From different reports, it (AZO) and indium-doped including usage areas. We nanocrystalline films with is realized that there is a need to consider all sides of aluminum-doped zinc oxide zinc oxide (IZO) thin film...From different reports, it (AZO) and indium-doped including usage areas. We nanocrystalline films with is realized that there is a need to consider all sides of aluminum-doped zinc oxide zinc oxide (IZO) thin films with their optical, luminescence and surface properties establish an assessment to carry out further information to summarize AZO and IZO impact of the layer number.展开更多
Nowadays organosilicon luminescent materials are of increasing interest due to the variety of their synthetic or modification techniques and application fields.Ladder polyphenylsilsesquioxanes(L-PPSQ)are a unique clas...Nowadays organosilicon luminescent materials are of increasing interest due to the variety of their synthetic or modification techniques and application fields.Ladder polyphenylsilsesquioxanes(L-PPSQ)are a unique class of organosilicon polymers,which can be ideal matrices for the luminescent composites due to their high thermal stability,optical transparency and mechanical strength.In this work,new mechanically strong,heat-resistant,transparent and sensitive to ammonia vapor luminescent composite films based on L-PPSQ have been obtained.As the source of Europium ions oligophenyleuropiumsiloxane was used,demonstrating perfect compatibility to the matrix due to the similar nature.To improve luminescent properties of the films,new organosilicon ligands were introduced into the composites and their influence on the properties of the materials was studied.Valuable properties of described composites may allow their further application as multifunctional coatings.展开更多
Transparent zinc oxide(ZnO) thin films are fabricated by a simple sol-gel spin-coating technique on glass substrates with different solution concentrations(0.3-1.2 M) using zinc acetate dehydrate [Zn(CH_3COO)_2&...Transparent zinc oxide(ZnO) thin films are fabricated by a simple sol-gel spin-coating technique on glass substrates with different solution concentrations(0.3-1.2 M) using zinc acetate dehydrate [Zn(CH_3COO)_2·2H_2O] as precursor and isopropanol and monoethanolamine(MEA) as solvent and stabilizer, respectively. The molar ratio of zinc acetate dehydrate to MEA is 1.0. X-ray diffraction, ultraviolet-visible spectroscopy and photoluminescence spectroscopy are employed to investigate the effect of solution concentration on the structural and optical properties of the ZnO thin films. The obtained results of all thin films are discussed in detail and are compared with other experimental data.展开更多
The transparent luminescent thin films of doped terbium complex were obtained by sol gel method. The result indicates that rare earth carboxylates with poor solubility can be homogeneously doped into sol matrix in si...The transparent luminescent thin films of doped terbium complex were obtained by sol gel method. The result indicates that rare earth carboxylates with poor solubility can be homogeneously doped into sol matrix in situ. The fluorescence spectra show that the thin film material emits the characteristic narrow band emission of Tb 3+ under the UV excitation.展开更多
A novel type sandwich-like composite films composed of ZIF-8 and CdTe QDs were successfully constructed through facile layer-by-layer assembly strategy and their potential applications were also explored.Based on the ...A novel type sandwich-like composite films composed of ZIF-8 and CdTe QDs were successfully constructed through facile layer-by-layer assembly strategy and their potential applications were also explored.Based on the limitation effects of the aperture of ZIF-8,CdTe QDs/ZIF-8 fluorescent composite films exhibit obvious selective optical response toward hydrogen peroxide and folic acid.Furthermore,tunable colorful light emission composite films in the red-green region are obtained through incorporating two different sized QDs and ZIF-8 films into one composite films.展开更多
Using different-solution-concentration precursors with citric acid as chelating agent and polyvinyl alcohol as dispersing media, Dy3+ activated LaVO4 films were deposited on indium tin oxide (ITO) substrates. The s...Using different-solution-concentration precursors with citric acid as chelating agent and polyvinyl alcohol as dispersing media, Dy3+ activated LaVO4 films were deposited on indium tin oxide (ITO) substrates. The scanning electronic microscope (SEM) showed that the compact and crack-free LaVO4:Dy3+ film could be obtained at a suitable solution concentration. The deposited films could absorb the ultraviolet light below 400 nm and were transparent in the visible and infrared region as evidenced by the transmission spectra, and the photolumines- cence spectra exhibited the characteristic emissions of Dy3+ peaking at 484 (blue) and 576 (yellow) nm due to the transitions of 4F9/2→6Hls/2 and 4F9/2→6H13/2, respectively. The potential application of LaVOa:Dy3+ film in the dye-sensitized solar cell (DSSC) was also discussed.展开更多
Electrodeposition is an old and effective method for the fabrication of organic films.Though electrodeposited organic films have been widely used in various applications,highly luminescent films have been a great chal...Electrodeposition is an old and effective method for the fabrication of organic films.Though electrodeposited organic films have been widely used in various applications,highly luminescent films have been a great challenge because the electrochemically doped state may strongly quench the fluorescence.In the first part of this review,the organic electrodeposition techniques,along with general electropolymerization and other special electrodepositions are introduced.In the second part of the review,we describe how to electrochemically fabricate luminescent films for organic light-emitting diodes(OLEDs).With the rational molecular design and well-controlled electrodeposition process,we have not only demonstrated high-performance OLEDs,but also paved a promising way to practice active-matrix OLEDs(AMOLEDs)and super-resolution OLEDs.In particular,RGB 3×3 array OLEDs based on active-matrix substrates,RGB passive-matrix OLEDs(PMOLEDs)with a resolution of 210 ppi,and monochromatic OLEDs with a super-resolution of 2822 ppi have been successfully fabricated.It is highly anticipated that the organic electrodeposition technology is of comparable or perhaps even higher contenders in manufacturing and downscaling OLEDs and AMOLEDs with low-cost and high-resolution for the human-computer interaction fields such as augmented reality(AR),virtual reality(VR),etc.展开更多
文摘From different reports, it (AZO) and indium-doped including usage areas. We nanocrystalline films with is realized that there is a need to consider all sides of aluminum-doped zinc oxide zinc oxide (IZO) thin films with their optical, luminescence and surface properties establish an assessment to carry out further information to summarize AZO and IZO impact of the layer number.
基金financially supported by the Russian Science Foundation(No.23-79-10256)。
文摘Nowadays organosilicon luminescent materials are of increasing interest due to the variety of their synthetic or modification techniques and application fields.Ladder polyphenylsilsesquioxanes(L-PPSQ)are a unique class of organosilicon polymers,which can be ideal matrices for the luminescent composites due to their high thermal stability,optical transparency and mechanical strength.In this work,new mechanically strong,heat-resistant,transparent and sensitive to ammonia vapor luminescent composite films based on L-PPSQ have been obtained.As the source of Europium ions oligophenyleuropiumsiloxane was used,demonstrating perfect compatibility to the matrix due to the similar nature.To improve luminescent properties of the films,new organosilicon ligands were introduced into the composites and their influence on the properties of the materials was studied.Valuable properties of described composites may allow their further application as multifunctional coatings.
文摘Transparent zinc oxide(ZnO) thin films are fabricated by a simple sol-gel spin-coating technique on glass substrates with different solution concentrations(0.3-1.2 M) using zinc acetate dehydrate [Zn(CH_3COO)_2·2H_2O] as precursor and isopropanol and monoethanolamine(MEA) as solvent and stabilizer, respectively. The molar ratio of zinc acetate dehydrate to MEA is 1.0. X-ray diffraction, ultraviolet-visible spectroscopy and photoluminescence spectroscopy are employed to investigate the effect of solution concentration on the structural and optical properties of the ZnO thin films. The obtained results of all thin films are discussed in detail and are compared with other experimental data.
文摘The transparent luminescent thin films of doped terbium complex were obtained by sol gel method. The result indicates that rare earth carboxylates with poor solubility can be homogeneously doped into sol matrix in situ. The fluorescence spectra show that the thin film material emits the characteristic narrow band emission of Tb 3+ under the UV excitation.
基金financially supported by the National Key Research and Development Program of China(No.2018YFA0704502)financial support of the National Natural Science Foundation of China(Nos.22033008,21871263 and 22071245)Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZZ103)。
文摘A novel type sandwich-like composite films composed of ZIF-8 and CdTe QDs were successfully constructed through facile layer-by-layer assembly strategy and their potential applications were also explored.Based on the limitation effects of the aperture of ZIF-8,CdTe QDs/ZIF-8 fluorescent composite films exhibit obvious selective optical response toward hydrogen peroxide and folic acid.Furthermore,tunable colorful light emission composite films in the red-green region are obtained through incorporating two different sized QDs and ZIF-8 films into one composite films.
基金Project supported by the Higher Educational Natural Science Foundation of Anhui Province (KJ2010A012)National Natural Science Foundation of China (50901074)supported by the "211 Pro-ject" of Anhui University and Anhui University Young Scientific Research Fund (2009QN006A)
文摘Using different-solution-concentration precursors with citric acid as chelating agent and polyvinyl alcohol as dispersing media, Dy3+ activated LaVO4 films were deposited on indium tin oxide (ITO) substrates. The scanning electronic microscope (SEM) showed that the compact and crack-free LaVO4:Dy3+ film could be obtained at a suitable solution concentration. The deposited films could absorb the ultraviolet light below 400 nm and were transparent in the visible and infrared region as evidenced by the transmission spectra, and the photolumines- cence spectra exhibited the characteristic emissions of Dy3+ peaking at 484 (blue) and 576 (yellow) nm due to the transitions of 4F9/2→6Hls/2 and 4F9/2→6H13/2, respectively. The potential application of LaVOa:Dy3+ film in the dye-sensitized solar cell (DSSC) was also discussed.
基金financially supported by the National Natural Science Foundation of China(Nos.U20A6002 and 21733005)the National Key R&D Program of China(No.2020YFA0714604)+1 种基金the Basic and Applied Basic Research Major Program of Guangdong Province(No.2019B030302007)Research and Development Funds for Science and Technology Program of Guangzhou(No.202007020004)。
文摘Electrodeposition is an old and effective method for the fabrication of organic films.Though electrodeposited organic films have been widely used in various applications,highly luminescent films have been a great challenge because the electrochemically doped state may strongly quench the fluorescence.In the first part of this review,the organic electrodeposition techniques,along with general electropolymerization and other special electrodepositions are introduced.In the second part of the review,we describe how to electrochemically fabricate luminescent films for organic light-emitting diodes(OLEDs).With the rational molecular design and well-controlled electrodeposition process,we have not only demonstrated high-performance OLEDs,but also paved a promising way to practice active-matrix OLEDs(AMOLEDs)and super-resolution OLEDs.In particular,RGB 3×3 array OLEDs based on active-matrix substrates,RGB passive-matrix OLEDs(PMOLEDs)with a resolution of 210 ppi,and monochromatic OLEDs with a super-resolution of 2822 ppi have been successfully fabricated.It is highly anticipated that the organic electrodeposition technology is of comparable or perhaps even higher contenders in manufacturing and downscaling OLEDs and AMOLEDs with low-cost and high-resolution for the human-computer interaction fields such as augmented reality(AR),virtual reality(VR),etc.