We offered the new theory of neutron (magnetic isotope) catalysis. For the first time it was shown that the number of neutrons in the atom, which have anomalous magnetic effect, have a great influence on the chemica...We offered the new theory of neutron (magnetic isotope) catalysis. For the first time it was shown that the number of neutrons in the atom, which have anomalous magnetic effect, have a great influence on the chemical properties. Our proposed theory of neutron (magnetic isotope) catalysis takes into account the influence of the magnetic field on the catalytic processes.展开更多
In this paper,we study the influences of magnetic fields on the coexistence of diquark and chiral condensates in an extended Nambu-Jona-Lasinio model with QCD axial anomaly,as it relates to color-flavor-locked quark m...In this paper,we study the influences of magnetic fields on the coexistence of diquark and chiral condensates in an extended Nambu-Jona-Lasinio model with QCD axial anomaly,as it relates to color-flavor-locked quark matter.Due to the coupling of rotated-charged quarks to magneticfields,diquark condensates become split,and the coexistence region is thus superseded in favor of a specific diquark Bose-Einstein condensation(BEC),denoted as the BECIphase.For strong magnetic fields,we find that the BECItransition is pushed to larger quark chemical potentials.The effect of magnetic catalysis tends to disrupt the BEC-BCS(Bardeen-Cooper-Schrieffer)crossover predicted in previous works.For intermediate fields,the effect of inverse magnetic catalysis is observed,and the axial-anomaly-induced phase structure is essentially unchanged.展开更多
Cesium carbonate supported on hydroxyapatite coated Nio.sZno.sFe2O4 magnetic nanoparticles (Nio.sZno.sFe2O4@Hap-Cs2CO3) was found to be magnetically separable, highly efficient, green and recyclable heterogeneous ca...Cesium carbonate supported on hydroxyapatite coated Nio.sZno.sFe2O4 magnetic nanoparticles (Nio.sZno.sFe2O4@Hap-Cs2CO3) was found to be magnetically separable, highly efficient, green and recyclable heterogeneous catalyst. The synthesized nanocatalyst has been characterized with several methods (FT-IR, SEM, TEM, XRD and XRF) and these analyzes confirmed which the cesium carbonate is well supported to catalyst surface. After full characterization, its catalytic activity was investigated in the synthesis of pyranopyrazole derivatives and the reactions were carried out at room temperature in 50:50 water/ethanol with excellent yields (88-95%). More importantly, the Nio.5Zno.sFe204@Hap-Cs2CO3 was easily separated from the reaction mixture by external magnetic field and efficiently reused at least six runs without any loss of its catalytic activity. Thus, the developed nanomagnetic base catalyst is potentially useful for the green and economic production of organic compounds.展开更多
Magnetic nanoparticles Fe3O4@SiO2 supported cinchona alkaloids (quinine and quinidine) were successfully synthesized as magnetically recoverable organocatalysts and characterized by FT-IR, XPS, SEM measurements, and...Magnetic nanoparticles Fe3O4@SiO2 supported cinchona alkaloids (quinine and quinidine) were successfully synthesized as magnetically recoverable organocatalysts and characterized by FT-IR, XPS, SEM measurements, and elemental analysis. Their catalytic activity and stereoselectivity were preliminarily evaluated in the asymmetric Michael addition reaction of 1,3-dicarbonyls and maleimides. The supported quinine catalyst exhibited good catalytic efficiency and modest to high enantioselectivity. The magnetic recoverabiliW and recyclability of the catalyst were also examined.展开更多
文摘We offered the new theory of neutron (magnetic isotope) catalysis. For the first time it was shown that the number of neutrons in the atom, which have anomalous magnetic effect, have a great influence on the chemical properties. Our proposed theory of neutron (magnetic isotope) catalysis takes into account the influence of the magnetic field on the catalytic processes.
基金supported by the National Natural Science Foundation of China(NSFC)under Contract No.10875058。
文摘In this paper,we study the influences of magnetic fields on the coexistence of diquark and chiral condensates in an extended Nambu-Jona-Lasinio model with QCD axial anomaly,as it relates to color-flavor-locked quark matter.Due to the coupling of rotated-charged quarks to magneticfields,diquark condensates become split,and the coexistence region is thus superseded in favor of a specific diquark Bose-Einstein condensation(BEC),denoted as the BECIphase.For strong magnetic fields,we find that the BECItransition is pushed to larger quark chemical potentials.The effect of magnetic catalysis tends to disrupt the BEC-BCS(Bardeen-Cooper-Schrieffer)crossover predicted in previous works.For intermediate fields,the effect of inverse magnetic catalysis is observed,and the axial-anomaly-induced phase structure is essentially unchanged.
基金Islamic Azad University,Bandar Abbas Branch for financial support
文摘Cesium carbonate supported on hydroxyapatite coated Nio.sZno.sFe2O4 magnetic nanoparticles (Nio.sZno.sFe2O4@Hap-Cs2CO3) was found to be magnetically separable, highly efficient, green and recyclable heterogeneous catalyst. The synthesized nanocatalyst has been characterized with several methods (FT-IR, SEM, TEM, XRD and XRF) and these analyzes confirmed which the cesium carbonate is well supported to catalyst surface. After full characterization, its catalytic activity was investigated in the synthesis of pyranopyrazole derivatives and the reactions were carried out at room temperature in 50:50 water/ethanol with excellent yields (88-95%). More importantly, the Nio.5Zno.sFe204@Hap-Cs2CO3 was easily separated from the reaction mixture by external magnetic field and efficiently reused at least six runs without any loss of its catalytic activity. Thus, the developed nanomagnetic base catalyst is potentially useful for the green and economic production of organic compounds.
基金Financial support from the National Natural Science Foundation of China(No. 21472096)
文摘Magnetic nanoparticles Fe3O4@SiO2 supported cinchona alkaloids (quinine and quinidine) were successfully synthesized as magnetically recoverable organocatalysts and characterized by FT-IR, XPS, SEM measurements, and elemental analysis. Their catalytic activity and stereoselectivity were preliminarily evaluated in the asymmetric Michael addition reaction of 1,3-dicarbonyls and maleimides. The supported quinine catalyst exhibited good catalytic efficiency and modest to high enantioselectivity. The magnetic recoverabiliW and recyclability of the catalyst were also examined.