Surfactant enhanced chemofiltration on Nylon membranes pre-treated with hexadecyltrimethylammonium bromide (HTAB) and eosin dye (eo) is proposed for zinc traces quantification by solid surphase spectro- fluorimetry (S...Surfactant enhanced chemofiltration on Nylon membranes pre-treated with hexadecyltrimethylammonium bromide (HTAB) and eosin dye (eo) is proposed for zinc traces quantification by solid surphase spectro- fluorimetry (SSF, λexc = 532 nm;λem = 548 nm). Operational variables which have influence on quantitative retention of metal complex have been studied and optimized. At optimal experimental conditions, quantita- tive recovery was reached with a detection limit of 0.662 pg?L–1 and quantification limit of 2.20 pg?L–1. The calibration sensitivity was of 1.22 L?pg–1 for the new methodology with a linear range of 2.20 pg?L–1 to 779 pg?L–1 Zn (II). The tolerance levels of potential interfering ions were studied with good results. Recuperation studies were carried out by standard addition method applied to natural water samples (San Juan, Argentine) without previous treatment. The reproducibility (between-days precision) was also evaluated over 3 days by performing five determinations each day. CV% was 0.37. The performing obtained in sensitivity and selec- tivity thanks to chemofiltration step, converts the proposed methodology in an adequate alternative to con- ventional techniques for Zn (II) traces determination.展开更多
A novel organic fluorophor with high solid state luminescent efficiency based on 1,4-bis(2,2-di(pyridin-2-yl)- vinyl)benzene (BDP2VB) was designed and synthesized. It emits faintly in solution, but becomes a str...A novel organic fluorophor with high solid state luminescent efficiency based on 1,4-bis(2,2-di(pyridin-2-yl)- vinyl)benzene (BDP2VB) was designed and synthesized. It emits faintly in solution, but becomes a strong emitter in the aggregate state, demonstrating its aggregation induced emission (AIE) property. According to the crystal struc- ture analysis, J-type aggregation was formed in the packing mode of the molecule, which was demonstrated to be beneficial to gain high fluorescent quantum efficiency in solid state. Additionally, the emission color of BDP2VB can change dramatically in solid state as well as in solution by the protonation stimuli.展开更多
A new metal-organic framework (MOF),{[Zn_7 (BPS)_4 (OH)_6 (H_2O)_2]·5 H_2O]_n}(1), (H_2 BPS=4,4′-bibenzoic acid-2,2′-sulfone), based on a wavy and infinite chain-shaped secondary building units, has been synthe...A new metal-organic framework (MOF),{[Zn_7 (BPS)_4 (OH)_6 (H_2O)_2]·5 H_2O]_n}(1), (H_2 BPS=4,4′-bibenzoic acid-2,2′-sulfone), based on a wavy and infinite chain-shaped secondary building units, has been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and further confirmed by PXRD, TGA and IR spectrum. The solid-state emission spectra reveal that compound 1 presents strong luminescence emission bands at room temperature. The fluorescent properties of compound 1 in diverse organic solvents indicated that 1 has palpable luminescent sense effects for DMF and DMAC.展开更多
文摘Surfactant enhanced chemofiltration on Nylon membranes pre-treated with hexadecyltrimethylammonium bromide (HTAB) and eosin dye (eo) is proposed for zinc traces quantification by solid surphase spectro- fluorimetry (SSF, λexc = 532 nm;λem = 548 nm). Operational variables which have influence on quantitative retention of metal complex have been studied and optimized. At optimal experimental conditions, quantita- tive recovery was reached with a detection limit of 0.662 pg?L–1 and quantification limit of 2.20 pg?L–1. The calibration sensitivity was of 1.22 L?pg–1 for the new methodology with a linear range of 2.20 pg?L–1 to 779 pg?L–1 Zn (II). The tolerance levels of potential interfering ions were studied with good results. Recuperation studies were carried out by standard addition method applied to natural water samples (San Juan, Argentine) without previous treatment. The reproducibility (between-days precision) was also evaluated over 3 days by performing five determinations each day. CV% was 0.37. The performing obtained in sensitivity and selec- tivity thanks to chemofiltration step, converts the proposed methodology in an adequate alternative to con- ventional techniques for Zn (II) traces determination.
基金973 Program,the National Natural Science Foundation of China,the Research Fund for the Doctoral Program of Higher Education of China,the Project of Jilin Province
文摘A novel organic fluorophor with high solid state luminescent efficiency based on 1,4-bis(2,2-di(pyridin-2-yl)- vinyl)benzene (BDP2VB) was designed and synthesized. It emits faintly in solution, but becomes a strong emitter in the aggregate state, demonstrating its aggregation induced emission (AIE) property. According to the crystal struc- ture analysis, J-type aggregation was formed in the packing mode of the molecule, which was demonstrated to be beneficial to gain high fluorescent quantum efficiency in solid state. Additionally, the emission color of BDP2VB can change dramatically in solid state as well as in solution by the protonation stimuli.
基金supported by the National Natural Science Foundation of China(Nos. 21771111, 21601092 and 21371104)the Tianjin Natural Science Foundation(Nos. 15JCZDJC38800 and 16JCZDJC36900)
文摘A new metal-organic framework (MOF),{[Zn_7 (BPS)_4 (OH)_6 (H_2O)_2]·5 H_2O]_n}(1), (H_2 BPS=4,4′-bibenzoic acid-2,2′-sulfone), based on a wavy and infinite chain-shaped secondary building units, has been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and further confirmed by PXRD, TGA and IR spectrum. The solid-state emission spectra reveal that compound 1 presents strong luminescence emission bands at room temperature. The fluorescent properties of compound 1 in diverse organic solvents indicated that 1 has palpable luminescent sense effects for DMF and DMAC.
基金Project supported by the National Natural Science Foundation of China(Nos.21606116,51873160)the Natural Science Foundations of Jiangxi Province(No.20161BAB213070)the Department of Education of Jiangxi Province(No.GJJ170176)~~