Structural Engineering of Anode Materials for Low-Temperature Lithium-Ion Batteries:Mechanisms,Strategies,and Prospects

The severe degradation of electrochemical performance for lithium-ion batteries(LIBs)at low temperatures poses a significant challenge to their practical applications.Consequently,extensive efforts have been contributed to explore novel anode materials with high electronic conductivity and rapid Li^(+)diffusion kinetics for achieving favorable low-temperature performance of LIBs.Herein,we try to review the recent reports on the synthesis and characterizations of low-temperature anode materials.First,we summarize the underlying mechanisms responsible for the performance degradation of anode materials at subzero temperatures.Second,detailed discussions concerning the key pathways(boosting electronic conductivity,enhancing Li^(+)diffusion kinetics,and inhibiting lithium dendrite)for improving the low-temperature performance of anode materials are presented.Third,several commonly used low-temperature anode materials are briefly introduced.Fourth,recent progress in the engineering of these low-temperature anode materials is summarized in terms of structural design,morphology control,surface&interface modifications,and multiphase materials.Finally,the challenges that remain to be solved in the field of low-temperature anode materials are discussed.This review was organized to offer valuable insights and guidance for next-generation LIBs with excellent low-temperature electrochemical performance.

Conventional Geothermal Systems and Unconventional Geothermal Developments: An Overview

This paper provides an overview of conventional geothermal systems and unconventional geothermal developments as a common reference is needed for discussions between energy professionals. Conventional geothermal systems have the heat, permeability and fluid, requiring only drilling down to °C, normal heat flow or decaying radiogenic granite as heat sources, and used in district heating. Medium-temperature (MT) 100°C - 190°C, and high-temperature (HT) 190°C - 374°C resources are mostly at plate boundaries, with volcanic intrusive heat source, used mostly for electricity generation. Single well capacities are °C - 500°C) and a range of depths (1 m to 20 Km), but lack permeability or fluid, thus requiring stimulations for heat extraction by conduction. HVAC is 1 - 2 m deep and shallow geothermal down to 500 m in wells, both capturing °C, with °C are either advanced by geothermal developers at <7 Km depth (Enhanced Geothermal Systems (EGS), drilling below brittle-ductile transition zones and under geothermal fields), or by the Oil & Gas industry (Advanced Geothermal Systems, heat recovery from hydrocarbon wells or reservoirs, Superhot Rock Geothermal, and millimeter-wave drilling down to 20 Km). Their primary aim is electricity generation, relying on closed-loops, but EGS uses fractures for heat exchange with earthquake risks during fracking. Unconventional approaches could be everywhere, with shallow geothermal already functional. The deeper and hotter unconventional alternatives are still experimental, overcoming costs and technological challenges to become fully commercial. Meanwhile, the conventional geothermal resources remain the most proven opportunities for investments and development.

Low-temperature characteristicsof rubbers and performance testsof type 120 emergencyvalve diaphragms

Purpose–The type 120 emergency valve is an essential braking component of railway freight trains,butcorresponding diaphragms consisting of natural rubber(NR)and chloroprene rubber(CR)exhibit insufficientaging resistance and low-temperature resistance,respectively.In order to develop type 120 emergency valverubber diaphragms with long-life and high-performance,low-temperatureresistant CR and NR were processed.Design/methodology/approach–The physical properties of the low-temperature-resistant CR and NRwere tested by low-temperature stretching,dynamic mechanical analysis,differential scanning calorimetryand thermogravimetric analysis.Single-valve and single-vehicle tests of type 120 emergency valves werecarried out for emergency diaphragms consisting of NR and CR.Findings–The low-temperature-resistant CR and NR exhibited excellent physical properties.The elasticityand low-temperature resistance of NR were superior to those of CR,whereas the mechanical properties of thetwo rubbers were similar in the temperature range of 0℃–150℃.The NR and CR emergency diaphragms metthe requirements of the single-valve test.In the low-temperature single-vehicle test,only the low-temperaturesensitivity test of the NR emergency diaphragm met the requirements.Originality/value–The innovation of this study is that it provides valuable data and experience for futuredevelopment of type 120 valve rubber diaphragms.

Boosting oxygen reduction activity and CO_(2) resistance on bismuth ferrite-based perovskite cathode for low-temperature solid oxide fuel cells below 600℃

Developing efficient and stable cathodes for low-temperature solid oxide fuel cells(LT-SOFCs) is of great importance for the practical commercialization.Herein,we propose a series of Sm-modified Bi_(0.7-x)Sm_xSr_(0.3)FeO_(3-δ) perovskites as highly-active catalysts for LT-SOFCs.Sm doping can significantly enhance the electrocata lytic activity and chemical stability of cathode.At 600℃,Bi_(0.675)Sm_(0.025)Sr_(0.3)FeO_(3-δ)(BSSF25) cathode has been found to be the optimum composition with a polarization resistance of 0.098 Ω cm^2,which is only around 22.8% of Bi_(0.7)Sr_(0.3)FeO_(3-δ)(BSF).A full cell utilizing BSSF25 displays an exceptional output density of 790 mW cm^(-2),which can operate continuously over100 h without obvious degradation.The remarkable electrochemical performance observed can be attributed to the improved O_(2) transport kinetics,superior surface oxygen adsorption capacity,as well as O_(2)p band centers in close proximity to the Fermi level.Moreover,larger average bonding energy(ABE) and the presence of highly acidic Bi,Sm,and Fe ions restrict the adsorption of CO_(2) on the cathode surface,resulting in excellent CO_(2) resistivity.This work provides valuable guidance for systematic design of efficient and durable catalysts for LT-SOFCs.

Applications of artificial intelligence in geothermal resource exploration: A review

Artificial intelligence (AI) has become increasingly important in geothermal exploration,significantly improving the efficiency of resource identification.This review examines current AI applications,focusing on the algorithms used,the challenges addressed,and the opportunities created.In addition,the review highlights the growth of machine learning applications in geothermal exploration over the past decade,demonstrating how AI has improved the analysis of subsurface data to identify potential resources.AI techniques such as neural networks,support vector machines,and decision trees are used to estimate subsurface temperatures,predict rock and fluid properties,and identify optimal drilling locations.In particular,neural networks are the most widely used technique,further contributing to improved exploration efficiency.However,the widespread adoption of AI in geothermal exploration is hindered by challenges,such as data accessibility,data quality,and the need for tailored data science training for industry professionals.Furthermore,the review emphasizes the importance of data engineering methodologies,data scaling,and standardization to enable the development of accurate and generalizable AI models for geothermal exploration.It is concluded that the integration of AI into geothermal exploration holds great promise for accelerating the development of geothermal energy resources.By effectively addressing key challenges and leveraging AI technologies,the geothermal industry can unlock cost‐effective and sustainable power generation opportunities.

Progress in research on the exploration and evaluation of deep geothermal resources in the Fujian-Guangdong-Hainan region,China

Deep geothermal resources in the Fujian-Guangdong-Hainan region,China,offer significant potential for sustainable energy.The diverse igneous rock formations along the southeast coast present intricate geological challenges that impede exploration and evaluation efforts.In this study,we address critical concerns related to the Fujian-Guangdong-Hainan region's deep geothermal resources,encompassing heat source composition,formation conditions,strategic favorable areas,and exploration directions.Our methods involve the analysis of regional geothermal reservoirs and cap rocks.Major findings include:the primary heat sources in the Fujian-Guangdong-Hainan region consist of the radioactive heat generation from granites in the crust,heat conduction in the mantle,and,in specific areas like Yangjiang and Shantou,melts within the middle and lower crust;the deep,high-temperature geothermal resources in the region predominantly reside in basins'depressed areas.These areas are characterized by the confluence of triple heat sources:heat from the Earth's crust,mantle,and other supplementary sources;our analysis led to the identification of three strategic areas favorable for deep geothermal resources in the Fujian-Guangdong-Hainan region.These are the Beibu Gulf Basin's continental area,the Yuezhong Depression,and the Fuzhou-Zhangzhou area.

Geothermo-mechanical alterations due to heat energy extraction in enhanced geothermal systems: Overview and prospective directions

Geothermal energy from deep underground (or geological) formations,with or without its combination with carbon capture and storage (CCS),can be a key technology to mitigate anthropogenic greenhouse gas emissions and meet the 2050 net‐zero carbon emission target.Geothermal resources in low‐permeability and medium‐and high‐temperature reservoirs in sedimentary sequence require hydraulic stimulation for enhanced geothermal systems (EGS).However,fluid migration for geothermal energy in EGS or with potential CO_(2) storage in a CO_(2)‐EGS are both dependent on the in situ flow pathway network created by induced fluid injection.These thermo‐mechanical interactions can be complex and induce varying alterations in the mechanical response when the working fluid is water (in EGS) or supercritical CO_(2)(in CO_(2)‐EGS),which could impact the geothermal energy recovery from geological formations.Therefore,there is a need for a deeper understanding of the heat extraction process in EGS and CO_(2)‐EGS.This study presents a systematic review of the effects of changes in mechanical properties and behavior of deep underground rocks on the induced flow pathway and heat recovery in EGS reservoirs with or without CO_(2) storage in CO_(2) ‐EGS.Further,we proposed waterless‐stimulated EGS as an alternative approach to improve heat energy extraction in EGS.Lastly,based on the results of our literature review and proposed ideas,we recommend promising areas of investigation that may provide more insights into understanding geothermo‐mechanics to further stimulate new research studies and accelerate the development of geothermal energy as a viable clean energy technology.

Current status and construction scheme of smart geothermal field technology

To address the key problems in the application of intelligent technology in geothermal development,smart application scenarios for geothermal development are constructed.The research status and existing challenges of intelligent technology in each scenario are analyzed,and the construction scheme of smart geothermal field system is proposed.The smart geothermal field is an organic integration of geothermal development engineering and advanced technologies such as the artificial intelligence.At present,the technology of smart geothermal field is still in the exploratory stage.It has been tested for application in scenarios such as intelligent characterization of geothermal reservoirs,dynamic intelligent simulation of geothermal reservoirs,intelligent optimization of development schemes and smart management of geothermal development.However,it still faces many problems,including the high computational cost,difficult real-time response,multiple solutions and strong model dependence,difficult real-time optimization of dynamic multi-constraints,and deep integration of multi-source data.The construction scheme of smart geothermal field system is proposed,which consists of modules including the full database,intelligent characterization,intelligent simulation and intelligent optimization control.The connection between modules is established through the data transmission and the model interaction.In the next stage,it is necessary to focus on the basic theories and key technologies in each module of the smart geothermal field system,to accelerate the lifecycle intelligent transformation of the geothermal development and utilization,and to promote the intelligent,stable,long-term,optimal and safe production of geothermal resources.

Impact of well placement and flow rate on production efficiency and stress field in the fractured geothermal reservoirs

Geothermal energy has gained wide attention as a renewable alternative for mitigating greenhouse gas emissions.The advancements in enhanced geothermal system technology have enabled the exploitation of previously inaccessible geothermal resources.However,the extraction of geothermal energy from deep reservoirs poses many challenges due to high‐temperature and high‐geostress conditions.These factors can significantly impact the surrounding rock and its fracture formation.A comprehensive understanding of the thermal–hydraulic–mechanical(THM)coupling effect is crucial to the safe and efficient exploitation of geothermal resources.This study presented a THM coupling numerical model for the geothermal reservoir of the Yangbajing geothermal system.This proposed model investigated the geothermal exploitation performance and the stress distribution within the reservoir under various combinations of geothermal wells and mass flow rates.The geothermal system performance was evaluated by the criteria of outlet temperature and geothermal productivity.The results indicate that the longer distance between wells can increase the outlet temperature of production wells and improve extraction efficiency in the short term.In contrast,the shorter distance between wells can reduce the heat exchange area and thus mitigate the impact on the reservoir stress.A larger mass flow rate is conducive to the production capacity enhancement of the geothermal system and,in turn causes a wider range of stress disturbance.These findings provide valuable insights into the optimization of geothermal energy extraction while considering reservoir safety and long‐term sustainability.This study deepens the understanding of the THM coupling effects in geothermal systems and provides an efficient and environmentally friendly strategy for a geothermal energy system.

Geochemical and Isotopic Techniques Constraints on the Origin,Evolution,and Residence Time of Low-enthalpy Geothermal Water in Western Wugongshan,SE China

Geothermal resources are increasingly gaining attention as a competitive,clean energy source to address the energy crisis and mitigate climate change.The Wugongshan area,situated in the southeast coast geothermal belt of China,is a typical geothermal anomaly and contains abundant medium-and low-temperature geothermal resources.This study employed hydrogeochemical and isotopic techniques to explore the cyclic evolution of geothermal water in the western Wugongshan region,encompassing the recharge origin,water-rock interaction mechanisms,and residence time.The results show that the geothermal water in the western region of Wugongshan is weakly alkaline,with low enthalpy and mineralization levels.The hydrochemistry of geothermal waters is dominated by Na-HCO_(3)and Na-SO_(4),while the hydrochemistry types of cold springs are all Na-HCO_(3).The hydrochemistry types of surface waters and rain waters are NaHCO_(3)or Ca-HCO_(3).The δD and δ^(18)O values reveal that the geothermal waters are recharged by atmospheric precipitation at an altitude between 550.0 and 1218.6 m.Molar ratios of maj or solutes and isotopic compositions of^(87)Sr/^(86)Sr underscore the significant role of silicate weathering,dissolution,and cation exchange in controlling geothermal water chemistry.Additionally,geothermal waters experienced varying degrees of mixing with cold water during their ascent.Theδ^(13)C values suggest that the primary sources of carbon in the geothermal waters were biogenic and organic.Theδ^(34)S value suggests that the sulfates in geothermal water originate from sulfide minerals in the surrounding rock.Age dating using 3H and^(14)C isotopes suggests that geothermal waters have a residence time exceeding 1 kaBP and undergo a long-distance cycling process.

Geothermal energy for sustainable and green energy supply in the future

Deep Underground Science and Engineering(DUSE)publishes this special issue on geothermal energy.The guest editors of this special issue are Prof.Ranjith Pathegama Gamage(Monash University,Australia),Prof.Zhongwei Huang(China University of Petroleum,Beijing,China),and Prof.Bing Bai(Institute of Rock and Soil Mechanics,Chinese Academy of Sciences,Wuhan,China).Geothermal energy is one sustainable and renewable energy and currently a hot research topic in research and development.Geothermal energy supply is one of the long-term efforts for carbon footprint reductions to tackle climate change issues.The development of geothermal energy includes exploration and extraction processes.This special issue is to highlight the challenges on the exploration and extraction of geothermal energy such as initial high cost and difficulties in heat extraction from deep underground.This special issue focuses on new geothermal extraction system,new theory,new technology,new application of latest techniques such as artificial intelligence,and potential environmental effects.

Effects of fracture evolution and non-Darcy flow on the thermal performance of enhanced geothermal system in 3D complex fractured rock

In fractured geothermal reservoirs,the fracture networks and internal fluid flow behaviors can significantly impact the thermal performance.In this study,we proposed a non-Darcy rough discrete fracture network(NR-DFN)model that can simultaneously consider the fracture evolution and non-Darcy flow dynamics in studying the thermo-hydro-mechanical(THM)coupling processes for heat extraction in geothermal reservoir.We further employed the model on the Habanero enhanced geothermal systems(EGS)project located in Australia.First,our findings illustrate a clear spatial-temporal variation in the thermal stress and pressure perturbations,as well as uneven spatial distribution of shear failure in 3D fracture networks.Activated shear failure is mainly concentrated in the first fracture cluster.Secondly,channeling flow have also been observed in DFNs during heat extraction and are further intensified by the expansion of fractures driven by thermal stresses.Moreover,the combined effect of non-Darcy flow and fracture evolution triggers a rapid decline in the resulting heat rate and temperature.The NR-DFN model framework and the Habanero EGS's results illustrate the importance of both fracture evolution and non-Darcy flow on the efficiency of EGS production and have the potential to promote the development of more sustainable and efficient EGS operations for stakeholders.

Hydrothermal alteration of the surface volcanic rocks at the Acoculco geothermal field,Mexico:a multi-parametric approach

The studies on hydrothermal alteration-induced eff ects in surface and subsurface rocks provide useful information in the characterization and exploitation of a geothermal reservoir.Generally,these studies are based on traditional,and reliable methods like petrography(primary and secondary minerals,and grade of alteration),and geochemistry(mobility of elements,changes in mass and concentration of elements,and fluid inclusions).Recently,apart from these established methods,some methods based on the geochemical(Chemical Index of Alteration,CIA;Weathering Index of Parkar,WIP;Loss on Ignition,LOI;and Sulfur,S)and rock magnetic properties(magnetic susceptibility,χlf;and percentage frequency-dependent susceptibility,χfd%)are also being applied in the identification of whether a rock is an altered or a fresh one.The Acoculco Geothermal Field(AGF),Mexico,is characterized by high temperature and very low permeability,and it is considered a promissory Enhanced Geothermal System.The following changes are observed in the rocks as a result of an increase in hydrothermal alteration:(1)an increase in CIA,LOI,and S values,and a decrease in WIP;(2)an increase in quartz and quartz polymorph minerals(silicification),and clay minerals(argillization);and(3)decrease inχlf values.At AGF,the most altered surface acid rocks are characterized by entirely quartz and its polymorphs,and clay minerals.The present study also indicates the applicability of the binary plots of major elements(felsic vs mafic component)and rock magnetic parameters(χlf vs.χfd%).The rock withχfd%value of 2-10 andχlf value<0.5×10^(-6)m^(3) kg^(-1)indicate the presence of single domain and stable single domain grains,which in turn suggests that it is an altered rock.These methods are simple to apply,rapid,reliable,and have the potential to become eff ective tools for the identifi cation of hydrothermally altered rocks during the initial stage of geothermal exploration.

Evaluation of development potential of pumped hydroelectric storage and geothermal utilization system in abandoned coal mine

Every year in China,a significant number of mines are closed or abandoned.The pumped hydroelectric storage(PHS)and geothermal utilization are vital means to efficiently repurpose resources in abandoned mine.In this work,the development potentials of the PHS and geothermal utilization systems were evaluated.Considering the geological conditions and meteorological data available of Jiahe abandoned mine,a simple evaluation model for PHS and geothermal utilization was established.The average efficiency of the PHS system exceeds 70%and the regulatable energy of a unit volume is over 1.53 kW·h/m^(3).The PHS system achieves optimal performance when the wind/solar power ratio reaches 0.6 and 0.3 in daily and year scale,respectively.In the geothermal utilization system,the outlet temperature and heat production are significantly affected by the injection flow rate.The heat production performance is more stable at lower rate flow,and the proportion of heat production is higher in the initial stage at greater flow rate.As the operating time increases,the proportion of heat production gradually decreases.The cyclic heat storage status has obvious advantages in heat generation and cooling.Furthermore,the energy-saving and emission reduction benefits of PHS and geothermal utilization systems were calculated.

A combined method using Lattice Boltzmann Method(LBM)and Finite Volume Method(FVM)to simulate geothermal reservoirs in Enhanced Geothermal System(EGS)

With the development of industrial activities,global warming has accelerated due to excessive emission of CO_(2).Enhanced Geothermal System(EGS)utilizes deep geothermal heat for power generation.Although porous medium theory is commonly employed to model geothermal reservoirs in EGS,Hot Dry Rock(HDR)presents a challenge as it consists of impermeable granite with zero porosity,potentially distorting the physical interpretation.To address this,the Lattice Boltzmann Method(LBM)is employed to simulate CO_(2)flow within geothermal reservoirs and the Finite Volume Method(FVM)to solve the energy conservation equation for temperature distribution.This combined method of LBM and FVM is imple-mented using MATLAB.The results showed that the Reynolds numbers(Re)of 3,000 and 8,000 lead to higher heat extraction rates from geothermal reservoirs.However,higher Re values may accelerate thermal breakthrough,posing challenges to EGS operation.Meanwhile,non-equilibrium of density in fractures becomes more pronounced during the system's life cycle,with non-Darcy's law becoming significant at Re values of 3,000 and 8,000.Density stratification due to buoyancy effects significantly impacts temperature distribution within geothermal reservoirs,with buoyancy effects at Re=100 under gravitational influence being noteworthy.Larger Re values(3,000 and 8,000)induce stronger forced convection,leading to more uniform density distribution.The addition of proppant negatively affects heat transfer performance in geothermal reservoirs,especially in single fractures.Practical engineering considerations should determine the quantity of proppant through detailed numerical simulations.

Structural Controls Analysis and Its Correlation with Geothermal Occurrence at Barrier Volcanic Complex (BVC), Turkana, Kenya

Geothermal is a clean energy source that is freely available in the subsurface. The exploitation of this vital resource needs intensive exploration in order to identify and quantify its occurrence. The three parameters considered when assessing the viability of a geothermal system include;heat source, fractures and fluids. Geological structures are important in transportation of fluids to and from the heat source aiding in recharge of the geothermal system and enhancing productivity. Remote sensing method was applied in mapping the structures at Barrier Volcanic Complex (BVC) by using hill shading technique which utilized four illumination angles of the sun (azimuth) i.e. 45°, 90°, 150°, and 315°, constant elevation of 45° and exaggeration of 10. The data used was Shuttle Radar Topographic Mission (SRTM) Satellite Imagery. ArcGIS Software was used for lineaments delineation and density mapping, PCI Geomatica was used to generate major faults, while Georose and Rockworks 17 were used to generate the rose diagrams. Geological structural analysis was done by delineating lineaments, determining the density distribution of lineaments and finally determining the structural trends of lineaments. The generated major faults in the area and the location of the occurrence of surface manifestations were compared with the generated lineaments. A total of 260 lineaments were generated whereby at 45° there was a total of 60 lineaments, at 90° 95 lineaments, at 150° 61 lineaments, and at 315° 44 lineaments. The results of structural analysis in the area as shown by the rose diagrams indicate an NNE-SSW and N-S trending of structures. In conclusion, the study area is highly fractured as indicated by the presence of numerous lineaments. These lineaments provide good recharge to the geothermal system and enhance the geothermal reservoir in the area.

Fluid-rock interaction experiments with andesite at 100℃ for potential carbon storage in geothermal reservoirs

Geothermal energy extraction often results in the release of naturally occurring carbon dioxide(CO_(2))as a byproduct.Research on carbon storage using volcanic rock types other than basalt under both acidic and elevated temperature conditions has been limited so far.Our study uses batch reactor experiments at 100℃ to investigate the dissolution of andesite rock samples obtained from an active geothermal reservoir in Sumatra(Indonesia).The samples are subjected to reactions with neutral-pH fluids and acidic fluids,mimicking the geochemical responses upon reinjection of geothermal fluids,either without or with dissolved acidic gases,respectively.Chemical elemental analysis reveals the release of Ca^(2+)ions into the fluids through the dissolution of feldspar.The overall dissolution rate of the rock samples is 2.4×10^(–11)to 4.2×10^(–11)mol/(m^(2)·s),based on the Si release during the initial 7 h of the experiment.The dissolution rates are about two orders of magnitude lower than those reported for basaltic rocks under similar reaction conditions.This study offers valuable insights into the potential utilization of andesite reservoirs for effective CO_(2) storage via mineralization.

Progress and prospect of mid-deep geothermal reinjection technology

Mid-deep geothermal reinjection technology is crucial for the sustainable development of geothermal resources,which has garnered significant attention and rapid growth in recent years.Currently,various geothermal reinjection technologies lag behind,lacking effective integration to address issues like low reinjection rates and thermal breakthrough.This paper reviews the basic principles and development history of mid-deep geothermal reinjection technology,focusing on various technical methods used in the process and analyzing their applicability,advantages,and disadvantages under different geological conditions.It highlights the unique challenges posed by deep geothermal resources,including high temperature,high pressure,high stress,chemical corrosion,and complex geological structures.Additionally,it addresses challenges in equipment selection and durability,system stability and operation safety,environmental impact,and sustainable development.Finally,the paper explores future directions for mid-deep geothermal reinjection technology,highlighting key areas for further research and potential pathways for technological innovation.This comprehensive analysis aims to accelerate the advancement of geothermal reinjection technology,offering essential guidance for the efficient reinjection and sustainable development of geothermal resources.

Advances in sodium-ion batteries at low-temperature: Challenges and strategies

With the continuing boost in the demand for energy storage,there is an increasing requirement for batteries to be capable of operation in extreme environmental conditions.Sodium-ion batteries(SIBs) have emerged as a highly promising energy storage solution due to their promising performance over a wide range of temperatures and the abundance of sodium resources in the earth's crust.Compared to lithiumion batteries(LIBs),although sodium ions possess a larger ionic radius,they are more easily desolvated than lithium ions.Fu rthermore,SIBs have a smaller Stokes radius than lithium ions,resulting in improved sodium-ion mobility in the electrolyte.Nevertheless,SIBs demonstrate a significant decrease in performance at low temperatures(LT),which constrains their operation in harsh weather conditions.Despite the increasing interest in SIBs,there is a notable scarcity of research focusing specifically on their mechanism under LT conditions.This review explores recent research that considers the thermal tolerance of SIBs from an inner chemistry process perspective,spanning a wide temperature spectrum(-70 to100℃),particularly at LT conditions.In addition,the enhancement of electrochemical performance in LT SIBs is based on improvements in reaction kinetics and cycling stability achieved through the utilization of effective electrode materials and electrolyte components.Furthermore,the safety concerns associated with SIBs are addressed and effective strategies are proposed for mitigating these issues.Finally,prospects conducted to extend the environmental frontiers of commercial SIBs are discussed mainly from three viewpoints including innovations in materials,development and research of relevant theoretical mechanisms,and intelligent safety management system establishment for larger-scale energy storage SIBs.

Temperature inversion enables superior stability for low-temperature Zn-ion batteries

It is challenging for aqueous Zn-ion batteries(ZIBs)to achieve comparable low-temperature(low-T)performance due to the easy-frozen electrolyte and severe Zn dendrites.Herein,an aqueous electrolyte with a low freezing point and high ionic conductivity is proposed.Combined with molecular dynamics simulation and multi-scale interface analysis(time of flight secondary ion mass spectrometry threedimensional mapping and in-situ electrochemical impedance spectroscopy method),the temperature independence of the V_(2)O_(5)cathode and Zn anode is observed to be opposite.Surprisingly,dominated by the solvent structure of the designed electrolyte at low temperatures,vanadium dissolution/shuttle is significantly inhibited,and the zinc dendrites caused by this electrochemical crosstalk are greatly relieved,thus showing an abnormal temperature inversion effect.Through the disclosure and improvement of the above phenomena,the designed Zn||V_(2)O_(5)full cell delivers superior low-T performance,maintaining almost 99%capacity retention after 9500 cycles(working more than 2500 h)at-20°C.This work proposes a kind of electrolyte suitable for low-T ZIBs and reveals the inverse temperature dependence of the Zn anode,which might offer a novel perspective for the investigation of low-T aqueous battery systems.