The aim of this study is a present of a simple solvothermal synthesis approach to preparation of Cu-based magnetic metal organic framework(MMOF)and subsequently its application as sorbent for ultrasound assisted magne...The aim of this study is a present of a simple solvothermal synthesis approach to preparation of Cu-based magnetic metal organic framework(MMOF)and subsequently its application as sorbent for ultrasound assisted magnetic solid phase extraction(UAMSPE)of ampicillin(AMP)from cow milk samples prior to high performance liquid chromatography-Ultraviolet(HPLC-UV)determination.Characteristics of prepared MMOF were fully investigated by different techniques which showed the exclusive properties of proposed sorbent in terms of proper functionality,desirable magnetic property and also high specific surface area.Different influential factors on extraction recovery including sorbent dosage,ultrasonic time,washing solvent volume and eluent solvent volume were assessed using central composite design(CCD)based response surface methodology(RSM)as an operative and powerful optimization tool.This is the first report for determination of AMP using MMOF.The proposed method addressed some drawbacks of other methods and sorbents for determination of AMP.The presented method decreases the extraction time(4 min)and also enhances adsorption capacity(250 mg/g).Moreover,the magnetic property of presented sorbent(15 emu/g)accelerates the extraction process which does not need filtration,centrifuge and precipitation procedures.Under the optimized conditions,the proposed method is applicable for linear range of 1.0-5000.0 μg/L with detection limit of 0.29 μg/L,satisfactory recoveries(≥95.0%)and acceptable repeatability(RSD less than 4.0%).The present study indicates highly promising perspectives of MMOF for highly effective analysis of AMP in complicated matrices.展开更多
A magnetic metal organic framework（MMOF） was synthesized and used to separate Sr^2＋ in aqueous solution. The shape and structure of prepared Fe3O4@UiO-66-NH2 were characterized, and the absorbed concentration of st...A magnetic metal organic framework（MMOF） was synthesized and used to separate Sr^2＋ in aqueous solution. The shape and structure of prepared Fe3O4@UiO-66-NH2 were characterized, and the absorbed concentration of strontium was determined through inductively coupled plasma mass spectrometry. The results indicated that Fe3O4 and UiO-66-NH2 combined through chemical bonding. The experimental adsorption results for separation of Sr^2＋ in aqueous solution indicated that the adsorption of Sr^2＋ to Fe3O4@UiO-66-NH2 increased drastically from pH 11 to pH 13. The adsorption isotherm model indicated that the adsorption of Sr^2＋ conformed to the Freundlich isotherm model（R2 = 0.9919）. The MMOF thus inherited the superior qualities of magnetic composites and metal organic frameworks, and can easily be separated under an external magnetic field. This MMOF thus has potential applications as a magnetic adsorbent for low level radionuclide （90）Sr.展开更多
Today,a variety of pesticides are used to fight plant pests in the world.The entry of these resistant pollutants into water resources can have devastating effects on human health and the environment,hence their remova...Today,a variety of pesticides are used to fight plant pests in the world.The entry of these resistant pollutants into water resources can have devastating effects on human health and the environment,hence their removal from the environment is a vital task.In the present work,the magnetic iron-based metalorganic framework(Fe_(3) O_(4)/MIL-101(Fe)) was synthesized by a simple and feasible method and characterized by FT-IR,XRD,BET,FESEM,TEM,TGA,and VSM techniques.The synthesized nanocom posite was successfully applied for the removal of fenitrothion(FEN) pesticide from the aqueous solutions.The isothermal and kinetic models were also investigated.The Langmuir isotherm model(type I) and pseudo-second-order kinetic model were more consistent in the adsorption process.The thermodynamic parameters of fenitrothion sorption were also calculated.The results revealed that the adsorption of fenitrothion onto Fe_(3) O_(4)/MIL-101(Fe) was spontaneous and endothermic under optimized conditions.Moreover,the removal efficiency of FEN was predicted using the developed fuzzy logic model.Four input variables including the initial concentration of FEN(mg·L^(-1)),pH of the solution,adsorbent dosage(mg).and contact time(min) versus removal efficiency as output were fuzzified by the usage of an artificial intelligence-based method.The fuzzy subsets consisted of Triangular and Trapezoidal membership functions(MFs) with six levels and a total of 23 rules in IF-THEN format which was applied on a Mamdani inference system.The obtained coefficient of determination value(R_(pred)^(2)=0.98205) proved the excellent accuracy of the fuzzy logic model as a powerful tool for the prediction of FEN removal efficiency.展开更多
Transition metal phthalocyanines (TMPc) and relevant derivatives can act as pervasive molecules for their electronic, magnetic, and optical applications. Numerous researches based on TMPc are carried out, attempting t...Transition metal phthalocyanines (TMPc) and relevant derivatives can act as pervasive molecules for their electronic, magnetic, and optical applications. Numerous researches based on TMPc are carried out, attempting to synthesize novel two-dimensional (2D) metal-organic frameworks. Recently, some 2D poly-TMPc frameworks including FePc [J. Am. Chem. Soc. 133, 1203 (2011)], CoPc [Chem. Commun. 51, 2836 (2015)], and Ni-NiPc [J. Mater. Chem. A 6, 1188 (2018)] frameworks have been successfully synthesized experimentally. Meanwhile, potential applications in catalysis, gas storage, and spintronics were predicted by theoretical studies. Here, we propose a new kind of 2D poly-TMPc frameworks with kagome lattice (denoted as kag-TMPc) and systematically investigate their electronic and magnetic properties by employing first-principles calculations. We have demonstrated that the 2D kag-MnPc framework displays quite stable ferromagnetic ordering with Curie temperature about 125 K as indicated by Monte Carlo simulations based on Heisenberg model and prefers out-of-plane easy-magnetization axis. The 2D kag-CrPc framework is an ideal candidate for S=2 kagome antiferromagnet with RT3 magnetic order. Particularly, the investigations on optical absorption suggest that when the TMPc molecules are self-assembled into 2D kag- TMPc frameworks, their absorption wave bands are broadened, especially in visible region.展开更多
One new mixed-ligand coordination polymer,namely[Co2（btc）（bpdc）（0.5）（py）3]n（1）,was hydrothermally synthesized using biphenyl-2,4,4＇-tricarboxylic acid（H3btc） as a main building block,along with two auxili...One new mixed-ligand coordination polymer,namely[Co2（btc）（bpdc）（0.5）（py）3]n（1）,was hydrothermally synthesized using biphenyl-2,4,4＇-tricarboxylic acid（H3btc） as a main building block,along with two auxiliary ligands（H2bpdc = 2,2＇-bipyridine-5,5＇-dicarboxylic acid and py =pyridine）.The product 1 was characterized by IR spectroscopy,elemental,thermogravimetric,and single-crystal X-ray diffraction analyses.Single-crystal X-ray diffraction studies show that compound 1 possesses an intricate 3D metal-organic framework based on tetracobalt（Ⅱ） units.Magnetic susceptibility measurement indicates that compound 1 shows an antiferromagnetic coupling between the Co（Ⅱ） ions.展开更多
The cyanide groups of letrozole(1-[bis(4-cyanophenyl)methyl]-1,2,4-triazole) were hydrolyzed into the carboxylic groups under alkaline conditions. Then the hydrolysis product(1-[bis(4-carboxylphenyl)methyl]-1,2,4-tria...The cyanide groups of letrozole(1-[bis(4-cyanophenyl)methyl]-1,2,4-triazole) were hydrolyzed into the carboxylic groups under alkaline conditions. Then the hydrolysis product(1-[bis(4-carboxylphenyl)methyl]-1,2,4-triazole, H2ltzda) reacted with Co(NO3)2·6H2O in the presence of different bipyridl-typed ligands under hydrothermal conditions. As a result, two new Co(Ⅱ) MOFs were obtained, formulated as [Co2(ltzda)2(bpp)2]n(1) and {[Co2(ltzda)2(bpy)]·4H2O}n(2)(bpp = 1,3-di(4-pyridyl)propane, bpy = 4,4’-bipyridine). Two MOFs have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic measure. 1 displays a 2D metal-organic framework containing wave layers and 2 shows a pillared-layer structure existing in a 2-fold interpenetrated mode.展开更多
A copper metal-organic framework（MOF） compound based on 2,5-thiophenedicarboxylic acid（H2 TDC） ligand, namely Cu（TDC）（H2 O）？DMA（1, DMA = N,N？-dimethylacetamide）, has been synthesized in gram-scale via a on...A copper metal-organic framework（MOF） compound based on 2,5-thiophenedicarboxylic acid（H2 TDC） ligand, namely Cu（TDC）（H2 O）？DMA（1, DMA = N,N？-dimethylacetamide）, has been synthesized in gram-scale via a one-pot solvothermal route in a high yield of 81.3%. Single-crystal X-ray analysis reveals that the structure of 1 features a three-dimensional（3D） open framework constructed by TDC interconnecting 1D chains of [-Cu（COO）（H2 O）Cu-]n. Thermal property was investigated by TG-MS. The magnetic measurements indicate the existence of weak antiferromagnetic interactions between the Cu2＋ centers in 1.展开更多
Rational design of magnetic materials with desired magnetic properties has attracted wide interest in recent decades. Herein, we present a new 2D cobalt（II） metal-organic framework, namely [Co（MQ）2（V2O6）2]n·...Rational design of magnetic materials with desired magnetic properties has attracted wide interest in recent decades. Herein, we present a new 2D cobalt（II） metal-organic framework, namely [Co（MQ）2（V2O6）2]n·4nH2O 1, which was hydrothermally synthesized by the reaction of Co（NO3）2·4H2O, N-methyl-4,4′-bipyridinium（MQ＋） chlorine salt and NH4VO3. Single-crystal X-ray diffraction analysis reveals that 1 crystallizes in C2/c space group with a = 16.290（5）, b = 7.815（2）, c = 25.297（7） A, β = 108.459（5）°, V = 3054.8（15） A3, Z = 4, Dc = 1.890 g/cm3, μ = 1.791 mm-1, F（000） = 1748, the final R = 0.0444 and wR = 0.1208 with I 〉 2σ（I）. The individual Co（II） is connected and well separated by diamagnetic [V2O6]2-linkers. Magnetic measurements confirm that 1 exhibits ferrimagnetic interactions.展开更多
Magnetic carbon-based composites are the most attractive candidates for electromagnetic(EM)absorption because they can terminate the propagation of surplus EM waves in space by interacting with both electric and magne...Magnetic carbon-based composites are the most attractive candidates for electromagnetic(EM)absorption because they can terminate the propagation of surplus EM waves in space by interacting with both electric and magnetic branches.Metal-organic frameworks(MOFs)have demonstrated their great potential as sacrificing precursors of magnetic metals/carbon composites,because they provide a good platform to achieve high dispersion of magnetic nanoparticles in carbon matrix.Nevertheless,the chemical composition and microstructure of these composites are always highly dependent on their precursors and cannot promise an optimal EM state favorable for EM absorption,which more or less discount the superiority of MOFs-derived strategy.It is hence of great importance to develop some accompanied methods that can regulate EM properties of MOFs-derived magnetic carbon-based composites e ectively.This review comprehensively introduces recent advancements on EM absorption enhancement in MOFs-derived magnetic carbon-based composites and some available strategies therein.In addition,some challenges and prospects are also proposed to indicate the pending issues on performance breakthrough and mechanism exploration in the related field.展开更多
Multifunctional lanthanide metal-organic frameworks（MOFs）, M（H4TCPS）（H20）l.5[M=Tb（JUC-95a）, Er（JUC-95b）, Dy（JUC-95c）, Tm（JUC-95d）, Y（JUC-95e） and Pr（JUC-95f）; H4TCPS=tetrakis（4-carboxyphenyl）silane...Multifunctional lanthanide metal-organic frameworks（MOFs）, M（H4TCPS）（H20）l.5[M=Tb（JUC-95a）, Er（JUC-95b）, Dy（JUC-95c）, Tm（JUC-95d）, Y（JUC-95e） and Pr（JUC-95f）; H4TCPS=tetrakis（4-carboxyphenyl）silane] were synthesized via the reaction of the lanthanide metal ions（Ln3） with a rigid silicon-centered tetrahedral carbo- xylate ligand H4TCPS via a hydrothermal synthesis method. X-Ray diffraction（XRD） analyses reveal that they are extremely similar in structure and crystallized in a monoclinic system with space group C2/c. Two eight-coordinated metal centers and four tetrahedral H4TCPS groups constructed a paddle-wheel building block. The paddle-wheel buil- ding blocks assembled with each other via one oxygen bridge from a water molecule to lead to a 1D infinite inorganic rod-shaped chain, --Y--O--C--O--Y--, along the [001] direction. These 1D inorganic rod-shaped chains linked with the phenyl groups of the tetrahedral HaTCPS ligand to form a 3D framework. In addition, the luminescent and magnetic properties of these compounds show that they could be potential antiferromagnetic and fluorescent mate- rials.展开更多
基金This work was financially supported by Graduate School and Research Council of Yasouj University.
文摘The aim of this study is a present of a simple solvothermal synthesis approach to preparation of Cu-based magnetic metal organic framework(MMOF)and subsequently its application as sorbent for ultrasound assisted magnetic solid phase extraction(UAMSPE)of ampicillin(AMP)from cow milk samples prior to high performance liquid chromatography-Ultraviolet(HPLC-UV)determination.Characteristics of prepared MMOF were fully investigated by different techniques which showed the exclusive properties of proposed sorbent in terms of proper functionality,desirable magnetic property and also high specific surface area.Different influential factors on extraction recovery including sorbent dosage,ultrasonic time,washing solvent volume and eluent solvent volume were assessed using central composite design(CCD)based response surface methodology(RSM)as an operative and powerful optimization tool.This is the first report for determination of AMP using MMOF.The proposed method addressed some drawbacks of other methods and sorbents for determination of AMP.The presented method decreases the extraction time(4 min)and also enhances adsorption capacity(250 mg/g).Moreover,the magnetic property of presented sorbent(15 emu/g)accelerates the extraction process which does not need filtration,centrifuge and precipitation procedures.Under the optimized conditions,the proposed method is applicable for linear range of 1.0-5000.0 μg/L with detection limit of 0.29 μg/L,satisfactory recoveries(≥95.0%)and acceptable repeatability(RSD less than 4.0%).The present study indicates highly promising perspectives of MMOF for highly effective analysis of AMP in complicated matrices.
基金financially supported by the National Natural Science Foundation of China[Grant No.20477058]by the Chinese Ministry of Science and Technology[Grant No.2014YF211000]
文摘A magnetic metal organic framework（MMOF） was synthesized and used to separate Sr^2＋ in aqueous solution. The shape and structure of prepared Fe3O4@UiO-66-NH2 were characterized, and the absorbed concentration of strontium was determined through inductively coupled plasma mass spectrometry. The results indicated that Fe3O4 and UiO-66-NH2 combined through chemical bonding. The experimental adsorption results for separation of Sr^2＋ in aqueous solution indicated that the adsorption of Sr^2＋ to Fe3O4@UiO-66-NH2 increased drastically from pH 11 to pH 13. The adsorption isotherm model indicated that the adsorption of Sr^2＋ conformed to the Freundlich isotherm model（R2 = 0.9919）. The MMOF thus inherited the superior qualities of magnetic composites and metal organic frameworks, and can easily be separated under an external magnetic field. This MMOF thus has potential applications as a magnetic adsorbent for low level radionuclide （90）Sr.
文摘Today,a variety of pesticides are used to fight plant pests in the world.The entry of these resistant pollutants into water resources can have devastating effects on human health and the environment,hence their removal from the environment is a vital task.In the present work,the magnetic iron-based metalorganic framework(Fe_(3) O_(4)/MIL-101(Fe)) was synthesized by a simple and feasible method and characterized by FT-IR,XRD,BET,FESEM,TEM,TGA,and VSM techniques.The synthesized nanocom posite was successfully applied for the removal of fenitrothion(FEN) pesticide from the aqueous solutions.The isothermal and kinetic models were also investigated.The Langmuir isotherm model(type I) and pseudo-second-order kinetic model were more consistent in the adsorption process.The thermodynamic parameters of fenitrothion sorption were also calculated.The results revealed that the adsorption of fenitrothion onto Fe_(3) O_(4)/MIL-101(Fe) was spontaneous and endothermic under optimized conditions.Moreover,the removal efficiency of FEN was predicted using the developed fuzzy logic model.Four input variables including the initial concentration of FEN(mg·L^(-1)),pH of the solution,adsorbent dosage(mg).and contact time(min) versus removal efficiency as output were fuzzified by the usage of an artificial intelligence-based method.The fuzzy subsets consisted of Triangular and Trapezoidal membership functions(MFs) with six levels and a total of 23 rules in IF-THEN format which was applied on a Mamdani inference system.The obtained coefficient of determination value(R_(pred)^(2)=0.98205) proved the excellent accuracy of the fuzzy logic model as a powerful tool for the prediction of FEN removal efficiency.
基金the National Key Research Development Program of China (No.2016YFA0200604 and No.2017YFA0204904)the National Natural Science Foundation of China (No.21473174)+1 种基金the Fundamental Research Funds for the Central Universities (No.WK2340000074 and No.WK2060190084)The computational resources of Super-computing Center of University of Science and Technology of China, Supercomputing Center of Chinese Academy of Sciences, Tianjing, and Shanghai Supercomputer Centers are also acknowledged.
文摘Transition metal phthalocyanines (TMPc) and relevant derivatives can act as pervasive molecules for their electronic, magnetic, and optical applications. Numerous researches based on TMPc are carried out, attempting to synthesize novel two-dimensional (2D) metal-organic frameworks. Recently, some 2D poly-TMPc frameworks including FePc [J. Am. Chem. Soc. 133, 1203 (2011)], CoPc [Chem. Commun. 51, 2836 (2015)], and Ni-NiPc [J. Mater. Chem. A 6, 1188 (2018)] frameworks have been successfully synthesized experimentally. Meanwhile, potential applications in catalysis, gas storage, and spintronics were predicted by theoretical studies. Here, we propose a new kind of 2D poly-TMPc frameworks with kagome lattice (denoted as kag-TMPc) and systematically investigate their electronic and magnetic properties by employing first-principles calculations. We have demonstrated that the 2D kag-MnPc framework displays quite stable ferromagnetic ordering with Curie temperature about 125 K as indicated by Monte Carlo simulations based on Heisenberg model and prefers out-of-plane easy-magnetization axis. The 2D kag-CrPc framework is an ideal candidate for S=2 kagome antiferromagnet with RT3 magnetic order. Particularly, the investigations on optical absorption suggest that when the TMPc molecules are self-assembled into 2D kag- TMPc frameworks, their absorption wave bands are broadened, especially in visible region.
基金supported by the Natural Science Foundation of Shanxi Province(No.2013011011-6)the Subject Team of Taiyuan University of Science and Technology
文摘One new mixed-ligand coordination polymer,namely[Co2（btc）（bpdc）（0.5）（py）3]n（1）,was hydrothermally synthesized using biphenyl-2,4,4＇-tricarboxylic acid（H3btc） as a main building block,along with two auxiliary ligands（H2bpdc = 2,2＇-bipyridine-5,5＇-dicarboxylic acid and py =pyridine）.The product 1 was characterized by IR spectroscopy,elemental,thermogravimetric,and single-crystal X-ray diffraction analyses.Single-crystal X-ray diffraction studies show that compound 1 possesses an intricate 3D metal-organic framework based on tetracobalt（Ⅱ） units.Magnetic susceptibility measurement indicates that compound 1 shows an antiferromagnetic coupling between the Co（Ⅱ） ions.
基金supported by the Project of Science&Technology in Henan Province(No.172102310441)the National Natural Science Foundation of China(No.21571093)
文摘The cyanide groups of letrozole(1-[bis(4-cyanophenyl)methyl]-1,2,4-triazole) were hydrolyzed into the carboxylic groups under alkaline conditions. Then the hydrolysis product(1-[bis(4-carboxylphenyl)methyl]-1,2,4-triazole, H2ltzda) reacted with Co(NO3)2·6H2O in the presence of different bipyridl-typed ligands under hydrothermal conditions. As a result, two new Co(Ⅱ) MOFs were obtained, formulated as [Co2(ltzda)2(bpp)2]n(1) and {[Co2(ltzda)2(bpy)]·4H2O}n(2)(bpp = 1,3-di(4-pyridyl)propane, bpy = 4,4’-bipyridine). Two MOFs have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic measure. 1 displays a 2D metal-organic framework containing wave layers and 2 shows a pillared-layer structure existing in a 2-fold interpenetrated mode.
基金supported by the NNSFC(No.21771183)Chunmiao project of Haixi Institute of Chinese Academy of Sciences(CMZX-2014-001)
文摘A copper metal-organic framework（MOF） compound based on 2,5-thiophenedicarboxylic acid（H2 TDC） ligand, namely Cu（TDC）（H2 O）？DMA（1, DMA = N,N？-dimethylacetamide）, has been synthesized in gram-scale via a one-pot solvothermal route in a high yield of 81.3%. Single-crystal X-ray analysis reveals that the structure of 1 features a three-dimensional（3D） open framework constructed by TDC interconnecting 1D chains of [-Cu（COO）（H2 O）Cu-]n. Thermal property was investigated by TG-MS. The magnetic measurements indicate the existence of weak antiferromagnetic interactions between the Cu2＋ centers in 1.
基金Supported by the National Key Project on Basic Research(No.2013CB933203)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000)+2 种基金the Natural Science Foundation of China(No.21373224,21577143 and 51502289)the Natural Science Foundation of Fujian Province(No.2014H0054 and 2015J05044)the One Hundred Talents Program of the Chinese Academy of Sciences
文摘Rational design of magnetic materials with desired magnetic properties has attracted wide interest in recent decades. Herein, we present a new 2D cobalt（II） metal-organic framework, namely [Co（MQ）2（V2O6）2]n·4nH2O 1, which was hydrothermally synthesized by the reaction of Co（NO3）2·4H2O, N-methyl-4,4′-bipyridinium（MQ＋） chlorine salt and NH4VO3. Single-crystal X-ray diffraction analysis reveals that 1 crystallizes in C2/c space group with a = 16.290（5）, b = 7.815（2）, c = 25.297（7） A, β = 108.459（5）°, V = 3054.8（15） A3, Z = 4, Dc = 1.890 g/cm3, μ = 1.791 mm-1, F（000） = 1748, the final R = 0.0444 and wR = 0.1208 with I 〉 2σ（I）. The individual Co（II） is connected and well separated by diamagnetic [V2O6]2-linkers. Magnetic measurements confirm that 1 exhibits ferrimagnetic interactions.
基金supported by the financial support from Natural Science Foundation of China(21776053 and 21676065)。
文摘Magnetic carbon-based composites are the most attractive candidates for electromagnetic(EM)absorption because they can terminate the propagation of surplus EM waves in space by interacting with both electric and magnetic branches.Metal-organic frameworks(MOFs)have demonstrated their great potential as sacrificing precursors of magnetic metals/carbon composites,because they provide a good platform to achieve high dispersion of magnetic nanoparticles in carbon matrix.Nevertheless,the chemical composition and microstructure of these composites are always highly dependent on their precursors and cannot promise an optimal EM state favorable for EM absorption,which more or less discount the superiority of MOFs-derived strategy.It is hence of great importance to develop some accompanied methods that can regulate EM properties of MOFs-derived magnetic carbon-based composites e ectively.This review comprehensively introduces recent advancements on EM absorption enhancement in MOFs-derived magnetic carbon-based composites and some available strategies therein.In addition,some challenges and prospects are also proposed to indicate the pending issues on performance breakthrough and mechanism exploration in the related field.
基金The authors acknowledge the financial support provided by the US Department of Energy through the Massey Chair Project at the University of Turabo and recognize the support of the National Science Foundation under the Project CHE-0959334. We as well recognize the help provided by Dr. Samuel Hemandez allowing us to use the Raman scattering facility.
基金Supported by the National Basic Research Program of China（Nos.2011 CB808703, 2012CB821700） and the National Natural Science Foundation of China（Nos.91022030, 21101072）.
文摘Multifunctional lanthanide metal-organic frameworks（MOFs）, M（H4TCPS）（H20）l.5[M=Tb（JUC-95a）, Er（JUC-95b）, Dy（JUC-95c）, Tm（JUC-95d）, Y（JUC-95e） and Pr（JUC-95f）; H4TCPS=tetrakis（4-carboxyphenyl）silane] were synthesized via the reaction of the lanthanide metal ions（Ln3） with a rigid silicon-centered tetrahedral carbo- xylate ligand H4TCPS via a hydrothermal synthesis method. X-Ray diffraction（XRD） analyses reveal that they are extremely similar in structure and crystallized in a monoclinic system with space group C2/c. Two eight-coordinated metal centers and four tetrahedral H4TCPS groups constructed a paddle-wheel building block. The paddle-wheel buil- ding blocks assembled with each other via one oxygen bridge from a water molecule to lead to a 1D infinite inorganic rod-shaped chain, --Y--O--C--O--Y--, along the [001] direction. These 1D inorganic rod-shaped chains linked with the phenyl groups of the tetrahedral HaTCPS ligand to form a 3D framework. In addition, the luminescent and magnetic properties of these compounds show that they could be potential antiferromagnetic and fluorescent mate- rials.
