This study presents an analytical solution of thermal and mechanical displacements, strains, and stresses for a thick-walled rotating spherical pressure vessel made of functionally graded materials (FGMs). The pressur...This study presents an analytical solution of thermal and mechanical displacements, strains, and stresses for a thick-walled rotating spherical pressure vessel made of functionally graded materials (FGMs). The pressure vessel is subject to axisymmetric mechanical and thermal loadings within a uniform magnetic field. The material properties of the FGM are considered as the power-law distribution along the thickness. Navier’s equation, which is a second-order ordinary differential equation, is derived from the mechanical equilibrium equation with the consideration of the thermal stresses and the Lorentz force resulting from the magnetic field. The distributions of the displacement, strains, and stresses are determined by the exact solution to Navier’s equation. Numerical results clarify the influence of the thermal loading, magnetic field, non-homogeneity constant, internal pressure, and angular velocity on the magneto-thermo-elastic response of the functionally graded spherical vessel. It is observed that these parameters have remarkable effects on the distributions of radial displacement, radial and circumferential strains, and radial and circumferential stresses.展开更多
In this study,the effects of high magnetic field gradients on the segregation of alloying elements,crystallized phases,and particles in alloys during solidification process and corresponding microstructures were discu...In this study,the effects of high magnetic field gradients on the segregation of alloying elements,crystallized phases,and particles in alloys during solidification process and corresponding microstructures were discussed.It was confirmed that applying an external high magnetic field gradient during solidification process is an effective processing route for controlling segregation in alloys and then fabricating functional materials which have special mierostruetures and properties.Such controlling and fabrication were realized by controlling the migration of the alloying elements, crystallized phases,and particles in the liquid matrix on the basis of the Lorentz and magnetic forces.展开更多
Recently we have studied the rare earth ion-selective electrodes with active materials of the func-tional polymers and found that the process chosen for the functional polymers had an effect on the propertiesof gadoli...Recently we have studied the rare earth ion-selective electrodes with active materials of the func-tional polymers and found that the process chosen for the functional polymers had an effect on the propertiesof gadolinium ion selective electrode besides the effects of their structures.1.Effect of preparation process of the grafted polymers on the properties ofgadolinium ion selective electrodesThe electrode membranes which consist of functional polymers as active materials were prepared by re-action of gadolinium chloride with the radiation grafted clmer of acrlic acid and polystyrene of which展开更多
In this paper,the functional polymeric active materials were prepared by the grafting copolymerization and their structure and properties were studied.The results show that the structure and properties of these ac- ti...In this paper,the functional polymeric active materials were prepared by the grafting copolymerization and their structure and properties were studied.The results show that the structure and properties of these ac- tive materials have the relative large effects on the properties of gadolinium ion selective electrodes.展开更多
Magnetically responsive hierarchical magnetite/silica/poly（ethyleneglycol dimethacrylate-co-4-vinylpyridine） （Fe3O4/SiO2/P（EGDMA-co-VPy）） tri-layer microspheres were used as stabilizers for gold metallic nanoeol...Magnetically responsive hierarchical magnetite/silica/poly（ethyleneglycol dimethacrylate-co-4-vinylpyridine） （Fe3O4/SiO2/P（EGDMA-co-VPy）） tri-layer microspheres were used as stabilizers for gold metallic nanoeolloids as a facilely recoverable catalyst with the reduction of 4-nitrophenol to 4-aminophenol as a model reaction. The magnetic microsphere stabilized gold metallic nanocolloids were prepared by in situ reduction of gold chloride trihydrate with borohydride as reductant via the stabilization effect of the pyridyl groups to gold nanoparticles on the surface of the outer shell-layer of the inorganic/polymer tri-layer microspheres.展开更多
In this paper, the mechanical responses of a thick-walled functionally graded hollow cylinder subject to a uniform magnetic field and inner-pressurized loads are studied. Rather than directly assume the material const...In this paper, the mechanical responses of a thick-walled functionally graded hollow cylinder subject to a uniform magnetic field and inner-pressurized loads are studied. Rather than directly assume the material constants as some specific function forms displayed in pre-studies, we firstly give the volume fractions of different constituents of the functionally graded material(FGM) cylinder and then determine the expressions of the material constants. With the use of the Voigt method, the corresponding analytical solutions of displacements in the radial direction, the strain and stress components, and the perturbation magnetic field vector are derived. In the numerical part, the effects of the volume fraction on the displacement, strain and stress components, and the magnetic perturbation field vector are investigated. Moreover, by some appropriate choices of the material constants, we find that the obtained results in this paper can reduce to some special cases given in the previous studies.展开更多
In this paper,an exact closed-form solution for a curved sandwich panel with two piezoelectric layers as actuator and sensor that are inserted in the top and bottom facings is presented.The core is made from functiona...In this paper,an exact closed-form solution for a curved sandwich panel with two piezoelectric layers as actuator and sensor that are inserted in the top and bottom facings is presented.The core is made from functionally graded(FG)material that has heterogeneous power-law distribution through the radial coordinate.It is assumed that the core is subjected to a magnetic field whereas the core is covered by two insulated composite layers.To determine the exact solution,first characteristic equations are derived for different material types in a polar coordinate system,namely,magneto-elastic,elastic,and electro-elastic for the FG,orthotropic,and piezoelectric materials,respectively.The displacement-based method is used instead of the stress-based method to derive a set of closed-form real-valued solutions for both real and complex roots.Based on the elasticity theory,exact solutions for the governing equations are determined layer-by-layer that are considerably more accurate than typical simplified theories.The accuracy of the presented method is compared and validated with the available literature and the finite element simulation.The effects of geometrical and material parameters such as FG index,angular span along with external conditions such as magnetic field,mechanical pressure,and electrical difference are investigated in detail through numerical examples.展开更多
This paper presents an analytical solution for the interaction of electric potentials, electric displacements, elastic deformations, and thermoelasticity, and describes electromagnetoelastic responses and perturbation...This paper presents an analytical solution for the interaction of electric potentials, electric displacements, elastic deformations, and thermoelasticity, and describes electromagnetoelastic responses and perturbation of the magnetic field vector in hollow structures （cylinder or sphere）, subjected to mechanical load and electric potential. The material properties, thermal expansion coefficient and magnetic permeability of the structure are assumed to be graded in the radial direction by a power law distribution. In the present model we consider the solution for the case of a hollow structure made of viscoelastic isotropic material, reinforced by elastic isotropic fibers, this material is considered as structurally anisotropic material. The exact solutions for stresses and perturbations of the magnetic field vector in FGM hollow structures are determined using the infinitesimal theory of magnetothermoelasticity, and then the hollow structure model with viscoelastic material is solved using the correspondence principle and Illyushin＇s approximation method. Finally, numerical results are carried out and discussed.展开更多
The inclusion complex formation of α-CD, β-CD, and γ-CD with various water-soluble polymers has beeninvestigated, and the relationship between the chain cross-sectional areas of the polymers and the diameters of th...The inclusion complex formation of α-CD, β-CD, and γ-CD with various water-soluble polymers has beeninvestigated, and the relationship between the chain cross-sectional areas of the polymers and the diameters of the cavities ofcyclodextrins (molecular recognition) was found. Polyrotaxanes and tubular polymers were prepared on the basis ofmolecular recognition. Several kinds of polymers having tetraphenylporphyrin (TPP) and paramagnetic metallotetraphenyl-porphyrin (AgTPP, CuTPP, VOTPP or ZnTPP) have been prepared by radical polymerization of the correspondingmonomers. Visible spectra of these polymers show hypochromism in the Sorer bands of TPP moieties as compared withthose of monomers. Polymer effects were observed in the magnetic behavior and oxygen adsorption of paramagneticmetallotetraphenylporphyrin moieties. Moreover, polymer effects on photophysical and photochemical behavior were foundin the amphiphilic polymers covalently tethered with small amounts of zinc(Ⅱ)-tetraphenylporphyrin (ZnTPP).展开更多
A novel bi-functional photorefractive acrylate polymer with pendant carbazolyl groups and azo derivatives as side chains was synthesized. Photorefractive experiments showed a high two-beam coupling gain coefficient of...A novel bi-functional photorefractive acrylate polymer with pendant carbazolyl groups and azo derivatives as side chains was synthesized. Photorefractive experiments showed a high two-beam coupling gain coefficient of 93 cm(-1), diffraction efficiency of 12% and electro-optic coefficient of 26 pm/V were obtained.展开更多
文摘This study presents an analytical solution of thermal and mechanical displacements, strains, and stresses for a thick-walled rotating spherical pressure vessel made of functionally graded materials (FGMs). The pressure vessel is subject to axisymmetric mechanical and thermal loadings within a uniform magnetic field. The material properties of the FGM are considered as the power-law distribution along the thickness. Navier’s equation, which is a second-order ordinary differential equation, is derived from the mechanical equilibrium equation with the consideration of the thermal stresses and the Lorentz force resulting from the magnetic field. The distributions of the displacement, strains, and stresses are determined by the exact solution to Navier’s equation. Numerical results clarify the influence of the thermal loading, magnetic field, non-homogeneity constant, internal pressure, and angular velocity on the magneto-thermo-elastic response of the functionally graded spherical vessel. It is observed that these parameters have remarkable effects on the distributions of radial displacement, radial and circumferential strains, and radial and circumferential stresses.
基金Item Sponsored by the National Natural Science Foundation of China (Grant Nos.51006020 and 51174056) the Fundamental Research Funds for the Central Universities (Grant Nos.N090109001+3 种基金N100409008and N100609001) the National Basic Research Program of China (Grant Nos.2011CB612206 and 2011CB610405) the Wuhan National High Magnetic Field Center (Grant No.WHMFCK2011006)
文摘In this study,the effects of high magnetic field gradients on the segregation of alloying elements,crystallized phases,and particles in alloys during solidification process and corresponding microstructures were discussed.It was confirmed that applying an external high magnetic field gradient during solidification process is an effective processing route for controlling segregation in alloys and then fabricating functional materials which have special mierostruetures and properties.Such controlling and fabrication were realized by controlling the migration of the alloying elements, crystallized phases,and particles in the liquid matrix on the basis of the Lorentz and magnetic forces.
文摘Recently we have studied the rare earth ion-selective electrodes with active materials of the func-tional polymers and found that the process chosen for the functional polymers had an effect on the propertiesof gadolinium ion selective electrode besides the effects of their structures.1.Effect of preparation process of the grafted polymers on the properties ofgadolinium ion selective electrodesThe electrode membranes which consist of functional polymers as active materials were prepared by re-action of gadolinium chloride with the radiation grafted clmer of acrlic acid and polystyrene of which
文摘In this paper,the functional polymeric active materials were prepared by the grafting copolymerization and their structure and properties were studied.The results show that the structure and properties of these ac- tive materials have the relative large effects on the properties of gadolinium ion selective electrodes.
基金supported by the National Natural Science Foundation of China(No.20874049)
文摘Magnetically responsive hierarchical magnetite/silica/poly（ethyleneglycol dimethacrylate-co-4-vinylpyridine） （Fe3O4/SiO2/P（EGDMA-co-VPy）） tri-layer microspheres were used as stabilizers for gold metallic nanoeolloids as a facilely recoverable catalyst with the reduction of 4-nitrophenol to 4-aminophenol as a model reaction. The magnetic microsphere stabilized gold metallic nanocolloids were prepared by in situ reduction of gold chloride trihydrate with borohydride as reductant via the stabilization effect of the pyridyl groups to gold nanoparticles on the surface of the outer shell-layer of the inorganic/polymer tri-layer microspheres.
基金supported by the National Natural Science Foundation of China(No.11772041)
文摘In this paper, the mechanical responses of a thick-walled functionally graded hollow cylinder subject to a uniform magnetic field and inner-pressurized loads are studied. Rather than directly assume the material constants as some specific function forms displayed in pre-studies, we firstly give the volume fractions of different constituents of the functionally graded material(FGM) cylinder and then determine the expressions of the material constants. With the use of the Voigt method, the corresponding analytical solutions of displacements in the radial direction, the strain and stress components, and the perturbation magnetic field vector are derived. In the numerical part, the effects of the volume fraction on the displacement, strain and stress components, and the magnetic perturbation field vector are investigated. Moreover, by some appropriate choices of the material constants, we find that the obtained results in this paper can reduce to some special cases given in the previous studies.
文摘In this paper,an exact closed-form solution for a curved sandwich panel with two piezoelectric layers as actuator and sensor that are inserted in the top and bottom facings is presented.The core is made from functionally graded(FG)material that has heterogeneous power-law distribution through the radial coordinate.It is assumed that the core is subjected to a magnetic field whereas the core is covered by two insulated composite layers.To determine the exact solution,first characteristic equations are derived for different material types in a polar coordinate system,namely,magneto-elastic,elastic,and electro-elastic for the FG,orthotropic,and piezoelectric materials,respectively.The displacement-based method is used instead of the stress-based method to derive a set of closed-form real-valued solutions for both real and complex roots.Based on the elasticity theory,exact solutions for the governing equations are determined layer-by-layer that are considerably more accurate than typical simplified theories.The accuracy of the presented method is compared and validated with the available literature and the finite element simulation.The effects of geometrical and material parameters such as FG index,angular span along with external conditions such as magnetic field,mechanical pressure,and electrical difference are investigated in detail through numerical examples.
文摘This paper presents an analytical solution for the interaction of electric potentials, electric displacements, elastic deformations, and thermoelasticity, and describes electromagnetoelastic responses and perturbation of the magnetic field vector in hollow structures （cylinder or sphere）, subjected to mechanical load and electric potential. The material properties, thermal expansion coefficient and magnetic permeability of the structure are assumed to be graded in the radial direction by a power law distribution. In the present model we consider the solution for the case of a hollow structure made of viscoelastic isotropic material, reinforced by elastic isotropic fibers, this material is considered as structurally anisotropic material. The exact solutions for stresses and perturbations of the magnetic field vector in FGM hollow structures are determined using the infinitesimal theory of magnetothermoelasticity, and then the hollow structure model with viscoelastic material is solved using the correspondence principle and Illyushin＇s approximation method. Finally, numerical results are carried out and discussed.
文摘The inclusion complex formation of α-CD, β-CD, and γ-CD with various water-soluble polymers has beeninvestigated, and the relationship between the chain cross-sectional areas of the polymers and the diameters of the cavities ofcyclodextrins (molecular recognition) was found. Polyrotaxanes and tubular polymers were prepared on the basis ofmolecular recognition. Several kinds of polymers having tetraphenylporphyrin (TPP) and paramagnetic metallotetraphenyl-porphyrin (AgTPP, CuTPP, VOTPP or ZnTPP) have been prepared by radical polymerization of the correspondingmonomers. Visible spectra of these polymers show hypochromism in the Sorer bands of TPP moieties as compared withthose of monomers. Polymer effects were observed in the magnetic behavior and oxygen adsorption of paramagneticmetallotetraphenylporphyrin moieties. Moreover, polymer effects on photophysical and photochemical behavior were foundin the amphiphilic polymers covalently tethered with small amounts of zinc(Ⅱ)-tetraphenylporphyrin (ZnTPP).
文摘A novel bi-functional photorefractive acrylate polymer with pendant carbazolyl groups and azo derivatives as side chains was synthesized. Photorefractive experiments showed a high two-beam coupling gain coefficient of 93 cm(-1), diffraction efficiency of 12% and electro-optic coefficient of 26 pm/V were obtained.
