Synthesis of Magnesium Aluminate Spinel-corundum Composite with Waste Slide Plate and Magnesia Carbon Brick

Magnesium aluminate spinel -corundum composite was prepared with waste slide plate and magnesia carbon brick. Microstructure and sintering ability of as-prepared magnesium aluminate spinel -corundum composite were investigated with XRD, SEM, and DSC/TG. With the addition of waste slide plate increasing or synthesis tem- perature rising, the bulk density of the specimen increases and the apparent porosity decreases, but the crystallinity of the specimen decreases and the magnesium alaminate spinel phase increases. The obtained composite contains 72% spinel and 26% corundum. Primary phase and secondary phase are bonded by glass phase. The results show that it is feasible to synthesis magnesium aluminate spinel - corundum material with waste slide plate and magnesia carbon brick.

根部加强的镁合金搅拌摩擦焊分析

常规搅拌摩擦焊中,不同厚度的材料所适配的最佳搅拌针长度也不相同,搅拌针过长或过短都会对焊接效果产生不利影响.为了解决这一局限性,提出了一种在焊缝背面添加适当厚度同种材料垫板的新型焊接工艺,在该工艺中,搅拌针长度大于被焊板材厚度,将垫板与母材焊接在一起,一方面,降低了对搅拌针长度的要求;另一方面,可消除焊缝减薄产生的不利影响.结果表明,采用该方法分析1.5 mm厚AZ31B镁合金的对接焊,接头抗拉强度最大可达母材的91.19%,此外,分析了焊缝横截面微观组织和显微硬度分布,通过所建立的卷积神经网络模型,对接头抗拉强度随参数变化的分布情况进行了预测,获取了最佳工艺参数.

AZ31B镁合金表面镍基复合镀层的制备及耐蚀性能研究

为了提高镁合金的耐腐蚀性,以AZ31B镁合金为基体,采用化学镀与脉冲电镀技术在其表面制备了Ni-P/Ni复合镀层。采用扫描电镜(SEM)、X射线衍射(XRD)分析了镀层表面的形貌和成分。通过电化学极化、阻抗测试和接触角研究了该复合镀层的耐腐蚀性和疏水性。结果表明:峰值电流密度为30 mA/cm^(2)时,镀层的晶粒最细致,接触角最高为117.3°,自腐蚀电位最高(-0.4510 V),腐蚀电流密度最低(1.94×10^(-7)A/cm^(2)),阻抗值最大,明显优于镁合金基体,这说明该复合镀层可提高镁合金疏水性和耐腐蚀性。

刨花覆面玻镁板制备及其性能研究

为拓展玻镁板的应用领域并提升抗折强度,在玻镁板上下表面铺装均匀施加了丙烯酸/异氰酸酯共混胶的松木刨花,热压制得刨花覆面玻镁板。通过正交试验,研究热压温度、热压时间、施胶量等因素对刨花覆面玻镁板抗折强度(MOR)和弹性模量(MOE)的影响。结果表明,热压温度对刨花覆面玻镁板抗折强度和弹性模量影响最大。刨花覆面玻镁板的优化制备工艺为热压温度为160℃,热压时间为180 s,施胶量为9%,所制得的刨花覆面玻镁板MOR和MOE分别为10.51 MPa和1 681 MPa。

Determining the microstructure and properties of magnesium aluminum composite panels by hot rolling and annealing

The researchers made magnesium aluminum composite panels by asymmetric metal packaging and studied rolling temperature,holding time,and high temperature heat treatment,such as short time and low temperatures over long periods of time parameters under the new preparation method.We tested the new magnesium aluminum composite panels’tensing properties and bending performance by using scanning electric mirror and EDS.It is concluded that the new magnesium aluminum composite panels’elongation is 24%under the tensile strength of 260 MPa.Regarding performance when compared with other methods,traditional magnesium aluminum composite panels’elongation is 10%,which shows its advanced nature.At the same time,bending performance test showed that the combination of the composite board has higher performance,offering the reference value for the preparation of magnesium–aluminum composite plate.

Properties of fluoride film and its effect on electroless nickel deposition on magnesium alloys

The physical characteristics and microstructure of the fluoride film formed during activation were investigated using SEM,XPS and SAM,and its stability in electroless nickel(EN) bath was analyzed.The effects of the fluoride film on EN deposition were studied additionally.The results show that the fluoride film on magnesium alloys is a kind of porous film composed of MgF2 with thickness of 1.6-3.2 μm.The composition of the activation bath and pretreatment of EN processing have influence on the composition of the fluoride film.The fluoride is stable and dissolves little in EN bath;as a result,the fluoride film can protect magnesium substrate from the corrosion of EN bath.The composition of fluoride determines the initial deposition of EN and part of the fluoride film finally exists as inclusion in EN coating.

Electroless nickel fabrication on surface modified magnesium substrates

In recent years,magnesium(Mg)has evolved as a salient material,in affiliation with electroless nickel(Ni)coating,which have found applications in automobiles,aerospace and confederate fields attributing to its excellent inherent weight sensitive properties.However,being acknowledged for its remarkable auxiliary properties like flexible machining,appreciable weight sensitivity and ability to be patently diecast into mesh constructs,magnesium is prejudiced by aeronautical standards predominantly for its inferior corrosion resistance properties.In this sense,electroless nickel plating on magnesium and its alloys has been suggested to extricate it from corrosion problem and make it more competitive in industrial and defence applications.Autocatalytic fixation of metal ions onto respective substrates accrues and alters their mechanical,electrochemical and tribological properties,destitute of any electric current aid.This proficiently identified technique is prosecuted with the assistance of a series of sequenced operations involving a prior pretreatment,which corresponds to the chemical cleaning of the substrate surface;electroless coating;and a later activation process which is a mild etching of the electroless coated surface.The susceptibility of magnesium to this methodology has advanced and propagated its exercise and applicability in aircraft,satellites and allied aeronautical fields.Contemporarily,researchers have proposed various eco-friendly and modified duplex and composite coatings which have transmuted properties of these appendages by tailoring alloy compositions and reagents employed.This review article systematically colligates various considerations and evaluations on electroless nickel applications of magnesium and its alloys and explicates how it anchors its practice in the respective domains.Furthermore,a comprehensive analysis is devised based on the pre-existing treatment methods for accomplishing the same.

基于共轭梯度算法的镁板热轧压下量PID控制优化

为了进一步提高镁合金板热轧厚度成形控制能力,设计了一种基于共轭梯度算法的镁合金板热轧压下量PID控制方法。基于共轭梯度算法对压下量PID控制优化,引入到双辊热轧镁合金板带横向厚度分布的预测与控制中。研究结果表明:板带预测压下量分布和真实情况相吻合,说明基于共轭梯度算法的导电用镁合金板热轧压下量PID控制优化设计具有良好可靠性。该预测模型平均绝对误差为4.2μm,这验证了基于共轭梯度算法的导电用镁合金板热轧压下量PID控制优化是可行的。该研究有助于提高热轧镁合金板材的成形效率,也可托找到其它的合金轧制领域,具有很好的应用推广价值。

Corrosion and wear properties of electroless Ni-P plating layer on AZ91D magnesium alloy

A direct electroless Ni-P plating treatment was applied to AZ91D magnesium alloy for improving its corrosion resistance and wear resistance. Corrosion resistance of the Ni-P coatings was evaluated by potentiodynamic polarization and immersing experiments in 3.5% NaCl solution. The wear resistance of the coatings was investigated by the wear track and the mass change after ball-on-disk experiment. The results show that corrosion resistance and wear resistance of the AZ91D alloy are greatly improved after direct electroless Ni-P plating. No discoloration is noticed until 4 d of immersion in 3.5% NaCl solution. Potentiodynamic polarization experiments show that the free corrosion potential of magnesium alloy is shifted from -1 500 mV to -250 mV and passivation occurs at 1 350 mV after direct electroless plating. The friction coefficients and wear rates of Ni-P coating and Ni-P coating after tempering are 0.10-0.351, 9.038×10-3 mm3/m and 0.13-0.177, 3.056×10-4 mm3/m, respectively, at a load of 1.5 N with dry sliding. Although minor hurt on corrosion resistance was caused, significant improvement of wear resistance was obtained after tempering treatment of the coating.

Influence of pH values on electroless Ni-P-SiC plating on AZ91D magnesium alloy

A novel Ni-P-SiC composite coating was prepared by electroless plating in order to improve the corrosion capacity and wear resistance of AZ91D magnesium alloy.The influence of pH values on deposition rates and properties of the coatings was studied.The microstructure and phase structure of the Ni-P-SiC coatings were analyzed by scanning electron microscopy(SEM)and X-ray diffractometry(XRD).The corrosion and wear resistance performances of the coatings were also investigated through electrochemical technique and pin-on-disk tribometer,respectively.The results indicate that the composite coating is composed of Ni, P and SiC.It exhibits an amorphous structure and good adhesion to the substrate.The coatings have higher open circuit potential than that of the substrate.The composite coating obtained at pH value of 5.2 possesses optimal integrated properties,which shows similar corrosion resistance and ascendant wear resistance properties to the substrate.

镁晶板-钢筋混凝土叠合楼板耐火性能试验研究

镁晶板—钢筋混凝土叠合楼板的下层为预制新型耐火材料镁晶板,上层为现浇钢筋混凝土板。为了研究镁晶板—钢筋混凝土叠合楼板在不同荷载比下的耐火性能及耐火等级,对3块叠合楼板试件进行ISO-834标准升温下的受火试验,得到叠合板不同位置的受火时间—温度曲线和受火时间—跨中位移曲线。试验表明,叠合板具有良好的耐火性能,耐火极限可达到1.5 h以上。利用有限元软件ABAQUS分析了试件的耐火性能,通过与试验结果对比,验证了模型的可靠性,进而采用模型考察荷载比、镁晶板厚度、混凝土保护层厚度、钢筋和混凝土的强度对叠合楼板耐火极限的影响。分析表明,荷载比和镁晶板厚度对叠合楼板耐火极限影响较大。基于参数分析结果,给出不同荷载比和不同镁晶板厚度叠合板的耐火极限。

Corrosion resistance of Mg-Mn-Ce magnesium alloy modified by polymer plating

Polymeric nano-film on the surface of Mg-Mn-Ce magnesium alloy was fabricated by polymer plating of 6-dihexylamino-1,3,5-triazine-2,4-dithiol monosodium(DHN) to improve its corrosion resistance.The electrochemical reaction process was analyzed by cyclic voltammetry and two obvious peaks of oxidation reaction were observed.The static contact angle of distilled water on polymer-plated surface can be up to 106.3°while on the blank surface it is 45.8°.Potentiodynamic polarization results show that the polymeric film can increase the corrosion potential from -1.594 V vs SCE for blank to -0.382 V vs SCE.The results of electrochemical impedance spectroscopy indicate that the charge transfer resistances of blank and polymer-plated Mg-Mn-Ce alloy are 485Ω·cm^2 and 2 717Ω·cm^2,respectively.The method of polymer plating can provide a novel approach for fabricating hydrophobic film on Mg-Mn-Ce alloy surface and improving its anti-corrosion property.

Electroless nickel-plating on die cast magnesium alloy AZ91D

Electroless nickel-plating on die cast magnesium alloy AZ91D was investigated. Growth of the electroless nickel-plating coating was characterized using scanning electron microscopy. Corrosion resistance of the coating was evaluated by open circuit potential and potentiodynamic polarization curves in 3.5%(mass fraction) NaCl solution. The results show that plating deposition is initiated on the crevices and then spread onto primary α phase. The corrosion potentials for die cast magnesium alloy AZ91D and nickel-plating coating are about -1.45 V and -0.36 V(vs. SCE),respectively. No discoloration,cracks,blisters,or peeling appear by heat-quench test. The results show that the corrosion potential of Ni-P coating is increased by 1 000 mV and corrosion resistance for die cast magnesium alloy AZ91D is improved. The adhesion between the coating and the substrate is excellent. Electroless nickel plating is a promising method to enhance magnesium alloys resistance for attacking.

Direct electroless Ni-P plating on AZ91D magnesium alloy

An electroless Ni-P plating treatment was applied on AZ91D magnesium alloy to improve its corrosion resistance. Optimum pretreatment conditions and optimum bath of electroless nickel plating for magnesium alloy were found through many experiments. In order to avoid bother of pre-plating medium layer, a set of procedure of direct electroless Ni-P under the acid condition was investigated. The properties of the coating with 10% phosphorus were investigated. The results show that a coating with high hardness, low porosity and good adhesive strength is obtained. X-ray diffraction patterns show that the structure of the coating is an amorphous phase. After annealing at 400℃, the amorphous phase of Ni-P is transformed to crystalline phases, and some intermetallics as Ni3P and Ni5P2 are deposited from Ni-P solid solution along with an enhancing hardness from Hv 450 to Hv 910.

Electroplating zinc transition layer for electroless nickel plating on AM60 magnesium alloys

Electroplating zinc coating as transition layer of electroless nickel plating on AM60 magnesium alloys was investigated. The zinc film can be deposited in a pyrophosphate bath at 50-60℃under current density of 0.5-1.5 A/dm2. A new fore treatment technology was applied by acid cleaning with a solution containing molybdate and phosphorous acid, by alkaline cleaning in a bath containing molybdate and sodium hydroxide. The subsequent electroless plating was carried out in nickel sulfate bath. The SEM observation shows that the deposition is uniform and compact. The polarization curve measurements show that the corrosion potential of the zinc plating in 3.5% NaCl is about -1.3 V(vs SCE) which is noble than that of magnesium substrate. The zinc electroplating can be applied as the pretreatment process for electroless nickel plating on magnesium alloys.

镁/铝板材同速异径蛇形轧制复合弯曲曲率研究

针对镁/铝板材轧制复合过程中金属流动性差异大,轧后容易出现弯曲的问题,提出了同速异径蛇形轧制复合工艺,可以降低轧后弯曲曲率。采用ANSYS/LS-DYNA有限元软件模拟了AZ31B/5052的轧制复合过程,分析了蛇形轧制复合过程中轧制温度、辊径比、压下量、错位量、层厚比及初始总板厚等参量与弯曲曲率的关系,并通过实验对模拟结果进行了验证。结果表明,相比于异步轧制,蛇形轧制能够降低复合板的弯曲曲率;相同轧制条件下,异步轧制弯曲曲率在一定范围内随层厚比的增大而减小,在1.01~1.20辊径比范围内,弯曲曲率随辊径比的增大而增大;在一定范围内,复合板的弯曲曲率随错位量的增大而减小,蛇形轧制有效抑制了轧后弯曲;当总板厚为8 mm、层厚比为0.25、压下量为3.6 mm、轧制温度为400℃、辊径比为1.01以及错位量为15 mm时进行轧制复合所得复合板接近平直。

A novel dual nickel coating on AZ91D magnesium alloy

Magnesium alloys covered with metal coating display excellent corrosion resistance,wear resistance,conductivity and electromagnetic shielding properties.The electroless plating Ni-P as bottom layer following the electroplating nickel as surface layer on AZ91D magnesium alloy was investigated.The coating surface morphology was observed with SEM and the structure was analyzed with XRD.Electrochemical tests and salt spray tests were carried out to study the corrosion resistance.The experimental results indicate that the dual coating is uniform,compact and pore-free.The adhesion strength between magnesium alloy substrate and electroless plating Ni-P bottom layer and electroplating nickel surface layer is perfect.The corrosion resistance of AZ91D magnesium alloy is greatly improved after being protected with the dual coating.

20mm厚AZ31镁合金厚板搅拌摩擦焊接接头的显微组织演变及强化机制

采用搅拌摩擦焊焊接20mm厚AZ31镁合金板材,并沿厚度方向分5层对接头的显微组织和力学性能进行表征。结果表明:焊接温度和温降速率的不同导致搅拌区晶粒尺寸不均匀,且在材料流动行为的作用下,接头不同区域形成不同强织构。此外,接头各层的屈服强度和抗拉强度从上表面至下表面整体呈逐渐增加的趋势,伸长率沿接头厚度方向首先由9.5%升高至10.5%,然后逐渐降低至6.0%。整体接头的抗拉强度达到母材的88.5%。接头的主要强化机制为细晶强化。

搅拌针转速对厚板镁合金SSFSW焊缝组织及性能的影响

对9 mm厚板AZ31B镁合金进行静止轴肩搅拌摩擦焊(stationary shoulder friction stir welding,SSFSW)工艺试验,探讨搅拌针转速(500~1000 r/min)对焊缝组织及力学性能的影响规律.结果表明,在给定焊接速度80 mm/min下,搅拌针转速在600~800 r/min范围可获得表面光滑、无内部缺陷的对接焊缝,当转速为1000 r/min时焊缝表面出现不连续凹坑但内部仍无缺陷.随着转速增加,晶粒尺寸由(11.11±1.68)μm增加到(18.95±1.83)μm;在700 r/min时焊核区晶粒尺寸沿板厚差异最小.焊缝中间硬度分布具有不均匀性且随转速增加而减小,最大差异为10.97 HV,最低硬度47 HV位于前进侧的热力影响区与焊核区界面处.在700 r/min下接头力学性能最佳,强度系数为90.2%、对应断后伸长率为母材69.3%.随着转速增加,断裂模式由韧-脆混合断裂转变为剪切-韧性混合断裂.

不同镀层在中东海湾地区光伏电站钢桩基防腐中的试验研究

中东海湾地区常年高温多湿,土壤为中、重度盐碱化,富含氯离子及硫酸根离子,土壤湿度大,导电率强,属重度土壤腐蚀地区。该地区光伏电站常采用H型或C型钢桩基并采用热浸镀锌和镀镁铝锌对钢桩表面进行镀层防腐工艺。通过扫描电子显微镜研究镀层的表面形态,通过能谱仪与X射线衍射仪研究镀层中合金元素分布特征,同时研究其维氏硬度、耐磨性、耐氯性、耐碱性,并进行模拟土壤环境的电化学腐蚀试验研究。研究验结果表明:镀镁铝锌中由于镁的引入,改善了镀层的晶体结构,有助于提升其防腐性能,更适合于光伏支架钢桩基的长期防腐。