CuO-CeO2 catalysts were prepared by a urea precipitation method for the oxidative steam reforming of ethanol at low-temperature.The catalytic performance was evaluated and the catalysts were characterized by inductive...CuO-CeO2 catalysts were prepared by a urea precipitation method for the oxidative steam reforming of ethanol at low-temperature.The catalytic performance was evaluated and the catalysts were characterized by inductively coupled plasma atomic emission spectroscopy,X-ray diffraction,temperature-programmed reduction,field emission scanning electron microscopy and thermo-gravimetric analysis.Over CuOCeO2 catalysts,H2 with low CO content was produced in the whole tested temperature range of 250–450 C.The non-noble metal catalyst 20CuCe showed higher H2production rate than 1%Rh/CeO2 catalyst at 300–400 C and the advantage was more obvious after 20 h testing at400 C.These results further confirmed that CuO-CeO2 catalysts may be suitable candidates for low temperature hydrogen production from ethanol.展开更多
In Western Siberia(Russia) there are about 100 Artemia lakes with total area over 1 600 km 2.Geographically these lakes are located between 51°–56°N and 61°–82°E.In general these lakes are shallo...In Western Siberia(Russia) there are about 100 Artemia lakes with total area over 1 600 km 2.Geographically these lakes are located between 51°–56°N and 61°–82°E.In general these lakes are shallow(depth less than 1.5 m),small or medium size(0.1 to 10 km 2);they are chloride;their total salinity is from 40 to 250 g/L.The harvesting of cysts per year is only in 20–40 lakes.In Russia 550 tons of dry Artemia cysts(14%–18% of the world production) were harvested annually.This includes about 350 tons in the Altai region and 200 tons in other regions.During our regular 20-year study period the cyst harvest was:95 tons in Kurgan;65 tons in Omsk,20 tons in Novosibirsk,20 tons in Tyumen.Ways of increasing cyst harvest in Russia are considered in this article.During the last 30 years the harvest of cysts in Russia has increased from 7–20 to 500–600 tons.A significant influence of dryness of the year was found on productivity in selected lakes,but taken for all the lakes together,the relationship was not significant.The optimal salinity for productivity of cysts in the lakes was determined.Analysis of productivity of the lakes and the harvesting results showed that the stocks of cysts are underutilized by approximately 1.7 times.展开更多
Combining the H2 production with brine remediation is regarded as a sustainable approach to achieving clean H2 energy. However, designing stable Cl− oxidation reaction (COR) electrocatalyst is the key to realize this ...Combining the H2 production with brine remediation is regarded as a sustainable approach to achieving clean H2 energy. However, designing stable Cl− oxidation reaction (COR) electrocatalyst is the key to realize this route. Herein, a type of oxygen-modified Co nanoparticles anchored graphitic carbon nanofibers catalyst (Co/GCFs) was synthesized through a two-step strategy of adsorption and pyrolysis. The Co/GCFs-2.4 exhibits high selectivity and stability for COR at neutral electrolyte. It is worth noting that unlike the water oxidation, the chemical valence of cobalt has not changed during the COR. Further results demonstrated that the oxygen-modified Co nanoparticles provide active sites for selective COR, meanwhile, the graphitic carbon gives rise to strong catalytic stability. Thanks to the superior COR and H2 production activity of Co/GCFs-2.4, a two-electrode brine electrocatalysis system employing Co/GCFs-2.4 as both cathode and anode for H2 production exhibited robust stability, efficient and high Faraday efficiency (98%-100%). We propose that this work provides a novel strategy for designing efficient and stable catalysts with electrocatalytic COR and HER activities at neutral brine water for practically coupling with H2 production by water electrolysis and brine water remediation.展开更多
基金supported by the National Basic Research Program of China (2010CB732304)the National Natural Science Foundation of China (21177142 and 20973193)
文摘CuO-CeO2 catalysts were prepared by a urea precipitation method for the oxidative steam reforming of ethanol at low-temperature.The catalytic performance was evaluated and the catalysts were characterized by inductively coupled plasma atomic emission spectroscopy,X-ray diffraction,temperature-programmed reduction,field emission scanning electron microscopy and thermo-gravimetric analysis.Over CuOCeO2 catalysts,H2 with low CO content was produced in the whole tested temperature range of 250–450 C.The non-noble metal catalyst 20CuCe showed higher H2production rate than 1%Rh/CeO2 catalyst at 300–400 C and the advantage was more obvious after 20 h testing at400 C.These results further confirmed that CuO-CeO2 catalysts may be suitable candidates for low temperature hydrogen production from ethanol.
基金Supported by the Federal State Centre for Fisheries(Russia,Tyumen)
文摘In Western Siberia(Russia) there are about 100 Artemia lakes with total area over 1 600 km 2.Geographically these lakes are located between 51°–56°N and 61°–82°E.In general these lakes are shallow(depth less than 1.5 m),small or medium size(0.1 to 10 km 2);they are chloride;their total salinity is from 40 to 250 g/L.The harvesting of cysts per year is only in 20–40 lakes.In Russia 550 tons of dry Artemia cysts(14%–18% of the world production) were harvested annually.This includes about 350 tons in the Altai region and 200 tons in other regions.During our regular 20-year study period the cyst harvest was:95 tons in Kurgan;65 tons in Omsk,20 tons in Novosibirsk,20 tons in Tyumen.Ways of increasing cyst harvest in Russia are considered in this article.During the last 30 years the harvest of cysts in Russia has increased from 7–20 to 500–600 tons.A significant influence of dryness of the year was found on productivity in selected lakes,but taken for all the lakes together,the relationship was not significant.The optimal salinity for productivity of cysts in the lakes was determined.Analysis of productivity of the lakes and the harvesting results showed that the stocks of cysts are underutilized by approximately 1.7 times.
基金This work was financially supported by the National Natural Science Foundation of China(No.51902312)Natural Science Foundation of Anhui Province(Nos.1908085QC139 and 1908085QB83)+4 种基金the Youth Science Fund of Anhui Agricultural University(No.2018zd25)the Science Foundation for Distinguished Young Scholars of Anhui Province(No.2008085J13)the Key research and development Project of Anhui Province(No.1804h07020148)the Fundamental Research Funds for the Central Universities(Nos.JZ2019HGBH0204 and PA2019GDPK0061)The authors thank the 1W1B station for XAFS measurement in Beijing Synchrotron Radiation Facility.
文摘Combining the H2 production with brine remediation is regarded as a sustainable approach to achieving clean H2 energy. However, designing stable Cl− oxidation reaction (COR) electrocatalyst is the key to realize this route. Herein, a type of oxygen-modified Co nanoparticles anchored graphitic carbon nanofibers catalyst (Co/GCFs) was synthesized through a two-step strategy of adsorption and pyrolysis. The Co/GCFs-2.4 exhibits high selectivity and stability for COR at neutral electrolyte. It is worth noting that unlike the water oxidation, the chemical valence of cobalt has not changed during the COR. Further results demonstrated that the oxygen-modified Co nanoparticles provide active sites for selective COR, meanwhile, the graphitic carbon gives rise to strong catalytic stability. Thanks to the superior COR and H2 production activity of Co/GCFs-2.4, a two-electrode brine electrocatalysis system employing Co/GCFs-2.4 as both cathode and anode for H2 production exhibited robust stability, efficient and high Faraday efficiency (98%-100%). We propose that this work provides a novel strategy for designing efficient and stable catalysts with electrocatalytic COR and HER activities at neutral brine water for practically coupling with H2 production by water electrolysis and brine water remediation.
