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Acute suppurative terminal cholangitis:Clinical characteristics of a new subtype of acute cholangitis
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作者 Rong-Tao Zhu Ye Li +5 位作者 Chi-Xian Zhang Wei-Jie Wang Ruo-Peng Liang Jian Li Kai Bai Yu-Ling Sun 《Hepatobiliary & Pancreatic Diseases International》 SCIE CAS CSCD 2024年第3期293-299,共7页
Background:Acute suppurative terminal cholangitis(ASTC)is rarer than acute obstructive cholangitis and is not well studied.To explore this subtype of acute cholangitis,we described our clinical experience with ASTC.Me... Background:Acute suppurative terminal cholangitis(ASTC)is rarer than acute obstructive cholangitis and is not well studied.To explore this subtype of acute cholangitis,we described our clinical experience with ASTC.Methods:We performed a retrospective review of patients with ASTC admitted to our center from September 2014 to August 2020.We analyzed their clinical characteristics,including etiology,clinical manifestations,imaging features,treatment and prognosis.Results:A total of 32 ASTC patients were included in the analysis.The majority of the patients had a history of biliary operations,and clinical manifestations were occult and atypical.The positive rate of bacterial culture was 46.9%.All the patients had typical imaging features on computed tomography and magnetic resonance imaging.Treatment with effective antibiotics was provided as soon as diagnosis was established.After treatment,most patients had a good outcome.Elevated levels of total bilirubin,aspartate aminotransferase,procalcitonin and gamma-glutamyltransferase were the characteristics of critically ill patients and were associated with relatively poor prognosis.Conclusions:Our results demonstrated that ASTC should be recognized as a new subtype of acute cholangitis,and that earlier diagnosis and more personalized treatments are needed. 展开更多
关键词 Acute suppurative terminal cholangitis Acute cholangitis Gram-negative bacterial infections DIAGNOSIS Treatment
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The Impact of Privatization on Terminal Efficiency: A Case Study of Tema Port
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作者 Bernard Kwei Tetteh Calvin Elorm Atsunyo Alex Boateng 《Journal of Transportation Technologies》 2024年第3期358-371,共14页
Port and terminal efficiency are of utmost importance to the container shipping industry due to their significance in enhancing the competitive advantage of ports within a region. Consequently, there have always been ... Port and terminal efficiency are of utmost importance to the container shipping industry due to their significance in enhancing the competitive advantage of ports within a region. Consequently, there have always been notable variations of studies around it. This paper analyzes the impact of privatization on terminal efficiency using the Port of Tema as a Case Study. The main objective of this paper is to analyze the efficiency trends of the public and private terminals in the port over the years. To achieve this objective, DEA-CCR methodology was employed to calculate the annual technical efficiency trends of the private and public terminals using four input variables and three output variables. The main results of the paper indicated that the public and private terminals were efficient for multiple years. However, the efficiency scores over the years demonstrated inconsistency, exhibiting notable fluctuations. The findings of this study will aid policymakers across the region on policies relating to the efficiency and ownership structure of ports and terminals. 展开更多
关键词 PRIVATIZATION terminal Efficiency DEA Tema Port
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Mixed Integer Robust Programming Model for Multimodal Fresh Agricultural Products Terminal Distribution Network Design
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作者 Feng Yang Zhong Wu Xiaoyan Teng 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第1期719-738,共20页
The low efficiency and high cost of fresh agricultural product terminal distribution directly restrict the operation of the entire supply network.To reduce costs and optimize the distribution network,we construct a mi... The low efficiency and high cost of fresh agricultural product terminal distribution directly restrict the operation of the entire supply network.To reduce costs and optimize the distribution network,we construct a mixed integer programmingmodel that comprehensively considers tominimize fixed,transportation,fresh-keeping,time,carbon emissions,and performance incentive costs.We analyzed the performance of traditional rider distribution and robot distribution modes in detail.In addition,the uncertainty of the actual market demand poses a huge threat to the stability of the terminal distribution network.In order to resist uncertain interference,we further extend the model to a robust counterpart form.The results of the simulation show that the instability of random parameters will lead to an increase in the cost.Compared with the traditional rider distribution mode,the robot distribution mode can save 12.7%on logistics costs,and the distribution efficiency is higher.Our research can provide support for the design of planning schemes for transportation enterprise managers. 展开更多
关键词 Fresh agricultural product terminal distribution network rider delivery robot delivery UNCERTAINTY
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Machine learning for predicting the outcome of terminal ballistics events
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作者 Shannon Ryan Neeraj Mohan Sushma +4 位作者 Arun Kumar AV Julian Berk Tahrima Hashem Santu Rana Svetha Venkatesh 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期14-26,共13页
Machine learning(ML) is well suited for the prediction of high-complexity,high-dimensional problems such as those encountered in terminal ballistics.We evaluate the performance of four popular ML-based regression mode... Machine learning(ML) is well suited for the prediction of high-complexity,high-dimensional problems such as those encountered in terminal ballistics.We evaluate the performance of four popular ML-based regression models,extreme gradient boosting(XGBoost),artificial neural network(ANN),support vector regression(SVR),and Gaussian process regression(GP),on two common terminal ballistics’ problems:(a)predicting the V50ballistic limit of monolithic metallic armour impacted by small and medium calibre projectiles and fragments,and(b) predicting the depth to which a projectile will penetrate a target of semi-infinite thickness.To achieve this we utilise two datasets,each consisting of approximately 1000samples,collated from public release sources.We demonstrate that all four model types provide similarly excellent agreement when interpolating within the training data and diverge when extrapolating outside this range.Although extrapolation is not advisable for ML-based regression models,for applications such as lethality/survivability analysis,such capability is required.To circumvent this,we implement expert knowledge and physics-based models via enforced monotonicity,as a Gaussian prior mean,and through a modified loss function.The physics-informed models demonstrate improved performance over both classical physics-based models and the basic ML regression models,providing an ability to accurately fit experimental data when it is available and then revert to the physics-based model when not.The resulting models demonstrate high levels of predictive accuracy over a very wide range of projectile types,target materials and thicknesses,and impact conditions significantly more diverse than that achievable from any existing analytical approach.Compared with numerical analysis tools such as finite element solvers the ML models run orders of magnitude faster.We provide some general guidelines throughout for the development,application,and reporting of ML models in terminal ballistics problems. 展开更多
关键词 Machine learning Artificial intelligence Physics-informed machine learning terminal ballistics Armour
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Improved STNModels and Heuristic Rules for Cooperative Scheduling in Automated Container Terminals
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作者 Hongyan Xia Jin Zhu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第2期1637-1661,共25页
Improving the cooperative scheduling efficiency of equipment is the key for automated container terminals to copewith the development trend of large-scale ships. In order to improve the solution efficiency of the exis... Improving the cooperative scheduling efficiency of equipment is the key for automated container terminals to copewith the development trend of large-scale ships. In order to improve the solution efficiency of the existing spacetimenetwork (STN) model for the cooperative scheduling problem of yard cranes (YCs) and automated guidedvehicles (AGVs) and extend its application scenarios, two improved STN models are proposed. The flow balanceconstraints in the original model are decomposed, and the trajectory constraints of YCs and AGVs are added toacquire the model STN_A. The coupling constraint in STN_A is updated, and buffer constraints are added toSTN_A so that themodel STN_B is built.As the size of the problem increases, the solution speed of CPLEX becomesthe bottleneck. So a heuristic method containing three groups of heuristic rules is designed to obtain a near-optimalsolution quickly. Experimental results showthat the computation time of STN_A is shortened by 49.47% on averageand the gap is reduced by 1.69% on average compared with the original model. The gap between the solution ofthe heuristic rules and the solution of CPLEX is less than 3.50%, and the solution time of the heuristic rules is onaverage 99.85% less than the solution time of CPLEX. Compared with STN_A, the computation time for solvingSTN_B increases by 58.93% on average. 展开更多
关键词 Automated container terminal BUFFER cooperative scheduling heuristic rules space-time network
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Clinical Epidemiology and Surgical Treatment of Spontaneous Perforations of the Terminal Ileum: A Multicentre Study in Cameroon
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作者 Eric Patrick Savom Richard II Mbele +5 位作者 Mahamat Yannick Ekani Boukar Abdal Deudeu Cédric Paterson Atangana Fred Dikongue Dikongue Guy Aristide Bang Marc Leroy Guifo 《Surgical Science》 2024年第5期311-320,共10页
Background: Perforations of the terminal ileum are a frequent clinical situation and a therapeutic challenge. Surgical treatment is controversial. Several surgical modalities have been proposed and postoperative morbi... Background: Perforations of the terminal ileum are a frequent clinical situation and a therapeutic challenge. Surgical treatment is controversial. Several surgical modalities have been proposed and postoperative morbidity and mortality remain high. The aim of this study was to review our experience in the surgical management of perforations of the terminal ileum. Patients and methods: This is a descriptive cross-sectional study with retrospective data collection from January 1, 2017 to December 31, 2021, in five hospitals in Cameroon. Patients’ demographic, clinical presentation, surgical findings and 30-days postoperative outcomes data were collected. Results: We collected 34 files. The sex ratio was 1.4 and the average age was 20.28 years. The average consultation time was 9.1 days. Abdominal pain was present in all our patients. Peritoneal irritation was present in 46 cases (88.5%). The mean time to treatment after admission was 17.5 hours. The perforation was unique in 40 cases (76.9%) and located between 6 and 10 cm from the ileocecal valve in 29 cases (55.8%). Typhoid was the most suspected etiology intraoperatively in 38 cases (73.1%). A simple suture was performed in 18 patients (34.6%), resection with anastomosis in 11 patients (21.2%) and an ileostomy in 5 patients (9.6%). The average length of hospitalization was 21.74 days. Postoperative morbidity and mortality were 32.7% and 17.3% respectively. Conclusion: Perforations of the terminal ileum are common and affect young people. Surgical procedures are varied. Reducing consultation and care times and respecting treatment principles could improve postoperative morbidity and mortality, which remain high. 展开更多
关键词 Perforation of the terminal Ileum Simple Suture RESECTION MORBIDITY MORTALITY
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An Improved Bounded Conflict-Based Search for Multi-AGV Pathfinding in Automated Container Terminals
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作者 Xinci Zhou Jin Zhu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第6期2705-2727,共23页
As the number of automated guided vehicles(AGVs)within automated container terminals(ACT)continues to rise,conflicts have becomemore frequent.Addressing point and edge conflicts ofAGVs,amulti-AGVconflict-free path pla... As the number of automated guided vehicles(AGVs)within automated container terminals(ACT)continues to rise,conflicts have becomemore frequent.Addressing point and edge conflicts ofAGVs,amulti-AGVconflict-free path planning model has been formulated to minimize the total path length of AGVs between shore bridges and yards.For larger terminalmaps and complex environments,the grid method is employed to model AGVs’road networks.An improved bounded conflict-based search(IBCBS)algorithmtailored to ACT is proposed,leveraging the binary tree principle to resolve conflicts and employing focal search to expand the search range.Comparative experiments involving 60 AGVs indicate a reduction in computing time by 37.397%to 64.06%while maintaining the over cost within 1.019%.Numerical experiments validate the proposed algorithm’s efficacy in enhancing efficiency and ensuring solution quality. 展开更多
关键词 Automated terminals multi-AGV multi-agent path finding(MAPF) conflict based search(CBS) AGV path planning
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Transformation of marginal zone lymphoma into high-grade B-cell lymphoma expressing terminal deoxynucleotidyl transferase:A case report
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作者 Zhi-Min Fan Dao-Lei Wu +4 位作者 Neng-Wen Xu Li Ye Li-Ping Yan Lin-Jie Li Jun-Yu Zhang 《World Journal of Clinical Cases》 SCIE 2024年第15期2655-2663,共9页
BACKGROUND High-grade B-cell lymphoma(HGBL)is an unusual malignancy that includes myelocytomatosis viral oncogene(MYC),B-cell lymphoma-2(BCL-2),and/or BCL-6 rearrangements,termed double-hit or triple-hit lymphomas,and... BACKGROUND High-grade B-cell lymphoma(HGBL)is an unusual malignancy that includes myelocytomatosis viral oncogene(MYC),B-cell lymphoma-2(BCL-2),and/or BCL-6 rearrangements,termed double-hit or triple-hit lymphomas,and HGBL-not otherwise specific(HGBL-NOS),which are morphologically characteristic of HGBL but lack MYC,BCL-2,or BCL-6 rearrangements.HGBL is partially transformed by follicular lymphoma and other indolent lymphoma,with few cases of marginal zone lymphoma(MZL)transformation.HGBL often has a poor prognosis and intensive therapy is currently mainly advocated,but there is no good treatment for these patients who cannot tolerate chemotherapy.CASE SUMMARY We reported a case of MZL transformed into HGBL-NOS with TP53 mutation and terminal deoxynucleotidyl transferase expression.Gene analysis revealed the gene expression profile was identical in the pre-and post-transformed tissues,suggesting that the two diseases are homologous,not secondary tumors.The chemotherapy was ineffective and the side effect was severe,so we tried combination therapy including venetoclax and obinutuzumab.The patient tolerated treatment well,and reached partial response.The patient had recurrence of hepatocellular carcinoma and died of multifunctional organ failure.He survived for 12 months after diagnosis.CONCLUSION Venetoclax combined with obinutuzumab might improve the survival in some HGBL patients,who are unsuitable for chemotherapy. 展开更多
关键词 Marginal zone lymphoma High-grade B-cell lymphoma terminal deoxynucleotidyl transferase Venetoclax TP53 mutation Case report
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A Pre-Selection-Based Ant Colony System for Integrated Resources Scheduling Problem at Marine Container Terminal
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作者 Rong Wang Xinxin Xu +2 位作者 Zijia Wang Fei Ji Nankun Mu 《Computers, Materials & Continua》 SCIE EI 2024年第8期2363-2385,共23页
Marine container terminal(MCT)plays a key role in the marine intelligent transportation system and international logistics system.However,the efficiency of resource scheduling significantly influences the operation pe... Marine container terminal(MCT)plays a key role in the marine intelligent transportation system and international logistics system.However,the efficiency of resource scheduling significantly influences the operation performance of MCT.To solve the practical resource scheduling problem(RSP)in MCT efficiently,this paper has contributions to both the problem model and the algorithm design.Firstly,in the problem model,different from most of the existing studies that only consider scheduling part of the resources in MCT,we propose a unified mathematical model for formulating an integrated RSP.The new integrated RSP model allocates and schedules multiple MCT resources simultaneously by taking the total cost minimization as the objective.Secondly,in the algorithm design,a pre-selection-based ant colony system(PACS)approach is proposed based on graphic structure solution representation and a pre-selection strategy.On the one hand,as the RSP can be formulated as the shortest path problem on the directed complete graph,the graphic structure is proposed to represent the solution encoding to consider multiple constraints and multiple factors of the RSP,which effectively avoids the generation of infeasible solutions.On the other hand,the pre-selection strategy aims to reduce the computational burden of PACS and to fast obtain a higher-quality solution.To evaluate the performance of the proposed novel PACS in solving the new integrated RSP model,a set of test cases with different sizes is conducted.Experimental results and comparisons show the effectiveness and efficiency of the PACS algorithm,which can significantly outperform other state-of-the-art algorithms. 展开更多
关键词 Resource scheduling problem(RSP) ant colony system(ACS) marine container terminal(MCT) pre-selection strategy
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Investigation on Breakdown Characteristics of Various Surface Terminal Structures for GaN-Based Vertical P-i-N Diodes
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作者 Song Shi Guanyu Wang +5 位作者 Yingcong Xiang Chuan Guo Xing Wang Yinlin Pu Huilan Li Zhixian Li 《Journal of Applied Mathematics and Physics》 2024年第2期554-568,共15页
GaN-based vertical P-i-N diode with mesa edge terminal structure due to electric field crowding effect, the breakdown voltage of the device is significantly reduced. This work investigates three terminal structures, i... GaN-based vertical P-i-N diode with mesa edge terminal structure due to electric field crowding effect, the breakdown voltage of the device is significantly reduced. This work investigates three terminal structures, including deeply etched, bevel, and stepped-mesas terminal structures, to suppress electric field crowding effects at the device and junction edges. Deeply-etched mesa terminal yields a breakdown voltage of 1205 V, i.e., 89% of the ideal voltage. The bevel-mesa terminal achieves about 89% of the ideal breakdown voltage, while the step-mesa terminal is less effective in mitigating electric field crowding, at about 32% of the ideal voltage. This work can provide an important reference for the design of high-power, high-voltage GaN-based P-i-N power devices, finding a terminal protection structure suitable for GaNPiN diodes to further enhance the breakdown performance of the device and to unleash the full potential of GaN semiconductor materials. 展开更多
关键词 GaN P-I-N Mesa Edge terminal Electric Field Crowding
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PROPERTIES AND MORPHOLOGY OF UNSATURATED POLYESTER/ACRYLATE-TERMINATED POLYURETHANE/ORGANO-MONTMORILLONITE NANOCOMPOSITES 被引量:6
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作者 Chang-jiang You Jin-guo Xu +2 位作者 Song Xi Xiao-xia Duan Jie Shen and De-min Jia College of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,China 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2005年第5期471-478,共8页
Unsaturated polyester resin (UPR)/acrylate-terminated polyurethane (ATPU)/organo-modified montmorillonite (OMMT) nanocomposites were prepared by the in situ intercalative polymerization method. Samples were prep... Unsaturated polyester resin (UPR)/acrylate-terminated polyurethane (ATPU)/organo-modified montmorillonite (OMMT) nanocomposites were prepared by the in situ intercalative polymerization method. Samples were prepared by the sequential mixing, i.e. mixture of the ATPU and styrene (S) and OMMT were prepared in the first step; UPR was then added to the pre-intercalates of ATPU/S/OMMT. Results indicate that the mechanical properties and thermal properties of UPR/ATPU/OMMT nanocomposites greatly depend on the amount of ATPU and OMMT. Results show that the addition of ATPU could increase the impact strength of UPR/ATPU composites, but the tensile strength, flexural strength and heat resistance of the materials are obviously decreased. When the weight ratio between UPR, ATPU and OMMT were 82:15:3, the impact strength and heat distortion-temperature of nanocomposite were greatly improved, meanwhile there was little change for other properties of the nanocomposites. The synergistic enhancement effects of ATPU and OMMT on the composites were observed. The structures and morphology of the composites were investigated by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. 展开更多
关键词 Unsaturated polyester Acrylic terminal polyurethane Organo-modified montmorillonite Nanocomposite.
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Terminal Blend橡胶泡沫沥青制备及性能评价 被引量:1
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作者 温永 王祯国 +2 位作者 董永康 裴建中 张久鹏 《建筑材料学报》 EI CAS CSCD 北大核心 2023年第10期1129-1136,共8页
为弥补传统泡沫沥青高温稳定性和黏附性的不足,解决传统橡胶沥青发泡效果不理想的缺陷,对terminal blend(TB)橡胶泡沫沥青进行了研究,探究了TB橡胶泡沫沥青发泡效果的影响规律,对其微观形貌与特征进行了表征,同时评估了TB橡胶泡沫沥青... 为弥补传统泡沫沥青高温稳定性和黏附性的不足,解决传统橡胶沥青发泡效果不理想的缺陷,对terminal blend(TB)橡胶泡沫沥青进行了研究,探究了TB橡胶泡沫沥青发泡效果的影响规律,对其微观形貌与特征进行了表征,同时评估了TB橡胶泡沫沥青的高温性能、温度敏感性和黏度.结果表明:采用TB橡胶沥青制备泡沫沥青具备可行性;相比传统泡沫沥青,TB橡胶泡沫沥青在温度敏感性降低的同时,还显著提升了高温性能和黏度;微观结果显示TB橡胶泡沫沥青的发泡过程仅为物理过程,而且受发泡温度和发泡用水量的影响,其中后者对整体发泡效果的影响更加明显;TB橡胶泡沫沥青的最佳发泡温度为160°C、发泡用水量为2.7%. 展开更多
关键词 道路工程 泡沫沥青 terminal blend 发泡特性 膨胀率 半衰期 简化效能指数
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Low-cost fabrication of highly dispersed atomically-thin MoS2 nanosheets with abundant active Mo-terminated edges 被引量:1
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作者 Fei Wang Ming Hao +6 位作者 Wei Liu Penji Yan Baizeng Fang Sijia Li Jinsheng Liang Maomao Zhu Li Cui 《Nano Materials Science》 CAS CSCD 2021年第3期205-212,共8页
In this work,highly dispersed atomically-thin MoS2 nanosheets were fabricated at one thousandth of the commercial cost using sepiolite(SEP)mineral nanofibers as carriers via a microwave hydrothermal method.Atomresolve... In this work,highly dispersed atomically-thin MoS2 nanosheets were fabricated at one thousandth of the commercial cost using sepiolite(SEP)mineral nanofibers as carriers via a microwave hydrothermal method.Atomresolved microscopy revealed the MoS2 nanosheets were only 1–4 atomic layers thick.The Mo atoms anchored on the mineral surface served as nucleation sites for the nanosheet growth.The MoS2 layers were in staggered stacking yielding abundant atomic steps at the nanosheets’edges,where catalytically active molybdenum terminations dominated instead of the inert sulfur atoms commonly reported.DFT calculations disclosed that the bonding of Mo(MoS2)and O(SEP)at the MoS2/sepiolite(MSEP)interface enabled SEP to be a unique support,superior to the other minerals for growing such highly-dispersed ultrathin MoS2 architecture.In a typical photocatalyisis application,the MSEP demonstrated a significantly improved photocatalytic performance for RhB degradation compared with the MoS2 nanosheets assembled microspheres.This work provides an important new strategy for low-cost batch preparation of high quality 2D materials via assembly on mineral materials. 展开更多
关键词 Molybdenum disulfide NANOSHEETS Mineral nanofibers Microwave hydrothermal Molybdenum termination Density functional theory
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Electronic properties of hydrogen- and oxygen-terminated diamond surfaces exposed to the air 被引量:1
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作者 刘峰斌 汪家道 +1 位作者 陈大融 颜大运 《Chinese Physics B》 SCIE EI CAS CSCD 2009年第5期2041-2047,共7页
The electronic properties of hydrogen- and oxygen-terminated diamond surfaces exposed to the air are investigated by scanning probe microscopy (SPM). The results indicate that for the hydrogen-terminated diamond sur... The electronic properties of hydrogen- and oxygen-terminated diamond surfaces exposed to the air are investigated by scanning probe microscopy (SPM). The results indicate that for the hydrogen-terminated diamond surface a shallow acceptor above the valence-band-maximum (VBM) appears in the band gap. However, the oxygen-terminated diamond film exhibits a high resistivity with a wide band gap. Based on the density-functional-theory, the densities of states, corresponding to molecular adsorbate in hydrogenated and oxygenated diamond (100) surfaces, are studied. The results show that the shallow acceptor in the band gap for the hydrogen-terminated diamond film can be attributed to the interaction between the surface C H bonding orbitals and the adsorbate molecules, while for the oxygen-terminated diamond film, the interaction between the surface C-O bonding orbitals and the adsorbate molecules can induce occupied states in the valence-band. 展开更多
关键词 hydrogen-termination oxygen-termination electronic properties diamond film
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Optical properties of F- and H-terminated armchair silicon nanoribbons
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作者 鲁道邦 濮春英 +3 位作者 宋玉玲 潘群娜 周大伟 徐海如 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第12期578-582,共5页
The optical properties of F- and H-terminated silicon nanoribbons with armchair edges(F- and H- terminated ASi NRs)are compared by using the first-principles within the density function theory(DFT) framework. The ... The optical properties of F- and H-terminated silicon nanoribbons with armchair edges(F- and H- terminated ASi NRs)are compared by using the first-principles within the density function theory(DFT) framework. The results show that compared with for H-terminated 7-ASi NR, the dielectric function for the F-terminated 7-ASi NR has a red shift, which is mainly attributed to the narrower band gap because of the σ–π mixing effect of F–Si bonds in F-terminated 7-ASi NR.The peaks in the energy loss spectra for both systems represent the characteristics associated with the plasma resonance,which correspond to the trailing edges in the reflection spectra. These properties show that the different terminated atoms in7-ASi NRs affect mainly the optical properties in the low energy range. Because of the rich optical properties, the 7-ASi NR could be a potential candidate for photoelectric nanodevice. 展开更多
关键词 ASi NRs optical properties first principle terminATION
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MXene terminating groups=O,–F or–OH,–F or=O,–OH,–F,or=O,–OH,–Cl? 被引量:2
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作者 Tariq Bashir Sara Adeeba Ismail +3 位作者 Jiaqi Wang Wenhao Zhu Jianqing Zhao Lijun Gao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第1期90-104,I0003,共16页
MXenes are a novel family of two-dimensional(2D)materials that are fast gaining popularity due to their versatile characteristics.The surfaces of these materials are often functionalized by negatively charged terminal... MXenes are a novel family of two-dimensional(2D)materials that are fast gaining popularity due to their versatile characteristics.The surfaces of these materials are often functionalized by negatively charged terminal groups,such as=O,OH,and F during their synthesis,and it has been hypothesized that regulating the surface terminators enables to control the material characteristics.However,there is still a large gap between computational and experimental investigations regarding comprehending the surface functional groups.Surfaces with mixed terminations are consistently synthesized in experiments,although pure terminated surfaces are predicted by computational research.Here we summarized the nature of chemical bonding in transition metal carbide materials(MXenes)by1H and19F nuclear magnetic resonance(NMR),Raman,X-ray absorption near edge structure(XANES),extended X-ray absorption fine structure(EXAFS),ultraviolet photoelectron spectroscopy(UPS),X-ray photoelectron spectroscopy(XPS)/scanning transmission electron microscopy(STEM),and thermogravimetric analysis-mass spectrometry(TGA-MS)characterizations.Previous literature reveals that=O,–OH,–F,and–Cl are typical MXene surface terminators.However,recent comparative investigations on the valence band intensity distribution in MXenes reveal that the–OH cannot be considered an intrinsic termination species in MXenes.The surface terminals(=O,–OH,–F,and–Cl)of several MXenes,particularly V2CTxand Ti3C2Tx,will be identified and quantified here.We have also discussed different etching approaches for the synthesis of MXene,the dependence of MXene conductivity on MXene terminating groups,and the emission of various gaseous products that evolved during its chemical transformations.This paper provides significance,especially in the field of energy conversion and storage materials,where the intercalation process is crucial. 展开更多
关键词 MXene surface terminating groups Characterization CONDUCTIVITY Oxidation
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CURE CHARACTERISTICS OF HYDROXYL TERMINATED POLYBUTADIENE PREPOLYMER WITH BLOCKED TOLUENE DIISOCYANATE-Ⅱ
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作者 Prathima Kamath M.Srinivasan V.N.Krishnamurthy 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1994年第1期91-97,共7页
Cure characteristics of hydroxyl terminated polybutadiene (HTPB) prepolymer with avariety of blocked toluene diisocyanate (TDI) in the presence of triethylamine (TEA) andchloroacetic acid catalyst are reported. Phenol... Cure characteristics of hydroxyl terminated polybutadiene (HTPB) prepolymer with avariety of blocked toluene diisocyanate (TDI) in the presence of triethylamine (TEA) andchloroacetic acid catalyst are reported. Phenol, thiophenol, p-chloropheno1, p-nitrophenol,p-cresol, resorcinol, naphthols, caprolactam and butylated-hydroxytoluene were used as blockingagents. Viscosity measurements have been carried out using a mixture of HTPB and blocked TDIin cyclohexanone in the presence of the catalysts at 50℃ and 60℃ using Haake rotational vis-cometer. Viscosity measurements have also been carried out with 50% solids such as ammonium sulphate along with HTPB and TDI adduct. 展开更多
关键词 Hydroxyl terminated polybutadiene Blocked toluene diisocyanate Cure characteristics
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Surface Oxygen Adsorption and Electric Property of Hydrogen-Terminated Single Crystal Diamonds by UV/ozone Treatment
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作者 杨名超 万琳丰 +4 位作者 王旌丞 马子程 王鹏 高楠 李红东 《Chinese Physics Letters》 SCIE CAS CSCD 2020年第6期66-69,共4页
Surface terminations of diamond play an important role in determining the electric properties of diamond-based electronic devices.We report an ultraviolet/ozone(UV/ozone)treatment process on hydrogen-terminated single... Surface terminations of diamond play an important role in determining the electric properties of diamond-based electronic devices.We report an ultraviolet/ozone(UV/ozone)treatment process on hydrogen-terminated single crystal diamond(H-diamond)to modulate the carrier behavior related to varying oxygen adsorption on surfaces.By UV/ozone treatments,the induced oxygen radicals are chemically adsorbed on the H-terminated diamond and replace the original adsorbed H,which is analyzed by x-ray photoelectron spectroscopy.The concentration of oxygen adsorbed on surface increases from^3%to^8%with increasing the ozone treatment time from 20 s to 600 s.It is further confirmed by examining the wettability properties of the varying diamond surfaces,where the hydrophobic for H-termination transfers to hydrophilic for partly O-termination.Hall effect measurements show that the resistance(hole mobility)of the UV/ozone-treated H-diamond continuously increases(decrease)by two orders of magnitude with increasing UV/ozone treatment time from 20 s to 600 s.The results reveal that UV/ozone treatment becomes an efficient method to modulate the surface electrical properties of H-diamonds for further investigating the oxygenation effect on two-dimensional hole gas based diamond devices applied in some extreme environments. 展开更多
关键词 OZONE terminATION terminated
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A Self-Terminated Interleaver Design for Turbo Codes
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作者 Xu Heng-ping Rong Mong-tian +1 位作者 Pan Sheng Zhao Xun 《Wuhan University Journal of Natural Sciences》 CAS 2002年第2期195-198,共4页
Turbo codes can achieve excellent performance at low signal-to-noise ratio (SNR), but the performance can be severely degraded if no trellis termination is employed. This paper proved that if trellis termination bits ... Turbo codes can achieve excellent performance at low signal-to-noise ratio (SNR), but the performance can be severely degraded if no trellis termination is employed. This paper proved that if trellis termination bits were appended to RSC1, trellis of RSC2 could be terminated by designing the interleaver properly, consequently, derived the designing condition of such self-terminated interleaver (STI). Then we presented an algorithm of implementing a kind of STI, which could terminate RSC2 as well on condition that the RSC1 was terminated. We verified the performance of STI for turbo codes by simulation, and the simulation results showed that turbo codes with STI outperformed interleavers that could not terminate RSC2 as well. 展开更多
关键词 Turbo codes bit error rate (BER) trellis termination
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Preparation and Characterization of Carboxyl-terminated Poly(butadiene-co-acrylonitrile)-epoxy Resin Prepolymers for Fusion-bonded-epoxy Powder Coating 被引量:4
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作者 刘敬成 刘晓亚 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2012年第4期694-701,共8页
Liquid carboxyl-terminated poly(butadiene-co-acrylonitrile)(CTBN)-epoxy resin(EP) prepolymers were prepared with different contents of CTBN.The chemical reactions between EP and CTBN were characterized by Fourie... Liquid carboxyl-terminated poly(butadiene-co-acrylonitrile)(CTBN)-epoxy resin(EP) prepolymers were prepared with different contents of CTBN.The chemical reactions between EP and CTBN were characterized by Fourier ransform infrared(FTIR) spectroscopy and gel permeation chromatography(GPC).The scanning electron micrograph(SEM) and dynamic mechanical analysis(DMA) of curing films showed phase separation,and the rubber particles were finely dispersed in the epoxy matrix.Mechanical properties analysis of curing films showed that impact strength and elongation at break increased significantly upon the addition of CTBN,indicating good toughness of the modified epoxy resins.Thermogravimetric analysis(TGA) showed that the incorporation of CTBN had little effect on the thermal stability of EP.Fusion-bonded-epoxy(FBE) powder coatings modified with CTBN-EP prepolymers were prepared.The experimental results demonstrate the ability of CTBN-EP prepolymers,toughening technology to dramatically enhance the flexibility and impact resistance of FBE coatings without compromising other key properties such as corrosion protection. 展开更多
关键词 epoxy powder coating carboxyl-terminated butadiene acrylonitrile PREPOLYMERS
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