Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-di...Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-dimensional fine interpolation,analysis of spatial distribution patterns,and extraction of quantitative mineral-seeking markers.The Yechangping molybdenum(Mo)deposit is a significant and extensive porphyry-skarn deposit in the East Qinling-Dabie Mo polymetallic metallogenic belt at the southern margin of the North China Block.Abundant borehole data on oreforming elements underpin deep geochemical predictions.The methodology includes the following steps:(1)Threedimensional geological modeling of the deposit was established.(2)Correlation,cluster,and factor analyses post delineation of mineralization stages and determination of mineral generation sequence to identify(Cu,Pb,Zn,Ag)and(Mo,W,mfe)assemblages.(3)A three-dimensional geochemical block model was constructed for Mo,W,mfe,Cu,Zn,Pb,and Ag using the ordinary kriging method,and the variational function was developed.(4)Spatial distribution and enrichment characteristics analysis of ore-forming elements are performed to extract geological information,employing the variogram and w(Cu+Pb+Zn+Ag)/w(Mo+W)as predictive indicators.(5)Identifying the western,northwestern,and southwestern areas of the mine with limited mineralization potential,contrasted by the northeastern and southeastern areas favorable for mineral exploration.展开更多
This paper presents the results of our recent studies on the upper mantle composition in the Qinling Belt and East China . It discusses the methods of estimating the upper mantle composition, its selected elements and...This paper presents the results of our recent studies on the upper mantle composition in the Qinling Belt and East China . It discusses the methods of estimating the upper mantle composition, its selected elements and its constitution characteristics .The results indicate that ore-forming elements on ore types and their distribution in this area are strongly controlled by the upper mantle heterogeneity .展开更多
Coal gangue is the most used filling material during reclamation of areas suffering subsidence from min- ing. Main trace element levels (F, As, Hg, and Pb) in shallow groundwater in the reclamation area may be affecte...Coal gangue is the most used filling material during reclamation of areas suffering subsidence from min- ing. Main trace element levels (F, As, Hg, and Pb) in shallow groundwater in the reclamation area may be affected by leaching from the gangue. This can has an impact on the application of the water for agricul- tural irrigation or use as drinking water. Therefore, it is of great significance to understand the effect coal gangue has on the shallow groundwater of a reclaimed area. We studied the effect of coal gangue on fluo- rine, arsenic, mercury, and lead levels in the shallow groundwater of a reclamation area by testing the water and the coal gangue. One well near the reclamation area was used as a control well and element levels in water from this well and from the soil next to the well were also measured. The results show that the levels of these elements are increasing in the reclamation area over time. The increase in fluorine, arsenic, mercury, and lead in monitor wells varies from 7.42% to 8.26%, from 7.13% to 7.90%, from 4.85% to 6.48%, and from 4.69% to 6.42%, respectively. Fluorine and arsenic levels are lower in monitor wells than in the control water. The other elements are found in greater concentration than in the control. The Nemerow index also indicates that the shallow groundwater in the reclamation area I is moderately affected by the back-filling coal gangue, while the shallow groundwater in the reclamation area II and III are slightly affected by the back-filling coal gangue. This shallow groundwater could be used for agri- cultural irrigation or for drinking.展开更多
It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of gr...It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of grains has its own domain and dislocation structure. There are mono- and polydomains with and without dislocations. The grains of the main phase of monoand polydomains without dislocations and polydomains with dislocations were formed by diffusion in the solid phase. In these conditions NiAl3 phase is located on the grain boundary of the main phase. The Ni2Al3 phase is located at the triple joints of the main phase.展开更多
Electrocatalytic N_(2) reduction under ambient-condition is considered to be the most appealing strategy to the conventional Haber-Bosch process for synthetic ammonia to alleviate greenhouse emissions and reduce envir...Electrocatalytic N_(2) reduction under ambient-condition is considered to be the most appealing strategy to the conventional Haber-Bosch process for synthetic ammonia to alleviate greenhouse emissions and reduce environmental pollution, mainly powered by renewable energy. Recent years, rapid advances have been gained in this attractive research field, and numerous electrocatalysts have been exploited. However, its conversion efficiency is still far behind the requirement of industrial applications owing to the breakage of the N≡N triple bond, which is an energetically challenging kinetically complex multistep reaction and the strong competing reaction of hydrogen evolution reaction. Recently, main group metal-based catalysts have been demonstrated promising application prospect for ammonia production, significantly boosting their further application in this field. However, a comprehensive review of main group metal-based catalysts towards electrochemical ammonia production applications is still lacking. In this review, the fundamentals of N_(2) reduction, such as the reaction pathways, the reaction potential and the challenges of N_(2) reduction have been comprehensively discussed. And then, the role, mechanism, and effect of each main group element-based catalysts used for N_(2) reduction (Li, K, Al, Ga, Sn, Sb, Bi, and their compounds) are systematically summarized. Finally, several state-of-the-art strategies to promote their NRR catalytic performance, as well as the existing problems and prospects are put forward. This review is expected to guide the design and establishment of more efficient electrocatalytic N_(2) reduction systems based on main group metal elements in the future.展开更多
Through a detailed study of the abundances and spatial-temporal distribution patterns of Te,Bi,As,Se,Cu,Pb,Zn,Au,and Ag in the rock types of different geological epochs in the Dashuigou independent tellurium deposit,a...Through a detailed study of the abundances and spatial-temporal distribution patterns of Te,Bi,As,Se,Cu,Pb,Zn,Au,and Ag in the rock types of different geological epochs in the Dashuigou independent tellurium deposit,and in combination with other research findings of previous researchers in this area,the authors conclude as follows:Abundances of the main ore-forming elements Te,Bi,As,Se,Au,and Ag are not high in the regional geological background,generally lower or close to their respective crustal Clark values,but almost all altered country rocks contain high levels of ore-forming elements.This indicates that the deposit’s ore-forming elements do not come from the country rocks.This also indicates that the geological thermal events that cause alteration and mineralization originate from depths and may be related to mantle plumes.Considering the distribution pattern of these ore-forming elements in the ore bodies’hanging wall and footwall,the metallogenic mechanism may be as follows:Mineralization is not achieved through lateral secretion in the horizontal or near horizontal direction,but rather through the upward movement and emplacement of deep ore-forming elements driven by geological processes such as mantle plumes.In addition,the migration of deep ore-forming elements is not achieved through dispersed infiltration between overlying rock particles,but through non widespread concentrated penetrating channels.This type of channel is likely to be the expansion structures where faults from different directions intersect,or where linear faults intersect with circular structures.展开更多
Drinking water supply for the Main Ethiopian Rift (MER) area principally relies on groundwater wells and springs and is characterized by fluoride contamination. New analyses reveal that the F^- geochemical anomaly is ...Drinking water supply for the Main Ethiopian Rift (MER) area principally relies on groundwater wells and springs and is characterized by fluoride contamination. New analyses reveal that the F^- geochemical anomaly is associated with other potentially toxic elements such as As,B,Mo,U,Al,Fe and Mn. Particularly,35%of the 23 investigated groundwater wells and 70%of the 14 hot springs(and展开更多
In this study,vehicle exhaust particles were collected three locations (the middle,entrance and outside) of the Dapu Road tunnel in downtown Shanghai,and the particle samples were characterized using SEM,XAFS,ICP-MS a...In this study,vehicle exhaust particles were collected three locations (the middle,entrance and outside) of the Dapu Road tunnel in downtown Shanghai,and the particle samples were characterized using SEM,XAFS,ICP-MS and M?ssbauer spectrometry,and the oxidative damage was assessed by plasmid DNA.Most iron-containing particles are found from vehicle exhaust,and iron oxide is the major species in all samples.Its concentration in the particles inside the tunnel is higher than that the outside particles.The iron particles inside the tunnel have higher proportion of water-soluble fraction in hydrous iron sulfate form or smaller size.ZnCl2 is the main soluble fraction in zinc-containing particles,while higher percentage of insoluble fraction existed in the particles outside of tunnel.Major species of lead-containing particles are PbSO4,Pb3(PO4)2 and PbCO3.In addition,the soluble fraction of other transition metallic elements as Ti and V is higher in the particles inside the tunnel than that outside the tunnel.The plasmid DNA assay results indicate that the particles from vehicle exhaust have a stronger oxidative damage and inflammation than that from outside of the tunnel.展开更多
With the aid of commercial finite element analysis software package ANSYS,investigations are made on the contributions of main components to stiffness of the main module for parallel machine tools,and it is found that...With the aid of commercial finite element analysis software package ANSYS,investigations are made on the contributions of main components to stiffness of the main module for parallel machine tools,and it is found that the frame is the main contributor.Then,influences of constraints,strut length and working ways of the main module have also been investigated.It can be concluded that when one of the main planes of the frame without linear drive unit is constrained,the largest whole stiffness can be acquired.And,the stiffness is much better when the main module is used in a vertical machine tool instead of a horizontal one.Finally,the principle of stiffness variation is summarized when the mobile platform reaches various positions within its working space and when various loads are applied.These achievements have provided critical instructions for the design of the main module for parallel machine tools.展开更多
All the indium-rich deposits with indium contents in ores more than 100×10^-6 seems to be of cassiterite-sulfide deposits or Sn-bearing Pb-Zn deposits, e.g., in the Dachang Sn deposit in Guangxi, the Dulong Sn-Zn...All the indium-rich deposits with indium contents in ores more than 100×10^-6 seems to be of cassiterite-sulfide deposits or Sn-bearing Pb-Zn deposits, e.g., in the Dachang Sn deposit in Guangxi, the Dulong Sn-Zn deposit in Yunnan, and the Meng'entaolegai Ag-Pb-Zn deposit in Inner Mongolia, the indium contents in ores range from 98×10^-6 to 236×10^-6 and show a good positive correlation with contents of zinc and tin, and their correlation coefficients are 0.8781 and 0.7430, respectively. The indium contents from such Sn-poor deposits as the Fozichong Pb-Zn deposit in Guangxi and the Huanren Pb-Zn deposit in Liaoning are generally lower than 10×10^-6, i.e., whether tin is present or not in a deposit implies the enrichment extent of indium in ores. Whether the In enrichment itself in the ore -forming fluids or the ore-forming conditions has actually caused the enrichment/depletion of indium in the deposits? After studying the fluid inclusions in quartz crystallized at the main stage of mineralization of several In-rich and In-poor deposits in China, this paper analyzed the contents and studied the variation trend of In, Sn, Pb and Zn in the ore-forming fluids. The results show that the contents of lead and zinc in the ore-forming fluids of In-rich and -poor deposits are at the same level, and the lead contents range from 22×10^-6 to 81×10^-6 and zinc from 164×10^-6 to 309×10^-6, while the contents of indium and tin in the ore-forming fluids of In-rich deposits are far higher than those of Inpoor deposits, with a difference of 1-2 orders of magnitude. Indium and tin contents in ore-forming fluid of In-rich deposits are 1.9×10^-6-4.1×10^-6 and 7×10^-6-55×10^-6, and there is a very good positive correlation between the two elements, with a correlation coefficient of 0.9552. Indium and tin contents in ore-forming fluid of In-poor deposits are 0.03×10^-6-0.09×10^-6 and 0.4×10^-6-2.0×10^-6, respectively, and there is no apparent correlation between them. This indicates, on one hand, that In-rich oreforming fluids are the material basis for the formation of In-rich deposits, and, on the other hand, tin probably played a very important role in the transport and enrichment of indium.展开更多
This contribution describes development and application of a user-friendly finite element program,UT3PC, to address three important problems in underground coal mine design:(1) safety of main entries,(2) barrier pilla...This contribution describes development and application of a user-friendly finite element program,UT3PC, to address three important problems in underground coal mine design:(1) safety of main entries,(2) barrier pillar size needed for entry protection, and(3) safety of bleeder entries during the advance of an adjacent longwall panel.While the finite element method is by far the most popular engineering design tool of the digital age, widespread use by the mining community has been impeded by the relatively high cost of and the need for lengthy specialized training in numerical methods.Implementation of UT3PC overcomes these impediments in three easy steps.First, a material properties file is prepared for the considered site.Next, mesh generation is automatic through an interactive process.A third and last step is simply execution of the program.Examples using data from several western coal mines illustrate the ease of using the application for analysis of main entries, barrier pillars, and bleeder entry safety.展开更多
Many temporary and permanent reservoirs of water occur on or near coal-waste dumps in the Lower-and Upper Silesian Coal Basins(Poland).Little or nothing is known of the degree to which their water chemistry might refl...Many temporary and permanent reservoirs of water occur on or near coal-waste dumps in the Lower-and Upper Silesian Coal Basins(Poland).Little or nothing is known of the degree to which their water chemistry might reflect(i)reservoir type,i.e.,whether permanent or temporary,(ii)level of coal-waste thermal activity,i.e.,whether inactive or self-heating or burnt-out or(iii)region,i.e.,whether the dumps are in Upper-or Lower Silesia.To provide some answers,concentrations of selected ions(NH_(4)^(+),HCO_(3)^(-),F^(-),Cl^(-),Br^(-),NO_(2)^(-),NO_(3)^(-),PO_(4)^(3-),SO_(4)^(2-))were determined by ion chromatography and of nineteen elements(Al,B,Ba,Ca,Cd,Cr,Cu,Fe,K,Li,Mg,Mn,Na,P,Pb,S,Si,Sr,Zn)by inductively coupled plasma mass spectrometry(ICP-MS).The data allow a number of the following observations.When permanent reservoirs are considered,there is a clear relationship between concentrations of ions and major and trace elements and dump thermal activity.The highest concentrations occur where the thermal activity is high as inorganic components are transformed into more water-soluble forms.As dump thermal activity shows a regional pattern,it follows also that elemental and ion concentrations in the dump waters show significant regional differences.In temporary reservoirs,concentrations of ions and major and trace elements are much lower and any correlations between components less significant than in the permanent reservoirs;these reservoirs exist for too short a time for any balance between coal waste-and water components to be established.展开更多
In this paper, progress in strain study of blocks and faults by GPS data are discussed, and the concept that active structures between blocks are the main body of crustal strain is clarified. By energy transfer princi...In this paper, progress in strain study of blocks and faults by GPS data are discussed, and the concept that active structures between blocks are the main body of crustal strain is clarified. By energy transfer principle of elastic mechanics, the relation between strain around faults and tectonic force on fault surfaces is set up and main body element model of crustal strain is constructed. Finally, the relation between mechanical evolution of model and seismogenic process of Kunlun earthquake (Ms=8.1) is discussed by continuous GPS data of datum stations. The result suggests that the relatively relaxed change under background of strong compressing and shearing may help to trigger moderate-strong earthquakes.展开更多
The Gaoshan gold-silver deposit, located between the Yuyao-Lishui Fault and Jiangshan- Shaoxing fault in Longquan Area, occurs in the Suichang-Longquan gold-silver polymetallic metallogenic belt. This study conducted ...The Gaoshan gold-silver deposit, located between the Yuyao-Lishui Fault and Jiangshan- Shaoxing fault in Longquan Area, occurs in the Suichang-Longquan gold-silver polymetallic metallogenic belt. This study conducted an investigation for ore-forming fluids using microthermometry, D-O isotope and trace element. The results show that two types of fluid inclusions involved into the formation of the deposit are pure liquid phase and gas-liquid phase aqueous inclusions. The homogenization temperature and salinity of major mineralization phase ranges from 156~C to 236~C (average 200~C) and 0.35% to 8.68% (NaCleqv) (average 3.68%), respectively, indicating that the ore-forming fluid is characteristic of low temperature and low salinity. The ore- forming pressure ranges between in 118.02 to 232.13"105 pa, and it is estabmiated that the ore- forming depth ranges from 0.39 to 0.77 km, indicating it is a hypabyssal deposit in genesis. The low rare earth elements content in pyrites, widely developed fluorite in late ore-forming stage and lack of chlorargyrite (AgCI), indicates that the ore-forming fluid is rich in F rather than CI. The ratios of Y/ Ho, Zr/Hf and Nb/Ta of between different samples have little difference, indicating that the later hydrothermal activities had no effects on the former hydrothermal fluid. The chondrite-normalized REE patterns of pyrites from country rocks and ore veins are basically identical, with the characteristics of light REE enrichment and negative Eu anomalies, implying that the ore-forming fluid was oxidative and derived partly from the country rocks. The JD and jlSo of fluid inclusions in quartz formed during the main metallogenic stage range from -105%o to -69 %0 and -6.01%o to -3.81%o, respectively. The D-O isotopic diagram shows that the metallogenic fluid is characterized by the mixing of formation water and meteoric water, without involvement of magmatic water. The geological and geochemical characteristics of the Gaoshan gold-silver deposit are similar to those of continental volcanic hydrothermal deposit, and could be assigned to the continental volcanic hydrothermal gold-silver deposit type.展开更多
In this paper we firstly select main factors relating to urbanization level of Xiantao District in Hubei Province by main element, then, make model of urbanization level by analysis of multiple liner regression, and l...In this paper we firstly select main factors relating to urbanization level of Xiantao District in Hubei Province by main element, then, make model of urbanization level by analysis of multiple liner regression, and lastly predict its urbanization level展开更多
The use of finite element method leads to replacing the initial domain by an approaching domain. Under some appropriate assumptions, we prove that there exists a W1,+∞-diffeomorphism from the original domain to the a...The use of finite element method leads to replacing the initial domain by an approaching domain. Under some appropriate assumptions, we prove that there exists a W1,+∞-diffeomorphism from the original domain to the approaching domain.展开更多
基金supported by the Key Research Project of China Geological Survey(Grant No.DD20230564)the Research Project of Natural Resources Department of Gansu Province(Grant No.202219)。
文摘Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-dimensional fine interpolation,analysis of spatial distribution patterns,and extraction of quantitative mineral-seeking markers.The Yechangping molybdenum(Mo)deposit is a significant and extensive porphyry-skarn deposit in the East Qinling-Dabie Mo polymetallic metallogenic belt at the southern margin of the North China Block.Abundant borehole data on oreforming elements underpin deep geochemical predictions.The methodology includes the following steps:(1)Threedimensional geological modeling of the deposit was established.(2)Correlation,cluster,and factor analyses post delineation of mineralization stages and determination of mineral generation sequence to identify(Cu,Pb,Zn,Ag)and(Mo,W,mfe)assemblages.(3)A three-dimensional geochemical block model was constructed for Mo,W,mfe,Cu,Zn,Pb,and Ag using the ordinary kriging method,and the variational function was developed.(4)Spatial distribution and enrichment characteristics analysis of ore-forming elements are performed to extract geological information,employing the variogram and w(Cu+Pb+Zn+Ag)/w(Mo+W)as predictive indicators.(5)Identifying the western,northwestern,and southwestern areas of the mine with limited mineralization potential,contrasted by the northeastern and southeastern areas favorable for mineral exploration.
文摘This paper presents the results of our recent studies on the upper mantle composition in the Qinling Belt and East China . It discusses the methods of estimating the upper mantle composition, its selected elements and its constitution characteristics .The results indicate that ore-forming elements on ore types and their distribution in this area are strongly controlled by the upper mantle heterogeneity .
基金The project was funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘Coal gangue is the most used filling material during reclamation of areas suffering subsidence from min- ing. Main trace element levels (F, As, Hg, and Pb) in shallow groundwater in the reclamation area may be affected by leaching from the gangue. This can has an impact on the application of the water for agricul- tural irrigation or use as drinking water. Therefore, it is of great significance to understand the effect coal gangue has on the shallow groundwater of a reclaimed area. We studied the effect of coal gangue on fluo- rine, arsenic, mercury, and lead levels in the shallow groundwater of a reclamation area by testing the water and the coal gangue. One well near the reclamation area was used as a control well and element levels in water from this well and from the soil next to the well were also measured. The results show that the levels of these elements are increasing in the reclamation area over time. The increase in fluorine, arsenic, mercury, and lead in monitor wells varies from 7.42% to 8.26%, from 7.13% to 7.90%, from 4.85% to 6.48%, and from 4.69% to 6.42%, respectively. Fluorine and arsenic levels are lower in monitor wells than in the control water. The other elements are found in greater concentration than in the control. The Nemerow index also indicates that the shallow groundwater in the reclamation area I is moderately affected by the back-filling coal gangue, while the shallow groundwater in the reclamation area II and III are slightly affected by the back-filling coal gangue. This shallow groundwater could be used for agri- cultural irrigation or for drinking.
文摘It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of grains has its own domain and dislocation structure. There are mono- and polydomains with and without dislocations. The grains of the main phase of monoand polydomains without dislocations and polydomains with dislocations were formed by diffusion in the solid phase. In these conditions NiAl3 phase is located on the grain boundary of the main phase. The Ni2Al3 phase is located at the triple joints of the main phase.
基金This work was supported by the National Natural Science Foundation of China(No.52071171)the Liaoning Revitalization Talents Program-Pan Deng Scholars(XLYC1802005)+4 种基金the Liaoning Bai-QianWan Talents Program(LNBQW2018B0048)the National Science Fund of Liaoning Province for Excellent Young Scholars(2019-YQ-04)the Key Project of Scientific Research of the Education Department of Liaoning Province(LZD201902)the Department of Education of Liaoning Province(LQN201903 and LQN202008)the Foundation for Young Scholars of Liaoning University(LDQN2019007).
文摘Electrocatalytic N_(2) reduction under ambient-condition is considered to be the most appealing strategy to the conventional Haber-Bosch process for synthetic ammonia to alleviate greenhouse emissions and reduce environmental pollution, mainly powered by renewable energy. Recent years, rapid advances have been gained in this attractive research field, and numerous electrocatalysts have been exploited. However, its conversion efficiency is still far behind the requirement of industrial applications owing to the breakage of the N≡N triple bond, which is an energetically challenging kinetically complex multistep reaction and the strong competing reaction of hydrogen evolution reaction. Recently, main group metal-based catalysts have been demonstrated promising application prospect for ammonia production, significantly boosting their further application in this field. However, a comprehensive review of main group metal-based catalysts towards electrochemical ammonia production applications is still lacking. In this review, the fundamentals of N_(2) reduction, such as the reaction pathways, the reaction potential and the challenges of N_(2) reduction have been comprehensively discussed. And then, the role, mechanism, and effect of each main group element-based catalysts used for N_(2) reduction (Li, K, Al, Ga, Sn, Sb, Bi, and their compounds) are systematically summarized. Finally, several state-of-the-art strategies to promote their NRR catalytic performance, as well as the existing problems and prospects are put forward. This review is expected to guide the design and establishment of more efficient electrocatalytic N_(2) reduction systems based on main group metal elements in the future.
文摘Through a detailed study of the abundances and spatial-temporal distribution patterns of Te,Bi,As,Se,Cu,Pb,Zn,Au,and Ag in the rock types of different geological epochs in the Dashuigou independent tellurium deposit,and in combination with other research findings of previous researchers in this area,the authors conclude as follows:Abundances of the main ore-forming elements Te,Bi,As,Se,Au,and Ag are not high in the regional geological background,generally lower or close to their respective crustal Clark values,but almost all altered country rocks contain high levels of ore-forming elements.This indicates that the deposit’s ore-forming elements do not come from the country rocks.This also indicates that the geological thermal events that cause alteration and mineralization originate from depths and may be related to mantle plumes.Considering the distribution pattern of these ore-forming elements in the ore bodies’hanging wall and footwall,the metallogenic mechanism may be as follows:Mineralization is not achieved through lateral secretion in the horizontal or near horizontal direction,but rather through the upward movement and emplacement of deep ore-forming elements driven by geological processes such as mantle plumes.In addition,the migration of deep ore-forming elements is not achieved through dispersed infiltration between overlying rock particles,but through non widespread concentrated penetrating channels.This type of channel is likely to be the expansion structures where faults from different directions intersect,or where linear faults intersect with circular structures.
文摘Drinking water supply for the Main Ethiopian Rift (MER) area principally relies on groundwater wells and springs and is characterized by fluoride contamination. New analyses reveal that the F^- geochemical anomaly is associated with other potentially toxic elements such as As,B,Mo,U,Al,Fe and Mn. Particularly,35%of the 23 investigated groundwater wells and 70%of the 14 hot springs(and
基金supported by Knowledge Innovation Project of Chinese Academy of Sciences (KJCX3.SYW.N3,key program)the National Natural Science Foundation of China (10490182,key program and 10675159)
文摘In this study,vehicle exhaust particles were collected three locations (the middle,entrance and outside) of the Dapu Road tunnel in downtown Shanghai,and the particle samples were characterized using SEM,XAFS,ICP-MS and M?ssbauer spectrometry,and the oxidative damage was assessed by plasmid DNA.Most iron-containing particles are found from vehicle exhaust,and iron oxide is the major species in all samples.Its concentration in the particles inside the tunnel is higher than that the outside particles.The iron particles inside the tunnel have higher proportion of water-soluble fraction in hydrous iron sulfate form or smaller size.ZnCl2 is the main soluble fraction in zinc-containing particles,while higher percentage of insoluble fraction existed in the particles outside of tunnel.Major species of lead-containing particles are PbSO4,Pb3(PO4)2 and PbCO3.In addition,the soluble fraction of other transition metallic elements as Ti and V is higher in the particles inside the tunnel than that outside the tunnel.The plasmid DNA assay results indicate that the particles from vehicle exhaust have a stronger oxidative damage and inflammation than that from outside of the tunnel.
文摘With the aid of commercial finite element analysis software package ANSYS,investigations are made on the contributions of main components to stiffness of the main module for parallel machine tools,and it is found that the frame is the main contributor.Then,influences of constraints,strut length and working ways of the main module have also been investigated.It can be concluded that when one of the main planes of the frame without linear drive unit is constrained,the largest whole stiffness can be acquired.And,the stiffness is much better when the main module is used in a vertical machine tool instead of a horizontal one.Finally,the principle of stiffness variation is summarized when the mobile platform reaches various positions within its working space and when various loads are applied.These achievements have provided critical instructions for the design of the main module for parallel machine tools.
基金the Key 0rientation Research Project of the Chinese Academy of Sciences (KZCX2-YW- 111);the National Natural Science Foundation of China (Grant Nos. 40172037 and 40072036) for its financial support.
文摘All the indium-rich deposits with indium contents in ores more than 100×10^-6 seems to be of cassiterite-sulfide deposits or Sn-bearing Pb-Zn deposits, e.g., in the Dachang Sn deposit in Guangxi, the Dulong Sn-Zn deposit in Yunnan, and the Meng'entaolegai Ag-Pb-Zn deposit in Inner Mongolia, the indium contents in ores range from 98×10^-6 to 236×10^-6 and show a good positive correlation with contents of zinc and tin, and their correlation coefficients are 0.8781 and 0.7430, respectively. The indium contents from such Sn-poor deposits as the Fozichong Pb-Zn deposit in Guangxi and the Huanren Pb-Zn deposit in Liaoning are generally lower than 10×10^-6, i.e., whether tin is present or not in a deposit implies the enrichment extent of indium in ores. Whether the In enrichment itself in the ore -forming fluids or the ore-forming conditions has actually caused the enrichment/depletion of indium in the deposits? After studying the fluid inclusions in quartz crystallized at the main stage of mineralization of several In-rich and In-poor deposits in China, this paper analyzed the contents and studied the variation trend of In, Sn, Pb and Zn in the ore-forming fluids. The results show that the contents of lead and zinc in the ore-forming fluids of In-rich and -poor deposits are at the same level, and the lead contents range from 22×10^-6 to 81×10^-6 and zinc from 164×10^-6 to 309×10^-6, while the contents of indium and tin in the ore-forming fluids of In-rich deposits are far higher than those of Inpoor deposits, with a difference of 1-2 orders of magnitude. Indium and tin contents in ore-forming fluid of In-rich deposits are 1.9×10^-6-4.1×10^-6 and 7×10^-6-55×10^-6, and there is a very good positive correlation between the two elements, with a correlation coefficient of 0.9552. Indium and tin contents in ore-forming fluid of In-poor deposits are 0.03×10^-6-0.09×10^-6 and 0.4×10^-6-2.0×10^-6, respectively, and there is no apparent correlation between them. This indicates, on one hand, that In-rich oreforming fluids are the material basis for the formation of In-rich deposits, and, on the other hand, tin probably played a very important role in the transport and enrichment of indium.
文摘This contribution describes development and application of a user-friendly finite element program,UT3PC, to address three important problems in underground coal mine design:(1) safety of main entries,(2) barrier pillar size needed for entry protection, and(3) safety of bleeder entries during the advance of an adjacent longwall panel.While the finite element method is by far the most popular engineering design tool of the digital age, widespread use by the mining community has been impeded by the relatively high cost of and the need for lengthy specialized training in numerical methods.Implementation of UT3PC overcomes these impediments in three easy steps.First, a material properties file is prepared for the considered site.Next, mesh generation is automatic through an interactive process.A third and last step is simply execution of the program.Examples using data from several western coal mines illustrate the ease of using the application for analysis of main entries, barrier pillars, and bleeder entry safety.
基金the National Science Center of Poland(grants NCN No 2011/03/B/ST10/06331 and No 2017/27/B/ST 10/00680)enabled this project.Dr.Padhraig Kennan(University College,Dublin,Ireland)helped with language corrections.
文摘Many temporary and permanent reservoirs of water occur on or near coal-waste dumps in the Lower-and Upper Silesian Coal Basins(Poland).Little or nothing is known of the degree to which their water chemistry might reflect(i)reservoir type,i.e.,whether permanent or temporary,(ii)level of coal-waste thermal activity,i.e.,whether inactive or self-heating or burnt-out or(iii)region,i.e.,whether the dumps are in Upper-or Lower Silesia.To provide some answers,concentrations of selected ions(NH_(4)^(+),HCO_(3)^(-),F^(-),Cl^(-),Br^(-),NO_(2)^(-),NO_(3)^(-),PO_(4)^(3-),SO_(4)^(2-))were determined by ion chromatography and of nineteen elements(Al,B,Ba,Ca,Cd,Cr,Cu,Fe,K,Li,Mg,Mn,Na,P,Pb,S,Si,Sr,Zn)by inductively coupled plasma mass spectrometry(ICP-MS).The data allow a number of the following observations.When permanent reservoirs are considered,there is a clear relationship between concentrations of ions and major and trace elements and dump thermal activity.The highest concentrations occur where the thermal activity is high as inorganic components are transformed into more water-soluble forms.As dump thermal activity shows a regional pattern,it follows also that elemental and ion concentrations in the dump waters show significant regional differences.In temporary reservoirs,concentrations of ions and major and trace elements are much lower and any correlations between components less significant than in the permanent reservoirs;these reservoirs exist for too short a time for any balance between coal waste-and water components to be established.
基金National Natural Science Foundation of China (40274023) and National Program for Key Science & Technology Projects (2004BA601B01-02-01).
文摘In this paper, progress in strain study of blocks and faults by GPS data are discussed, and the concept that active structures between blocks are the main body of crustal strain is clarified. By energy transfer principle of elastic mechanics, the relation between strain around faults and tectonic force on fault surfaces is set up and main body element model of crustal strain is constructed. Finally, the relation between mechanical evolution of model and seismogenic process of Kunlun earthquake (Ms=8.1) is discussed by continuous GPS data of datum stations. The result suggests that the relatively relaxed change under background of strong compressing and shearing may help to trigger moderate-strong earthquakes.
基金funded by “Preliminary Study On the Metallogenic Conditions and Prospecting Direction of Gold-Silver Deposits,Suichang-Longquan Area,Zhejiang(No.:YK1401)”“Summary and Research Project of the Mineral Geology of China by Mineral Type(Group)(No.:12120114039601)”+1 种基金“Research Project of the Metallogenic Regularity of the National Important Mineral Areas(No.:1212011121037)”“Comprehensive Research Project of China’s Mineral Geology and Regional Metallogenic Regularity(China’s Mineral Geology)(No.:1212011220369)”
文摘The Gaoshan gold-silver deposit, located between the Yuyao-Lishui Fault and Jiangshan- Shaoxing fault in Longquan Area, occurs in the Suichang-Longquan gold-silver polymetallic metallogenic belt. This study conducted an investigation for ore-forming fluids using microthermometry, D-O isotope and trace element. The results show that two types of fluid inclusions involved into the formation of the deposit are pure liquid phase and gas-liquid phase aqueous inclusions. The homogenization temperature and salinity of major mineralization phase ranges from 156~C to 236~C (average 200~C) and 0.35% to 8.68% (NaCleqv) (average 3.68%), respectively, indicating that the ore-forming fluid is characteristic of low temperature and low salinity. The ore- forming pressure ranges between in 118.02 to 232.13"105 pa, and it is estabmiated that the ore- forming depth ranges from 0.39 to 0.77 km, indicating it is a hypabyssal deposit in genesis. The low rare earth elements content in pyrites, widely developed fluorite in late ore-forming stage and lack of chlorargyrite (AgCI), indicates that the ore-forming fluid is rich in F rather than CI. The ratios of Y/ Ho, Zr/Hf and Nb/Ta of between different samples have little difference, indicating that the later hydrothermal activities had no effects on the former hydrothermal fluid. The chondrite-normalized REE patterns of pyrites from country rocks and ore veins are basically identical, with the characteristics of light REE enrichment and negative Eu anomalies, implying that the ore-forming fluid was oxidative and derived partly from the country rocks. The JD and jlSo of fluid inclusions in quartz formed during the main metallogenic stage range from -105%o to -69 %0 and -6.01%o to -3.81%o, respectively. The D-O isotopic diagram shows that the metallogenic fluid is characterized by the mixing of formation water and meteoric water, without involvement of magmatic water. The geological and geochemical characteristics of the Gaoshan gold-silver deposit are similar to those of continental volcanic hydrothermal deposit, and could be assigned to the continental volcanic hydrothermal gold-silver deposit type.
文摘In this paper we firstly select main factors relating to urbanization level of Xiantao District in Hubei Province by main element, then, make model of urbanization level by analysis of multiple liner regression, and lastly predict its urbanization level
基金Partially supported by Professor Xu Yuesheng and his program "One hundred distinguished Young Scientists" Partially supported by "Programme Sino-Francais de Recherches Advancees(PRA).
文摘The use of finite element method leads to replacing the initial domain by an approaching domain. Under some appropriate assumptions, we prove that there exists a W1,+∞-diffeomorphism from the original domain to the approaching domain.