Dependence of Lower Molding Temperature Limit and Molding Time on Molding Mechanism in Dental Thermoforming

Effectiveness and safety of a sports mouthguard depend on its thickness and material, and the thermoforming process affects these. The purpose of this study was to clarify the effects of differences in molding mechanisms on the lower molding temperature limit and molding time in dental thermoforming. Ethylene vinyl acetate resin mouthguard sheet and two thermoforming machines;vacuum blower molding machine and vacuum ejector/pressure molding machine were used. The molding pressures for suction molding were −0.018 MPa for vacuum blower molding and −0.090 MPa for vacuum ejector molding, and for pressure molding was set to 0.090 MPa or 0.450 MPa. Based on the manufacturer’s standard molding temperature of 95˚C, the molding temperature was lowered in 2.5˚C increments to determine the lower molding temperature limit at which no molding defects occurred. In order to investigate the difference in molding time depending on the molding mechanism, the duration of molding pressure was adjusted in each molding machine, and the molding time required to obtain a sample without molding defects was measured. The molding time of each molding machine were compared using one-way analysis of variance. The lower molding temperature limit was 90.0˚C for the vacuum blower machine, 77.5˚C for the vacuum ejector machine, 77.5˚C for the pressure molding machine at 0.090 MPa, and 67.5˚C for the pressure molding machine at 0.45 MPa. The lower molding temperature limit was higher for lower absolute values of molding pressure. The molding time was shorter for pressure molding than for suction molding. Significant differences were observed between all conditions except between the pressure molding machine at 0.090 MPa and 0.45 MPa (P < 0.01). A comparison of the differences in lower molding temperature limit and molding time due to molding mechanisms in dental thermoforming revealed that the lower molding temperature limit depends on the molding pressure and that the molding time is longer for suction molding than for pressure molding.

Effects of thawing-induced softening on fracture behaviors of frozen rock

Due to the presence of ice and unfrozen water in pores of frozen rock,the rock fracture behaviors are susceptible to temperature.In this study,the potential thawing-induced softening effects on the fracture behaviors of frozen rock is evaluated by testing the tension fracture toughness(KIC)of frozen rock at different temperatures(i.e.-20℃,-15℃,-12℃,-10℃,-8℃,-6℃,-4℃,-2℃,and 0℃).Acoustic emission(AE)and digital image correlation(DIC)methods are utilized to analyze the microcrack propagation during fracturing.The melting of pore ice is measured using nuclear magnetic resonance(NMR)method.The results indicate that:(1)The KIC of frozen rock decreases moderately between-20℃ and-4℃,and rapidly between-4℃ and 0℃.(2)At-20℃ to-4℃,the fracturing process,deduced from the DIC results at the notch tip,exhibits three stages:elastic deformation,microcrack propagation and microcrack coalescence.However,at-4℃e0℃,only the latter two stages are observed.(3)At-4℃e0℃,the AE activities during fracturing are less than that at-20℃ to-4℃,while more small events are reported.(4)The NMR results demonstrate a reverse variation trend in pore ice content with increasing temperature,that is,a moderate decrease is followed by a sharp decrease and-4℃ is exactly the critical temperature.Next,we interpret the thawing-induced softening effect by linking the evolution in microscopic structure of frozen rock with its macroscopic fracture behaviors as follow:from-20℃ to-4℃,the thickening of the unfrozen water film diminishes the cementation strength between ice and rock skeleton,leading to the decrease in fracture parameters.From-4℃ to 0℃,the cementation effect of ice almost vanishes,and the filling effect of pore ice is reduced significantly,which facilitates microcrack propagation and thus the easier fracture of frozen rocks.

Experiment and constitutive modelling of creep deformation in the frozen silt-concrete interface

To ensure the long-term safety and stability of bridge pile foundations in permafrost regions,it is necessary to investigate the rheological effects on the pile tip and pile side bearing capacities.The creep characteristics of the pile-frozen soil interface are critical for determining the long-term stability of permafrost pile foundations.This study utilized a self-developed large stress-controlled shear apparatus to investigate the shear creep characteristics of the frozen silt-concrete interface,and examined the influence of freezing temperatures(−1,−2,and−5°C),contact surface roughness(0,0.60,0.75,and 1.15 mm),normal stress(50,100,and 150 kPa),and shear stress on the creep characteristics of the contact surface.By incorporating the contact surface’s creep behavior and development trends,we established a creep constitutive model for the frozen silt-concrete interface based on the Nishihara model,introducing nonlinear elements and a damage factor.The results revealed significant creep effects on the frozen silt-concrete interface under constant load,with creep displacement at approximately 2-15 times the instantaneous displacement and a failure creep displacement ranging from 6 to 8 mm.Under different experimental conditions,the creep characteristics of the frozen silt-concrete interface varied.A larger roughness,lower freezing temperatures,and higher normal stresses resulted in a longer sample attenuation creep time,a lower steady-state creep rate,higher long-term creep strength,and stronger creep stability.Building upon the Nishihara model,we considered the influence of shear stress and time on the viscoelastic viscosity coefficient and introduced a damage factor to the viscoplasticity.The improved model effectively described the entire creep process of the frozen silt-concrete interface.The results provide theoretical support for the interaction between pile and soil in permafrost regions.

The relationship between dolomite textures and their formation temperature: a case study from the Permian-Triassic of the Sichuan Basin and the Lower Paleozoic of the Tarim Basin

Study of dolomite texture can contribute to understanding the process of dolomitization.This research reports textures and homogenization temperatures of dolomites from the Permian-Triassic strata in the Sichuan Basin and the Lower Paleozoic strata in the Tarim Basin,which provided insights into relationships between dolomite textures and their formation temperatures.Our results are summarized as follows：1） dolomites with well-preserved texture indicate low dolomitization temperature.However,in certain diagenetic environments,the hydrothermal dolomitization may completely or partially preserve the original texture of dolomites.2） The formation temperatures of non-planar dolomites are always higher than those of planar dolomites.3） The formation temperatures of dolomite cements are generally higher than those of replacive dolomites.4） Although the formation temperatures of saddle dolomite cements have a wide range,they show higher values than those of the planar subhedral to euhedral dolomite cements.Thus,saddle dolomites could generally be an indicator of high precipitation temperature.5） The fluid Mg/Ca ratio is another element controlling dolomite morphology.Micritic dolomites,which precipitate from hypersaline fluids with a high Mg/Ca ratio in a subaerial environment could also have features of non-planar anhedral crystal shape because of rapid nucleation and crystallization during dolomitization.

Average temperature calculation for straight single-row-piped frozen soil wall

The average temperature of frozen soil wall is an essential parameter in the process of design, construction, and safety manage- ment of artificial ground freezing engineering. It is the basis of calculating frozen soil＇s mechanical parameters, fiarther prediction of bearing capacity and, ultimately, safety evaluation of the frozen soil wall. Regarding the average temperature of sin- gle-row-piped frozen soil wall, this paper summarizes several current calculation methods and their shortcomings. Furthermore, on the basis of Bakholdin＇s analytical solution for the temperature field under straight single-row-piped freezing, two new calcula- tion models, namely, the equivalent trapezoid model and the equivalent triangle model, are proposed. These two approaches are used to calculate the average temperature of a certain cross section which indicates the condition of the whole frozen soil wall. Considering the possible parameter range according to the freezing pipe layout that might be applied in actual construction, this paper compares the average temperatures of frozen soil walls obtained by the equivalent trapezoid method and the equivalent tri- angle method with that obtained by numerical integration of Bakholdin＇s analytical solution. The results show that the discrepancies are extremely small and these two new approaches are better than currently prevailing methods. However, the equivalent triangle method boasts higher accuracy and a simpler formula compared with the equivalent trapezoid method.

Analysis of Low-level Temperature Inversions and Their Effects on Aerosols in the Lower Atmosphere

High-quality and continuous radiosonde, aerosol and surface meteorology datasets are used to investigate the statistical characteristics of meteorological parameters and their effects on aerosols. The data were collected at the Atmospheric Radiation Measurement Southern Great Plains climate research facility during 2000–15. The parameters and vertical distribution of temperature inversion layers were found to have strong diurnal and seasonal changes. For surface-based temperature inversion (SBI), the mean frequency and depth of temperature inversion layers were 39.4% and 198 m, respectively. The temperature difference between the top and bottom of SBI was 4.8℃, and so the temperature gradient was 2.4℃(100 m)^-1. The detailed vertical distributions of temperature inversion had been determined, and only the temperature inversion layers below 1000 m showed diurnal and seasonal variations. Mean surface aerosol number concentrations increased by 43.0%, 21.9% and 49.2% when SBIs were present at 0530, 1730 and 2330 LST, respectively. The effect of SBI on surface aerosol concentration was weakest in summer (18.1%) and strongest in winter (58.4%). During elevated temperature inversion events, there was no noticeable difference in surface aerosol number concentrations. Temperature differences and temperature gradients across SBIs correlated fairly well with aerosol number concentrations, especially for temperature gradients. The vertical distribution of aerosol optical properties with and without temperature inversions was different. Surface aerosol measurements were representative of the air within (below), but not above, SBIs and EIs. These results provide a basis for developing a boundary layer aerosol accumulation model and for improving radiative transfer models in the lower atmosphere.

Summertime temperature variations in the middle and lower reaches of Yangtze River and their related circulation anomalies in the past five decades

Using the daily data of temperature from China Meteorological Administration and the NCEP/NCAR reanalysis from 1960 to 2005, we have analyzed the relationships between the summertime high/low temperature events in the middle and lower reaches of the Yangtze River （MLRYR） and the related circulation anomalies in the Eastern Hemisphere. Our results have demonstrated that a significantly increasing trend is observed in daily minimum temperature in the past 50 years. And in some regions in the Northern Hemisphere, the opposite scenarios are observed in circulation anomalies in lower and upper parts of the troposphere in the years when the temperatures are higher than normal, as compared to those in the years when the temperatures are lower than normal in the middle and lower reaches of the Yangtze River （MLRYR）. Additionally, the anomalous circulation structure in vertical direction in both the high and lower temperature years are barotropic. It is found that the emergence and maintenance of the aforementioned anomalous circulations are related to three kinds of wave train teleconnection patterns. Further more, influences of the long wave surface radiation on the air temperature are stronger in the nighttime than that in the daytime. While both the maximum and minimum temperatures have negative relationships with the sensible heat flux but positive relationships with the latent heat flux. To some extent, the anomalous dynamic heating （cooling） caused by the vertical thermal advection as well as the diabatic heating （cooling） caused by diabatic processes can explain the formation of the high （low） temperature events in the middle and lower reaches of the Yangtze River （MLRYR） in boreal summer.

P-Wave Velocity in Rocks of Dabieshan, China at High Pressure and High Temperature: Constraints for Composition of Lower Crust and Crust-Mantle Recycling

P-wave velocities in the rocks of Dabieshan, central China were measured at pressures up to 5.0 GPa and temperatures up to 1 300℃. The ultrahigh pressure eclogites have the highest density and P-wave velocity (Vp) and lower anisotropy. Pressure derivatives of the eclogites range from 0. 22 to 0. 33 km. s-1 GPa-1. Average temperature derivative of the eclogites is - 3. 41×10-4 km. s-1. °C -1. The density and VP of the eclogites imply that there will be two united possibilities related to crust-mantle recycling after the eclogite formed in the deep lithosphere. One is that some eclogites in the deep lithosphere were detached and sunk into deeper mantle due to their denser density. Another is that some eclogites returned to the crust and exposed to the surface.Small amounts (<12%) of eclogites may be still exist in the deep crust beneath Dabieshan based on our calculation.

Synthesis and Characterization of Liquid Crystal with Lower Temperature of Phase Change of meso-tetra-(4-n-lauroyloxyphenyl)porphyrin

The synthesis and characterization of meso-tetra (4-n-lauroyloxy phenyl) porphyrin with long ester chains are reported. The domains of stability and the structure of the liquid crystalline phases are determined by optical microscopy and differential scanning calorimerials (DSC).

Alumina Solubility in Na_3AlF_6-K_3AlF_6-AlF_3 Molten Salt System Prospective for Aluminum Electrolysis at Lower Temperature

The alumina solubility in the title system within the composition range of KR{m（K3AlF6）/[m（K3AlF6）＋ m（Na3AlF6）]} 10%―50%, a ternary Na3AlF6-K3AlF6-AlF3 molten system with 23%―29%（mass fraction） AlF3 was investigated by measuring the mass loss of a rotating sintered corundum disc. And the following empirical equation was derived when superheat degree was no more than 60 °C： w（Al2O3）sat=A×（T/1000）B, where A= –1.85774＋ 26.754234w（AlF3）–0.3683–0.00783KR2.363＋0.010266KR2.3048＋0.7902w（AlF3）0.00652, B=112.4625–53.2567w（AlF3）0.4236＋ 5.1079w（AlF3）0.9241＋0.01542w（AlF3）1.3540. Considering both higher alumina solubility and not too high superheat de gree are required, alumina solubility of different compositions at not the same temperature but the same superheat degree was studied, which will be more industrial helpful for selecting prospective compositions. The results show that the composition deserved to be further tested in lower temperature cells is 10%―30% KR and 23%―26%（mass fraction） AlF3.

Effects of Storage Temperature on the Effective Activity of Straw Frozen Semen after Thawing

The aim was to discuss the optimal storage environment and proper insemination time after thawing of 0.25 mL straw frozen semen. Straw frozen semen was thawed at 40 ℃ for 20 s, and then stored at 0 -4 ℃, 14 - 16 ℃, 25 -27 ℃ for 2, 4, 6, 8 and 10 h, respectively. The sperm motility was detected. After thawing, semen was stored at 0 - 4 ℃ and 14 - 16 ℃ for 10 h. Their sperm motilities （0.434 ±0. 016 7 and 0.423 ±0.019 6） had no significant differences （P 〉 0.05） with initial thawing motility （0.441 ± 0.030）. Sperm motility reduced as the storage time prolonged at 25 -27 ℃. Sperm motility after 6 h had signifi- cant differences with that of initial thawing motility （P 〈 O. 05 ）, and sperm motilities after 8 and 10 h showed extremely significant differences （P 〈 0.01 ）. Thus, sperm motility after thawing was still very high after stored at 0 -4 ℃ and 14 - 16 ℃ within 10 h, which met the requirements for insemination. Under this temperature and time ranges, sperm could be carried over long distances, which had small effects on sperm quality and reached the expected insemination effects. However, under the temperature of 25 - 27 ℃, semen should be used for insemination within 6 h after thawing.

Effects of Lower Temperature in Spring on Tea Yield in Xuancheng Area

Data of daily mean temperature, precipitation, sunshine hours and tea yield in Xuancheng area from 1979 to 2008 were used to analyze the relationship between lower temperature in spring and tea yield. The results showed during 1979 -2008, the per unit area yield of tea in Xu- ancheng area fluctuated greatly in various years. The relative meteorological yield of tea changed greatly during 1979 -2008, and the decrease in tea yield occurred frequently over the past 30 years. Over the past 30 years, the probability of lower temperature in spring was 56.7%, and the probability of serious and extremely serious lower temperature in spring was 43.4%. In each off year with decrease in tea yield, medium or above lower temperature in spring occurred, showing that the impact of lower temperature in spring on tea yield was very obvious.

Simulating Experiment for Temperature Field of Frozen Subgrade Using RegulationTubes

The main factors that influence the temperature field of frozen subgrade were analyzed.The experimental equipment for simulating frozen subgrade was built up,and the declining regulating tubes were placed at the foot of the embankment. By means of this equipment two simulating experiments of controlling temperature filed of frozen sub- grade were carried out in the laboratory.One method is to collect natural cold energy,and the other one is to collect natural cold energy ccompanied by artificial refrigeration simultaneously.The result indicates that the latter is an ef- fective method for maintaining the stability of the frozen subgrade.

土壤电阻率的负温特性及冻土对接地极冲击响应的影响

西藏地区由于独特的气候与地理环境,在其冻土地区存在雷电与低温共存现象。低温下冻土作为含冰复杂体系,其在雷击下的冲击散流性能仍不明晰,因此该文就冻土电阻率的负温特性以及接地极的冲击特性开展研究。首先研究了不同含水量、含盐量的土壤电阻率随温度的变化规律;然后在冲击电流作用下,以永冻土试品的表层土壤融化厚度和季节性冻土试品的表层土壤冻结厚度为变量,探究了其对相应冻土中垂直接地极暂态电位的影响规律;最后结合冻结条件下土壤冲击放电的形貌特征与地中电场强度和电流密度的分布特性,探讨了负温下接地极暂态电位变化的本质原因。试验研究表明:考虑盐分对土壤的影响,当其温度在一次冻结温度Tf与二次冻结温度Ts之间时,电阻率随温度下降缓慢上升,只有当温度降至二次冻结温度时,才存在突增现象;在永冻土中,当冻土温度高于Ts时,接地极仍具有较好的散流性能。由此可知降低Ts可以减小水分冻结对土壤电阻率的影响,为避免极寒地区接地极失效提供了新思路。

流体加热融雪系统运行对道路结构温度分布特性影响分析

为了明确流体加热道路融雪系统运行对道路结构短期/长期温度分布特性的影响,利用室外足尺试验系统对比分析了普通水泥混凝土路面结构与流体加热道路融雪系统道路结构在温度、温变速率及温度梯度分布特性等方面的差异,阐明了系统运行对道路结构短期/长期温度分布特性的影响规律。结果表明:融雪系统运行初期,快速上升的流体温度对管壁-路面材料界面存在强烈的温度冲击作用;随着系统持续运行,管壁-路面材料界面的温变速率逐渐减小并趋于稳定,且小于普通路面最大温变速率;同时,融雪系统的运行增大了路面结构内部的温度梯度,改变了路面结构一定深度范围内的热量传递方向。融雪系统道路结构年周期温度分布的观测结果表明:融雪系统的运行可在较短的时间内释放大量热能,降低了道路结构内部热量的散失,有效延缓了季节性冰冻地区冬季道路结构温度的降低及冻结深度的发展。

温度对季冻区粉质黏土强度及变形特性的影响

为研究温度变化对天然状态及饱和状态下粉质黏土强度以及变形的影响,以典型季冻区广泛分布的粉质黏土为研究对象,通过全球数字系统(global digital system,GDS)非饱和土三轴测试系统对天然状态下非饱和土以及GDS温控式静/动三轴测试系统对饱和粉质黏土,在不同温度条件下进行三轴试验。对试验结果进行研究分析可得:非饱和以及饱和粉质黏土的应力-应变曲线均呈现出应变硬化的特性。非饱和粉质黏土的黏聚力随温度降低表现出不断增加的趋势,而内摩擦角随温度降低逐渐减小,但整体变化趋势较小。饱和土的黏聚力与非饱和土变化趋势相同,随温度的降低其黏聚力逐渐增加,但相同温度时其黏聚力小于非饱和土,其内摩擦角则呈先减小后增加的转变趋势。无竖向压力作用时,相同围压条件下,非饱和与饱和粉质黏土轴向变形量随温度降低而增加,相同温度条件下,两者的轴向变形量随围压的增加会有所减小。试验成果可为季冻区粉质黏土地层工程的设计施工提供理论依据。

农业冻土冰含量测量方法试验研究

农业冻土中的冰含量作为冻土冻融过程的关键变量之一,影响着土壤水分动态变化、土壤养分流失和农田生态环境维稳等。根据质量守恒原理和体积变换关系,自制一种农业冻土冰含量测量的试验装置,进行-20、-25、-30℃和土壤含水率为15.7%、23.5%、31.4%的冰含量测量试验。结果表明,农业冻土样品中冰含量随冻结温度降低冰质量含量增加。冻结温度达到-30℃时,冰质量含量达到一个恒定的峰值。相同冻结温度不同含水率状态下,冰质量含量百分比趋于一个平均值,且最大值和最小值之差约为2%。

一种冻土温度场方程的解析解

冻土在我国分布十分广泛,冻胀现象是冻土区经常出现的问题,其导致的工程病害屡见不鲜。冻胀主要是由土体内部温度变化及水分迁移造成的,是一类极其复杂的温度、渗流及应力多场耦合问题。通过对冻土中的温度场进行分析,求解含冰量及孔隙率随温度变化条件下的冻土一般性瞬态热传导方程,获得其近似解析解并应用于冻土热传导过程的预测。通过与有限元计算所得精确解对比,验证其有效性。研究成果对冻土冻胀问题的深入研究具有一定的理论和实践意义。

冻融条件下路基温度场和湿度场分布式感知试验

搭建土体冻融多物理场感知室内试验装置,布设传统点式传感器和分布式光纤,对土体冻融过程中路基温度场、湿度场和变形情况开展试验监测,探究单端冻结、双端融化条件下土体温度场和湿度场的分布式感知特征,验证主动加热分布式光纤技术的监测效果。试验结果表明,-15℃单端冻结条件下,土体冻结过程按降温速率分为快速冷却、逐步降温、稳定平衡三阶段,冻结锋面逐渐下移,最大冻深约占土柱高度的35%。孔隙水受冻胀迁移力影响向冻结锋面移动,引起冻融前后土体湿度场重分布,并导致土体冻胀变形,变形量为土体最大冻深的7.8%~10.9%。分布式光纤可准确得到冻融过程中土体温度场、湿度场变化特征,识别土体内冻结区域范围,温度、湿度监测拟合优度R2分别达0.98和0.94。

四川盆地深层页岩气钻井关键技术新进展及发展展望

四川盆地页岩气资源丰富,目前深层页岩气已成为该盆地天然气增储上产的重点领域,但随着埋深增加和构造背景变化,地质工程条件将更加复杂,钻井过程中将面临井漏风险高、井下工具高温易失效、水平井轨迹控制难度大等技术难题。为此,在系统分析已完钻井实钻数据的基础上,依据深层页岩气区块地质工程特征,系统梳理了影响安全优快钻井的关键技术难点,形成了以地质工程一体化导向技术、钻井提速技术、防漏治漏与复杂防治技术为主体的深层页岩气安全优快钻井关键技术系列。研究结果表明:(1)以精细地质建模优选地质工程“双甜点”、实时靶体追踪为主的地质工程一体化导向技术,实现了地质目标的精准优选和精确追踪;(2)以“高效PDC钻头选型+个性化优化+大扭矩螺杆”高效破岩技术、“MSE+CCS”参数实时优化技术、油基钻井液地面降温+高温旋转导向技术为主的钻井提速技术,实现了页岩气钻井提速提效;(3)以井壁稳定性评价、裂缝性漏层识别、井漏与复杂防治为主的复杂防治技术,从源头降低了井下漏失和卡钻风险。结论认为:(1)形成的深层页岩气安全优快钻井技术,显著提高了机械钻速和铂金靶体钻遇率,在现场规模化推广应用200余口井,单井平均钻井周期降低42.7%,钻井提速效果显著,有力支撑了深层页岩气效益规模开发;(2)深层页岩气钻井将聚焦“地质工程一体化、水平段一趟钻、防漏治漏及智能钻井决策”等方面的技术攻关。