Effect of temperature on suspension magnetization roasting of hematite using biomass waste as reductant:A perspective of gas evolution

The magnetization reduction of hematite using biomass waste can effectively utilize waste and reduce CO_(2) emission to achieve the goals of carbon peaking and carbon neutrality.The effects of temperatures on suspension magnetization roasting of hematite using biomass waste for evolved gases have been investigated using TG-FTIR,Py-GC/MS and gas composition analyzer.The mixture reduction process is divided into four stages.In the temperature range of 200-450℃ for mixture,the release of CO_(2),acids,and ketones is dominated in gases products.The yield and concentration of small molecules reducing gases increase when the temperature increases from 450 to 900℃.At 700℃,the volume concentrations of CO,H_(2) and CH_(4) peak at 8.91%,8.90% and 4.91%,respectively.During the suspension magnetization roasting process,an optimal iron concentrate with an iron grade of 70.86%,a recovery of 98.66% and a magnetic conversion of 45.70% is obtained at 700℃.Therefore,the magnetization reduction could react greatly in the temperature range of 600 to 700℃ owing to the suitable reducing gases.This study shows a detail gaseous evolution of roasting temperature and provides a new insight for studying the reduction process of hematite using biomass waste.

Research on Dynamic Model's Building of Active Magnetic Suspension Systems

An experimental method is introduced in this paper to build the dynamics of AMSS (the active magnetic suspension system), which doesn’t depend on system’s physical parameters. The rotor can be reliably suspended under the unit feedback control system designed with the primary dynamic model obtained. Online identification in frequency domain is processed to give the precise model. Comparisons show that the experimental method is much closer to the precise model than the theoretic method based on magnetic circuit law. So this experimental method is a good choice to build the primary dynamic model of AMSS.

Reaction behavior and non-isothermal kinetics of suspension magnetization roasting of limonite and siderite

In order to develop limonite and decrease CO_(2) emissions,siderite is proposed as a clean reductant for suspension magnetization roasting(SMR) of limonite.An iron concentrate(iron grade:65.92wt%,iron recovery:98.54wt%) was obtained by magnetic separation under the optimum SMR conditions:siderite dosage 40wt%,roasting temperature 700℃,roasting time 10 min.According to the magnetic analysis,SMR achieved the conversion of weak magnetic minerals to strong magnetic minerals,thus enabling the recovery of iron via magnetic separation.Based on the phase transformation analysis,during the SMR process,limonite was first dehydrated and converted to hematite,and then siderite decomposed to generate magnetite and CO,where CO reduced the freshly formed hematite to magnetite.The microstructure evolution analysis indicated that the magnetite particles were loose and porous with a destroyed structure,making them easier to be ground.The non-isothermal kinetic results show that the main reaction between limonite and siderite conformed to the two-dimension diffusion mechanism,suggesting that the diffusion of CO controlled the reaction.These results encourage the application of siderite as a reductant in SMR.

Mechanism for suspension magnetization roasting of iron ore using straw-type biomass reductant

As an alternative reductant for fossil fuel in the future,straw-type biomass contributes to emission reduction and green utilization in the suspension roasting process.In this study,the influences of the roasting time,roasting temperature and dose of straw-type biomass after suspension magnetization roasting(SMR) and separation were investigated.The optimal conditions were determined to be a roasting time of 7.5 min with a straw-type biomass dose of 20 wt% and a roasting temperature of 800℃ in which an iron grade of 71.07% and recovery of 94.17% were obtained for the iron concentrate.The maximum saturation magnetization under optimal conditions was 35.05 A·m^(2)·g^(-1),and the gaseous regulation of the biomass revealed that cumulative reducing gas volume was 293.93 mL at the optimal roasting time of450 s.The transformation of hematite to magnetite was detected by X-ray diffraction(XRD).During microstructure evolution,the outer layer consisting of fissures and tiny holes continuously deepened toward the core.

Application of suspension magnetization roasting as technology for high-efficiency separation of valuable iron minerals from high-iron bauxite

A technology for suspension magnetization roasting−magnetic separation was proposed to separate iron minerals for recovery.The optimum parameters were as follows:a roasting temperature of 650℃,a roasting time of 20 min,a CO concentration of 20%,and particles with a size less than 37μm accounting for 67.14%of the roasted product.The total iron content and iron recovery of the magnetic concentrate were 56.71%and 90.50%,respectively.The phase transformation,magnetic transition,and microstructure evolution were systematically characterized through iron chemical phase analysis,X-ray diffraction,vibrating sample magnetometry,X-ray photoelectron spectroscopy,and transmission electron microscopy.The results demonstrated the transformation of hematite to magnetite,with the iron content in magnetite increasing from 0.41%in the raw ore to 91.47%in the roasted product.

Mechanism of microwave assisted suspension magnetization roasting of oolitic hematite ore

Oolitic hematite is an iron ore resource with rich reserves,complex composition,low grade,fine disseminated particle sizes,and a unique oolitic structure.In this study,a microwave-assisted suspension magnetization roasting technology was proposed to recover and utilize the ore.The results showed that under the conditions of microwave pretreatment temperature of 1050℃ for 2 min,a magnetic concentrate with an iron grade of 58.72%at a recovery of 89.32%was obtained by microwave suspension magnetization roasting and magnetic separation.Moreover,compared with the no microwave pretreatment case,the iron grade and recovery increased by 3.17%and 1.58%,respectively.Microwave pretreatment increased the saturation magnetization of the roasted products from 24.974 to 39.236(A∙m^(2))/kg and the saturation susceptibility from 0.179×10^(−3) m^(3)/kg to 0.283×10^(−3) m^(3)/kg.Microcracks were formed between the iron and gangue minerals,and they gradually extended to the core of oolite with the increase in the pretreatment time.The reducing gas diffused from outside to inside along the microcracks,which promoted the selective transformation of the weak magnetic hematite into the strong magnetic magnetite.

Siderite pyrolysis in suspension roasting:An in-situ study on kinetics,phase transformation,and product properties

Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigated to improve the selective conversion of siderite to magnetite and CO,enriching the theoretical system of green SMR using siderite as a reductant.According to the gas products analyses,the peak value of the reaction rate increased with increasing temperature,and its curves presented the feature of an early peak and long tail.The mechanism function of the siderite pyrolysis was the contraction sphere model(R_(3)):f(α)=3(1−α)2/3;E_(α)was 46.4653 kJ/mol;A was 0.5938 s^(−1);the kinetics equation was k=0.5938exp[−46.4653/(RT)].The in-situ HT-XRD results indicated that siderite was converted into magnetite and wüstite that exhibited a good crystallinity in SMR under a N_(2) atmosphere.At 620℃,the saturation magnetization(M_(s)),remanence magnetization(Mr),and coercivity(Hc)of the product peaked at 53.63×10^(-3)A·m^(2)/g,10.23×10^(-3)A·m^(2)/g,and 12.40×10^(3)A/m,respectively.Meanwhile,the initial particles with a smooth surface were transformed into particles with a porous and loose structure in the roasting process,which would contribute to reducing the grinding cost.

Magnetic suspension hip joint： an ideal design of an artificial joint

Background Artificial joints present certain problems such as osteal absorption and lysis induced by wear debris which leads to loosening of the prosthesis over a period of time. Here we propose a design of an artificial magnetic suspension joint that was prepared by integrating the medical theories of modern material science, magnetism, and medical physics.Methods According to clinical characteristic of biological and mechanical for hip joint, we designed the appearance and dimensions of magnetic suspension joint and placed neodymium-iron-boron permanent magnets in the prosthesis.As the same time, we performed mechanical and biological experiments using artificial magnetic suspension hip joints models.Results By simulated the human hip structure and the external load, we discovered the artificial magnetic suspension hip joints models had much lesser amount and size of wear debris than the ceramic/ceramic artificial hip joint prosthesis in friction wear tests. The force between the artificial joints with magnetic materials that we have calculated is feasible for application of artificial joint. The design of artificial magnetic suspension hip joints models was plausible technically and safe biologically.Conclusion Artificial magnetic suspension hip joints may effectively reduce the incidence of the loosening of prosthesis over a period of time.

Study of cobalt ferrite nanosuspensions for low-frequency ferromagnetic hyperthermia

High-coercive cobalt ferrite nanoparticles were synthesized and studied for magnetic hyperthermia by direct injection of their suspension into a tumor and application of a strong audio-frequency magnetic field for heating. Physical （dynamic magnetic hysteresis and heat generation in both liquid and solid dispersions）, biological （toxicity and penetration of particles in therapeutic quantities into mouse tumor tissue） as well as other properties of the particles were studied. A model was developed to describe the magnetodynamics in suspensions of magnetic nanoclusters with an account for both Brownian and regular rotations, to provide understanding of observed phenomena. The experimental and theoretical techniques developed have formed a basis for controllable synthesis of the magnetic nanoparticles for low-frequency heat generation in medical and other applications.

Dynamic magnetic hysteresis in a liquid suspension of acicular maghemite particles

This paper presents theoretical and experimental studies on the magnetodynamics and energy absorption in a dilute suspension of small ferromagnetic particles with magnetic hysteresis and mechanical mobility in an AC magnetic field. Experiments with 0.1% suspensions of acicular particles of gamma ferric oxide in solid and liquid matrices, subjected to a 430 Hz magnetic field with an intensity of up to 1200 Oe, revealed important role of particle mobility. The main qualitative and quantitative features of the phenomenon are in agreement with a model of joint magneto-mechanical dynamics of particles with a chain-of-spheres mode of incoherent magnetic reversal.

正弦激励下三磁铁磁悬浮动力吸振器的被动减振性能研究

本本文设计了一种新型的三磁铁磁悬浮动力吸振器(TMSDVA),并进行了建模和测试首先建立了TMSDVA悬臂梁减振系统的等效动力学模型.基于等效磁化电流理论,建立了非线性磁悬浮力的计算模型,并分析了非线性磁悬浮力的特征.然后用Runge-Kutta方法求解系统在正弦激励下的动力学响应.通过对仿真结果的分析发现,适当调整TMSDVA的阻尼系数不仅可以降低TMSDVA的减振效果对激励幅值的敏感性,还可以整体提高TMSDVA的减振效果.最后通过实验验证了理论分析的正确性.综合来看,TMSDVA在工程结构的被动减振方面具有潜在应用价值.