The dynamic characteristics of a liquid thin film lubricated head disk system are analyzed. The shear thinning effect is taken into account by introducing modification coefficients into the lubricant rheological mode...The dynamic characteristics of a liquid thin film lubricated head disk system are analyzed. The shear thinning effect is taken into account by introducing modification coefficients into the lubricant rheological model. The perturbation theory is employed to set up the dynamic pressure equation. The Reynolds equation and dynamic pressure equations are solved by finite difference method. The results obtained by the difference methods agree well with that calculated by the close solutions. IBM3370 slider is employed as a physical model. The slider of the system can keep flying at 20 nm height, which promises a potential application on high density recording device.展开更多
In order to understand lubrication mechanism at the nanoscale, researchers have used many physical experimental approaches, such as surface force apparatus, atomic force microscopy and ball-on-disk tribometer. The res...In order to understand lubrication mechanism at the nanoscale, researchers have used many physical experimental approaches, such as surface force apparatus, atomic force microscopy and ball-on-disk tribometer. The results show that the variation rules of the friction force, film thicknessand viscosity of the lubricant at the nanoscale are different from elastohydrodynamic lubrication (EHL). It is speculated that these differences are attributed to the special arrangement of the molecules at the nanoscale. However, it is difficult to obtain the molecular orientation and distribution directly from the lubricant molecules in these experiments. In recent years, more and more attention has been paid to use new techniques to overcome the shortcomings of traditional experiments, including various spectral methods. The most representative achievements in the experimental research of molecular arrangement are reviewed in this paper: The change of film structure of a liquid crystal under confinement has been obtained using X-ray method. The molecular orientation change of lubricant films has been observed using absorption spectroscopy. Infrared spectroscopy has been used to measure the anisotropy of molecular orientation in the contact region when the lubricant film thickness is reduced to a few tens of nanometers. In situ Raman spectroscopy has been performed to measure the molecular orientation of the lubricant film semi-quantitatively. These results prove that confinement and shear in the contact region can change the arrangement of lubricant molecules. As a result, the lubrication characteristics are affected. The shortages of these works are also discussed based on practicable results. Further work is needed to separate the information of the solid-liquid interface from the bulk liquid film.展开更多
Observation was carried out of the structure of sulphuric,oxalic or phosphoric film on Al after treatment of reanodizing and electrolytic depositing lubricant in (NH_4)_2MoS_4 solution,as well as of the deposited prod...Observation was carried out of the structure of sulphuric,oxalic or phosphoric film on Al after treatment of reanodizing and electrolytic depositing lubricant in (NH_4)_2MoS_4 solution,as well as of the deposited products by means of EMPA,TEM and energy spectro-scopic analysis.The deposited products are mixture of compounds of S and Mo rather than single MoS_2 and most of them dcposited near the surface layer of the film.Some regular long pores without barrier layer occurred in the film,but the regular fine channels without relation to the structural element parameters of original anodized film were found in the thickened barrier layer of phosphoric film.Sulphur may be remained as Mo sulphide in the film during heating under Ar protective environment.展开更多
The inlet film thickness directly affects film and stress distribution of rolling interfaces. Unsteady factors, such as unsteady back tension, may disturb the inlet film thickness. However, the current models of unste...The inlet film thickness directly affects film and stress distribution of rolling interfaces. Unsteady factors, such as unsteady back tension, may disturb the inlet film thickness. However, the current models of unsteady inlet film thickness lack unsteady disturbance factors and do not take surface topography into consideration. In this paper, based on the hydrodynamic analysis of inlet zone an unsteady rolling film model which concerns the direction of surface topography is built up. Considering the small fluctuation of inlet angle, absolute reduction, reduction ratio, inlet strip thickness and roll radius as the input variables and the fluctuation of inlet film thickness as the output variable, the non-linear relationship between the input and output is discussed. The discussion results show that there is 180° phase difference between the inlet film thickness and the input variables, such as the fluctuant absolute reduction, the fluctuant reduction ratio and non-uniform inlet strip thickness, but there is no phase difference between unsteady roll radius and the output. The inlet angle, the steady roll radius and the direction of surface topography have significant influence on the fluctuant amplitude of unsteady inlet film thickness. This study proposes an analysis method for unsteady inlet film thickness which takes surface topography and new disturbance factors into consideration.展开更多
On the basis of thin film lubrication theory, the influence of fluid film(disordered film), ordered film and adsorbed film on tribological behavior of lubricating oil in thin-film lubrication(TFL) regime was studied. ...On the basis of thin film lubrication theory, the influence of fluid film(disordered film), ordered film and adsorbed film on tribological behavior of lubricating oil in thin-film lubrication(TFL) regime was studied. The μ-L(friction coefficient versus load) curves of different oil viscosity and additive dosage were obtained by a high frequency reciprocating test rig and the adsorption capacity of additive on steel surface were measured by QCM-D. Based on the Stribeck curve and thin film lubrication theory model, some conclusions can be drawn up, namely:(1) The μ-L curves and the parameters of L0 and μ0, obtained from the high frequency reciprocating test rig with ball-disc contact, can be used to study tribological behaviors of lubricating oil under TFL conditions.(2) In comparison with the high viscosity base fluid, the lower one can enter into TFL regime under lower load and keeps a lower friction coefficient in TFL regime.(3) The polar molecules in additive formulation produce ordered adsorbed layer on steel surface to reduce friction coefficient. And in TFL regime, the molecule's polarity, layer thickness and saturation degree on steel surface probably can influence lubricant's tribological behaviors between the moving interfaces. Moreover, the further study would be focused on the competitive adsorption of different additives, the formation of dual- and/or tri-molecular adsorption layers, and other aspects.展开更多
Molecular dynamics(MD) simulations using the polymer consistent force field(PCFF) were adopted to investigate the pressure and thickness dependent density of squalane film in a nanogap at 373 K, with three differe...Molecular dynamics(MD) simulations using the polymer consistent force field(PCFF) were adopted to investigate the pressure and thickness dependent density of squalane film in a nanogap at 373 K, with three different initial film thicknesses, and for a wide range of pressures. The equivalent densities predicted by MD simulations were compared with the empirical data. Results show that the squalane atoms tend to form layers parallel to the confining substrates but the orientations of squalane molecules are irregular throughout the film. In addition, distinct excluded volumes are not found at the interfaces of the film and substrates. Furthermore, with the same initial film thickness h_0, the film thickness h and compressibility decrease with increasing pressure, but the compressibility is similar for films with different initial film thicknesses. The equivalent densities predicted by MD simulations with the maximum initial film thickness(9.44 nm) are accurate to the values of Tait equation. The MD simulation with adequate initial film thickness can accurately and conveniently predict the bulk densities of lubricants.展开更多
The characteristics of lubricant film at head/disk interface (HDI) are essential to the stability of hard disk drives. In this study, the theoretical models of the lubricant flow and depletion are deduced based on N...The characteristics of lubricant film at head/disk interface (HDI) are essential to the stability of hard disk drives. In this study, the theoretical models of the lubricant flow and depletion are deduced based on Navier-Stokes (NS) and continuity equations. The air bearing pressure on the surface of the lubrication film is solved by the modified Reynolds equation based on Fukui and Kaneko (FK) model. Then the lubricant film deformations for a plane slider and double-track slider are obtained. The equation of lubricant film thickness is deduced with the consideration of van der Waals force, the air bearing pressure, the surface tension, and the external stresses. The lubricant depletion under heat source is simulated and the effects of different working conditions including initial thickness, flying height and the speed of the disk on lubricant depletion are discussed. The main factors that cause the lubricant flow and depletion are analyzed and the ways to reduce the film thickness deformation are proposed. The simulation results indicate that the shearing stress is the most important factor that causes the thickness deformation and other terms listed in the equation have little influence. The thickness deformation is dependent on the working parameter, and the thermal condition evaporation is the most important factor.展开更多
The molecular dynamics simulation of ultra-thin films under confined shear was performed to investigate the relation between dynamic properties of ultra-thin films and their microstructure. The solid walls were modell...The molecular dynamics simulation of ultra-thin films under confined shear was performed to investigate the relation between dynamic properties of ultra-thin films and their microstructure. The solid walls were modelled using an Au crystal and the fluid molecules were modeled using decane. The simulation results indicate that the microstructure of ultra-thin films is a kind of solid-like layering structure. The density and velocity profiles of the fluid molecules are symmetric. The slip and shear thinning behavior was founded and interpreted.A mathematic model was set up according to the results of the simulation and experiments.展开更多
Experimental results of the lubricating behaviour of Pb-Sn alloy films formed by ion-plating on brass substrates are given. It is shown that the film microhardness, friction coefficient and wear life per thickness are...Experimental results of the lubricating behaviour of Pb-Sn alloy films formed by ion-plating on brass substrates are given. It is shown that the film microhardness, friction coefficient and wear life per thickness are under the influence of the substrate. The wear failure of film appears to be film adhesion and transferring by the mating surface.展开更多
The tribological tests were performed using Nitinol 60 alloy pin sliding over GCr15 steel disc in the tribometer system. Four kinds of oils were experimentally investigated as lubrication oils for lubricating Nitinol ...The tribological tests were performed using Nitinol 60 alloy pin sliding over GCr15 steel disc in the tribometer system. Four kinds of oils were experimentally investigated as lubrication oils for lubricating Nitinol 60 alloy in the boundary lubrication regime. The experimental results were compared with a reference dry friction. It was found that Nitinol 60 alloy can be lubricated significantly and has shown remarkable lubrication performance. A superlubricity behavior of Nitinol 60 alloy was observed under castor oil lubrication. An ultra-low coefficient of friction of Nitinol 60 alloy about 0.008 between Nitinol 60 alloy and GCr15 steel was obtained under castor oil lubrication condition after a running-in period. Accordingly, the present study is focused on the lubrication behaviors of castor oil as potential lubrication oil for Nitinol 60 alloy. In the presence of castor oil, coefficient of friction is kept at 0.008 at steady state, corresponding to so-called superlubricity regime (when sliding is then approaching pure rolling). The mechanism of superlubricity is attributed to the triboformed OH-terminated surfaces from friction-induced dissociation of castor oil and the boundary lubrication films formed on the contact surface due to high polarity and long chain of castor oil allowing strong interactions with the lubricated surfaces.展开更多
A liquid lubricated head disk system is introduced. Subjected to high shear rate the rheology of the ultra thin film is different from that of the bulk continuum theory. The shear thinning effect is considered in set...A liquid lubricated head disk system is introduced. Subjected to high shear rate the rheology of the ultra thin film is different from that of the bulk continuum theory. The shear thinning effect is considered in setting up the mathematical model of the ultra thin film rheology. The Reynolds equation and the perturbation theory are employed to set up the static pressure distribution model and to deduce the dynamic pressure equation. The static and dynamic equations are solved by finite difference method. Based on the dynamic analysis the dynamic response of the slider is simulated and some valuable results are obtained about the static and dynamic characteristics of the liquid lubricated head disk systems.展开更多
Scanning electron microscopy and X-ray energy dispersive spectrum analysis show that the clusters of intermetallic AlFeSi particle are distributed on or near the aluminum foil stock surfaces heterogeneously. 3D finite...Scanning electron microscopy and X-ray energy dispersive spectrum analysis show that the clusters of intermetallic AlFeSi particle are distributed on or near the aluminum foil stock surfaces heterogeneously. 3D finite element modeling shows that these clusters of hard particles induce the fracture of the nano-scale lubricant oil film at first and further lead to severe deformation in the nearby aluminum foil substrate along the rolling direction. Consequently, the optical property in this region differs from that in the surroundings, resulting in surface defects.展开更多
Static and dynamic numerical simulations of high recording density disk drivers are presented in this paper. The shear thinning effect on the viscosity is taken into account in the lubricant rheological model. The per...Static and dynamic numerical simulations of high recording density disk drivers are presented in this paper. The shear thinning effect on the viscosity is taken into account in the lubricant rheological model. The perturbation theory and short bearing theory are employed to set up the static and dynamic lubrication model on the head disk interface. Close solutions are given for the pressure distribution, load capacity and the dynamic characteristics such as stiffness and damping coefficients, which provide a simple method to analyze the dynamic response of the slider supported by the ultra thin fluid film lubricated bearing. Based on the close solutions the static and dynamic responses of the IBM 3380 slider are simulated. Some interesting results are obtained for the analysis of the slider’s flying stability.展开更多
Neodymium dialkylthiophosphate (NdDDP) with alkyls of isopropyl and isooctyl were synthesized by exchanged reaction respectively. The structures of the two NdDDPs were determined using IR and XRD. Properties of anti...Neodymium dialkylthiophosphate (NdDDP) with alkyls of isopropyl and isooctyl were synthesized by exchanged reaction respectively. The structures of the two NdDDPs were determined using IR and XRD. Properties of anti-wear and friction-reducing of the two additives were investigated with four ball experiment and the commercial anti-wear additive ZDDP was selected as control. The elemental analysis of the wear scars after 10 s friction at low stress were investigated by EDXA (Energy Dispersion Analysis of X-ray). Primary results showed that the NdDDPs possess better lubrication ability than ZDDP. This might mainly be contributed to the formation of a boundary film containing Nd2O3, FeS and sulphate, phosphate, organo-sulfide, etc., and a neodymium-rich diffused layer which changes the crystal structure of the surface of friction materials.展开更多
Ni-Cr/h-BN self-lubricating composities were prepared by powder metallurgy (P/M) method.The effects of hexagonal boron nitride (h-BN) content on the mechanical and tribological properties of the Ni-Cr/h-BN composites ...Ni-Cr/h-BN self-lubricating composities were prepared by powder metallurgy (P/M) method.The effects of hexagonal boron nitride (h-BN) content on the mechanical and tribological properties of the Ni-Cr/h-BN composites were investigated.The corresponding frictional models were established to analyze the formation of the lubricant h-BN films on the surfaces of the Ni-Cr/h-BN composites.The results show that,when the content of h-BN increases from 5% to 15% (mass fraction),the bending strength of the Ni-Cr/h-BN composite decreases from 96.670 MPa to 17.319 MPa,and the hardness (HB) decreases from 33 to 14.The friction coefficient of the Ni-Cr/h-BN composite decreases firstly from 0.385 to 0.216,and then increases to 0.284,while the wear rate decreases firstly from 4.14×10-9 kg/(N·m) to 1.35×10-9 kg/(N·m),then increases to 2.36×10-9 kg/(N·m).The best comprehensive mechanical and tribological properties can be obtained between 10% and 12% h-BN addition.展开更多
The acid number of the mixed solution of 150SN oil and oleic acid characterizes the volume content of oleic acid in the solution, based on which the adsorptive capability of oleic acid is studied on the 45 steel balls...The acid number of the mixed solution of 150SN oil and oleic acid characterizes the volume content of oleic acid in the solution, based on which the adsorptive capability of oleic acid is studied on the 45 steel balls and disks. Boundary lubrication tests are carried out on a self designed ball-on-disk machine, The base oil is pure 150SN oil, and oleic acid as additive are added into the lubricant. Disks have surface roughness values (Ra) of 0.8 μn and 0.4 μn. The electrical contact resistance method is used to determine the lubrication status. Hypothesize that the molecular film is monomolecular layer in condensed state and the opposing surfaces are completely separated by molecular film. A boundary lubrication model is established according to experimental results and hypothesizes. The experimental and calculatienal results show that the adsorption of polar molecules on steel surface is the main factor to form the boundary lubrication film. Load and sliding speed contribute little to the friction coefficient of boundary lubrication. The properties of steel surface and additive for the lubricant significantly influence on the characters of boundary lubrication. The smaller the surface roughness value is, the smaller the friction coefficient of the boundary lubrication is.展开更多
The spread of perfluoropolyether (PFPE) droplets on solid surfaces has been measured from the top-down view through a microscope system. Effects of substrates, molecular weight and end-group functionality on spreadi...The spread of perfluoropolyether (PFPE) droplets on solid surfaces has been measured from the top-down view through a microscope system. Effects of substrates, molecular weight and end-group functionality on spreading of the PFPE droplets have been studied experimentally and the results were compared with those by molecular dynamics (MD) simulations. Silicon wafer and diamond-like carbon (DLC) substrates were used to study the effect of substrates on spreading. Two types of PFPE, Z-dol and Z-tetraol, with the same chain structure and various molecular weights (2000 and 4000 g/mol) were employed in experiments. Effect of molecular weight has been investigated through comparing the spreading of Z-dol 2000 and Z-dol 4000, and it is found that the increase of molecular weight will decrease the mobility of PFPE. Comparison between spreading of Z-dol and Z-tetraol of the same molecular weight proved that functional end group plays a significant role on the spreading of PFPE, which confirmed the MD simulation results.展开更多
Molecular dynamics simulations are used to study the boundary lubrication behaviors of squalane lubricant between two iron wall structures during shearing at different pressures and temperatures.Boundary lubrication m...Molecular dynamics simulations are used to study the boundary lubrication behaviors of squalane lubricant between two iron wall structures during shearing at different pressures and temperatures.Boundary lubrication models with a smooth iron wall and a nanostructured iron wall,respectively,are constructed,and the density distribution of the lubricating film and the velocity distribution in the shearing process are analyzed.The mechanical response of the solid wall is output,and the friction coefficient is calculated.A tribological test is performed with a UMT-2 tribometer under sliding conditions to evaluate the reliability of the simulation method.The results show that the surface nanostructure has a significant effect on the film thickness and delamination of the lubricating film but little effect on the velocity distribution of the lubricating film.The nano strip groove helps to reduce the friction coefficient of the boundary lubrication system.展开更多
Molecular dynamic simulations based on a coarse-gralned, bead-spring model are adopted to investigate the spreading of both nonfunctional and functional perfluoropolyether (PFPE) on solid substrates. For nonfunction...Molecular dynamic simulations based on a coarse-gralned, bead-spring model are adopted to investigate the spreading of both nonfunctional and functional perfluoropolyether (PFPE) on solid substrates. For nonfunctional PFPE, the spreading generally exhibits a smooth profile with a precursor film. The spreading profiles on different substrates are compared, which indicate that the bead-substrate interaction has a significant effect on the spreading behaviour, especially on the formation of the precursor film. For functional PFPE, the spreading generally exhibits a complicated terraced profile. The spreading profiles with different endbeads are compared, which indicate that the endbead-substrate interaction and the endbead-endbead interaction, especially the latter, have a significant effect on the spreading behaviour.展开更多
Lubricant spreading on solid substrates has drawn considerable attention not only for the microscopic wetting theory but also for the dramatic application in head-disk interface of magnetic storage drive systems. Mole...Lubricant spreading on solid substrates has drawn considerable attention not only for the microscopic wetting theory but also for the dramatic application in head-disk interface of magnetic storage drive systems. Molecular dynamic simulation based on a coarse-grained bead-spring model has been used to study such a spreading process. The spreading profiles indicate that the hydrogen bonds among lubricant molecules and the hydrogen bonds between lubricant molecules and polar atoms of solid substrates will complicate the spreading process in a tremendous degree. The hydrogen bonds among lubricant molecules will strengthen the lubricant combination intensity, which may hinder most molecules from flowing down to the substrates and diffusing along the substrates. And the hydrogen bonds between lubricant molecules and polar atoms of solid substrates will confine the lubricant molecules around polar atoms, which may hinder the molecules from diffusing along the substrates and cause precursor film to vanish.展开更多
文摘The dynamic characteristics of a liquid thin film lubricated head disk system are analyzed. The shear thinning effect is taken into account by introducing modification coefficients into the lubricant rheological model. The perturbation theory is employed to set up the dynamic pressure equation. The Reynolds equation and dynamic pressure equations are solved by finite difference method. The results obtained by the difference methods agree well with that calculated by the close solutions. IBM3370 slider is employed as a physical model. The slider of the system can keep flying at 20 nm height, which promises a potential application on high density recording device.
基金Supported by National Natural Science Foundation of China(Grant Nos.51335005,51321092)
文摘In order to understand lubrication mechanism at the nanoscale, researchers have used many physical experimental approaches, such as surface force apparatus, atomic force microscopy and ball-on-disk tribometer. The results show that the variation rules of the friction force, film thicknessand viscosity of the lubricant at the nanoscale are different from elastohydrodynamic lubrication (EHL). It is speculated that these differences are attributed to the special arrangement of the molecules at the nanoscale. However, it is difficult to obtain the molecular orientation and distribution directly from the lubricant molecules in these experiments. In recent years, more and more attention has been paid to use new techniques to overcome the shortcomings of traditional experiments, including various spectral methods. The most representative achievements in the experimental research of molecular arrangement are reviewed in this paper: The change of film structure of a liquid crystal under confinement has been obtained using X-ray method. The molecular orientation change of lubricant films has been observed using absorption spectroscopy. Infrared spectroscopy has been used to measure the anisotropy of molecular orientation in the contact region when the lubricant film thickness is reduced to a few tens of nanometers. In situ Raman spectroscopy has been performed to measure the molecular orientation of the lubricant film semi-quantitatively. These results prove that confinement and shear in the contact region can change the arrangement of lubricant molecules. As a result, the lubrication characteristics are affected. The shortages of these works are also discussed based on practicable results. Further work is needed to separate the information of the solid-liquid interface from the bulk liquid film.
文摘Observation was carried out of the structure of sulphuric,oxalic or phosphoric film on Al after treatment of reanodizing and electrolytic depositing lubricant in (NH_4)_2MoS_4 solution,as well as of the deposited products by means of EMPA,TEM and energy spectro-scopic analysis.The deposited products are mixture of compounds of S and Mo rather than single MoS_2 and most of them dcposited near the surface layer of the film.Some regular long pores without barrier layer occurred in the film,but the regular fine channels without relation to the structural element parameters of original anodized film were found in the thickened barrier layer of phosphoric film.Sulphur may be remained as Mo sulphide in the film during heating under Ar protective environment.
基金Supported by National Natural Science Foundation of China(Grant No.51175035)PhD Program Foundation of Ministry of Education of China(Grant No.20100006110024)Beijing Higher Education Young Elite Teacher Project of China(Grant No.YETP0367)
文摘The inlet film thickness directly affects film and stress distribution of rolling interfaces. Unsteady factors, such as unsteady back tension, may disturb the inlet film thickness. However, the current models of unsteady inlet film thickness lack unsteady disturbance factors and do not take surface topography into consideration. In this paper, based on the hydrodynamic analysis of inlet zone an unsteady rolling film model which concerns the direction of surface topography is built up. Considering the small fluctuation of inlet angle, absolute reduction, reduction ratio, inlet strip thickness and roll radius as the input variables and the fluctuation of inlet film thickness as the output variable, the non-linear relationship between the input and output is discussed. The discussion results show that there is 180° phase difference between the inlet film thickness and the input variables, such as the fluctuant absolute reduction, the fluctuant reduction ratio and non-uniform inlet strip thickness, but there is no phase difference between unsteady roll radius and the output. The inlet angle, the steady roll radius and the direction of surface topography have significant influence on the fluctuant amplitude of unsteady inlet film thickness. This study proposes an analysis method for unsteady inlet film thickness which takes surface topography and new disturbance factors into consideration.
基金the PetroChina for its financial support (Grant number: 2011B-2503-2)
文摘On the basis of thin film lubrication theory, the influence of fluid film(disordered film), ordered film and adsorbed film on tribological behavior of lubricating oil in thin-film lubrication(TFL) regime was studied. The μ-L(friction coefficient versus load) curves of different oil viscosity and additive dosage were obtained by a high frequency reciprocating test rig and the adsorption capacity of additive on steel surface were measured by QCM-D. Based on the Stribeck curve and thin film lubrication theory model, some conclusions can be drawn up, namely:(1) The μ-L curves and the parameters of L0 and μ0, obtained from the high frequency reciprocating test rig with ball-disc contact, can be used to study tribological behaviors of lubricating oil under TFL conditions.(2) In comparison with the high viscosity base fluid, the lower one can enter into TFL regime under lower load and keeps a lower friction coefficient in TFL regime.(3) The polar molecules in additive formulation produce ordered adsorbed layer on steel surface to reduce friction coefficient. And in TFL regime, the molecule's polarity, layer thickness and saturation degree on steel surface probably can influence lubricant's tribological behaviors between the moving interfaces. Moreover, the further study would be focused on the competitive adsorption of different additives, the formation of dual- and/or tri-molecular adsorption layers, and other aspects.
基金Funded by the National Natural Science Foundation of China(No.51175085)the Tribology Science Fund of State Key Laboratory of Tribology(No.SKLTKF13A09)the Natural Science Foundation of Fujian Province(No.2016J01226)
文摘Molecular dynamics(MD) simulations using the polymer consistent force field(PCFF) were adopted to investigate the pressure and thickness dependent density of squalane film in a nanogap at 373 K, with three different initial film thicknesses, and for a wide range of pressures. The equivalent densities predicted by MD simulations were compared with the empirical data. Results show that the squalane atoms tend to form layers parallel to the confining substrates but the orientations of squalane molecules are irregular throughout the film. In addition, distinct excluded volumes are not found at the interfaces of the film and substrates. Furthermore, with the same initial film thickness h_0, the film thickness h and compressibility decrease with increasing pressure, but the compressibility is similar for films with different initial film thicknesses. The equivalent densities predicted by MD simulations with the maximum initial film thickness(9.44 nm) are accurate to the values of Tait equation. The MD simulation with adequate initial film thickness can accurately and conveniently predict the bulk densities of lubricants.
基金Project supported by the National Natural Science Foundation of China(Grant No.51275124)
文摘The characteristics of lubricant film at head/disk interface (HDI) are essential to the stability of hard disk drives. In this study, the theoretical models of the lubricant flow and depletion are deduced based on Navier-Stokes (NS) and continuity equations. The air bearing pressure on the surface of the lubrication film is solved by the modified Reynolds equation based on Fukui and Kaneko (FK) model. Then the lubricant film deformations for a plane slider and double-track slider are obtained. The equation of lubricant film thickness is deduced with the consideration of van der Waals force, the air bearing pressure, the surface tension, and the external stresses. The lubricant depletion under heat source is simulated and the effects of different working conditions including initial thickness, flying height and the speed of the disk on lubricant depletion are discussed. The main factors that cause the lubricant flow and depletion are analyzed and the ways to reduce the film thickness deformation are proposed. The simulation results indicate that the shearing stress is the most important factor that causes the thickness deformation and other terms listed in the equation have little influence. The thickness deformation is dependent on the working parameter, and the thermal condition evaporation is the most important factor.
文摘The molecular dynamics simulation of ultra-thin films under confined shear was performed to investigate the relation between dynamic properties of ultra-thin films and their microstructure. The solid walls were modelled using an Au crystal and the fluid molecules were modeled using decane. The simulation results indicate that the microstructure of ultra-thin films is a kind of solid-like layering structure. The density and velocity profiles of the fluid molecules are symmetric. The slip and shear thinning behavior was founded and interpreted.A mathematic model was set up according to the results of the simulation and experiments.
文摘Experimental results of the lubricating behaviour of Pb-Sn alloy films formed by ion-plating on brass substrates are given. It is shown that the film microhardness, friction coefficient and wear life per thickness are under the influence of the substrate. The wear failure of film appears to be film adhesion and transferring by the mating surface.
基金Project(51305331)supported by the National Natural Science Foundation of ChinaProject(2012M511993)supported by China Postdoctoral Science FoundationProject(TPL1202)supported by the Open Fund Program of the State Key Laboratory of Traction Power,Southwest Jiaotong University,China
文摘The tribological tests were performed using Nitinol 60 alloy pin sliding over GCr15 steel disc in the tribometer system. Four kinds of oils were experimentally investigated as lubrication oils for lubricating Nitinol 60 alloy in the boundary lubrication regime. The experimental results were compared with a reference dry friction. It was found that Nitinol 60 alloy can be lubricated significantly and has shown remarkable lubrication performance. A superlubricity behavior of Nitinol 60 alloy was observed under castor oil lubrication. An ultra-low coefficient of friction of Nitinol 60 alloy about 0.008 between Nitinol 60 alloy and GCr15 steel was obtained under castor oil lubrication condition after a running-in period. Accordingly, the present study is focused on the lubrication behaviors of castor oil as potential lubrication oil for Nitinol 60 alloy. In the presence of castor oil, coefficient of friction is kept at 0.008 at steady state, corresponding to so-called superlubricity regime (when sliding is then approaching pure rolling). The mechanism of superlubricity is attributed to the triboformed OH-terminated surfaces from friction-induced dissociation of castor oil and the boundary lubrication films formed on the contact surface due to high polarity and long chain of castor oil allowing strong interactions with the lubricated surfaces.
文摘A liquid lubricated head disk system is introduced. Subjected to high shear rate the rheology of the ultra thin film is different from that of the bulk continuum theory. The shear thinning effect is considered in setting up the mathematical model of the ultra thin film rheology. The Reynolds equation and the perturbation theory are employed to set up the static pressure distribution model and to deduce the dynamic pressure equation. The static and dynamic equations are solved by finite difference method. Based on the dynamic analysis the dynamic response of the slider is simulated and some valuable results are obtained about the static and dynamic characteristics of the liquid lubricated head disk systems.
基金Project(51074117)supported by the National Natural Science Foundation of ChinaProject(2009CDA044)supported by the Foundation for Distinguished Young Scientists of Hubei Province,ChinaProjects(201104493,20100471161)supported by the China Postdoctoral Science Foundation
文摘Scanning electron microscopy and X-ray energy dispersive spectrum analysis show that the clusters of intermetallic AlFeSi particle are distributed on or near the aluminum foil stock surfaces heterogeneously. 3D finite element modeling shows that these clusters of hard particles induce the fracture of the nano-scale lubricant oil film at first and further lead to severe deformation in the nearby aluminum foil substrate along the rolling direction. Consequently, the optical property in this region differs from that in the surroundings, resulting in surface defects.
文摘Static and dynamic numerical simulations of high recording density disk drivers are presented in this paper. The shear thinning effect on the viscosity is taken into account in the lubricant rheological model. The perturbation theory and short bearing theory are employed to set up the static and dynamic lubrication model on the head disk interface. Close solutions are given for the pressure distribution, load capacity and the dynamic characteristics such as stiffness and damping coefficients, which provide a simple method to analyze the dynamic response of the slider supported by the ultra thin fluid film lubricated bearing. Based on the close solutions the static and dynamic responses of the IBM 3380 slider are simulated. Some interesting results are obtained for the analysis of the slider’s flying stability.
文摘Neodymium dialkylthiophosphate (NdDDP) with alkyls of isopropyl and isooctyl were synthesized by exchanged reaction respectively. The structures of the two NdDDPs were determined using IR and XRD. Properties of anti-wear and friction-reducing of the two additives were investigated with four ball experiment and the commercial anti-wear additive ZDDP was selected as control. The elemental analysis of the wear scars after 10 s friction at low stress were investigated by EDXA (Energy Dispersion Analysis of X-ray). Primary results showed that the NdDDPs possess better lubrication ability than ZDDP. This might mainly be contributed to the formation of a boundary film containing Nd2O3, FeS and sulphate, phosphate, organo-sulfide, etc., and a neodymium-rich diffused layer which changes the crystal structure of the surface of friction materials.
基金Project(MKPT-03-182) supported by the Ministry of Science and Technology of China
文摘Ni-Cr/h-BN self-lubricating composities were prepared by powder metallurgy (P/M) method.The effects of hexagonal boron nitride (h-BN) content on the mechanical and tribological properties of the Ni-Cr/h-BN composites were investigated.The corresponding frictional models were established to analyze the formation of the lubricant h-BN films on the surfaces of the Ni-Cr/h-BN composites.The results show that,when the content of h-BN increases from 5% to 15% (mass fraction),the bending strength of the Ni-Cr/h-BN composite decreases from 96.670 MPa to 17.319 MPa,and the hardness (HB) decreases from 33 to 14.The friction coefficient of the Ni-Cr/h-BN composite decreases firstly from 0.385 to 0.216,and then increases to 0.284,while the wear rate decreases firstly from 4.14×10-9 kg/(N·m) to 1.35×10-9 kg/(N·m),then increases to 2.36×10-9 kg/(N·m).The best comprehensive mechanical and tribological properties can be obtained between 10% and 12% h-BN addition.
基金This project is supported by Specialized Research Fund for Doctoral Program of Higher Education, China(No.20030561007)
文摘The acid number of the mixed solution of 150SN oil and oleic acid characterizes the volume content of oleic acid in the solution, based on which the adsorptive capability of oleic acid is studied on the 45 steel balls and disks. Boundary lubrication tests are carried out on a self designed ball-on-disk machine, The base oil is pure 150SN oil, and oleic acid as additive are added into the lubricant. Disks have surface roughness values (Ra) of 0.8 μn and 0.4 μn. The electrical contact resistance method is used to determine the lubrication status. Hypothesize that the molecular film is monomolecular layer in condensed state and the opposing surfaces are completely separated by molecular film. A boundary lubrication model is established according to experimental results and hypothesizes. The experimental and calculatienal results show that the adsorption of polar molecules on steel surface is the main factor to form the boundary lubrication film. Load and sliding speed contribute little to the friction coefficient of boundary lubrication. The properties of steel surface and additive for the lubricant significantly influence on the characters of boundary lubrication. The smaller the surface roughness value is, the smaller the friction coefficient of the boundary lubrication is.
基金Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No20060003025)the State Key Development Program for Basic Research of China(Grant No2003CB716201)
文摘The spread of perfluoropolyether (PFPE) droplets on solid surfaces has been measured from the top-down view through a microscope system. Effects of substrates, molecular weight and end-group functionality on spreading of the PFPE droplets have been studied experimentally and the results were compared with those by molecular dynamics (MD) simulations. Silicon wafer and diamond-like carbon (DLC) substrates were used to study the effect of substrates on spreading. Two types of PFPE, Z-dol and Z-tetraol, with the same chain structure and various molecular weights (2000 and 4000 g/mol) were employed in experiments. Effect of molecular weight has been investigated through comparing the spreading of Z-dol 2000 and Z-dol 4000, and it is found that the increase of molecular weight will decrease the mobility of PFPE. Comparison between spreading of Z-dol and Z-tetraol of the same molecular weight proved that functional end group plays a significant role on the spreading of PFPE, which confirmed the MD simulation results.
基金This work was supported by the National Natural Science Foundation of China(Nos.51875105 and 51875106)the Jinjiang Science and Education Project of Fuzhou University(No.2019-JJFDKY-54)the Industry-Academy Cooperation Project of Fujian Province(No.2020H6025).
文摘Molecular dynamics simulations are used to study the boundary lubrication behaviors of squalane lubricant between two iron wall structures during shearing at different pressures and temperatures.Boundary lubrication models with a smooth iron wall and a nanostructured iron wall,respectively,are constructed,and the density distribution of the lubricating film and the velocity distribution in the shearing process are analyzed.The mechanical response of the solid wall is output,and the friction coefficient is calculated.A tribological test is performed with a UMT-2 tribometer under sliding conditions to evaluate the reliability of the simulation method.The results show that the surface nanostructure has a significant effect on the film thickness and delamination of the lubricating film but little effect on the velocity distribution of the lubricating film.The nano strip groove helps to reduce the friction coefficient of the boundary lubrication system.
基金Project supported by the National Natural Science Foundation of China (Grant No 50390060) and the State Key Development Program for Basic Research of China (Grant No 2003CB716201).
文摘Molecular dynamic simulations based on a coarse-gralned, bead-spring model are adopted to investigate the spreading of both nonfunctional and functional perfluoropolyether (PFPE) on solid substrates. For nonfunctional PFPE, the spreading generally exhibits a smooth profile with a precursor film. The spreading profiles on different substrates are compared, which indicate that the bead-substrate interaction has a significant effect on the spreading behaviour, especially on the formation of the precursor film. For functional PFPE, the spreading generally exhibits a complicated terraced profile. The spreading profiles with different endbeads are compared, which indicate that the endbead-substrate interaction and the endbead-endbead interaction, especially the latter, have a significant effect on the spreading behaviour.
基金Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No 20060003025)the Science Foundation for Post Doctoral Research from the Ministry of Science and Technology of China (Grant No 20070420017)the 111 Project (Grant No B08043) and the National Natural Science Foundation of China (Grant No 50705009)
文摘Lubricant spreading on solid substrates has drawn considerable attention not only for the microscopic wetting theory but also for the dramatic application in head-disk interface of magnetic storage drive systems. Molecular dynamic simulation based on a coarse-grained bead-spring model has been used to study such a spreading process. The spreading profiles indicate that the hydrogen bonds among lubricant molecules and the hydrogen bonds between lubricant molecules and polar atoms of solid substrates will complicate the spreading process in a tremendous degree. The hydrogen bonds among lubricant molecules will strengthen the lubricant combination intensity, which may hinder most molecules from flowing down to the substrates and diffusing along the substrates. And the hydrogen bonds between lubricant molecules and polar atoms of solid substrates will confine the lubricant molecules around polar atoms, which may hinder the molecules from diffusing along the substrates and cause precursor film to vanish.