To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut sh...To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut shell AC activated by nitric acid as the support and iron oxide as the active component.The crystal structure,surface morphology,pore structure,functional groups and valence states of the active components of Fe/AC catalysts were characterised by X-ray diffraction,scanning electron microscopy,nitrogen adsorption and desorption,Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy,respectively.The effect of Fe loading and calcination temperature on the low-temperature denitration of NH_(3)-SCR over Fe/AC catalysts was studied using NH_(3)as the reducing gas at low temperature(150℃).The results show that the iron oxide on the Fe/AC catalyst is spherical and uniformly dispersed on the surface of AC,thereby improving the crystallisation performance and increasing the number of active sites and specific surface area on AC in contact with the reaction gas.Hence,a rapid NH_(3)-SCR reaction was realised.When the roasting temperature remains constant,the iron oxide crystals formed by increasing the amount of loading can enter the AC pore structure and accumulate to form more micropores.When the roasting temperature is raised from 400 to 500℃,the iron oxide is mainly transformed fromα-Fe_(2)O_(3)toγ-Fe_(2)O_(3),which improves the iron oxide dispersion and increases its denitration active site,allowing gas adsorption.When the Fe loading amount is 10%,and the roasting temperature is 500℃,the NO removal rate of the Fe/AC catalyst can reach 95%.According to the study,the low-temperature NH_(3)-SCR mechanism of Fe/AC catalyst is proposed,in which the redox reaction between Fe~(2+)and Fe~(3+)will facilitate the formation of reactive oxygen vacancies,which increases the amount of oxygen adsorption on the surface,especially the increase in surface acid sites,and promotes and adsorbs more reaction gases(NH_(3),O_(2),NO).The transformation from the standard SCR reaction to the fast SCR reaction is accelerated.展开更多
Two series of perovskite-type oxides with composition (La_(1-x))Sr_xFeO_3(x≤0.8)and La_(1-x)Sr_xFe_(1-y)Co_yO_3(x=0.2; y=0.2, 0.4)powder productions were synthesized by EDTA complexing sol-gel method. The products we...Two series of perovskite-type oxides with composition (La_(1-x))Sr_xFeO_3(x≤0.8)and La_(1-x)Sr_xFe_(1-y)Co_yO_3(x=0.2; y=0.2, 0.4)powder productions were synthesized by EDTA complexing sol-gel method. The products were characterized by XRD, TEM, SEM, BET method(N_2 adsorption)and laser granularity analysis for different synthesis conditions to obtain the optimum conditions for the preparation process. Single-phased, uniform perovskite-type oxides with small particle size were obtained by EDTA sol-gel process with high stability and repeatability, and the process temperature is much lower than that of solid state reaction method.展开更多
Phenolic compounds have very strong toxicity, so it has been paid sharply attention to find an effective way of controlling the wastewater containing phenolic compounds. The work on this subject done by domestic and o...Phenolic compounds have very strong toxicity, so it has been paid sharply attention to find an effective way of controlling the wastewater containing phenolic compounds. The work on this subject done by domestic and overseas scholars is studied in this paper, and the progress of researches on low-temperature plasma treatment is summarized through the electrical discharge types, mechanism, kinetics of phenolic compounds decomposition and combination of several methods with low-temperature plasma treatment. In addition, the crucial problem and the developing tendency on low-temperature plasma treatment for phenol-bearing wastewater are briefly discussed.展开更多
By combing the characteristics of drilling in Antarctic region, performance requirements on drilling fluid for Antarctic low temperature conditions, and research progress of low temperature drilling fluid, current pro...By combing the characteristics of drilling in Antarctic region, performance requirements on drilling fluid for Antarctic low temperature conditions, and research progress of low temperature drilling fluid, current problems of the drilling fluid have been sorted out, and the development direction of the drilling fluid has been pointed out. Drilling in the Antarctic region mainly includes drilling in snow, ice and subglacial rock formations, and drilling in Antarctic low temperature conditions will face problems in four aspects:(1) low temperature and large temperature changes in the drilling area;(2) likely well leakage and drillstring-sticking in the snow layer, creep in the ice layer, ice chip gathering jamming in the warm ice layer, well wall collapse in the subglacial rock formations;(3) lack of infrastructure and difficulty in logistical support;(4) fragile environment and low carrying capacity. After years of development, progresses have been made on low-temperature drilling fluids for the Antarctic region. Low-temperature petroleum-based drilling fluid, ethanol/ethylene glycol-based drilling fluid, ester-based drilling fluid and silicone oil-based drilling fluid have been developed. However, these drilling fluids have problems such as insufficient low-temperature tolerance, low environmental performance and weak wellbore stability, etc. In order to meet the performance requirements of drilling fluid under low-temperature conditions in Antarctic region, the working mechanisms of low-temperature drilling fluid must be examined in depth;environment-friendly low-temperature base fluid of drilling fluid and related additives must be developed to prepare environmentally friendly low temperature drilling fluid systems;multi-functional integrated adjustment method for drilling fluid must be worked out to ensure well wall stability and improve cutting-carry capacity when drilling ice formations and ice-rock interlayers;and on-site support operation codes must be established to provide technical support for Antarctic drilling.展开更多
为了准确检测出采血管中乙二胺四乙酸(EDTA)的含量,本文拟对离子色谱法和电位滴定法检测EDTA含量的方法学进行对比。离子色谱法以TSK gel Super IC-AZ阴离子交换柱为分离柱,通过抑制电导检测器检测EDTA;电位滴定法以Ca^(2+)选择电极,以0...为了准确检测出采血管中乙二胺四乙酸(EDTA)的含量,本文拟对离子色谱法和电位滴定法检测EDTA含量的方法学进行对比。离子色谱法以TSK gel Super IC-AZ阴离子交换柱为分离柱,通过抑制电导检测器检测EDTA;电位滴定法以Ca^(2+)选择电极,以0.05 mmol/L Ca^(2+)标准溶液为滴定液,电位突跃法判定滴定终点,记录消耗滴定液的体积,计算EDTA含量。离子色谱法中,采血管中EDTA的质量浓度为1.48 mg/mL,样品平行测定相对标准偏差为0.51%(n=6);当加标样品中EDTA的质量浓度为2.12~30.00 mg/L时,其回收率为104.07%~113.60%;检出限和定量限分别为0.09和0.29 mg/L。电位滴定法中,采血管中EDTA的质量浓度为1.51 mg/mL,样品平行测定相对标准偏差为0.45%(n=6);当加标样品中EDTA的质量浓度为1.89~31.70 mg/L时,其加标回收率为100.16%~100.97%。2种方法均可准确测定采血管中EDTA的含量,离子色谱法可在定量限附近准确测定低浓度EDTA含量,电位滴定法无需标准物校准即可实现采血管中EDTA含量的准确测定。展开更多
基金Funded by the General Project of Science and Technology Plan of Yunnan Science and Technology Department(Nos.202001AT070029,2019FB077)Open Fund of Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education(No.FMRUlab-20-4)。
文摘To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut shell AC activated by nitric acid as the support and iron oxide as the active component.The crystal structure,surface morphology,pore structure,functional groups and valence states of the active components of Fe/AC catalysts were characterised by X-ray diffraction,scanning electron microscopy,nitrogen adsorption and desorption,Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy,respectively.The effect of Fe loading and calcination temperature on the low-temperature denitration of NH_(3)-SCR over Fe/AC catalysts was studied using NH_(3)as the reducing gas at low temperature(150℃).The results show that the iron oxide on the Fe/AC catalyst is spherical and uniformly dispersed on the surface of AC,thereby improving the crystallisation performance and increasing the number of active sites and specific surface area on AC in contact with the reaction gas.Hence,a rapid NH_(3)-SCR reaction was realised.When the roasting temperature remains constant,the iron oxide crystals formed by increasing the amount of loading can enter the AC pore structure and accumulate to form more micropores.When the roasting temperature is raised from 400 to 500℃,the iron oxide is mainly transformed fromα-Fe_(2)O_(3)toγ-Fe_(2)O_(3),which improves the iron oxide dispersion and increases its denitration active site,allowing gas adsorption.When the Fe loading amount is 10%,and the roasting temperature is 500℃,the NO removal rate of the Fe/AC catalyst can reach 95%.According to the study,the low-temperature NH_(3)-SCR mechanism of Fe/AC catalyst is proposed,in which the redox reaction between Fe~(2+)and Fe~(3+)will facilitate the formation of reactive oxygen vacancies,which increases the amount of oxygen adsorption on the surface,especially the increase in surface acid sites,and promotes and adsorbs more reaction gases(NH_(3),O_(2),NO).The transformation from the standard SCR reaction to the fast SCR reaction is accelerated.
文摘Two series of perovskite-type oxides with composition (La_(1-x))Sr_xFeO_3(x≤0.8)and La_(1-x)Sr_xFe_(1-y)Co_yO_3(x=0.2; y=0.2, 0.4)powder productions were synthesized by EDTA complexing sol-gel method. The products were characterized by XRD, TEM, SEM, BET method(N_2 adsorption)and laser granularity analysis for different synthesis conditions to obtain the optimum conditions for the preparation process. Single-phased, uniform perovskite-type oxides with small particle size were obtained by EDTA sol-gel process with high stability and repeatability, and the process temperature is much lower than that of solid state reaction method.
文摘Phenolic compounds have very strong toxicity, so it has been paid sharply attention to find an effective way of controlling the wastewater containing phenolic compounds. The work on this subject done by domestic and overseas scholars is studied in this paper, and the progress of researches on low-temperature plasma treatment is summarized through the electrical discharge types, mechanism, kinetics of phenolic compounds decomposition and combination of several methods with low-temperature plasma treatment. In addition, the crucial problem and the developing tendency on low-temperature plasma treatment for phenol-bearing wastewater are briefly discussed.
文摘By combing the characteristics of drilling in Antarctic region, performance requirements on drilling fluid for Antarctic low temperature conditions, and research progress of low temperature drilling fluid, current problems of the drilling fluid have been sorted out, and the development direction of the drilling fluid has been pointed out. Drilling in the Antarctic region mainly includes drilling in snow, ice and subglacial rock formations, and drilling in Antarctic low temperature conditions will face problems in four aspects:(1) low temperature and large temperature changes in the drilling area;(2) likely well leakage and drillstring-sticking in the snow layer, creep in the ice layer, ice chip gathering jamming in the warm ice layer, well wall collapse in the subglacial rock formations;(3) lack of infrastructure and difficulty in logistical support;(4) fragile environment and low carrying capacity. After years of development, progresses have been made on low-temperature drilling fluids for the Antarctic region. Low-temperature petroleum-based drilling fluid, ethanol/ethylene glycol-based drilling fluid, ester-based drilling fluid and silicone oil-based drilling fluid have been developed. However, these drilling fluids have problems such as insufficient low-temperature tolerance, low environmental performance and weak wellbore stability, etc. In order to meet the performance requirements of drilling fluid under low-temperature conditions in Antarctic region, the working mechanisms of low-temperature drilling fluid must be examined in depth;environment-friendly low-temperature base fluid of drilling fluid and related additives must be developed to prepare environmentally friendly low temperature drilling fluid systems;multi-functional integrated adjustment method for drilling fluid must be worked out to ensure well wall stability and improve cutting-carry capacity when drilling ice formations and ice-rock interlayers;and on-site support operation codes must be established to provide technical support for Antarctic drilling.
