Synthesis strategies of covalent organic frameworks: An overview from nonconventional heating methods and reaction media

Covalent organic frameworks(COFs), as an emerging class of porous crystalline materials constructed by covalent links between the building monomers, have gained tremendous attention. Over the past 15 years, COFs have made rapid progress and substantial development in the chemistry and materials fields. However, the synthesis of COFs has been dominated by solvothermal methods for a long time and it usually involves high temperature, high pressure and toxic organic solvents, which created many challenges for environmental considerations. Recently,the exploration of new approaches for facile fabrication of COFs has aroused extensive interest. Hence, in this review, we comprehensively describe the synthetic strategies of COFs from the aspects of nonconventional heating methods and reaction media. In addition, the advantages,limitations and properties of the preparation methods are compared. Finally, we outline the main challenges and development prospects of the synthesis of COFs in the future and propose some possible solutions.

Numerical simulation analysis on multi-layer low-temperature heating method of asphalt pavement in hot in-place recycling

Asphalt mixture pavement reheating is one of the important steps in hot in-place recycling(HIR).To improve the heating speed of asphalt pavement in HIR,based on the numerical analysis model of asphalt mixture heating process,a new multi-layer low-temperature heating method(MLHM)was proposed.Considering input heat flux,the thermal capacity and thermal resistance of asphalt mixture,the heat transfer model was established based on energy conservation law.By heating the asphalt mixture in layers,it changes the situation that the heat energy can only be input from the upper surface of the asphalt mixture pavement.Through the simulation of the heating method of asphalt mixture in the existing technology,the result shows that the existing heating methods lead to serious aging or charring of the asphalt mixture.By MLHM,the upper and the bottom of the asphalt mixture are heated at the same time,and the heating temperature is lower than other heat methods,which not only reduces the heating thickness and increases the heating area of the asphalt mixture pavement,but also improves the heating speed,saves the energy resource and ensures the heating quality.Especially,by MLHM,the heating uniformity is better and speed is faster.

A review of low-temperature heat recovery technologies for industry processes

The amount of low-temperature heat generated in industrial processes is high,but recycling is limited due to low grade and low recycling efficiency,which is one of the reasons for low energy efficiency.It implies that there is a great potential for low-temperature heat recovery and utilization.This article provided a detailed review of recent advances in the development of low-temperature thermal upgrades,power generation,refrigeration,and thermal energy storage.The detailed description will be given from the aspects of system structure improvement,work medium improvement,and thermodynamic and economic performance evaluation.It also pointed out the development bottlenecks and future development trends of various technologies.The low-temperature heat combined utilization technology can recover waste heat in an all-round and effective manner,and has great development prospects.

Trifunctional strategy for the design and synthesis of a Ni-CeO_(2)@SiO_(2)catalyst with remarkable low-temperature sintering and coking resistance for methane dry reforming

In this study,a trifunctional strategy was developed to prepare a confined Ni-based catalyst(Ni-CeO_(2)@SiO_(2))for dry reforming of methane(DRM)of two main greenhouse gases-CO_(2)and CH_(4).The Ni-CeO_(2)@SiO_(2)catalyst was fabricated by utilizing the confinement effect of the SiO_(2)shell and the synergistic interaction between Ni-Ce and the decoking effect of CeO_(2).The catalysts were systematically characterized via X-ray diffraction,N_(2 )adsorption/desorption,transmission electron microscopy,energy dispersive X-ray spectroscopy,hydrogen temperature reduction and desorption set by program,oxygen temperature program desorption,Raman spectroscopy,thermogravimetric analysis,and in situ diffuse reflectance infrared Fourier transform spectroscopy measurements to reveal their physicochemical properties and reaction mechanism.The Ni-CeO_(2)@SiO_(2)catalyst exhibited higher activity and stability than the catalyst synthesized via the traditional impregnation method.In addition,no carbon deposition was detected over Ni-CeO_(2)@SiO_(2)after a 100 h durability test at 800℃,and the average particle size of Ni nanoparticles(NPs)in the catalyst increased from 5.01 to 5.77 nm.Remarkably,Ni-CeO_(2)@SiO_(2)also exhibited superior low-temperature stability;no coke deposition was observed when the catalyst was reacted at 600℃ for 20 h.The high coking and sintering resistance of this confined Ni-based DRM catalyst can be attributed to its trifunctional effect.The trifunctional strategy developed in this study could be used as a guideline to design other high-performance catalysts for CO_(2)and CH4 dry forming and accelerate their industrialization.

Low-temperature heat capacities and standard molar enthalpy of formation of pyridine-2,6-dicarboxylic acid

This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 K. A polynomial equation of heat capacities as a function of temperature was fitted by the least-squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at intervals of 5 K. The constant-volume energy of combustion of the compound was determined by means of a precision rotating-bomb combustion calorimeter. The standard molar enthalpy of combustion of the compound was derived from the constant-volume energy of combustion. The standard molar enthalpy of formation of the compound was calculated from a combination of the datum of the standard molar enthalpy of combustion of the compound with other auxiliary thermodynamic quantities through a Hess thermochemical cycle.

Simulation Study of the Control Strategy of a DC Inverter Heat Pump Using a DC Distribution Network

Photovoltaics,energy storage,direct current and flexibility(PEDF)are important pillars of achievement on the path to manufacturing nearly zero energy buildings(NZEBs).HVAC systems,which are an important part of public buildings,play a key role in adapting to PDEF systems.This research studied the basic principles and operational control strategies of a DC inverter heat pump using a DC distribution network with the aim of contributing to the development and application of small DC distribution systems.Along with the characteristics of a DC distribution network and different operating conditions,a DC inverter heat pump has the ability to adapt to changes in the DC bus voltage and adds flexibility to the system.Theoretical models of the DC inverter heat pump integrated with an ice storage unit were developed.The control strategies of the DC inverter heat pump system considered the influence of both room temperature and varied bus voltage.A simulation study was conducted using MATLAB&Simulink software with simulation results validated by experimental data.The results showed that:(1)The bus fluctuation under the rated working voltage had little effect on the operation of the unit;(2)When the bus voltage was fluctuating from 80%-90%or 105%-107%,the heat pump could still operate normally by reducing the frequency;(3)When the bus voltage was less than 80%or more than 107%,the unit needed to be shut down for the sake of equipment safety,so that the energy storage device could adjust to the sharp decrease or rise of voltage.

Utilization and recycling of low-temperature waste heat of stainless steel continuous annealing furnace

Stainless steel continuous annealing furnace is mainly used for heat treatment of hot-rolled strip steel.The combustion air will be enabled to heat to 520℃by waste heat recovery system,but the discharge temperature is still up to about 300℃.Owing to with development of global emphasis on energy conservation energy saving and discharge reduction,it's significant to lower the discharge temperature to below 200℃, for the sake of achieving rational use of waste heat resource.Through the analysis of the existing heat recovery system by this study,it is proved that mixing low temperature with flue gas in high temperature standard will increase the capacity of the flue gas and deteriorate the quality of remaining heat resource.In stead of that,increasing the combustion air temperature to 600℃on the basis of stability temperature for the prerequisite of recuperator design,and giving priority to reducing fuel consumption are the better way.The recovery and recycle of low temperature gas are also be introduced.It is demonstrated by the way of setting a secondary recuperator at the exit of the primary recuperator,and using low temperature flue gas to heat the air used for drying the strip steel,the exhuast temperature of flue gas can be reduced to lower than 200℃.At the same time,the steam required for heating air is saved,the energy reserve as high as 2 300 t of standard coal per year.

Initiative Optimization Operation Strategy and Multi-objective Energy Management Method for Combined Cooling Heating and Power

This paper proposed an initiative optimization operation strategy and multi-objective energy management method for combined cooling heating and power U+0028 CCHP U+0029 with storage systems. Initially, the initiative optimization operation strategy of CCHP system in the cooling season, the heating season and the transition season was formulated. The energy management of CCHP system was optimized by the multi-objective optimization model with maximum daily energy efficiency, minimum daily carbon emissions and minimum daily operation cost based on the proposed initiative optimization operation strategy. Furthermore, the pareto optimal solution set was solved by using the niche particle swarm multi-objective optimization algorithm. Ultimately, the most satisfactory energy management scheme was obtained by using the technique for order preference by similarity to ideal solution U+0028 TOPSIS U+0029 method. A case study of CCHP system used in a hospital in the north of China validated the effectiveness of this method. The results showed that the satisfactory energy management scheme of CCHP system was obtained based on this initiative optimization operation strategy and multi-objective energy management method. The CCHP system has achieved better energy efficiency, environmental protection and economic benefits. © 2014 Chinese Association of Automation.

Low-temperature heat capacities and standard molar enthalpy of formation of 4-(2-aminoethyl)-phenol (C_8H_(11)NO)

This paper reports that low-temperature heat capacities of 4-（2-aminoethyl）-phenol （C8H11NO） are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15K were calculated and tabulated at the interval of 5K. The energy equivalent, εcalor, of the oxygen-bomb combustion calorimeter has been determined from 0.68g of NIST 39i benzoic acid to be εcalor=（14674.69±17.49）J·K^-1. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter to be ΔcU=-（32374.25±12.93）J·g^-1. The standard molar enthalpy of combustion for the compound was calculated to be ΔcHm = -（4445.47 ± 1.77） kJ·mol^-1 according to the definition of enthalpy of combustion and other thermodynamic principles. Finally, the standard molar enthalpy of formation of the compound was derived to be ΔfHm（C8H11NO, s）=-（274.68 ±2.06） kJ·mol^-1, in accordance with Hess law.

Low-temperature heat capacities of crystalline Ho(Gly)_(3)Cl_(3)·3H_(2)O from 78 to 348 K

Heat capacities of the rare-earth complex with glycine [Ho(Gly)3Cl3·3H2O] were measured with a high-precision automatic adiabatic calorimeter over the temperature range from 78 to 348 K.In the experimental temperature range,the heat capacities increased in a smooth and continuous manner and no phase transition or thermal anomaly occurred.Therefore,the sample was stable in the above temperature range.The values of experimental heat capacities were fitted to a polynomial equation with least square method and ...

Piezoelectric Power Harvesting Process via Phase Changes of Low-Boiling-Point Medium Together with Water for Recovering Low-Temperature Heats

Low-temperature thermal energy conversions down to exergy zero to electric power must contribute energy sustainability. That is to say, reinforcements of power harvesting technologies from extremely low temperatures less than 373 K might be at least one of minimum roles for the current generations. Then, piezoelectric power harvesting process for recovering low-temperature heats was invented by using a unique biphasic operating medium of an underlying water-insoluble/low-boiling-point medium (i.e. NOVEC manufactured by 3M Japan Ltd.) in small quantity and upper-layered water in large quantity. The higher piezoelectric power harvesting densities were naturally revealed with an increase in heating temperatures. Excessive cooling of the operating medium deteriorated the power harvesting efficiency. The denser operating medium was surpassingly helpful to the higher piezoelectric power harvesting density. Concretely, only about 5% density increase of main operating medium (i.e. water with dissolving alum at 0.10 mol/dm3) came to the champion piezoelectric power harvesting density of 92.6 pW/dm2 in this study, which was about 1.4 times compared to that with the original biphasic medium of pure water together with a small quantity of NOVEC.

Anomalous low-temperature heat capacity in antiperovskite compounds

The low-temperature heat capacities are studied for antiperovskite compounds AX M_3（A = Al, Ga, Cu, Ag, Sn, X = C,N, M = Mn, Fe, Co）. A large peak in（C- γ T）/T^3 versus T is observed for each of a total of 18 compounds investigated,indicating an existence of low-energy phonon mode unexpected by Debye T^3 law. Such a peak is insensitive to the external magnetic field up to 80 k Oe（1 Oe = 79.5775 A·m-1）. For compounds with smaller lattice constant, the peak shifts towards higher temperatures with a reduction of peak height. This abnormal peak in（C- γ T）/T^3 versus T of antiperovskite compound may result from the strongly dispersive acoustic branch due to the heavier A atoms and the optical-like mode from the dynamic rotation of X M_6 octahedron. Such a low-energy phonon mode may not contribute negatively to the normal thermal expansion in AX M_3 compounds, while it is usually concomitant with negative thermal expansion in open-structure material（e.g., ZrW_2O_8, Sc F_3）.

Heat flow balance and control strategies for a large GSHP

The possibility of underground imbalance between heat emission and absorption has a negative impact on the performance of ground-source heat pump systems （GSHPs）. Numerical and experimental researches were made in a residential building, which is supplied with a GSHP system and a ceiling radiation system combined with a replacement fresh air system. EnergyPlus simulations were used to estimate heating and cooling loads, and to assess the heat generated from the water pump, the fan and the heat pump unit. Then, Fluent simulations were used to compare three different control strategies of handling the underground heat exchange. These simulations were strongly based on an experimentally verified model. It is obtained that a ratio between cooling and heating loads is 5.08 ： 1 in a case study in Nanjing. Moreover, the control strategy based on the starting time is more efficient and reliable than the temperature and temperature difference strategies to control the underground heat exchange.

A Two-step Design Method for Shaft Work Targeting on Low-temperature Process

In low-temperature processes, there are interactions between heat exchanger network(HEN) and refrigeration system. The modification on HEN of the chilling train for increasing energy recovery does not always coordinate with the minimum shaft work consumption of the corresponding refrigeration system. In this paper, a systematic approach for optimizing low-temperature system is presented through mathematical method and exergy analysis. The possibility of "pockets", which appears as right nose section in the grand composite curve(EGCC) of the process, is first optimized. The EGCC with the pockets cutting down is designed as a separate part. A case study is used to illustrate the application of the approach for a HEN of a chilling train with propylene and ethylene refrigerant system in an ethylene production process.

Refrigerant Control Strategies for Residential Air-Conditioning and Heat-Pump System

This paper simulated the optimal refrigerant charge inventory of a refrigeration system in air-conditioning operation and heat-pump operation respectively,and studied the refrigerant control strategies in this system.The void fraction in two-phase fluid region was calculated by Harms model.And based on distributed parameter model and Harms model,the refrigerant charge inventory in condenser and evaporator were calculated and analyzed in air-conditioning conditions and heat-pump conditions,respectively.The calculating results of different refrigerant mass between refrigeration and heating conditions indicate that the optimal refrigerant charge inventory in heat-pump conditions is lower than that in air-conditioning conditions.To avoid the decrease of COP due to the surplus refrigerant in heating conditions,we introduced the liquid reservoir control method and associate capillary control method.Both of them could increase the heating capacity of the air-source heat pump.The difference of optimal refrigerant charge inventory in air-conditioning and heat-pump system can be controlled by the liquid reservoir or the associate capillary.

Exploration and Research on Translation Strategies of Terminologies in Treatise on Warm Heat Disease

Cultural Translation Theory,originated in the 20 th century,states that the study of translation is the study of cultural in-teraction.It aims to explain that translation should not merely be constrained at traditional linguistic level,but should go to a muchbroader area,that is to say,the cultural and historical frame to direct our translation.Wen Re Lun(Treatise on Warm Heat Disease)is a representative classic of Warm Disease Theory in Traditional Chinese Medicine(TCM),with considerable cultural tradition.From the perspective of Cultural Translation Theory,this thesis discussed the translation strategy of terminologies in Wen Re Lun.The principle,"mainly based on foreignization and domestication as minor",could be preferable to transmit the TCM essence byits own language.

Effect of Putrescine on Low-Temperature Acclimation in Chlamydomonas reinhardtii

Putrescine is reported to be necessary for cold acclimation under low-temperature stress.In this study,the effect of low-temperature on some physiological and biochemical parameters has been investigated using the green algae Chlamydomonas reinhardtii.The lipid peroxidation rate,amount of Rubisco protein,activities of antioxidant enzymes and gene expression of polyamine biosynthesis(odc2,and spd1),heat shock proteins(hsp70c,hsp90a,and hsp90c),and PSII repair mechanisms(psba,rep27,and tba1)were determined to understand the low-temperature response.Exogenous putrescine application significantly increased Rubisco protein concentration and catalase enzyme activities under low-temperature stress.Moreover,real-time RT-PCR results and gene expression analysis showed that polyamine metabolism induced gene expression at low-temperatures in the first 24 h.In the same way,the gene expression of heat shock proteins(hsp70c,hsp90a,and hsp90c)decreased under low-temperature treatment for 72 h;however,application of putrescine enhanced the gene expression in the first 24 h.The results obtained indicated that molecular response in the first 24 h could be important for cold acclimation.The psba and tba1 expressions were reduced under low-temperatures depending on the exposure time.In contrast,the exogenous putrescine enhanced the expression level of the psba response to low-temperature at 24 and 72 h.The results obtained in this study indicate that putrescine could play a role in the PS II repair mechanisms under low-temperature stress.

Analysis of treatment strategies of traditional Chinese medicine for COVID-19 in tropical regions based on the pathogens of dampness and heat

Objective:To summarize the treatment strategies of Traditional Chinese Medicine(TCM)for COVID-19 in tropical regions based on the pathogens of dampness and heat.Methods:For heat pathogen,analyzing heat in the superficies,lung and Yang Ming based on the different locations.Based on the progress of the disease,analyzing the stage of toxin and Qi deficiency induced by heat.For dampness pathogen,analyzing endogenous and external dampness based on the different locations.Analyzing dampness pathogen's special disease location—Moyuan and special symptom of dry cough with less sputum caused by sticky and stagnant characteristic of dampness.Results:The treatment strategies for heat and dampness pathogen were summarized.Conclusion:In the tropics,the pathogens of dampness and heat occur frequently and clinical treatments need to be dialectical.

Study of energy-efficient heat resistance and cooling technology for high temperature working face with multiple heat sources in deep mine

In the present research,we proposed a scheme to address the issues of severe heat damage,high energy consumption,low cooling system efficiency,and wastage of cold capacity in mines.To elucidate the seasonal variations of environmental temperature through field measurements,we selected a high-temperature working face in a deep mine as our engineering background.To enhance the heat damage control cability of the working face and minimize unnecessary cooling capac-ity loss,we introduced the multi-dimensional heat hazard prevention and control method called"Heat source barrier and cooling equipment".First,we utilize shotcrete and liquid nitrogen injection to eliminate the heat source and implemented pressure equalization ventilation to disrupt the heat transfer path,thereby creating a heat barrier.Second,we establish divi-sional prediction models for airflow temperature based on the variation patterns obtained through numerical simulation.Third,we devise the location and dynamic control strategy for the cooling equipment based on the prediction models.The results of field application show that the heat resistance and cooling linkage method comply with the safety requirement throughout the entire mining cycle while effectively reducing energy consumption.The ambient temperature is maintained below 30℃,resulting in the energy saving of 10%during the high-temperature period and over 50%during the low-temperature period.These findings serve as a valuable reference for managing heat damage in high-temperature working faces.

山地城市高温热浪灾害空间识别与风险评估——以重庆市为例

【目的】以重庆市为代表的山地城市高温热浪问题突出,对高温热浪风险进行准确识别与科学评估是增强城市韧性和气候适应性的重要途径。【方法】采集社会经济、地理信息和人口数据,识别高温热浪风险要素,构建以“危险性—山地城市暴露度—脆弱性”为框架的山地城市高温热浪风险评估体系,并选择重庆市2018年7—9月典型高温热浪事件展开评估。【结果】极高和高风险区县都分布在中心城区以内,其高温热浪平均风险水平超出中等级风险区的2倍,由危险性和暴露度共同主导,越靠近中心,综合风险越高;危险性与暴露度都呈“近高远低”的空间分布特征,脆弱性空间分布特征则为“近低远高”;危险性较小的区县往往收入、医疗、教育水平有限,脆弱性明显高于中心城区;根据高温热浪风险主导因子的不同,以“局地优化、区域互补”为思路,提出山地城市热灾害风险应对策略与规划建议。【结论】完善了风景园林应对气候变化的策略体系,推动构建健康、安全、舒适的城市人居环境,为落实山地城市气候韧性发展规划提供理论支持与指导。