-term operation optimization of circulating cooling water systems under fouling conditions

Fouling caused by excess metal ions in hard water can negatively impact the performance of the circulating cooling water system(CCWS)by depositing ions on the heat exchanger's surface.Currently,the operation optimization of CCWS often prioritizes short-term flow velocity optimization for minimizing power consumption,without considering fouling.However,low flow velocity promotes fouling.Therefore,it's crucial to balance fouling and energy/water conservation for optimal CCWS long-term operation.This study proposes a mixed-integer nonlinear programming(MINLP)model to achieve this goal.The model considers fouling in the pipeline,dynamic concentration cycle,and variable frequency drive to optimize the synergy between heat transfer,pressure drop,and fouling.By optimizing the concentration cycle of the CCWS,water conservation and fouling control can be achieved.The model can obtain the optimal operating parameters for different operation intervals,including the number of pumps,frequency,and valve local resistance coefficient.Sensitivity experiments on cycle and environmental temperature reveal that as the cycle increases,the marginal benefits of energy/water conservation decrease.In periods with minimal impact on fouling rate,energy/water conservation can be achieved by increasing the cycle while maintaining a low fouling rate.Overall,the proposed model has significant energy/water saving effects and can comprehensively optimize the CCWS through its incorporation of fouling and cycle optimization.

Observational characteristics and dynamic mechanism of low-salinity water lens for the offshore detachment of the Changjiang River diluted water in August 2006

The Changjiang River diluted water(CDW)spreads into the East China Sea(ECS)primarily in a plume pattern,although in some years,low-salinity water lenses(LSWLs)detach from the main body of the CDW.In-situ observations indicate that in August 2006,a LSWL detached from the main body of the CDW near the river mouth.In this paper,the effects of winds,tides,baroclinity and upwelling on LSWLs are explored with a threedimensional model.The results show that:(1)winds play a crucial role in these detachment events because windinduced northerly Eulerian residual currents impose an uneven force on the CDW and cut it off,thus forming a LSWL;(2)upwelling carries high-salinity water from the lower layer to the upper layer,truncating the low-salinity water tongue vertically,which is conducive to the detachment and maintenance of LSWLs;and(3)upwelling during the evolution of a LSWL is caused by the combined effects of winds and tides.The influences of windinduced upwelling are mainly near the shore,whereas the upwelling along the 30 m isobath is predominantly affected by tides,with the effect increasing from neap tide to spring tide.

Activating solution gas drive as an extra oil production mechanism after carbonated water injection

Enhanced oil recovery(EOR)methods are mostly based on different phenomena taking place at the interfaces between fluid–fluid and rock–fluid phases.Over the last decade,carbonated water injection(CWI)has been considered as one of the multi-objective EOR techniques to store CO2 in the hydrocarbon bearing formations as well as improving oil recovery efficiency.During CWI process,as the reservoir pressure declines,the dissolved CO2 in the oil phase evolves and gas nucleation phenomenon would occur.As a result,it can lead to oil saturation restoration and subsequently,oil displacement due to the hysteresis effect.At this condition,CO2 would act as insitu dissolved gas into the oil phase,and play the role of an artificial solution gas drive(SGD).In this study,the effect of SGD as an extra oil recovery mechanism after secondary and tertiary CWI(SCWI-TCWI)modes has been experimentally investigated in carbonate rocks using coreflood tests.The depressurization tests resulted in more than 25%and 18%of original oil in place(OOIP)because of the SGD after SCWI and TCWI tests,respectively.From the ultimate enhanced oil recovery point of view,the efficiency of SGD was observed to be more than one-third of that of CWI itself.Furthermore,the pressure drop data revealed that the system pressure depends more on the oil production pattern than water production.

Spatio-temporal Changes in Water Conservation Ecosystem Service During 1990–2019 in the Tumen River Basin, Northeast China

The water conservation(WC) function of ecosystems is related to regional ecological security and the sustainable development of water resources, and the assessment of WC and its influencing factors is crucial for ecological and water resource management.The Tumen River Basin(TRB) is located in the core of the Northeast Asian ecological network and has been experiencing severe ecological crises and water shortages in recent years due to climate change and human activities. However, these crises have not been fully revealed to the extent that corresponding scientific measures are lacking. This study analyzed the spatial and temporal evolution characteristics and drivers of WC in the TRB from 1990 to 2019 based on the water yield module of the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST) model. The results showed that: 1) under the combined effect of nature and socioeconomics, the WC depth of the TRB has slowly increased at a rate of 0.11 mm/yr in the past 30 years, with an average WC depth of 36.14 mm. 2) The main driving factor of the spatial variation in WC is precipitation, there is a significant interaction between precipitation and velocity, the interaction between each factor is higher than the contribution of a single factor, and the interactions between factors all have nonlinear enhancement and two-factor enhancement. 3) Among the seven counties and municipalities in the study area, the southern part of Helong City and the southeastern part of Longjing City are extremely important areas for WC(> 75 mm), and they should be regarded as regional water resources and ecological priority protection areas. It is foreseen that under extreme climate conditions in the future, the WC of the watershed is under great potential threat, and protection measures such as afforestation and forestation should begin immediately. Furthermore, the great interannual fluctuations in WC depth may place more stringent requirements on the choice of time scales in the ecosystem service assessment process.

Application of Empirical Method to Evaluate the Active OOIP and Other Recovery Fators for Water－drive Oilfields

In most literatures reservoir engineers usually claimed that oilfields are not identical to each other.To the author's experience on the type-curve matching work as mentioned above,it is not uncommon to find two fields exhibiting almost identical performances throughout their whole production life.In Fig.1,oil and water production figures of two well-known giant oilfields of former USSR-Romashkino(A)and Samotrol(B)are plo-tted together as Type-A curves with software“TWDTC".Surprisingly,nearly all the data points which covered 18-24 years of production history for both fields fell almost on one straight line.This implies that these two fields should have the same magnitude of active OOIP and in the same time,exercise similar waterflooding performance during their whole produciton life.

A Method for Calculating Oil Field Relative Permeability Curve by Using Water Drive Characteristic Curve in High Water Cut Stage

With the production of strong bottom water reservoir, it will soon enter the ultra-high water cut stage. After entering the ultra-high water cut period, the main means of stable production is liquid extraction. Large liquid volume has a certain impact on the physical property distribution and fluid seepage law of the oilfield. The relative permeability curve measured according to the industry standard is not used for the prediction of development indicators and the understanding of the dynamic law of the oilfield. In order to understand the characteristics of water drive law in high water cut stage of water drive oilfield, starting from the water drive characteristic curve in high water cut stage, the method for calculating the relative permeability curve is deduced. Through numerical simulation verification and fitting the actual production data, it is confirmed that the obtained relative permeability curve is in line with the reality of the oilfield, It can provide some guiding significance for understanding the production law and water drive law of strong bottom water reservoir in ultra-high water cut stage.

A NEW METHOD FOR IMPROVING WATER DRIVE RESULT AND LEASE TEST

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Driving forces and their interactions of soil erosion in soil and water conservation regionalization at the county scale with a high cultivation rate

Soil erosion control based on county scale Soil and Water Conservation Regionalization(SWCR)is an essential component of China's ecological civilization construction.In SWCR,the quantitative analysis of the spatial heterogeneity and driving factors of soil erosion among different regions is still lacking.It is of great significance for soil erosion control to deeply examine the factors contributing to soil erosion(natural,land use,and socioeconomic factors)and their interaction at the county and regional levels.This study focused on a highly cultivated area,Hechuan District of Chongqing in the Sichuan Basin.The district(with 30 townships)was divided into four soil and water conservation regions(Ⅰ-Ⅳ)using principal component and hierarchical cluster analysis.The driving factors of soil erosion were identified using the geographical detector model.The results showed thatⅰ)the high cultivation rate was a prominent factor of soil erosion,and the sloping farmland accounted for 78.4%of the soil erosion in the study area;ⅱ)land use factors demonstrated the highest explanatory power in soil erosion,and the average interaction of land use factors explained 60.1%of soil erosion in the study area;ⅲ)the interaction between natural factors,socioeconomic factors,and land use factors greatly contributes to regional soil erosion through nonlinear-enhancement of double-factor enhancement.This study highlights the importance of giving special attention to the effects of land use factors on soil erosion at the county scale,particularly in mountainous and hilly areas with extensive sloping farmland and a high cultivation rate.

水资源-能源-粮食-生态系统耦合协调及驱动力分析

为加深对我国水资源、能源、粮食、生态系统协同演变趋势的认识,构建水资源-能源-粮食-生态多维系统指标体系,运用耦合协调度模型对我国2005—2020年水资源-能源-粮食-生态系统耦合协调度进行评价,并采用多因素归因分析法进行驱动力分析。结果表明:我国水资源-能源-粮食-生态系统耦合协调度从2005年的0.55增长到2020年的0.84,各地区耦合协调度从勉强协调发展水平过渡到中级协调发展水平,各子系统对耦合协调度上升的驱动分别经历了由粮食子系统到生态子系统再到水资源子系统主导的过程;能源子系统的贡献率虽然比较小,但是未来可能是各地区提升水资源-能源-粮食-生态系统多维系统协调发展水平的突破口。

苏南水网地区水域景观破碎化时空演变特征及驱动因子研究——以吴江区为例

以苏州吴江区为对象,选取1990、2000、2010、2020年土地利用数据,利用Fragstats4.2对1990-2020年水域景观破碎化演化特征进行定量分析,并借助地理探测器模型探讨水域景观破碎化时空特征的驱动因子。结果表明:(1)从景观水平破碎化特征分析来看,研究期内吴江区水域景观破碎化程度先增大后减缓:1990-2000年水域景观受到人工建设干扰,空间分布离散;2000-2020年水域景观破碎化程度降低、整体空间格局趋向整合。从类型水平破碎化特征分析,河流、湖泊及内陆滩涂在1990-2000年破碎化程度日益加剧,斑块空间分布离散,2000-2020年水域斑块连接性逐渐增强;水库坑塘斑块类型分布在1990-2010年破碎程度降低,2010年后破碎化程度上升。(2)吴江区水域景观破碎化受到自然、社会等多元因素影响,各因子对水域景观破碎化时空分异的影响明显不同,且各驱动因子间存在显著交互增强效应,其中人类活动强度因子影响最为显著。研究结果可为探明水域景观破碎化形成机理提供思路,对苏南水网地区生态环境保护和可持续发展具有参考意义。

基于DPSIR模型的秦岭北麓陕西城市群水安全评估及驱动因子识别

水安全评估是水资源开发利用与区域发展的基础。为了加强秦岭北麓陕西城市群可持续建设,助力秦岭“中央水塔”绿色发展,基于DPSIR模型构建秦岭北麓陕西城市群水安全评估体系,结合主客观综合赋权法与模糊综合评价法对区域2011~2021年水安全进行评估分级,并利用灰色关联度法分析其水安全的驱动因子。结果表明:秦岭北麓陕西城市群2011~2021年水安全状态变化具有一致性,波动中稳步提升。西安市水安全等级相较宝鸡市、渭南市上升趋势显著,于2021年转为无警状态;宝鸡市一直保持低警状态,而渭南市长期处于中警状态。陕西城市群的水安全状态及发展趋势与人均GDP、年降水量、人均用水量等10个驱动因子密切相关,其中经济因子是水安全等级呈现一致性的根本保证,社会和生态因子则是造成水安全差异性的主要原因。

变化环境下河南省水资源情势与驱动力分析

为了解河南省水资源利用现状及趋势,为水资源管理部门提供参考,以应对变化环境下未来水资源供需所面临的挑战,基于河南省1999—2022年有关气象水文资料及水资源统计资料,采用统计分析、Mann-Kendall趋势检验及BP神经网络方法,对河南省水资源演变情势及其驱动力进行分析研究。结果表明:河南省降水量及水资源总量年际变化较大,整体不太稳定且丰枯水年交替频繁,供用水量呈现增长趋势但增速有所放缓;全省降水量、地下水资源量及水资源总量呈现不显著的减少趋势,地表水量及耗水量呈现不显著的增加趋势,供用水量呈现显著的增加趋势;降水量、年平均气温及下垫面的变化都是影响河南省水资源总量变化的重要因素。