The centralized processing of high-sulfur and high-acidity crude has contributed to improvement of the overall economic benefits of the oil refining enterprise, but has also resulted in crude emulsification, severe co...The centralized processing of high-sulfur and high-acidity crude has contributed to improvement of the overall economic benefits of the oil refining enterprise, but has also resulted in crude emulsification, severe corrosion of process units and environmental protection issues. The long-cycle, safe and smooth operation of process units were guaranteed after selection of optimal processing routes and adoption of a series of technical measures.展开更多
In this work,fatty acid and its derivatives were adopted as lubricity additives for low sulfur diesel.Tribological evaluation obtained from the High-Frequency Reciprocating Rig(HFRR)apparatus showed that the lubricati...In this work,fatty acid and its derivatives were adopted as lubricity additives for low sulfur diesel.Tribological evaluation obtained from the High-Frequency Reciprocating Rig(HFRR)apparatus showed that the lubricating performance of the additives increased in the following order:stearic acid>glycol monopalmitate>stearyl alcohol>ethyl palmitate>cetyl ethyl ether.The adsorption behavior of the additives on Fe(110)surface and Fe2O3(001)surface was investigated by molecular dynamics(MD)simulations to verify their lubricity performance.The results suggested that adsorption energies of the additives on Fe(110)surface are determined by the van der Waals forces,while adsorptions on Fe2O3(001)surface are significantly attributed to the electrostatic attractive forces.Higher values of adsorption energy of the additives on Fe2O3(001)surface indicate that the additive has more efficient lubricity enhancing properties.展开更多
In order to reduce the content of oxygen and sulfur in steel, and produce low-sulfur and low-oxygen steel, study on slag has been carried out. Refining slag system of CaO-SiO2-Al2O3 is put forward with the considerati...In order to reduce the content of oxygen and sulfur in steel, and produce low-sulfur and low-oxygen steel, study on slag has been carried out. Refining slag system of CaO-SiO2-Al2O3 is put forward with the consideration of slag amount from converter, oxidizability of slag and activity of oxygen in molten steel. On this basis, refining slagging system for low-sulfur and low-oxygen steel has been developed combined with the modification of slag from converter and composition control of refining slag in LF treatment process. The results show that oxygen content is not more than 15×10-6, as well as sulfur content is as low as 0.005% in tube blank steel. And it achieves the production of low-sulfur and low-oxygen steel.展开更多
文摘The centralized processing of high-sulfur and high-acidity crude has contributed to improvement of the overall economic benefits of the oil refining enterprise, but has also resulted in crude emulsification, severe corrosion of process units and environmental protection issues. The long-cycle, safe and smooth operation of process units were guaranteed after selection of optimal processing routes and adoption of a series of technical measures.
基金financially supported by "the Fundamental Research Funds for the Central Universities,China"(11CX06036A)
文摘In this work,fatty acid and its derivatives were adopted as lubricity additives for low sulfur diesel.Tribological evaluation obtained from the High-Frequency Reciprocating Rig(HFRR)apparatus showed that the lubricating performance of the additives increased in the following order:stearic acid>glycol monopalmitate>stearyl alcohol>ethyl palmitate>cetyl ethyl ether.The adsorption behavior of the additives on Fe(110)surface and Fe2O3(001)surface was investigated by molecular dynamics(MD)simulations to verify their lubricity performance.The results suggested that adsorption energies of the additives on Fe(110)surface are determined by the van der Waals forces,while adsorptions on Fe2O3(001)surface are significantly attributed to the electrostatic attractive forces.Higher values of adsorption energy of the additives on Fe2O3(001)surface indicate that the additive has more efficient lubricity enhancing properties.
文摘In order to reduce the content of oxygen and sulfur in steel, and produce low-sulfur and low-oxygen steel, study on slag has been carried out. Refining slag system of CaO-SiO2-Al2O3 is put forward with the consideration of slag amount from converter, oxidizability of slag and activity of oxygen in molten steel. On this basis, refining slagging system for low-sulfur and low-oxygen steel has been developed combined with the modification of slag from converter and composition control of refining slag in LF treatment process. The results show that oxygen content is not more than 15×10-6, as well as sulfur content is as low as 0.005% in tube blank steel. And it achieves the production of low-sulfur and low-oxygen steel.
