A study was made of magnetic field effects (MFEs) on the photoreduction reaction of 2-methyl-1,4-naphthoqui- none (MNQ) in Brij 35 micellar solution containing 4-lauroylamino-TEMPO (2,2,6,6-tetramethylpiperidine-1-oxy...A study was made of magnetic field effects (MFEs) on the photoreduction reaction of 2-methyl-1,4-naphthoqui- none (MNQ) in Brij 35 micellar solution containing 4-lauroylamino-TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) radical (L-R) under magnetic fields below 1.75 T by a nanosecond laser flash photolysis technique. The triplet MNQ mainly underwent the hydrogen abstraction from Brij 35 molecule to give a radical pair. The escaped radical yield increased with magnetic fields from 0 to 0.62 T and then saturated from 0.62 to 1.75 T. MFEs for both sys-tems can be explained by the relaxation mechanism. However, it was supposed that additional radical, L-R affected the MFEs mainly through enhancing the spin-spin interactions of radical pairs. The effect of the micelle size on MFEs of the studying system was also discussed.展开更多
Photolysis of benzyl phenylacetate (ACO_2A), benzyl p-methylphenylacetate (BCO_2A) and 1-naphthyl phenylacetate (ACO_2Np) in homogeneous and micellar solutions results in products typical of radical coupling reactions...Photolysis of benzyl phenylacetate (ACO_2A), benzyl p-methylphenylacetate (BCO_2A) and 1-naphthyl phenylacetate (ACO_2Np) in homogeneous and micellar solutions results in products typical of radical coupling reactions and loss of carbon dioxide. The cage effects upon direct photolysis of these esters in acetonitrile are significantly greater than zero and those in SDS or HDTBr micellar solutions are even greater. In the triplet sensitization reaction of ACO_2 Np in micellar solutions the cage effects are smaller than those obtained upon direct irradiation. However, the application of a 0.05 or 0.2 T external magnetic field in the photolysis in micellar solutions decreases the cage effects dramatically. All these results suggest that the photoextrusions of carbon dioxide from these esters proceed via radical intermediates, and upon direct photolysis the reactive states for the cleavage re- action involve both singlet and triplet excited states.展开更多
Experiments executed by author of the present article (period 1968-1992) showed that the magnetic spinorial particles (magnetic charges) are real structural components of atoms and substance and are immediate sources ...Experiments executed by author of the present article (period 1968-1992) showed that the magnetic spinorial particles (magnetic charges) are real structural components of atoms and substance and are immediate sources of all magnetic fields in Nature. Joint orbital currents of electric and magnetic charges within atomic shells are the natural sources of gravitational field which is a vortical electromagnetic field. The vector nature of the gravitational field, in essence, is analogous to the vortical magnetic field that allows entering in the physical representations of such States of the gravitational field as paragravitation and ferrogravitation. Physical masses (atoms, substance, etc.), which emit ferrogravitational field, are repelled by sources paragravitational field, for example, from Earth. It is a manifestation of the effect of levitation, which was discovered by the author of this article. The forces of the technical levitation, which are formed by technical ferrogravitational fields, can be used in transport, lifting and space technology, energy and many other areas of human activity. The main reason that the real magnetic charges were “buried alive” in modern theoretical physics is the conditions of their confinement in the structures of atoms and substance, which is radically different from the confinement of electrons. Very negative role is played here by erroneous electromagnetic concept Maxwell, in which the magnetic field was officially deprived of their own source: magnetic pole or magnetic charge.展开更多
Experimental and theoretical investigations by author of the present article (period: 1968-2013) have shown that the magnetic spinor particles (magnetic charges) are real structural components of atoms and substance a...Experimental and theoretical investigations by author of the present article (period: 1968-2013) have shown that the magnetic spinor particles (magnetic charges) are real structural components of atoms and substance and are immediate sources of all magnetic fields in Nature. Joint orbital currents of electric and magnetic charges within atomic shells are the natural sources of gravitational field which is a vortex electromagnetic field. The vector character of the elementary gravitational field is similar to the vortex magnetic field that allows entering in the submission of such fundamental states of the gravitational field, as a paragravitation and ferrogravitation. Physical masses (atoms, nucleons, substance, etc.), which emit ferrogravitational field are repelled off from sources paragravitational field, for example, from Earth. It is a manifestation of the effect of levitation, which was discovered by the author of this article. Technical forces levitation, that induced by technical ferrogravitational fields, could be used in transport, lifting and space technology, power engineering and many other areas of human activity. The main reasons that real magnetic charges are “buried alive” in modern theoretical notions are as physics their of confinement in the structures of atoms and substance which are radically different from the confinement of electrons so and fallacious electromagnetic concept Maxwell in which the magnetic field is by mistake deprived of its own source of the magnetic pole or of the magnetic charge.展开更多
Presented in this manuscript are conventional electrical engineering tools to model the earth as a rotating electrical machine. Calculations using known parameters of the earth and measured field data has resulted in ...Presented in this manuscript are conventional electrical engineering tools to model the earth as a rotating electrical machine. Calculations using known parameters of the earth and measured field data has resulted in new understanding of the earth’s electrical system and gyroscopic rotation. The material makeup of the inner earth is better understood based on derived permeability and permittivity constants. The planet has been modeled as simple coils and then as a parallel impedance circuit which has led to fundamental insight into planetary speed control and RLC combination for Schumann Resonance of 7.83 Hz. Torque and Voltage Constants and the inverse Speed Constant are calculated using three methods and all compare favorably with Newton’s Gravitational Constant. A helical resonator is referenced and Schumann’s Resonant ideal frequency is calculated and compared with others idealism. A new theory of gravity based on particle velocity selector at the poles is postulated. Two equations are presented as the needed links between Faraday’s electromagnetism and Newtonian physics. Acceleration and Deceleration of earth is explained as a centripetal governor. A new equation for planetary attraction and the attraction of atomic matter is theorized. Rotation of the earth’s electrical coil is explained in terms of the Richardson effect. Electric power transfer from the sun to the planets is proposed via Flux Transfer Events. The impact of this evolving science of electromagnetic modeling of planets will be magnified as the theory is proven, and found to be useful for future generations of engineers and scientists who seek to discover our world and other planets.展开更多
基金Project supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars State Education Ministry+1 种基金 and the Scientific Research Foundation for the Returned Overseas University of Science and Technology of China (No. 2047308
文摘A study was made of magnetic field effects (MFEs) on the photoreduction reaction of 2-methyl-1,4-naphthoqui- none (MNQ) in Brij 35 micellar solution containing 4-lauroylamino-TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) radical (L-R) under magnetic fields below 1.75 T by a nanosecond laser flash photolysis technique. The triplet MNQ mainly underwent the hydrogen abstraction from Brij 35 molecule to give a radical pair. The escaped radical yield increased with magnetic fields from 0 to 0.62 T and then saturated from 0.62 to 1.75 T. MFEs for both sys-tems can be explained by the relaxation mechanism. However, it was supposed that additional radical, L-R affected the MFEs mainly through enhancing the spin-spin interactions of radical pairs. The effect of the micelle size on MFEs of the studying system was also discussed.
基金This work was supported by the National Science Foundation of China and the National Laboratory for Structure Chemistry of Unstable and Stable Species
文摘Photolysis of benzyl phenylacetate (ACO_2A), benzyl p-methylphenylacetate (BCO_2A) and 1-naphthyl phenylacetate (ACO_2Np) in homogeneous and micellar solutions results in products typical of radical coupling reactions and loss of carbon dioxide. The cage effects upon direct photolysis of these esters in acetonitrile are significantly greater than zero and those in SDS or HDTBr micellar solutions are even greater. In the triplet sensitization reaction of ACO_2 Np in micellar solutions the cage effects are smaller than those obtained upon direct irradiation. However, the application of a 0.05 or 0.2 T external magnetic field in the photolysis in micellar solutions decreases the cage effects dramatically. All these results suggest that the photoextrusions of carbon dioxide from these esters proceed via radical intermediates, and upon direct photolysis the reactive states for the cleavage re- action involve both singlet and triplet excited states.
文摘Experiments executed by author of the present article (period 1968-1992) showed that the magnetic spinorial particles (magnetic charges) are real structural components of atoms and substance and are immediate sources of all magnetic fields in Nature. Joint orbital currents of electric and magnetic charges within atomic shells are the natural sources of gravitational field which is a vortical electromagnetic field. The vector nature of the gravitational field, in essence, is analogous to the vortical magnetic field that allows entering in the physical representations of such States of the gravitational field as paragravitation and ferrogravitation. Physical masses (atoms, substance, etc.), which emit ferrogravitational field, are repelled by sources paragravitational field, for example, from Earth. It is a manifestation of the effect of levitation, which was discovered by the author of this article. The forces of the technical levitation, which are formed by technical ferrogravitational fields, can be used in transport, lifting and space technology, energy and many other areas of human activity. The main reason that the real magnetic charges were “buried alive” in modern theoretical physics is the conditions of their confinement in the structures of atoms and substance, which is radically different from the confinement of electrons. Very negative role is played here by erroneous electromagnetic concept Maxwell, in which the magnetic field was officially deprived of their own source: magnetic pole or magnetic charge.
文摘Experimental and theoretical investigations by author of the present article (period: 1968-2013) have shown that the magnetic spinor particles (magnetic charges) are real structural components of atoms and substance and are immediate sources of all magnetic fields in Nature. Joint orbital currents of electric and magnetic charges within atomic shells are the natural sources of gravitational field which is a vortex electromagnetic field. The vector character of the elementary gravitational field is similar to the vortex magnetic field that allows entering in the submission of such fundamental states of the gravitational field, as a paragravitation and ferrogravitation. Physical masses (atoms, nucleons, substance, etc.), which emit ferrogravitational field are repelled off from sources paragravitational field, for example, from Earth. It is a manifestation of the effect of levitation, which was discovered by the author of this article. Technical forces levitation, that induced by technical ferrogravitational fields, could be used in transport, lifting and space technology, power engineering and many other areas of human activity. The main reasons that real magnetic charges are “buried alive” in modern theoretical notions are as physics their of confinement in the structures of atoms and substance which are radically different from the confinement of electrons so and fallacious electromagnetic concept Maxwell in which the magnetic field is by mistake deprived of its own source of the magnetic pole or of the magnetic charge.
文摘Presented in this manuscript are conventional electrical engineering tools to model the earth as a rotating electrical machine. Calculations using known parameters of the earth and measured field data has resulted in new understanding of the earth’s electrical system and gyroscopic rotation. The material makeup of the inner earth is better understood based on derived permeability and permittivity constants. The planet has been modeled as simple coils and then as a parallel impedance circuit which has led to fundamental insight into planetary speed control and RLC combination for Schumann Resonance of 7.83 Hz. Torque and Voltage Constants and the inverse Speed Constant are calculated using three methods and all compare favorably with Newton’s Gravitational Constant. A helical resonator is referenced and Schumann’s Resonant ideal frequency is calculated and compared with others idealism. A new theory of gravity based on particle velocity selector at the poles is postulated. Two equations are presented as the needed links between Faraday’s electromagnetism and Newtonian physics. Acceleration and Deceleration of earth is explained as a centripetal governor. A new equation for planetary attraction and the attraction of atomic matter is theorized. Rotation of the earth’s electrical coil is explained in terms of the Richardson effect. Electric power transfer from the sun to the planets is proposed via Flux Transfer Events. The impact of this evolving science of electromagnetic modeling of planets will be magnified as the theory is proven, and found to be useful for future generations of engineers and scientists who seek to discover our world and other planets.
