Fuel design is a complex multi-objective optimization problem in which facile and robust methods are urgently demanded.Herein,a complete workflow for designing a fuel blending scheme is presented,which is theoreticall...Fuel design is a complex multi-objective optimization problem in which facile and robust methods are urgently demanded.Herein,a complete workflow for designing a fuel blending scheme is presented,which is theoretically supported,efficient,and reliable.Based on the data distribution of the composition and properties of the blending fuels,a model of polynomial regression with appropriate hypothesis space was established.The parameters of the model were further optimized by different intelligence algorithms to achieve high-precision regression.Then,the design of a blending fuel was described as a multi-objective optimization problem,which was solved using a Nelder–Mead algorithm based on the concept of Pareto domination.Finally,the design of a target fuel was fully validated by experiments.This study provides new avenues for designing various blending fuels to meet the needs of next-generation engines.展开更多
This study investigates the spray characteristics of ternary blends composed of octanol, biodiesel, and diesel fuel.Experiments are conducted using six materials to examine the variation in spray characteristic and to...This study investigates the spray characteristics of ternary blends composed of octanol, biodiesel, and diesel fuel.Experiments are conducted using six materials to examine the variation in spray characteristic and to verify and compare a previously established spray tip penetration model with a modified model. The results show that the addition of OB100(30%of octanol, 70% of biodiesel) improves the spray characteristics of the fuel. Specifically, the addition of 10% or 20% of OB100 leads to a slight increase in the spray tip penetration, average spray cone angle, maximum spray width, and the spray area of the fuel blend;however, further addition of OB100 causes a corresponding decrease in these parameters. Based on previous research, this study uses kinematic viscosity instead of dynamic viscosity and density to modify the prediction model of spray tip penetration. The modified model exhibits a better fit quality and agreement with the experimental data,making it more suitable for predicting the spray tip penetration of fuel blends compared to the Hiroyasu-Arai model.展开更多
The natural rubber (NR) was mixed with chlorosulfonated polyethylene (CSM), due to the difference of polarity in NR and CSM made this blend incompatible and the third component was used. Epoxidzed natural rubber (ENR)...The natural rubber (NR) was mixed with chlorosulfonated polyethylene (CSM), due to the difference of polarity in NR and CSM made this blend incompatible and the third component was used. Epoxidzed natural rubber (ENR) was used as a third component. NR/CSM blended with the blend ratio of 50/50 was prepared by using a two-roll mill and vulcanization in a compression mold at 160°C. The ENR content was varied from 1 to 7 phr. The curing characteristics, morphology, mechanical properties, and automotive fuel swelling were investigated. The results indicated that the cure time of the blend rubbers was shorter as adding ENR. The mechanical properties of the blend rubbers were not affected by ENR content. However, automotive fuel resistance of the blend rubbers was found to increase with adding ENR in rubber blend.展开更多
Effect of 1,1-dibutoxybutane （DBB） addition on petroleum DF （diesel fuel） performance has been studied. The study wasstarted by preparing DBB from decomposition of 1 -butanol on manganese impregnated on activated ...Effect of 1,1-dibutoxybutane （DBB） addition on petroleum DF （diesel fuel） performance has been studied. The study wasstarted by preparing DBB from decomposition of 1 -butanol on manganese impregnated on activated carbon （Mn/AC） catalyst at 450 ℃ in stainless steel reactor. The product was distilled at 200 ℃ and the residue obtained was analyzed by GC-MS and HSQC NMR toconfirm its structure and purity. The DBB-DF mixtures were prepared at different compositions and determined their excess molarvolume, homogeneity, phase stability, ignition quality, lubricity, cold flow quality, energy content, and viscosity. The addition of DBBinto DF formed a homogeneous mixture and had a good phase stability. The mixtures gave positive excess molar volume values overthe whole concentration ranges. The ignition quality and lubricity of the mixtures increased without lost in cold flow quality. Slightdecreased in viscosity and energy content per mass unit were observed.展开更多
The preparation of ethanol-diesel fuel blends and their emission characteristics were investigated. Results showed the absolute ethanol can dissolve in diesel fuel at an arbitrary ratio and a small quantity of water(0...The preparation of ethanol-diesel fuel blends and their emission characteristics were investigated. Results showed the absolute ethanol can dissolve in diesel fuel at an arbitrary ratio and a small quantity of water(0.2%) addition can lead to the phase separation of blends. An organic additive was synthesized and it can develop the ability of resistance to water and maintain the stability of ethanol-diesel-trace amounts of water system. The emission characteristics of 10%, 20%, and 30% ethanol-diesel fuel blends, with or without additives, were compared with those of diesel fuel in a direct injection(DI) diesel engine. The experimental results indicated that the blend of ethanol with diesel fuel significantly reduced the concentrations of smoke, hydrocarbon(HC), and carbon monoxide(CO) in exhaust gas. Using 20% ethanol-diesel fuel blend with the additive of 2% of the total volume, the optimum mixing ratio was achieved, at which the bench diesel engine testing showed a significant decrease in exhaust gas. Bosch smoke number was reduced by 55%, HC emission by 70%, and CO emission by 45%, at 13 kW/1540 r/min. However, ethanol-diesel fuel blends produced a few ppm acetaldehydes and more ethanol in exhaust gas.展开更多
The depletion of fossil diesel fuels, global warming concerns and strict limits on regulated pollutant emissions are encouraging the use of renewable fuels. Biodiesel is the most used renewable fuel in compression ign...The depletion of fossil diesel fuels, global warming concerns and strict limits on regulated pollutant emissions are encouraging the use of renewable fuels. Biodiesel is the most used renewable fuel in compression ignition (CI) engine. The majority of literature agrees that the particulate matter (PM), unburnt total hydrocarbons (THC) and carbon dioxide (CO) emission from biodiesel are lower than from conventional diesel fuel. One of the most important reasons for this is the oxygen content of the biodiesel. This induces a more complete and cleaner combustion process. In addition to this the absence of aromatic compounds in biodiesel leads to particulate matter reduction with respect to diesel fuel. The potential emission benefits induced by the presence of oxygen in fuel molecules has increased the interest in using the bio-alcohols fuel blends in CI engines such as ethanol. Although alcohols are more suitable for blending with diesel fuel, properties like lubricity, viscosity, stability, heating value and cetane number of diesel-alcohol (Diesohol) still require improvement. One of the techniques is addition of biodiesel which can improve all of these properties forming diesel-biodiesel-alcohol (ternary) blends. The blends of diesel-biodiesel-ethanol can be used in the existing CI engines without any major modifications and most significant result of using this blend is the lower emission with almost the same performance as of diesel fuel alone. The present study focused on investigation of performance and combustion characteristics of ternary fuel blend in DI diesel engine operating at different injection opening pressure (IOP). The different injection opening pressures are: 180 bar, 200 bar and 220 bar.展开更多
The negative valve overlap (NVO) strategy of HCCI operation was experimentally investigated on a gasoline HCCI engine operated with variable valve timing in association with the addition of diesel fuel. The experiment...The negative valve overlap (NVO) strategy of HCCI operation was experimentally investigated on a gasoline HCCI engine operated with variable valve timing in association with the addition of diesel fuel. The experimental results show that, by using gasoline and diesel blended fuels, the required NVO interval for suitable HCCI combustion under a given engine speed and a moderate compression ratio condition could be reduced, and the HCCI combustion region was extended remarkably without substantial increase in NOx emissions under a given inlet and exhaust valve timing due to the improvement of charge ignitability. In addition, the possible scale of NVO was extended. A substantial increase in the lean limit of excess air ratio and the upper limit of load range can be achieved because of higher volumetric efficiency, resulting from the decrease in the required NVO and the presence of less residual gases in cylinder.展开更多
The blended-fuel based eddy-dissipation-concept combustion model was newly developed in the FireFOAM framework, and applied to simulate 30 cm×30 cm heptane-ethanol pool fire. Comparison was made of fire height, c...The blended-fuel based eddy-dissipation-concept combustion model was newly developed in the FireFOAM framework, and applied to simulate 30 cm×30 cm heptane-ethanol pool fire. Comparison was made of fire height, centerline temperature against experimental measurements, which shows that they match very well with each other. However, further studies are needed to examine the validation of this model in fire simulations with various scales.展开更多
本文研究了掺氢天然气直接内重整平管型固体氧化物电池短堆的长期稳定性和衰减机理。通过约3000小时的实测实验,结果显示,电堆的总体衰减率为2.3%·kh^(-1),电堆中三个金属连接板的面积比电阻分别增加了0.276Ω·cm^(2)、0.254...本文研究了掺氢天然气直接内重整平管型固体氧化物电池短堆的长期稳定性和衰减机理。通过约3000小时的实测实验,结果显示,电堆的总体衰减率为2.3%·kh^(-1),电堆中三个金属连接板的面积比电阻分别增加了0.276Ω·cm^(2)、0.254Ω·cm^(2)和0.249Ω·cm^(2),但电堆中两个电池的电压反而分别增加了3.38 m V·kh^(-1)和3.78 m V·kh^(-1)。电堆衰减主要由金属连接件表层氧化及其与阴极集流层材料反应生成Sr CrO_(4)物质,两者共同作用增大了电池与金属连接体间的界面电阻所致。结果表明,以掺氢天然气为燃料直接内重整平管型固体氧化物燃料电池电堆具有良好的稳定性。本文工作为掺氢天然气在固体氧化物燃料电池堆中的直接内重整应用提供了理论参考与实验依据。展开更多
基金the support from the National Key R&D Program of China(No.2021YFC2103701)the National Natural Science Foundation of China(No.22178248)the Haihe Laboratory of Sustainable Chemical Transformations。
文摘Fuel design is a complex multi-objective optimization problem in which facile and robust methods are urgently demanded.Herein,a complete workflow for designing a fuel blending scheme is presented,which is theoretically supported,efficient,and reliable.Based on the data distribution of the composition and properties of the blending fuels,a model of polynomial regression with appropriate hypothesis space was established.The parameters of the model were further optimized by different intelligence algorithms to achieve high-precision regression.Then,the design of a blending fuel was described as a multi-objective optimization problem,which was solved using a Nelder–Mead algorithm based on the concept of Pareto domination.Finally,the design of a target fuel was fully validated by experiments.This study provides new avenues for designing various blending fuels to meet the needs of next-generation engines.
基金supported by the National Key R&D Program of China (2021YFF0601004)Natural Science Foundation of Anhui Province (2208085QE159)。
文摘This study investigates the spray characteristics of ternary blends composed of octanol, biodiesel, and diesel fuel.Experiments are conducted using six materials to examine the variation in spray characteristic and to verify and compare a previously established spray tip penetration model with a modified model. The results show that the addition of OB100(30%of octanol, 70% of biodiesel) improves the spray characteristics of the fuel. Specifically, the addition of 10% or 20% of OB100 leads to a slight increase in the spray tip penetration, average spray cone angle, maximum spray width, and the spray area of the fuel blend;however, further addition of OB100 causes a corresponding decrease in these parameters. Based on previous research, this study uses kinematic viscosity instead of dynamic viscosity and density to modify the prediction model of spray tip penetration. The modified model exhibits a better fit quality and agreement with the experimental data,making it more suitable for predicting the spray tip penetration of fuel blends compared to the Hiroyasu-Arai model.
文摘The natural rubber (NR) was mixed with chlorosulfonated polyethylene (CSM), due to the difference of polarity in NR and CSM made this blend incompatible and the third component was used. Epoxidzed natural rubber (ENR) was used as a third component. NR/CSM blended with the blend ratio of 50/50 was prepared by using a two-roll mill and vulcanization in a compression mold at 160°C. The ENR content was varied from 1 to 7 phr. The curing characteristics, morphology, mechanical properties, and automotive fuel swelling were investigated. The results indicated that the cure time of the blend rubbers was shorter as adding ENR. The mechanical properties of the blend rubbers were not affected by ENR content. However, automotive fuel resistance of the blend rubbers was found to increase with adding ENR in rubber blend.
文摘Effect of 1,1-dibutoxybutane （DBB） addition on petroleum DF （diesel fuel） performance has been studied. The study wasstarted by preparing DBB from decomposition of 1 -butanol on manganese impregnated on activated carbon （Mn/AC） catalyst at 450 ℃ in stainless steel reactor. The product was distilled at 200 ℃ and the residue obtained was analyzed by GC-MS and HSQC NMR toconfirm its structure and purity. The DBB-DF mixtures were prepared at different compositions and determined their excess molarvolume, homogeneity, phase stability, ignition quality, lubricity, cold flow quality, energy content, and viscosity. The addition of DBBinto DF formed a homogeneous mixture and had a good phase stability. The mixtures gave positive excess molar volume values overthe whole concentration ranges. The ignition quality and lubricity of the mixtures increased without lost in cold flow quality. Slightdecreased in viscosity and energy content per mass unit were observed.
文摘The preparation of ethanol-diesel fuel blends and their emission characteristics were investigated. Results showed the absolute ethanol can dissolve in diesel fuel at an arbitrary ratio and a small quantity of water(0.2%) addition can lead to the phase separation of blends. An organic additive was synthesized and it can develop the ability of resistance to water and maintain the stability of ethanol-diesel-trace amounts of water system. The emission characteristics of 10%, 20%, and 30% ethanol-diesel fuel blends, with or without additives, were compared with those of diesel fuel in a direct injection(DI) diesel engine. The experimental results indicated that the blend of ethanol with diesel fuel significantly reduced the concentrations of smoke, hydrocarbon(HC), and carbon monoxide(CO) in exhaust gas. Using 20% ethanol-diesel fuel blend with the additive of 2% of the total volume, the optimum mixing ratio was achieved, at which the bench diesel engine testing showed a significant decrease in exhaust gas. Bosch smoke number was reduced by 55%, HC emission by 70%, and CO emission by 45%, at 13 kW/1540 r/min. However, ethanol-diesel fuel blends produced a few ppm acetaldehydes and more ethanol in exhaust gas.
文摘The depletion of fossil diesel fuels, global warming concerns and strict limits on regulated pollutant emissions are encouraging the use of renewable fuels. Biodiesel is the most used renewable fuel in compression ignition (CI) engine. The majority of literature agrees that the particulate matter (PM), unburnt total hydrocarbons (THC) and carbon dioxide (CO) emission from biodiesel are lower than from conventional diesel fuel. One of the most important reasons for this is the oxygen content of the biodiesel. This induces a more complete and cleaner combustion process. In addition to this the absence of aromatic compounds in biodiesel leads to particulate matter reduction with respect to diesel fuel. The potential emission benefits induced by the presence of oxygen in fuel molecules has increased the interest in using the bio-alcohols fuel blends in CI engines such as ethanol. Although alcohols are more suitable for blending with diesel fuel, properties like lubricity, viscosity, stability, heating value and cetane number of diesel-alcohol (Diesohol) still require improvement. One of the techniques is addition of biodiesel which can improve all of these properties forming diesel-biodiesel-alcohol (ternary) blends. The blends of diesel-biodiesel-ethanol can be used in the existing CI engines without any major modifications and most significant result of using this blend is the lower emission with almost the same performance as of diesel fuel alone. The present study focused on investigation of performance and combustion characteristics of ternary fuel blend in DI diesel engine operating at different injection opening pressure (IOP). The different injection opening pressures are: 180 bar, 200 bar and 220 bar.
基金Supported by the Engineering and Physical Sciences Research Council of the UK(No58338/01)
文摘The negative valve overlap (NVO) strategy of HCCI operation was experimentally investigated on a gasoline HCCI engine operated with variable valve timing in association with the addition of diesel fuel. The experimental results show that, by using gasoline and diesel blended fuels, the required NVO interval for suitable HCCI combustion under a given engine speed and a moderate compression ratio condition could be reduced, and the HCCI combustion region was extended remarkably without substantial increase in NOx emissions under a given inlet and exhaust valve timing due to the improvement of charge ignitability. In addition, the possible scale of NVO was extended. A substantial increase in the lean limit of excess air ratio and the upper limit of load range can be achieved because of higher volumetric efficiency, resulting from the decrease in the required NVO and the presence of less residual gases in cylinder.
基金supported by the National Basic Research Program of China(2012CB719704)EU IIFFP7 Project(909658)+1 种基金the National Natural Science Foundation of China(51276177)the Fundamental Research Funds for the Central Universities
文摘The blended-fuel based eddy-dissipation-concept combustion model was newly developed in the FireFOAM framework, and applied to simulate 30 cm×30 cm heptane-ethanol pool fire. Comparison was made of fire height, centerline temperature against experimental measurements, which shows that they match very well with each other. However, further studies are needed to examine the validation of this model in fire simulations with various scales.
基金financial supports from the National Key Research and Development Program of China (No.2022YFB4003602)National Natural Science Foundation of China (No. U20A20251,No.11932005)+1 种基金Key R&D projects in Zhejiang Province (No.2021C01101)Ningbo Key R&D project (No.2023Z145)。
文摘本文研究了掺氢天然气直接内重整平管型固体氧化物电池短堆的长期稳定性和衰减机理。通过约3000小时的实测实验,结果显示,电堆的总体衰减率为2.3%·kh^(-1),电堆中三个金属连接板的面积比电阻分别增加了0.276Ω·cm^(2)、0.254Ω·cm^(2)和0.249Ω·cm^(2),但电堆中两个电池的电压反而分别增加了3.38 m V·kh^(-1)和3.78 m V·kh^(-1)。电堆衰减主要由金属连接件表层氧化及其与阴极集流层材料反应生成Sr CrO_(4)物质,两者共同作用增大了电池与金属连接体间的界面电阻所致。结果表明,以掺氢天然气为燃料直接内重整平管型固体氧化物燃料电池电堆具有良好的稳定性。本文工作为掺氢天然气在固体氧化物燃料电池堆中的直接内重整应用提供了理论参考与实验依据。
