With Welsh Onion seeds employed as materials, effects of magnetized water on seed Germination were studied. The results showed the treatment of magnetized water soaking for 4 h promoted water absorption rate and amyla...With Welsh Onion seeds employed as materials, effects of magnetized water on seed Germination were studied. The results showed the treatment of magnetized water soaking for 4 h promoted water absorption rate and amylase ac- tivities of seeds significantly, which accelerated the transformation process of en- dosperm starch to soluble sugar, resulting in emergence of 36 hours in advance under low temperature condition. Germination rate and germination potential of magnetized water soaking were higher than the contrast by 6.7% and 10.0%, which helped cultivate vigorous seedling.展开更多
Herein,we report bifunctional molybdenum-doped nickel sulfide on nickel foam(Mo-NiS_(x)/NF)for magnetic field-enhanced overall water splitting under alkaline conditions.Proper doping of Mo can lead to optimization of ...Herein,we report bifunctional molybdenum-doped nickel sulfide on nickel foam(Mo-NiS_(x)/NF)for magnetic field-enhanced overall water splitting under alkaline conditions.Proper doping of Mo can lead to optimization of the electronic structure of NiS_(x),which accelerates the dissociation of H2O and the adsorption of OH−in the hydrogen evolution reaction(HER)and the oxygen evolution reaction(OER)processes,respectively.In addition,the magnetically active Mo-NiS_(x)/NF can further enhance the HER and OER activity under an applied magnetic field due to the magnetoresistance effect and the ferromagnetic(FM)exchange-field penetration effect.As a result,Mo-NiS_(x)/NF requires low overpotentials of 307 mV at 50mA cm^(−2)(for OER)and 136 mV at 10mA cm^(−2)(for HER)under a magnetic field of 10000 G.Furthermore,the electrolytic cell constructed by the bifunctional Mo-NiS_(x)/NFs as both the cathode and the anode shows a low cell voltage of 1.594 V at 10 mA cm^(−2)with optimal stability over 60 h under the magnetic field.Simultaneous enhancement of the HER and OER processes by an external magnetic field through rational design of electrocatalysts might be promising for overall water splitting applications.展开更多
This paper presents an experimental study to investigate the effect of using the magnetic water conditioner on the properties of water. The water flows through a closed loop, while the pH, TDS, and hardness represent ...This paper presents an experimental study to investigate the effect of using the magnetic water conditioner on the properties of water. The water flows through a closed loop, while the pH, TDS, and hardness represent its properties. For magnetic water conditioner with flux density of 170 mT, results showed that pH increased by 15.65% for 820 minutes of non-stop circulation. The increase in pH is divided to 93.5% for the first 360 minutes, and 6.5% for the last 460 minutes. TDS and Hardness of water are not affected by the magnetic water conditioner. Water remembers and keeps the impact of passing through the magnetic field for several hours, and pH decreased by 0.642 in24 hours. While the results lead to introduce and create the magnetized water saturation curve and water memory meter.展开更多
Enhancing oil recovery from clayey reservoirs is a significant challenge in petroleum industry due to complex interactions between fluids and rock surfaces,particularly clay swelling.This study presents the first empi...Enhancing oil recovery from clayey reservoirs is a significant challenge in petroleum industry due to complex interactions between fluids and rock surfaces,particularly clay swelling.This study presents the first empirical analysis of magnetic fields'impact on fluid flow in clayey porous media.Our core findings indicate that magnetic treatment of water increases oil recovery by an average of 15–30%in clayey media,with limited effectiveness in pure quartz media.Detailed experiments unraveled that improved recovery factor by magnetic treatment stem from both mitigated swelling and altered magnetic properties at clay surface;introducing 30%clay to porous medium decreased the recovery by 32%compared to pure quartz sand.Heating the clay to around 1000°C to reduce its swelling property improved the recovery by only 16%,suggesting magnetic treatment is not solely attributed to clay swelling mitigation.Treating ferromagnetic films at clay surface with HCl to produce non-magnetic FeCl_(3) resulted in a high recovery factor,similar to the clay-free medium.Moreover,it was determined that a magnetic field intensity of 43760–51740 A/m is optimal for fluid displacement in clayey media.Notably,the intensity of 47760 A/m increased recovery to 84.5%in a 30%clay medium,compared to 49.7%without treatment.Interestingly,it was observed that the maximum flow rate was associated with zero potential difference across the medium,providing a faster method to determine the optimum magnetic field intensity.Lastly,the concept of‘Magnetic memory’was investigated,referring to the persistence of magnetic field's influence after its removal.Our findings indicated that pressure build-up time stability lasted 10 days post-treatment,after which water behavior reverts,and clay swelling resumes.This insight into the temporal dynamics of magnetic field application provides a deeper understanding of its long-term impacts on fluid flow in clayey reservoirs.展开更多
To broaden the applications of magnetized water(MW) in medical science, the possible detoxicative effect of MW to anticancer drugs in vivo were studied. After being given ip with cyclophosphomide (CTX) 500 mg...To broaden the applications of magnetized water(MW) in medical science, the possible detoxicative effect of MW to anticancer drugs in vivo were studied. After being given ip with cyclophosphomide (CTX) 500 mg/kg, cisplatin (DDP) 40 mg/kg, harringtonine (HA) 20 mg/kg, mitomycin C (MMC) 8 mg/kg, lycobetaine (Lyc) 200 mg/kg, respectively, the mice were given MW ip 0.2 ml for 7 days. The average life span was calculated for each group. After being given subacutely lower doses of anticancer drugs ( CTX 100 mg/kg, HA 3 mg/kg ) ip 3 times, the mice were given MW ip 0.2 ml for 7 days and the blood white cells were counted as routine. It was shown that the mice in MW groups after ip anticancer drugs survived longer than those without MW. The effects of various anticancer drugs on life span were different. The white cell numbers of groups with MW were higher than that of the groups without MW. So it is possible that MW can remarkably extend the life span of mice and attenuate the leukopenia by mitigating the toxicity of anticancer drugs in vivo .展开更多
The corrosion characteristics of copper in magnetic action system were investigated by mass loss method,electrochemical test,scanning electron microscopy(SEM) and energy analysis. It is found that the corrosion proces...The corrosion characteristics of copper in magnetic action system were investigated by mass loss method,electrochemical test,scanning electron microscopy(SEM) and energy analysis. It is found that the corrosion process of copper is influenced by magnetic field. The flow corrosion rate of copper decreases at the initial segment,then drives to gentle stage at the final segment. From electrochemical test,the corrosion rate of copper in the magnetized sea water is minimal compared with that in 3.5% NaCl solution and sea water. Electrochemical impedance spectroscopy(EIS) plots of copper in 3.5% NaCl,sea water and magnetized sea water are similar. However,EIS plot of copper in magnetized sea water shifts rightwards due to the effect of magnetic field on sea water. The corrosion process of copper in magnetized sea water is pitting corrosion. The surfaces of samples are finer in magnetized sea water relative to those in 3.5% NaCl solution and sea water. The corrosion products of copper include large amount of Cu element,O element and Cl element. Cu2O and CuCl2 are the primary products. This suggests that electromagnetic treatment has remarkable effect on the corrosion of copper.展开更多
Capacity for agriculture production needs to be increased to meet the demands of the increasing human population. Within alternatives for an improvement in technology of agriculture in arid and sub arid countries’ ir...Capacity for agriculture production needs to be increased to meet the demands of the increasing human population. Within alternatives for an improvement in technology of agriculture in arid and sub arid countries’ irrigation with magnetized water (MH<sub>2</sub>O). This study was carried out to investigate the nutrients taken up by plants irrigated with (MH<sub>2</sub>O). During this study, we have grown Cucumis sativus in greenhouse for one month. The growth was carried on a sandy loamy soil type with two sets of pots 1) one set of pots without MH<sub>2</sub>O, as reference and 2) another set of pots was irrigated with MH<sub>2</sub>O. The results revealed that the plants’ leaves irrigated with MH<sub>2</sub>O were enriched in Zn, Cu and depleted in Ba, Ti and Sr relative to the plant grown in control conditions and unchanged in Fe, V, Ni;Mn and Cr. The roots of the same plants irrigated with MH<sub>2</sub>O were depleted in Fe, Mn, Ti, Ba, V, Ni, Cr, Zn and Sr. Translocation of elements from roots to leaves irrigated with MH<sub>2</sub>O seems more important than for plants irrigated with ordinary water. Based on the results of this study, irrigation with magnetized water may exhibit a positive effect on nutrition of plants. In addition to the effect of MH<sub>2</sub>O on growth, content of nutrients, revealed the effect on the quality of plants. These results show that irrigation with MH<sub>2</sub>O in arid countries with reduced water resources, may help to promote agriculture for an amelioration by increasing available elements.展开更多
Twelve of weaned Small-tail Han male lambs,with body weight of(7.99±1.04)kg,at 30 days of age,were divided into two groups to study the effect of drinking magnetized water(MW)on digestion and metabolism of lambs....Twelve of weaned Small-tail Han male lambs,with body weight of(7.99±1.04)kg,at 30 days of age,were divided into two groups to study the effect of drinking magnetized water(MW)on digestion and metabolism of lambs.The voluntary intake and ADG from 30 to 240 days of age were measured,twice of digestion and metabolism trial were carried out,and at the age of 240 days slaughter test was conducted.The results showed that drinking MW significantly increased voluntary feed intake(27.2%),ADG(27.4%)and apparent digestibility of DM(17.9%),OM(20.2%),CP(22.8%),and energy(12.7%),respectively.The nitrogen retention in two experimental trials significantly increased by 43.9%and 28.9%,respectively.Drinking MW significantly increased live body weight(24.5%),carcass weight(28.2%),carcass net meat weight(25.5%),carcass lean weight(32.5%)and carcass fat weight(31.3%),respectively.The fresh weights of liver,kidney,rumen,longissimus dorsi and leg muscle of lambs drinking MW increased significantly,but there was no significant difference in their contents of DM,OM and CP.It is concluded that drinking MW is beneficial for increasing voluntary feed intake,digestibility,and ADG,and improving slaughter performance of lambs.展开更多
Pretreatment of high content of Si- and Al-containing cyanide tailings by water leaching to remove some impurities, such as the major impurities minerals of Si and A1, as well as its effect on Fe extraction in the wat...Pretreatment of high content of Si- and Al-containing cyanide tailings by water leaching to remove some impurities, such as the major impurities minerals of Si and A1, as well as its effect on Fe extraction in the water leaching process was investigated. The effects of different parameters on iron recovery were studied, and the reaction parameters were proposed as follows: sodium carbonate content of 30%, water leaching at 60 ~C for 5 min, liquid/solid ratio of 15:1, and exciting current of 2 A. Under these optimal conditions, magnetic concentrate containing 59.11% total iron and a total iron recovery rate of 76.12% was obtained. In addition, the microstructure and phase transformation of the process of water leaching were studied by X-ray powder diffraction technique (XRD), Electronic image of backscattering (BEI), X-ray fluorescence (XRF), and energy dispersive spectrometry (EDS). The results indicate that the soluble compound impurities generated in the roasting process are washed out, and the dissoluble substances enter into nonmagnetic materials by water leaching, realizing the effective separation of impurities and Fe.展开更多
The low field nuclear magnetic resonance (NMR), as a nondestructive and noninvasive technique, was employed to investigate the water distribution and content in cement paste with different water-to-cement ratio (w/c r...The low field nuclear magnetic resonance (NMR), as a nondestructive and noninvasive technique, was employed to investigate the water distribution and content in cement paste with different water-to-cement ratio (w/c ratio) during early and later hydration stages. From the water distribution spectrum deduced from relaxation time distribution in paste, it is suggested that the water fills in the capillary pores at initial period, and then diffuses to the mesopores and gel pores in hydration products with the hydration proceeding. The decrease of peak area in water distribution spectrum reflects the transformation from physically bound water to chemically bound water. In addition, based on the connection between relaxation time and pore size, the relative content changes of water in various states and constrained in different types of pores were also measured. The results demonstrate that it is influenced by the formation of pore system and the original water-to-cement ratio in the paste. Consequently, the relative content of capillary water is dropped to less than 2% in the paste with low w/c ratio of 0.3 when being hydrated for 1 d, while the contents are still 16% and 36% in the pastes with w/c ratios of 0.4 and 0.5, respectively.展开更多
Electrochemical water splitting consists of two elementary reactions i.e.,hydrogen evolution reaction(HER)and oxygen evolution reaction(OER).Developing robust HER and OER technologies necessitates a molecular picture ...Electrochemical water splitting consists of two elementary reactions i.e.,hydrogen evolution reaction(HER)and oxygen evolution reaction(OER).Developing robust HER and OER technologies necessitates a molecular picture of reaction mechanism,yet the reactants for water splitting reactions are unfortunately not fully understood.Here we utilize magnetic field to understand proton transport in HER,and hydroxide ion transport in OER,to discuss the possible implications on understanding the reactants for HER and OER.Magnetic field is a known tool for changing the movement of charged species like ions,e.g.the magnetic‐field‐improved Cu^(2+)transportation near the electrode in Cu electrodeposition.However,applying a magnetic field does not affect the HER or OER rate across various pH,which challenges the traditional opinion that charged species(i.e.proton and hydroxide ion)act as the reactant.This anomalous response of HER and OER to magnetic field,and the fact that the transport of proton and hydroxide ion follow Grotthuss mechanism,collectively indicate water may act as the universal reactant for HER and OER across various pH.With the aid of magnetic field,this work serves as an understanding of water might be the reactant in HER and OER,and possibly in other electrocatalysis reactions involving protonation and deprotonation step.A model that simply focuses on the charged species but overlooking the complexity of the whole electrolyte phase where water is the dominant species,may not reasonably reflect the electrochemistry of HER and OER in aqueous electrolyte.展开更多
Increasing salinity of the groundwater is one of major challenges faced by agricultural sector in West Bank/Palestine. This study was carried out in the Lower Jordan Valley (LJV) under greenhouse field condition, wh...Increasing salinity of the groundwater is one of major challenges faced by agricultural sector in West Bank/Palestine. This study was carried out in the Lower Jordan Valley (LJV) under greenhouse field condition, where an area of 0.12 ha was irrigated with 3.5 dS/m magnetic treated water during the growing season 2012/2013. The results of this pilot project show that there are significant increases in the yield of red and yellow bell pepper of about 20% and 18% on fresh weight basis, respectively. Water use efficiency increased by 15% and an increase in shelf time of 7 d were also recorded. The chlorophyll content raised significantly in the leaves of treated plants compared to the controlled one by 2.5 mg/g. Bell pepper irrigated with magnetic water produces 37% more four champers than that of the controlled one. On the other hand, there were no clear significant effects on the height of the plant, number of fruits, distance between nods, size of fruits, number and thickness of walls and sugar contents. Applying visible/near infrared (VIS/N|R) spectroscopy test shows that it is possible to distinguish between treated and controlled bell pepper fruits. Multivariate data analysis (MVDA) method was used to test the classification of chemical elements in the fruit and it was found that treated and controlled fruit samples are divided into two groups according to their water treatment. An increase in all nutrient concentrations was found in fruits irrigated with magnetic treated water compared with the controlled one. Further testing is needed especially by involving other variables such as decreasing the volume of irrigated water and fertilizers.展开更多
The unfrozen water content of rock during freezing and thawing has an important influence on its physical and mechanical properties.This study presented a model for calculating the unfrozen water content of rock durin...The unfrozen water content of rock during freezing and thawing has an important influence on its physical and mechanical properties.This study presented a model for calculating the unfrozen water content of rock during freezing and thawing process,considering the influence of unfrozen water film and rock pore structure,which can reflect the hysteresis and super-cooling effects.The pore size distribution cu rves of red sandsto ne and its unfrozen water conte nt under different temperatures during the freezing and thawing process were measured using nuclear magnetic resonance(NMR) to validate the proposed model.Comparison between the experimental and calculated results indicated that the theoretical model accu rately reflected the water content change law of red sandstone during the freezing and thawing process.Furthermore,the influences of Hamaker constant and surface relaxation parameter on the model results were examined.The results showed that the appropriate magnitude order of Hamaker constant for the red sandstone was 10J to 10J;and when the relaxation parameter of the rock surface was within 25-30 μm/ms,the calculated unfrozen water content using the proposed model was consistent with the experimental value.展开更多
The effectiveness of a magnetic ion exchange resin (MIEX) for the treatment of Hongze Lake water in China was evaluated, The kinetics of natural organic matter (NOM) removal at various MIEX doses and contact time,...The effectiveness of a magnetic ion exchange resin (MIEX) for the treatment of Hongze Lake water in China was evaluated, The kinetics of natural organic matter (NOM) removal at various MIEX doses and contact time, multiple-loading experiments, impacts of MIEX prior to coagulation on coagulant demands and the effectiveness of combination of MIEX, pre-chlorination and coagulation were investigated. Kinetic experimental results show that more than 80% UV254 and 67% dissolved organic carbon (DOC) from raw water can be removed by the use of MIEX alone. 94% sulfate, 69% nitrate and 98% bromide removals are obtained after the first use of MIEX in multiple-loading experiments. It is suggested that MIEX can be loaded up to 1 250 bed volume (BV, volume ratio of tested water to resin) or more without saturation when regarding organics removal as a target. MIEX can remove organics to a greater extend than coagulation and lower the coagulant demand when combining with coagulation. Chlorination experimental results show that MIEX can remove 57% chlorine demand and 77% trihalomethane formation potential (THMFP) for raw water. Pre-chlorination followed by MIEX and coagulation can give additional organic and THMFP removals. The results suggest that MIEX provides a new method to solve thc problem algae reproduction.展开更多
A new kind of phenyl-functionalized magnetic fibrous mesoporous silica(Fe3 O4@Si O2@KCC-1-phenyl) was prepared by copolymerization as an efficient adsorbent for the magnetic extraction of phthalate esters from environ...A new kind of phenyl-functionalized magnetic fibrous mesoporous silica(Fe3 O4@Si O2@KCC-1-phenyl) was prepared by copolymerization as an efficient adsorbent for the magnetic extraction of phthalate esters from environmental water samples. The obtained Fe3 O4@Si O2@KCC-1-phenyl showed monodisperse fibrous spherical morphology, fairly strong magnetic response(29 emu/g), and an abundant π-electron system, which allowed rapid isolation of the Fe3 O4@Si O2@KCC-1-phenyl from solutions upon applying an appropriate magnetic field. Several variables that affect the extraction efficiency of the analytes,including the type of the elution solvent, amount of adsorbent, extraction time and reusability, were investigated and optimized. Under optimum conditions, the Fe3 O4@Si O2@KCC-1-phenyl was used for the extraction of four phthalate esters from environmental water samples followed by high-performance liquid chromatographic analysis. Validation experiments indicated that the developed method presented good linearity(0.1-20 ng/m L), low limit of detection(7.5-29 μg/L, S/N =3). The proposed method was applied to the determination of phthalate esters in different real water samples, with relative recoveries of 93%-103.4%and relative standard deviation of 0.8%-8.3%.展开更多
Spring water but not double-distilled water was exposed, in darkness, to a temporally patterned weak magnetic field that has been shown to affect planarian behavior and slow the rate of cancer cell proliferation. Expo...Spring water but not double-distilled water was exposed, in darkness, to a temporally patterned weak magnetic field that has been shown to affect planarian behavior and slow the rate of cancer cell proliferation. Exposure to the magnetic field caused a reliable shift in the peak (longer) wave-length of ~10 nm for fluorescence emissions and a ~20% increase (~100 counts) in fluorescence intensity. Spectral analyses verified a shift of 5 and 10 nm, equivalent to ~1.5 × 10-20 J “periodicity” across the measured wavelengths, which could reflect a change in the an intrinsic energy as predicted by Del Giudice and Preparata and could correspond to two lengths of O-H bonds. Wrapping the water sample containers during exposure with copper foil, aluminum foil, or plastic altered these fluorescent profiles. The most conspicuous effect was the elimination of a ~280 nm peak in the UV-VIS emission spectra only for samples wrapped with copper foil but not aluminum or plastic. These results suggest that weak magnetic fields produce alterations in the water-ionic complexes sufficient to be reliably measured by spectrophotometry. Because the effect was most pronounced when the spring water was exposed in darkness and was not disturbed the role of thixotropic phenomena and Del Giudice entrapment of magnetic fields within coherent domains of Pollack virtual exclusion zones (EZ) may have set the conditions for subsequent release of the energy as photons.展开更多
A hydroponic experiment was carried out to investigate the effects of magnetic water irrigation on the growth, nutritionalstatus and antioxidant enzyme activity of cotton seedlings. Four levels of magnetic-treated wat...A hydroponic experiment was carried out to investigate the effects of magnetic water irrigation on the growth, nutritionalstatus and antioxidant enzyme activity of cotton seedlings. Four levels of magnetic-treated water irrigation (0, 100, 300 and 500 mT)and three levels of salt stress (0, 100 and 200 mM NaCI) were applied. Salt stress adversely affected the dry weight, nutrient uptakeand antioxidant enzyme activities of cotton seedlings. Magnetic-treated water irrigation significantly increased cotton seedling dryweight. Cotton seedling dry weight increased by 14%, 22% and 29% under the treatments of 100, 300 and 500 mT magnetic waterirrigation, respectively, compared with the control, at a salt stress level of 100 mM NaC1. Moreover, magnetic water irrigationimproved N uptake, but did not significantly affect P and K uptake. Magnetic water irrigation significantly increased the activity ofsuperoxide dismutase (SOD), peroxidase (POD) and the proline content compared to the control (0 roT). Irrigation with magneticwater could be a promising technique in agriculture, especially under salt stress conditions. A suitable magnetic intensity of 300 mTis recommended.展开更多
Magnetic ion exchange(MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon(DOC). Two types of mechanisms, i.e., ion exchange...Magnetic ion exchange(MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon(DOC). Two types of mechanisms, i.e., ion exchange,reversible and irreversible adsorption, may occur during pollutants removal by MIEX. This work examined the removal mechanism of 17α-Ethinylestradiol(EE2) by MIEX. As one of typical estrogen micro-pollutants,EE2 existed as neutral molecule in natural water, and its charge density was close to zero [(0.00000219 ±0.00000015) meq·(μg EE2)^(-1)] based on the potentiometric titration method. However, the removal of EE2 by MIEX was much higher than that of other micro-pollutants previously reported. Multi-cycle adsorptionregeneration experiments and ion exchange stoichiometry analysis were conducted to elucidate the removal mechanism of EE2 by MIEX resin. The results suggested that the main removal mechanism of EE2 by MIEX was ion exchange instead of reversible micro-pore adsorption. The experimental analysis based on Donnan theory indicated that the internal micro-environment of resin beads was alkaline, in the alkaline environment EE2 would be ionized into negatively charged groups. As a result, ion exchange reaction occurred inside the pore of MIEX resin, and the removal process of EE2 by MIEX was dominated by the ion exchange reaction.展开更多
The role of metakaolin in the properties of Portland cement hydrated with ground water and sea water was described by magnetic susceptibility study. Cement pastes containing 0wt%, 10wt%, 20wt% and 30wt% replacement of...The role of metakaolin in the properties of Portland cement hydrated with ground water and sea water was described by magnetic susceptibility study. Cement pastes containing 0wt%, 10wt%, 20wt% and 30wt% replacement of metakaolin and in a water/cement (W/C) ratio of 0.4 were prepared. The susceptibility at different hydration periods was determined by Faraday Curie balance and it was related to the changes in setting time and compressive strength of admixtured cement. Compared with sea water-treated cement paste, the magnetic susceptibility of ground water-treated cement paste is higher in value. The observed result shows that, irrespective of water, the magnetic susceptibility increases with increasing metakaolin percentage replacement level in cement.展开更多
Sedimentation dynamics of magnetite (γ-Fe3O4) nanopowders (10 - 20 nm) in water in the presence of a gradient magnetic field was studied by optical and Nuclear Magnetic Resonance (NMR) relaxometry methods. The magnet...Sedimentation dynamics of magnetite (γ-Fe3O4) nanopowders (10 - 20 nm) in water in the presence of a gradient magnetic field was studied by optical and Nuclear Magnetic Resonance (NMR) relaxometry methods. The magnetic field B ≤ 0.3 T, dB/dz ≤ 0.13 T/cm was produced by the system of permanent strip magnets. The initial sedimentation rate of the nanoparticles in water and under magnetic fields is higher for less concentrated suspensions (c0 = 0.1 g/l) than for more concentrated ones (c0 = 1 g/l). This might be connected with the formation of gel structures due to strong magnetic attraction between ferromagnetic nanoparticles. In the gravitation field, the suspensions of the particles (10 - 20 nm) remain stable for over 20 hours. The sedimentation process can be greatly accelerated by the action of a vertical gradient magnetic field, reducing the sedimentation time down to several minutes. In a gradient magnetic field enhanced by a steel grid, sedimentation of the nanopowder (c0 = 0.1 g/l) for 180 minutes resulted in reduction of the iron concentration in water down to 0.4 mg/l. In flowing water regime, the residual iron concentration in water 0.3 mg/l is reached after 80 minutes.展开更多
基金Supported by China Spark Program for Science and Technology(2011GA740072)Shandong Provincial Soft Scientific Research Project(2015RKC35001)Shandong Provincial Agricultural High-quality Seed Engineering(2016LZGC019)~~
文摘With Welsh Onion seeds employed as materials, effects of magnetized water on seed Germination were studied. The results showed the treatment of magnetized water soaking for 4 h promoted water absorption rate and amylase ac- tivities of seeds significantly, which accelerated the transformation process of en- dosperm starch to soluble sugar, resulting in emergence of 36 hours in advance under low temperature condition. Germination rate and germination potential of magnetized water soaking were higher than the contrast by 6.7% and 10.0%, which helped cultivate vigorous seedling.
基金National Natural Science Foundation of China,Grant/Award Numbers:21871065,22071038Heilongjiang Touyan Team,Grant/Award Number:HITTY‐20190033Interdisciplinary Research Foundation of HIT,Grant/Award Number:IR2021205。
文摘Herein,we report bifunctional molybdenum-doped nickel sulfide on nickel foam(Mo-NiS_(x)/NF)for magnetic field-enhanced overall water splitting under alkaline conditions.Proper doping of Mo can lead to optimization of the electronic structure of NiS_(x),which accelerates the dissociation of H2O and the adsorption of OH−in the hydrogen evolution reaction(HER)and the oxygen evolution reaction(OER)processes,respectively.In addition,the magnetically active Mo-NiS_(x)/NF can further enhance the HER and OER activity under an applied magnetic field due to the magnetoresistance effect and the ferromagnetic(FM)exchange-field penetration effect.As a result,Mo-NiS_(x)/NF requires low overpotentials of 307 mV at 50mA cm^(−2)(for OER)and 136 mV at 10mA cm^(−2)(for HER)under a magnetic field of 10000 G.Furthermore,the electrolytic cell constructed by the bifunctional Mo-NiS_(x)/NFs as both the cathode and the anode shows a low cell voltage of 1.594 V at 10 mA cm^(−2)with optimal stability over 60 h under the magnetic field.Simultaneous enhancement of the HER and OER processes by an external magnetic field through rational design of electrocatalysts might be promising for overall water splitting applications.
文摘This paper presents an experimental study to investigate the effect of using the magnetic water conditioner on the properties of water. The water flows through a closed loop, while the pH, TDS, and hardness represent its properties. For magnetic water conditioner with flux density of 170 mT, results showed that pH increased by 15.65% for 820 minutes of non-stop circulation. The increase in pH is divided to 93.5% for the first 360 minutes, and 6.5% for the last 460 minutes. TDS and Hardness of water are not affected by the magnetic water conditioner. Water remembers and keeps the impact of passing through the magnetic field for several hours, and pH decreased by 0.642 in24 hours. While the results lead to introduce and create the magnetized water saturation curve and water memory meter.
文摘Enhancing oil recovery from clayey reservoirs is a significant challenge in petroleum industry due to complex interactions between fluids and rock surfaces,particularly clay swelling.This study presents the first empirical analysis of magnetic fields'impact on fluid flow in clayey porous media.Our core findings indicate that magnetic treatment of water increases oil recovery by an average of 15–30%in clayey media,with limited effectiveness in pure quartz media.Detailed experiments unraveled that improved recovery factor by magnetic treatment stem from both mitigated swelling and altered magnetic properties at clay surface;introducing 30%clay to porous medium decreased the recovery by 32%compared to pure quartz sand.Heating the clay to around 1000°C to reduce its swelling property improved the recovery by only 16%,suggesting magnetic treatment is not solely attributed to clay swelling mitigation.Treating ferromagnetic films at clay surface with HCl to produce non-magnetic FeCl_(3) resulted in a high recovery factor,similar to the clay-free medium.Moreover,it was determined that a magnetic field intensity of 43760–51740 A/m is optimal for fluid displacement in clayey media.Notably,the intensity of 47760 A/m increased recovery to 84.5%in a 30%clay medium,compared to 49.7%without treatment.Interestingly,it was observed that the maximum flow rate was associated with zero potential difference across the medium,providing a faster method to determine the optimum magnetic field intensity.Lastly,the concept of‘Magnetic memory’was investigated,referring to the persistence of magnetic field's influence after its removal.Our findings indicated that pressure build-up time stability lasted 10 days post-treatment,after which water behavior reverts,and clay swelling resumes.This insight into the temporal dynamics of magnetic field application provides a deeper understanding of its long-term impacts on fluid flow in clayey reservoirs.
文摘To broaden the applications of magnetized water(MW) in medical science, the possible detoxicative effect of MW to anticancer drugs in vivo were studied. After being given ip with cyclophosphomide (CTX) 500 mg/kg, cisplatin (DDP) 40 mg/kg, harringtonine (HA) 20 mg/kg, mitomycin C (MMC) 8 mg/kg, lycobetaine (Lyc) 200 mg/kg, respectively, the mice were given MW ip 0.2 ml for 7 days. The average life span was calculated for each group. After being given subacutely lower doses of anticancer drugs ( CTX 100 mg/kg, HA 3 mg/kg ) ip 3 times, the mice were given MW ip 0.2 ml for 7 days and the blood white cells were counted as routine. It was shown that the mice in MW groups after ip anticancer drugs survived longer than those without MW. The effects of various anticancer drugs on life span were different. The white cell numbers of groups with MW were higher than that of the groups without MW. So it is possible that MW can remarkably extend the life span of mice and attenuate the leukopenia by mitigating the toxicity of anticancer drugs in vivo .
文摘The corrosion characteristics of copper in magnetic action system were investigated by mass loss method,electrochemical test,scanning electron microscopy(SEM) and energy analysis. It is found that the corrosion process of copper is influenced by magnetic field. The flow corrosion rate of copper decreases at the initial segment,then drives to gentle stage at the final segment. From electrochemical test,the corrosion rate of copper in the magnetized sea water is minimal compared with that in 3.5% NaCl solution and sea water. Electrochemical impedance spectroscopy(EIS) plots of copper in 3.5% NaCl,sea water and magnetized sea water are similar. However,EIS plot of copper in magnetized sea water shifts rightwards due to the effect of magnetic field on sea water. The corrosion process of copper in magnetized sea water is pitting corrosion. The surfaces of samples are finer in magnetized sea water relative to those in 3.5% NaCl solution and sea water. The corrosion products of copper include large amount of Cu element,O element and Cl element. Cu2O and CuCl2 are the primary products. This suggests that electromagnetic treatment has remarkable effect on the corrosion of copper.
文摘Capacity for agriculture production needs to be increased to meet the demands of the increasing human population. Within alternatives for an improvement in technology of agriculture in arid and sub arid countries’ irrigation with magnetized water (MH<sub>2</sub>O). This study was carried out to investigate the nutrients taken up by plants irrigated with (MH<sub>2</sub>O). During this study, we have grown Cucumis sativus in greenhouse for one month. The growth was carried on a sandy loamy soil type with two sets of pots 1) one set of pots without MH<sub>2</sub>O, as reference and 2) another set of pots was irrigated with MH<sub>2</sub>O. The results revealed that the plants’ leaves irrigated with MH<sub>2</sub>O were enriched in Zn, Cu and depleted in Ba, Ti and Sr relative to the plant grown in control conditions and unchanged in Fe, V, Ni;Mn and Cr. The roots of the same plants irrigated with MH<sub>2</sub>O were depleted in Fe, Mn, Ti, Ba, V, Ni, Cr, Zn and Sr. Translocation of elements from roots to leaves irrigated with MH<sub>2</sub>O seems more important than for plants irrigated with ordinary water. Based on the results of this study, irrigation with magnetized water may exhibit a positive effect on nutrition of plants. In addition to the effect of MH<sub>2</sub>O on growth, content of nutrients, revealed the effect on the quality of plants. These results show that irrigation with MH<sub>2</sub>O in arid countries with reduced water resources, may help to promote agriculture for an amelioration by increasing available elements.
基金Supported by Educational Department of Xinjiang,China (XND 20131803)
文摘Twelve of weaned Small-tail Han male lambs,with body weight of(7.99±1.04)kg,at 30 days of age,were divided into two groups to study the effect of drinking magnetized water(MW)on digestion and metabolism of lambs.The voluntary intake and ADG from 30 to 240 days of age were measured,twice of digestion and metabolism trial were carried out,and at the age of 240 days slaughter test was conducted.The results showed that drinking MW significantly increased voluntary feed intake(27.2%),ADG(27.4%)and apparent digestibility of DM(17.9%),OM(20.2%),CP(22.8%),and energy(12.7%),respectively.The nitrogen retention in two experimental trials significantly increased by 43.9%and 28.9%,respectively.Drinking MW significantly increased live body weight(24.5%),carcass weight(28.2%),carcass net meat weight(25.5%),carcass lean weight(32.5%)and carcass fat weight(31.3%),respectively.The fresh weights of liver,kidney,rumen,longissimus dorsi and leg muscle of lambs drinking MW increased significantly,but there was no significant difference in their contents of DM,OM and CP.It is concluded that drinking MW is beneficial for increasing voluntary feed intake,digestibility,and ADG,and improving slaughter performance of lambs.
基金Projects(ZR2010EL006,Y2007F60) supported by the National Science Foundation of Shandong Province of ChinaProject(J12LA04) supported by High Education Science Technology Program of Shandong Province,China
文摘Pretreatment of high content of Si- and Al-containing cyanide tailings by water leaching to remove some impurities, such as the major impurities minerals of Si and A1, as well as its effect on Fe extraction in the water leaching process was investigated. The effects of different parameters on iron recovery were studied, and the reaction parameters were proposed as follows: sodium carbonate content of 30%, water leaching at 60 ~C for 5 min, liquid/solid ratio of 15:1, and exciting current of 2 A. Under these optimal conditions, magnetic concentrate containing 59.11% total iron and a total iron recovery rate of 76.12% was obtained. In addition, the microstructure and phase transformation of the process of water leaching were studied by X-ray powder diffraction technique (XRD), Electronic image of backscattering (BEI), X-ray fluorescence (XRF), and energy dispersive spectrometry (EDS). The results indicate that the soluble compound impurities generated in the roasting process are washed out, and the dissoluble substances enter into nonmagnetic materials by water leaching, realizing the effective separation of impurities and Fe.
基金Project(2009CB623105) supported by the National Basic Research Program of ChinaProject(51108341) supported by the National Natural Science Foundation of ChinaProjects(20110490703, 2012T50437) supported by China Postdoctoral Science Foundation
文摘The low field nuclear magnetic resonance (NMR), as a nondestructive and noninvasive technique, was employed to investigate the water distribution and content in cement paste with different water-to-cement ratio (w/c ratio) during early and later hydration stages. From the water distribution spectrum deduced from relaxation time distribution in paste, it is suggested that the water fills in the capillary pores at initial period, and then diffuses to the mesopores and gel pores in hydration products with the hydration proceeding. The decrease of peak area in water distribution spectrum reflects the transformation from physically bound water to chemically bound water. In addition, based on the connection between relaxation time and pore size, the relative content changes of water in various states and constrained in different types of pores were also measured. The results demonstrate that it is influenced by the formation of pore system and the original water-to-cement ratio in the paste. Consequently, the relative content of capillary water is dropped to less than 2% in the paste with low w/c ratio of 0.3 when being hydrated for 1 d, while the contents are still 16% and 36% in the pastes with w/c ratios of 0.4 and 0.5, respectively.
基金supported by the Singapore MOE Tier 2 MOE2018-T2-2-027the Singapore National Research Foundation under its Campus for Research Excellence and Technological Enterprise (CREATE) Programme
文摘Electrochemical water splitting consists of two elementary reactions i.e.,hydrogen evolution reaction(HER)and oxygen evolution reaction(OER).Developing robust HER and OER technologies necessitates a molecular picture of reaction mechanism,yet the reactants for water splitting reactions are unfortunately not fully understood.Here we utilize magnetic field to understand proton transport in HER,and hydroxide ion transport in OER,to discuss the possible implications on understanding the reactants for HER and OER.Magnetic field is a known tool for changing the movement of charged species like ions,e.g.the magnetic‐field‐improved Cu^(2+)transportation near the electrode in Cu electrodeposition.However,applying a magnetic field does not affect the HER or OER rate across various pH,which challenges the traditional opinion that charged species(i.e.proton and hydroxide ion)act as the reactant.This anomalous response of HER and OER to magnetic field,and the fact that the transport of proton and hydroxide ion follow Grotthuss mechanism,collectively indicate water may act as the universal reactant for HER and OER across various pH.With the aid of magnetic field,this work serves as an understanding of water might be the reactant in HER and OER,and possibly in other electrocatalysis reactions involving protonation and deprotonation step.A model that simply focuses on the charged species but overlooking the complexity of the whole electrolyte phase where water is the dominant species,may not reasonably reflect the electrochemistry of HER and OER in aqueous electrolyte.
文摘Increasing salinity of the groundwater is one of major challenges faced by agricultural sector in West Bank/Palestine. This study was carried out in the Lower Jordan Valley (LJV) under greenhouse field condition, where an area of 0.12 ha was irrigated with 3.5 dS/m magnetic treated water during the growing season 2012/2013. The results of this pilot project show that there are significant increases in the yield of red and yellow bell pepper of about 20% and 18% on fresh weight basis, respectively. Water use efficiency increased by 15% and an increase in shelf time of 7 d were also recorded. The chlorophyll content raised significantly in the leaves of treated plants compared to the controlled one by 2.5 mg/g. Bell pepper irrigated with magnetic water produces 37% more four champers than that of the controlled one. On the other hand, there were no clear significant effects on the height of the plant, number of fruits, distance between nods, size of fruits, number and thickness of walls and sugar contents. Applying visible/near infrared (VIS/N|R) spectroscopy test shows that it is possible to distinguish between treated and controlled bell pepper fruits. Multivariate data analysis (MVDA) method was used to test the classification of chemical elements in the fruit and it was found that treated and controlled fruit samples are divided into two groups according to their water treatment. An increase in all nutrient concentrations was found in fruits irrigated with magnetic treated water compared with the controlled one. Further testing is needed especially by involving other variables such as decreasing the volume of irrigated water and fertilizers.
基金the support of the Second Tibetan Plateau Scientific Expedition and Research Program (STEP)of China (Grant No.2019QZKK0904)the National Outstanding Youth Science Fund Project of National Natural Science Foundation of China (Grant No.51922104)+1 种基金Youth Innovation Promotion Association CASOpen Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences (Grant No.Z018014)。
文摘The unfrozen water content of rock during freezing and thawing has an important influence on its physical and mechanical properties.This study presented a model for calculating the unfrozen water content of rock during freezing and thawing process,considering the influence of unfrozen water film and rock pore structure,which can reflect the hysteresis and super-cooling effects.The pore size distribution cu rves of red sandsto ne and its unfrozen water conte nt under different temperatures during the freezing and thawing process were measured using nuclear magnetic resonance(NMR) to validate the proposed model.Comparison between the experimental and calculated results indicated that the theoretical model accu rately reflected the water content change law of red sandstone during the freezing and thawing process.Furthermore,the influences of Hamaker constant and surface relaxation parameter on the model results were examined.The results showed that the appropriate magnitude order of Hamaker constant for the red sandstone was 10J to 10J;and when the relaxation parameter of the rock surface was within 25-30 μm/ms,the calculated unfrozen water content using the proposed model was consistent with the experimental value.
基金Project(2008ZX07421-002) supported by the Key National Science and Technology Project of ChinaProject(50638020) supported by the National Natural Science Foundation of China
文摘The effectiveness of a magnetic ion exchange resin (MIEX) for the treatment of Hongze Lake water in China was evaluated, The kinetics of natural organic matter (NOM) removal at various MIEX doses and contact time, multiple-loading experiments, impacts of MIEX prior to coagulation on coagulant demands and the effectiveness of combination of MIEX, pre-chlorination and coagulation were investigated. Kinetic experimental results show that more than 80% UV254 and 67% dissolved organic carbon (DOC) from raw water can be removed by the use of MIEX alone. 94% sulfate, 69% nitrate and 98% bromide removals are obtained after the first use of MIEX in multiple-loading experiments. It is suggested that MIEX can be loaded up to 1 250 bed volume (BV, volume ratio of tested water to resin) or more without saturation when regarding organics removal as a target. MIEX can remove organics to a greater extend than coagulation and lower the coagulant demand when combining with coagulation. Chlorination experimental results show that MIEX can remove 57% chlorine demand and 77% trihalomethane formation potential (THMFP) for raw water. Pre-chlorination followed by MIEX and coagulation can give additional organic and THMFP removals. The results suggest that MIEX provides a new method to solve thc problem algae reproduction.
基金supported by the Commonwealth Scientific Foundation for Industry of Chinese Inspection and Quarantine (No.201210071) of the Ministry of National Science and Technology of ChinaChongqing Key Laboratory of Scientific Utilization of Tobacco Resources
文摘A new kind of phenyl-functionalized magnetic fibrous mesoporous silica(Fe3 O4@Si O2@KCC-1-phenyl) was prepared by copolymerization as an efficient adsorbent for the magnetic extraction of phthalate esters from environmental water samples. The obtained Fe3 O4@Si O2@KCC-1-phenyl showed monodisperse fibrous spherical morphology, fairly strong magnetic response(29 emu/g), and an abundant π-electron system, which allowed rapid isolation of the Fe3 O4@Si O2@KCC-1-phenyl from solutions upon applying an appropriate magnetic field. Several variables that affect the extraction efficiency of the analytes,including the type of the elution solvent, amount of adsorbent, extraction time and reusability, were investigated and optimized. Under optimum conditions, the Fe3 O4@Si O2@KCC-1-phenyl was used for the extraction of four phthalate esters from environmental water samples followed by high-performance liquid chromatographic analysis. Validation experiments indicated that the developed method presented good linearity(0.1-20 ng/m L), low limit of detection(7.5-29 μg/L, S/N =3). The proposed method was applied to the determination of phthalate esters in different real water samples, with relative recoveries of 93%-103.4%and relative standard deviation of 0.8%-8.3%.
文摘Spring water but not double-distilled water was exposed, in darkness, to a temporally patterned weak magnetic field that has been shown to affect planarian behavior and slow the rate of cancer cell proliferation. Exposure to the magnetic field caused a reliable shift in the peak (longer) wave-length of ~10 nm for fluorescence emissions and a ~20% increase (~100 counts) in fluorescence intensity. Spectral analyses verified a shift of 5 and 10 nm, equivalent to ~1.5 × 10-20 J “periodicity” across the measured wavelengths, which could reflect a change in the an intrinsic energy as predicted by Del Giudice and Preparata and could correspond to two lengths of O-H bonds. Wrapping the water sample containers during exposure with copper foil, aluminum foil, or plastic altered these fluorescent profiles. The most conspicuous effect was the elimination of a ~280 nm peak in the UV-VIS emission spectra only for samples wrapped with copper foil but not aluminum or plastic. These results suggest that weak magnetic fields produce alterations in the water-ionic complexes sufficient to be reliably measured by spectrophotometry. Because the effect was most pronounced when the spring water was exposed in darkness and was not disturbed the role of thixotropic phenomena and Del Giudice entrapment of magnetic fields within coherent domains of Pollack virtual exclusion zones (EZ) may have set the conditions for subsequent release of the energy as photons.
文摘A hydroponic experiment was carried out to investigate the effects of magnetic water irrigation on the growth, nutritionalstatus and antioxidant enzyme activity of cotton seedlings. Four levels of magnetic-treated water irrigation (0, 100, 300 and 500 mT)and three levels of salt stress (0, 100 and 200 mM NaCI) were applied. Salt stress adversely affected the dry weight, nutrient uptakeand antioxidant enzyme activities of cotton seedlings. Magnetic-treated water irrigation significantly increased cotton seedling dryweight. Cotton seedling dry weight increased by 14%, 22% and 29% under the treatments of 100, 300 and 500 mT magnetic waterirrigation, respectively, compared with the control, at a salt stress level of 100 mM NaC1. Moreover, magnetic water irrigationimproved N uptake, but did not significantly affect P and K uptake. Magnetic water irrigation significantly increased the activity ofsuperoxide dismutase (SOD), peroxidase (POD) and the proline content compared to the control (0 roT). Irrigation with magneticwater could be a promising technique in agriculture, especially under salt stress conditions. A suitable magnetic intensity of 300 mTis recommended.
基金Supported by the National Natural Science Foundation of China(51678408,51478314,51638011)the National Key Research and Development Program of China(2016YFC0400506)+1 种基金the Natural Science Foundation of Tianjin(14JCQNJC09000)the Research Fund of Tianjin Key Laboratory of Aquatic Science and Technology(TJKLASTZD-2016-06)
文摘Magnetic ion exchange(MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon(DOC). Two types of mechanisms, i.e., ion exchange,reversible and irreversible adsorption, may occur during pollutants removal by MIEX. This work examined the removal mechanism of 17α-Ethinylestradiol(EE2) by MIEX. As one of typical estrogen micro-pollutants,EE2 existed as neutral molecule in natural water, and its charge density was close to zero [(0.00000219 ±0.00000015) meq·(μg EE2)^(-1)] based on the potentiometric titration method. However, the removal of EE2 by MIEX was much higher than that of other micro-pollutants previously reported. Multi-cycle adsorptionregeneration experiments and ion exchange stoichiometry analysis were conducted to elucidate the removal mechanism of EE2 by MIEX resin. The results suggested that the main removal mechanism of EE2 by MIEX was ion exchange instead of reversible micro-pore adsorption. The experimental analysis based on Donnan theory indicated that the internal micro-environment of resin beads was alkaline, in the alkaline environment EE2 would be ionized into negatively charged groups. As a result, ion exchange reaction occurred inside the pore of MIEX resin, and the removal process of EE2 by MIEX was dominated by the ion exchange reaction.
文摘The role of metakaolin in the properties of Portland cement hydrated with ground water and sea water was described by magnetic susceptibility study. Cement pastes containing 0wt%, 10wt%, 20wt% and 30wt% replacement of metakaolin and in a water/cement (W/C) ratio of 0.4 were prepared. The susceptibility at different hydration periods was determined by Faraday Curie balance and it was related to the changes in setting time and compressive strength of admixtured cement. Compared with sea water-treated cement paste, the magnetic susceptibility of ground water-treated cement paste is higher in value. The observed result shows that, irrespective of water, the magnetic susceptibility increases with increasing metakaolin percentage replacement level in cement.
文摘Sedimentation dynamics of magnetite (γ-Fe3O4) nanopowders (10 - 20 nm) in water in the presence of a gradient magnetic field was studied by optical and Nuclear Magnetic Resonance (NMR) relaxometry methods. The magnetic field B ≤ 0.3 T, dB/dz ≤ 0.13 T/cm was produced by the system of permanent strip magnets. The initial sedimentation rate of the nanoparticles in water and under magnetic fields is higher for less concentrated suspensions (c0 = 0.1 g/l) than for more concentrated ones (c0 = 1 g/l). This might be connected with the formation of gel structures due to strong magnetic attraction between ferromagnetic nanoparticles. In the gravitation field, the suspensions of the particles (10 - 20 nm) remain stable for over 20 hours. The sedimentation process can be greatly accelerated by the action of a vertical gradient magnetic field, reducing the sedimentation time down to several minutes. In a gradient magnetic field enhanced by a steel grid, sedimentation of the nanopowder (c0 = 0.1 g/l) for 180 minutes resulted in reduction of the iron concentration in water down to 0.4 mg/l. In flowing water regime, the residual iron concentration in water 0.3 mg/l is reached after 80 minutes.